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Modifying current thin-film microextraction(TFME)solutions for analyzing prohibited substances:Evaluating new coatings using liquid chromatography

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Journal of Pharmaceutical Analysis 2022年第3期12卷 470-480页

作者： Łukasz Sobczak dominika.kołodziej Krzysztof Gorynski Bioanalysis Scientific Group Faculty of PharmacyCollegium Medicum in Bydgoszcz at Nicolaus Copernicus University in Torun85-089BydgoszczPoland

For identifying and quantifying prohibited substances,solid-phase microextraction(SPME)continues to arouse interest as a sample preparation ***,the practical implementation of this method in routine laboratory testing is currently hindered by the limited number of coatings compatible with the ubiquitous high-performance liquid chromatography(HPLC)*** octadecyl(C18)and polydimethylsiloxane/divinylbenzene ligands are currently marketed for this *** address this situation,the present study evaluated 12 HPLC-compatible coatings,including several chemistries not currently used in this *** stationary phases of SPME devices in the geometry of thin filmcoated blades were prepared by applying silica particles bonded with various functional ligands(C18,octyl,phenyl-hexyl,3-cyanopropyl,benzenesulfonic acid,and selected combinations of these),as well as unbonded silica,to a metal *** of these chemistries have not been previously used as microextraction *** 48 most commonly misused substances were selected to assess the extraction efficacy of each coating,and eight desorption solvent compositions were used to optimize the desorption *** samples were analyzed using an HPLC system coupled with triple quadrupole tandem mass *** evaluation enables selection of the best-performing coatings for quantifying prohibited substances and investigates the relationship between extraction efficacy and the physicochemical characteristics of the ***,using the most suitable coatings is essential for trace-level analysis of chemically diverse prohibited substances.

关键词： Sample preparation Solid-phase microextraction Thin-film microextraction Prohibited substances Drugs of abuse High-performance liquid chromatography

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Brain age estimation:premise,promise,and problems

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Neural Regeneration Research 2025年第8期20卷 2313-2314页

作者： Jarrad Perron Ji Hyun ko Graduate Program in Biomedical Engineering Price Faculty of EngineeringUniversity of ManitobaWinnipegMBCanada PrairieNeuro Research Centre Kleysen Institute for Advanced MedicineHealth Sciences CentreWinnipegMBCanada Department of Human Anatomy and Cell Science Rady Faculty of Health SciencesUniversity of ManitobaWinnipegMBCanada

Premise:The com bined effects of modern healthcare practices which prolong lifespan and declining birthrates have created unprecedented changes in age demographics worldwide that are especially pronounced in Japan,South korea,Europe,and North *** old age is the most significant predictor of dementia,global healthcare systems must rise to the challenge of providing care for those with neurodegenerative disorders.

关键词： estimation providing birth

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Influence of dietary isoflavone intake on gastrointestinal symptoms in ulcerative colitis individuals in remission

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World Journal of Gastroenterology 2017年第29期23卷 5356-5363页

作者： dominika Glabska dominika Guzek dominika Grudzińska Gustaw Lech Department of Dietetics Faculty of Human Nutrition and Consumer SciencesWarsaw University of Life Sciences(WULS-SGGW) Department of Organization and Consumption Economics Faculty of Human Nutrition and Consumer SciencesWarsaw University of Life Sciences(WULS-SGGW) Department of General Gastroenterological and Oncological SurgeryMedical University of Warsaw

