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Aligned Ion Conduction Pathway of Polyrotaxane‑Based Electrolyte with Dispersed Hydrophobic Chains for Solid‑State Lithium–Oxygen Batteries

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Nano-Micro Letters 2025年第2期17卷 169-186页

作者： Bitgaram Kim Myeong‑Chang Sung Gwang‑Hee lee Byoungjoon Hwang Sojung Seo Ji‑Hun Seo dong‑Wan Kim Department of Materials Science and Engineering Korea University145 Anam‑RoSeongbuk‑GuSeoul 02841Republic of Korea School of Civil Environmental and Architectural EngineeringKorea University145 Anam‑RoSeongbuk‑GuSeoul 02841Republic of Korea Materials Science and Chemical Engineering Center Institute for Advanced Engineering(IAE)Yongin 17180Republic of Korea

A critical challenge hindering the practical application of lithium–oxygen batteries(LOBs)is the inevitable problems associated with liquid electrolytes,such as evaporation and safety *** study addresses these problems by proposing a modified polyrotaxane(mPR)-based solid polymer electrolyte(SPE)design that simultaneously mitigates solvent-related problems and improves ***-SPE exhibits high ion conductivity(2.8×10^(−3)S cm^(−1)at 25℃)through aligned ion conduction pathways and provides electrode protection ability through hydrophobic chain *** this mPR-SPE into solid-state LOBs resulted in stable potentials over 300 *** situ Raman spectroscopy reveals the presence of an LiO_(2)intermediate alongside Li_(2)O_(2)during oxygen *** situ X-ray diffraction confirm the ability of the SPE to hinder the permeation of oxygen and moisture,as demonstrated by the air permeability *** present study suggests that maintaining a low residual solvent while achieving high ionic conductivity is crucial for restricting the sub-reactions of solid-state LOBs.

关键词： Solid polymer electrolyte Lithium-oxygen batteries Polyrotaxane ion conductivity Hydrophobic chain

Difference in extrusion temperature dependences of microstructure and mechanical properties between extruded AZ61 and AZ91 alloys

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Journal of Magnesium and Alloys 2023年第5期11卷 1683-1696页

作者： dong Hee lee Gyo Myeong lee Sung hyuk Park School of Materials Science and Engineering Kyungpook National UniversityDaegu 41566Republic of Korea

The effects of extrusion temperature on the microstructure and tensile properties of extruded AZ61 and AZ91 alloys are investigated by subjecting them to hot extrusion at 300 and 400℃.Although the average grain size of the extruded AZ61 alloy slightly increases from 9.5 to 12.6μm with increasing extrusion temperature,its resultant microstructural variation is *** contrast,the average grain size of the extruded AZ91 alloy significantly increases from 5.7 to 22.5μm with increasing extrusion temperature,and the type of Mg17Al12 precipitates formed in it changes from fine dynamic precipitates with a spherical shape to coarse static precipitates with a lamellar *** the extrusion temperature increases,the tensile yield strength of the extruded AZ61 alloy increases from 183 to 197 MPa while that of the extruded AZ91 alloy decreases from 232 to 224 *** tensile elongations of the extruded AZ61 and AZ91 alloys decrease with increasing extrusion temperature,but the degree of decrease is significant in the latter *** different extrusion temperature dependences of the tensile properties of the extruded AZ61 and AZ91 alloys are discussed in terms of their microstructural characteristics,strengthening mechanisms,and crack initiation sites.

关键词： Mg-Al-Zn alloys Extrusion temperature Precipitation Strengthening mechanism Tensile properties

New approaches to gastric cancer staging:Beyond endoscopic ultrasound,computed tomography and positron emission tomography

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World Journal of Gastroenterology 2014年第38期20卷 13783-13790页

作者： hyuk Yoon dong Ho lee Department of Internal Medicine Seoul National University Bundang Hospital Department of Internal Medicine and Liver Research Institute Seoul National University College of Medicine

Currently, there is no single gold standard modality for staging of gastric cancer and several methods have been used complementarily in the each clinical situation. To make up for the shortcomings of conventional modalities such as endoscopic ultrasound, computed tomography and 18F-fluoro-2-deoxyglucose positron emission tomography, numerous attempts with new approaches have been made for gastric cancer staging. For T staging, magnifying endoscopy with narrow-band was evaluated to differentiate mucosal cancer from submucosal cancer. Single/double contrast-enhanced ultrasound and diffusion-weighted magnetic resonance imaging were also tried to improve diagnostic accuracy of gastric cancer. For intraoperative staging with sentinel node mapping, indocyanine green infrared and fluorescence imaging was introduced. In addition, to detect micrometastasis, real-time reverse transcription-polymerase chain reaction system with multiple markers was studied. Staging laparoscopy using 5-aminolevulinic acid-mediated photodynamic diagnosis and percutaneous diagnostic peritoneal lavage were also evaluated. However, most studies reporting new staging methods is preliminary and further studies for validation in clinical practice are needed. In this mini-review, we discuss new progress in gastric cancer staging. Especially, we focus on new diagnostic approach to gastric cancer staging beyond the conventional modalities and briefly review the remarkable clinical results of the studies published over the past three years.