To analyse the association between isoflavone intake and ulcerative colitis motility symptoms in individuals in remission. METHODSCross-sectional study was conducted in a group of ulcerative colitis remission individuals, in sub-groups characterised by various intestinal motility and functioning characteristics (abdominal pain, flatulence, constipations, tenesmus). Total of 56 individuals with ulcerative colitis in remission (19 males and 37 females) were recruited for the study. Assessment of diet was based on self-reported data from each patient’s dietary records taken over a period of three typical, random days (2 weekdays and 1 d of the weekend). The daily isoflavone intake (daidzein, genistein, glycitein and total isoflavones) and daily isoflavone intake per 1000 kcal of diet were assessed. RESULTSNo correlations between isoflavone intake levels and number of bowel movements per day were observed both in the case of intake and intake per 1000 kcal of diet. In the group of individuals declaring lack of abdominal pain, the higher intakes of daidzein (P = 0.0075), daidzein per 1000 kcal of diet (P = 0.0358) and total isoflavone (P = 0.0358) were stated, than in the group of individuals declaring abdominal pain. In the group of individuals declaring lack of constipations, the lower intakes of glycitein (P = 0.0213) and glycitein per 1000 kcal of diet (P = 0.0213) were stated, than in the group of individuals declaring presence of constipations. No differences were observed in isoflavone intake between groups of ulcerative colitis individuals declaring lack of flatulence and declaring presence of flatulence, as well as between groups declaring lack of tenesmus and declaring presence of tenesmus. CONCLUSIONThe moderate dietary isoflavone intake may be beneficial for individuals with ulcerative colitis in remission, however, before including it into recommendations, further prospective studies are needed.

关键词： Abdominal pain Constipations ulcerative colitis Daidzein Genistein Glycitein Isoflavone

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Sorption of lanthanide ions on biochar composites

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Journal of Rare Earths 2018年第11期36卷 1212-1220页

作者： Dorota kotodyniska Justyna Bak Malwina Majdariska dominika Fila Department of Inorganic Chemistry Faculty of ChemistryMaria Curie-Sktodowska UniversityM.Curie Sktodowska 5q.220-031 tublinPoland

Sorption of lanthanum（Ⅲ）, cerium（Ⅲ and neodymium（Ⅲ） ions from the aqueous solutions of mixtures through adsorption on the biochar composites was investigated as a function of sorbent mass, pH, phase contact time and initial concentration of solutions at 295 K. The maximum removal of lanthanide ions takes place under the following conditions： 0.1 g of sorbent mass, pH 4 and 360 rain contact time for all studied initial concentrations of solutions. Kinetics of La（Ⅲ）, Ce（Ⅲ） and Nd（Ⅲ） ions sorption proceeded by a fast initial uptake reached equilibrium. This process was modelled by means of the pseudo first order, pseudo second order, intraparticle diffusion and Elovich models. The desorption of three lanthahide ions by nitric, hydrochloric and sulfuric acids at a concentration of 1 mol/L from biochar composites was also studied. In order to investigate the sorption mechanism FFIR, XRD and XPS analyses were performed after sorption of ions from the mixture.

关键词： Lanthanide ions Biochar composites Sorption mechanism Zerovalent iron Rare earths

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Analysis of 3.4 Ah lithium-sulfur pouch cells by electrochemical impedance spectroscopy

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Journal of Energy Chemistry 2022年第9期31卷 318-325,I0009页

作者： dominika Capkova Vaclav Knap Andrea Strakova Fedorkova Daniel-Ioan Stroe Department of Physical Chemistry Pavol Jozef Safarik University in KosiceKosice 04154Slovak Republic Faculty of Electrical Engineering Czech Technical University in PraguePrague 16627Czech Republic Department of Energy Technology Aalborg UniversityAalborg East 9220Denmark

Despite great progress in lithium-sulfur(Li-S) batteries, the electrochemical reactions in the cell are not yet fully understood. Electrode processes, complex interfaces and internal resistance may be characterized by electrochemical impedance spectroscopy(EIS). EIS is a non-destructive technique and easy to apply, though there are challenges in ensuring the reproducibility of measurements and the interpretation of impedance data. Here, we present the impedance behavior of a 3.4 Ah Li-S pouch cell characterized by EIS. The impedance changes were analyzed over the entire depth-of-discharge, depth-of-charge,and at various temperatures. Based on the formation of intermediates during(dis)charging, the changes of resistances are observed. Overall, the increase in temperature causes a decrease in electrolyte viscosity,lowering the surface energy which can improve the penetration of the electrolyte into the electrode pores. Moreover, the effect of superimposed AC current during EIS measurement was analyzed, and the results show the dependence of the charge transfer resistance on superimposed AC current which was lower compared to steady-state conditions and consents with theory.