关键词： Gastric cancer Neoplasm staging Diagnostic accuracy New methods New approaches

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Journal of Central South University 2011年第5期18卷 1602-1608页

作者： lee Sang-hyuk PARK Wook-Je JUNG dong-yean Department of Electrical and Electronic Engineering Xi'an Jiaotong-Liverpool University Institute for Information and Electronics Research Inha University253 Yonghyun-dongNam-GuIncheon402-751Korea Daeho Technology Korea Co. LtdChangwonGyeongnam641-773Korea

The similarity computations for fuzzy membership function pairs were carried *** number related knowledge was introduced,and conventional similarity was compared with distance based similarity *** usefulness of the proposed similarity measure was *** results show that the proposed similarity measure could be applied to ordinary fuzzy membership functions,though it was not easy to *** conventional results on the calculation of similarity for fuzzy membership pair,fuzzy membership-crisp pair and crisp-crisp pair were carried *** proposed distance based similarity measure represented rational performance with the heuristic point of ***,troublesome in fuzzy number based similarity measure for abnormal universe of discourse case was ***,the similarity measure computation for various membership function pairs was discussed with other conventional results.

关键词： similarity measure fuzzy number distance similarity evaluation fuzzy membership function

Influence of potassium pyrophosphate in electrolyte on coated layer of AZ91 Mg alloy formed by plasma electrolytic oxidation

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中国有色金属学会会刊：英文版 2009年第4期19卷 824-828页

作者： Jin-Young CHO Duck-Young HWANG dong-H eon lee Bongyoung YOO dong-hyuk SHIN Department of Metallurgy and Materials Scienc e Hanyang University

The effect of potassium pyrophosphate in the electrolyte on plasma electrolytic oxidation(PEO) process for AZ91 Mg alloy was *** morphologies and chemical compositions of the coating layer on the AZ91 Mg alloy were evaluated and corrosion resistance was also estimated by potentiodynamic polarization *** coating layer on AZ91 Mg alloy coated from the Bath 2 containing 0.03 mol/L of potassium pyrophosphate for 360 s exhibited considerably dense structure and contained 11%-18%(mass fraction) of *** higher content of phosphorous of coating layer coated from Bath 2 could be detected at the bottom of oxide layer,which strongly implied that the phosphorous ion might be concentrated at the barrier *** potential of coating layer of AZ91 Mg alloy increased and corrosion current density decreased with increasing the concentration of potassium *** polarization resistance(Rp) of coating layer of AZ91 Mg alloy coated from Bath 2 was 4.65×107 Ω/cm2,which was higher than that(Rp=3.56×104 Ω/cm2) of the sample coated from electrolyte without potassium *** coating layer coated from Bath 2 containing 0.03 mol/L potassium pyrophosphate exhibited the best corrosion resistance.

关键词： AZ91镁合金合金涂层焦磷酸钾电解氧化等离子体电解质腐蚀电流密度耐腐蚀性

M-IDM: A Multi-Classication Based Intrusion Detection Model in Healthcare IoT

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Computers, Materials & Continua 2021年第5期67卷 1537-1553页

作者： Jae dong lee Hyo Soung Cha Shailendra Rathore Jong hyuk Park Healthcare AI Team National Cancer CenterGoyang-si10408Korea Department of Computer Science and Engineering Seoul National University of Science and Technology(SeoulTech)Seoul01811Korea

In recent years,the application of a smart city in the healthcare sector via loT systems has continued to grow exponentially and various advanced network intrusions have emerged since these loT devices are being *** studies focused on security threat detection and blocking technologies that rely on testbed data obtained from a single medical IoT device or simulation using a well-known dataset,such as the NSL-KDD ***,such approaches do not reect the features that exist in real medical scenarios,leading to failure in potential threat *** address this problem,we proposed a novel intrusion classication architecture known as a Multi-class Classication based Intrusion Detection Model(M-IDM),which typically relies on data collected by real devices and the use of convolutional neural networks(i.e.,it exhibits better performance compared with conventional machine learning algorithms,such as naïve Bayes,support vector machine(SVM)).Unlike existing studies,the proposed architecture employs the actual healthcare IoT environment of National Cancer Center in South Korea and actual network data from real medical devices,such as a patient’s monitors(i.e.,electrocardiogram and thermometers).The proposed architecture classies the data into multiple classes:Critical,informal,major,and minor,for intrusion ***,we experimentally evaluated and compared its performance with those of other conventional machine learning algorithms,including naïve Bayes,SVM,and logistic regression,using neural networks.