关键词： Lithium-sulfur battery Impedance Equivalent circuit Temperature dependencies Charging/discharging differences Dynamic electrochemical impedance spectroscopy

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Metabolomic and elemental profiling of blood serum in bladder cancer

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Journal of Pharmaceutical Analysis 2022年第6期12卷 889-900页

作者： Krzysztof Ossolinski Tomasz Ruman Valerie Copie Brian P.Tripet Leonardo B.Nogueira Katiane O.P.C.Nogueira Artur kołodziej Aneta Płaza-Altamer Anna Ossolinska Tadeusz Ossolinski Joanna Nizioł Department of Urology John Paul II Hospital36-100KolbuszowaPoland Rzeszow University of Technology Faculty of Chemistry35-959RzeszowPoland The Department of Chemistry and Biochemistry Montana State UniversityBozemanMT59717USA Department of Geology Federal University of Ouro Preto35400-000Ouro PretoBrazil Department of Biological Sciences Federal University of Ouro Preto35400-000Ouro PretoBrazil Doctoral School of Engineering and Technical Sciences at the Rzeszow University of Technology 35-959RzeszowPoland

Bladder cancer(BC)is one of the most frequently diagnosed types of urinary *** advances in treatment methods,no specific biomarkers are currently in *** and untargeted profiling of metabolites and elements of human blood serum from 100 BC patients and the same number of normal controls(NCs),with external validation,was attempted using three analytical methods,i.e.,nuclear magnetic resonance,gold and silver-109 nanoparticle-based laser desorption/ionization mass spectrometry(LDI-MS),and inductively coupled plasma optical emission spectrometry(ICP-OES).All results were subjected to multivariate statistical *** potential serum biomarkers of BC,namely,isobutyrate,pyroglutamate,choline,and acetate,were quantified with proton nuclear magnetic resonance,which had excellent predictive ability as judged by the area under the curve(AUC)value of *** elements,Li and Fe,were also found to distinguish between cancer and control samples,as judged from ICP-OES data and AUC of 0.807(in validation set).Twenty-five putatively identified compounds,mostly related to glycans and lipids,differentiated BC from NCs,as detected using *** serum metabolites were found to discriminate between tumor grades and nine metabolites between tumor *** results from three different analytical platforms demonstrate that the identified distinct serum metabolites and metal elements have potential to be used for noninvasive detection,staging,and grading of BC.

关键词： Bladder cancer Biomarkers Human serum Metallomics Metabolomics

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Watershed characteristics and climate factors effect on the temporal variability of mercury in the southern Baltic Sea rivers

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Journal of Environmental Sciences 2018年第6期30卷 55-64页

作者： Karolina Gebka Magdalena Beldowska dominika Saniewska Karol Kuliński Jacek Beldowski The Institute of Oceanography University of Gdansk Marszalka Pilsudskiego Alley 46 81-378 Gdynia Poland The Institute of Oceanology of The Polish Academy of Sciences Powstaflc6w Warszawy Street 55 81-712 Sopot Poland