关键词： Smart city healthcare IoT neural network intrusion classication machine learning

Characterization of plasma electrolytic oxide formed on AZ91 Mg alloy in KMnO_4 electrolyte

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中国有色金属学会会刊：英文版 2009年第4期19卷 829-834页

作者： Duck-Young HWANG Ki-Ryong SHIN Bongyoung YOO dong-Heon lee Deok-Yong PARK dong-hyuk SHIN Department of Metallurgy and Materials Science Hanyang University Ansan 426-791 Korea Department of Applied Materials Engineering Hanbat National University Daejon 305-719 Korea 不详

The aim of this work is to investigate microstructure,corrosion resistance characteristics and nanohardness of the oxide layer on AZ91 Mg alloy by applying different voltage with KMnO4 contained *** are lots of closed pores that are filled with another oxide compound compared with the typical surface morphology with pore coated until 350 V of coating *** thickness of oxide layer increases with increasing coating *** oxide layer formed on AZ91 Mg alloy in electrolyte with potassium permanganate consists of MgO and *** potential of the oxide layer on AZ91 Mg alloy obtained at different plasma electrolytic oxidation(PEO) reaction stages increases with increasing coating *** corrosion resistance of AZ91 Mg alloy depends on the existence of the manganese oxide in the oxide *** inner barrier layer composed of the MgO and Mn2O3 may serve as diffusion barrier to enhance the corrosion resistance and may partially explain the excellent anti-corrosion performance in corrosion *** values increase with increasing coating *** increase in the nanohardness may be due to the effect of manganese oxide in the oxide layer on AZ91 Mg alloy coated from electrolyte containing KMnO4.

关键词： AZ91镁合金等离子体电解高锰酸钾氧化特性电解液氧化层厚度纳米硬度耐腐蚀性

Power interconnected system clustering with advanced fuzzy C-mean algorithm

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Journal of Central South University 2011年第1期18卷 190-195页

作者：王洪梅 KIM Jae-Hyung JUNG dong-Yean lee Sang-Min lee Sang-hyuk School of Mechatronics Changwon National University Daeho Tech Co.Ltd. Changwon 641-465Korea Department of Electronics Engineering Inha University

An advanced fuzzy C-mean （FCM） algorithm was proposed for the efficient regional clustering of multi-nodes interconnected systems. Due to various locational prices and regional coherencies for each node and point, modified similarity measure was considered to gather nodes having similar characteristics. The similarity measure was needed to contain locafi0nal prices as well as regional coherency. In order to consider the two properties simultaneously, distance measure of fuzzy C-mean algorithm had to be modified. Regional clustering algorithm for interconnected power systems was designed based on the modified fuzzy C-mean algorithm. The proposed algorithm produces proper classification for the interconnected power system and the results are demonstrated in the example of IEEE 39-bus interconnected electricity system.

关键词： fuzzy C-mean similarity measure distance measure interconnected system clustering

Variations in microstructure and bending formability of extruded Mg–Al–Zn–Ca–Y–MM alloy with precompression and subsequent annealing treatment conditions

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Journal of Magnesium and Alloys 2022年第9期10卷 2475-2490页

作者： Jong Un lee Sang-Hoon Kim dong Hee lee Hyun Ji Kim Young Min Kim Sung hyuk Park School of Materials Science and Engineering Kyungpook National UniversityDaegu 41566Republic of Korea Agency for Defense Development Daejeon 34186Republic of Korea Implementation Research Division Korea Institute of Materials ScienceChangwon 51508Republic of Korea

In this study, the bending formability of an extruded Mg–9Al–1Zn–0.3Mn–0.9Ca–0.6Y–0.5 MM(AZXWMM91100, wt%) alloy at room temperature is significantly improved through application of a combined precompression and subsequent annealing(PCA) treatment. As the amount of precompression applied along the extrusion direction(ED)(i.e., the total strain) increases from 4% to 6%, the area fraction of ED-oriented grains of the PCA-treated alloy increases, which consequently causes an improvement in its bending formability because these grains accommodate larger tensile strain along the ED during bending. As the temperature of the subsequent annealing treatment increases from 350 ℃ to 450 ℃, both the area fraction of the ED-oriented grains and the average grain size increase, and the residual dislocation density decreases owing to the promotion of boundary migration and occurrence of the recovery process at higher ***, the bending formability of both the 4%-precompressed and the 6%-precompressed samples increases with an increase in the annealing temperature. However, when the precompressed samples are annealed at 300 ℃, their bending formability is lower than that of the extruded alloy because the dislocations formed by precompression remain even after the subsequent annealing at this temperature.

关键词： Magnesium Extrusion Bending Formability Texture