Mercury（Hg） is a neurotoxic metal which can enter into the human organism mainly by fish consumption, skin and transpiration. In the coastal zone of the southern Baltic Sea, rivers are the main source of Hg. The Polish region represents the largest proportion of the Baltic Sea catchment and this research included four rivers of the Baltic watershed： the Reda,Zagórska Struga, Kacza and Gizdepka. The samples were collected in the years 2011–*** and particulate Hg concentration in these rivers were measured. Due to intensive rain,deposited mercury on the catchment area was washed out into the riverines water and introduced into the Baltic Sea. Consequently, the load of Hg increased three ***, the intensive dry atmospheric deposition during heating season caused the increase of the concentration of particulate Hg in the river water even by 85%. The research confirmed the role of the river flow magnitude in the load of mercury introduced into the sea by rivers. Moreover, a high variability of mercury concentration was connected to the additional sources such as the chemicals containing Hg and no municipal sewage *** analysis of stable isotopes indicated that the SPM contained terrestrial organic matter;however, there was no clear correlation between Hgtot, Corgand Ntotconcentrations and δ13C, δ15N, C/N in particulate matter.

关键词： Hg Suspended particulate matter Stable isotopes Atmospheric deposition Rivers

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Distribution of mercury in different environmental compartments in the aquatic ecosystem of the coastal zone of the Southern Baltic Sea

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Journal of Environmental Sciences 2010年第8期22卷 1144-1150页

作者： dominika Saniewska Magdalena Beldowska Jacek Beldowski Micha Saniewski Justyna Kwasniak Lucyna Falkowska Institute of Oceanography University of Gdansk Institute of Oceanology Polish Academy of Sciences Institute of Meteorology and Water Management Maritime Branch

The aim of this study was to characterize mercury （Hg） contamination in the coastal waters of the Southern Baltic Sea, and to investigate transformations of Hg in the initial links of the marine food chain. Concentrations of Hg in water, particulate matter, plankton and macrophytes at various stations in the coastal zone （a bay with restricted water exchange, near an industrial city, river mouths, and the open sea） were measured in 2006–2008. Hg concentrations observed in the Southern Baltic varied greatly, showing the highest average values in all environmental compartments near the river mouths. In shallow, sheltered parts of the gulf, where water exchange is restricted, Hg concentrations in the water and in macrophytes were elevated relative to those in the coastal zone of the deeper part of the bay and in the open Baltic. Distance to the river mouth, terrestrial runoff, and quantity and quality of organic matter were more important than seasonal variations in controlling Hg and HgSPM concentrations in water samples. Mercury concentrations in the surface microlayer at the air/sea interface were over 10 times higher than those in the bulk surface water. Concentrations of Hg in macrophytes in the winter were significantly higher than those in the warm seasons （spring, summer, autumn）. This was probably the combined effect of higher availability of Hg in porewaters and leaf growth inhibition.

关键词： mercury Baltic Sea coastal zone water particulate matter plankton macrophytes

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Searching for QCD critical point with light nuclei

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Nuclear Science and Techniques 2023年第5期34卷 192-195页

作者： Che Ming ko Cyclotron Institute and Department of Physics and Astronomy Texas A&M UniversityCollege StationTexas 77843‑3366USA

Density fluctuations and correlations due to a first-order quark-gluon plasma to hadronic matter phase transition and its critical end point,if they remain present after the hadronic evolution in a heavy ion collisions,can lead to an enhanced production of light nuclei in these *** would then result in a non-monotonic collision energy dependence of the yield ratio NtNp∕Nd2of proton number Np,deuteron number Nd,and triton number *** of this yield ratio as a function of collision energy thus provides the possibility to probe the equation of state of strong-interaction matter and its phase diagram.

关键词： critical collision light

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Grade zero part of forced graded algebras

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Science China Mathematics 2018年第2期61卷 269-286页

作者： Hankyung ko Mathematisches Institut Universitt Bonn

This paper concerns a certain subcategory of the category of representations for a semisimple algebraic group G in characteristic p, which arises from the semisimple modules for the corresponding quantum group at a p-th root of unity. The subcategory, thus, records the cohomological difference between quantum groups and algebraic groups. We define translation functors in this category and use them to obtain information on the irreducible characters for G when the Lusztig character formula does not hold.

关键词： algebraic groups quantum groups cohomology characters

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