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High-temperature transport properties of BaSn_(1−x)Sc_(x)O_(3−δ) ceramic materials as promising electrolytes for protonic ceramic fuel cells

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Journal of Advanced Ceramics 2022年第7期11卷 1131-1143页

作者： Inna A.ZVONAREVA AlexeyМ.MINEEV Natalia A.TARASOVA Xian-Zhu FU dmitry A.MEDVEDEV Institute of High Temperature Electrochemistry Ural Branch of the Russian Academy of SciencesYekaterinburg 620066Russia Ural Federal University Yekaterinburg 620002Russia Boreskov Institute of Catalysis Novosibirsk 630090Russia College of Materials Science and Engineering Shenzhen UniversityShenzhen 518060China

Protonic ceramic fuel cells(PCFCs)offer a convenient means for electrochemical conversion of chemical energy into electricity at intermediate temperatures with very high *** BaCeO_(3)-and BaZrO_(3)-based complex oxides have been positioned as the most promising PCFC electrolytes,the design of new protonic conductors with improved properties is of paramount *** the present work,we studied transport properties of scandium-doped barium stannate(Sc-doped BaSnO_(3)).Our analysis included the fabrication of porous and dense BaSn_(1−x)Sc_(x)O_(3−δ)ceramic materials(0≤x≤0.37),as well as a comprehensive analysis of their total,ionic,and electronic conductivities across all the experimental conditions realized under the PCFC operation:both air and hydrogen atmospheres with various water vapor partial pressures(p(H2O)),and a temperature range of 500–900℃.This work reports on electrolyte domain boundaries of the undoped and doped BaSnO_(3)for the first time,revealing that pure BaSnO_(3)exhibits mixed ionic–electronic conduction behavior under both oxidizing and reducing conditions,while the Sc-doping results in the gradual improvement of ionic(including protonic)conductivity,extending the electrolyte domain boundaries towards reduced *** latter property makes the heavilydoped BaSnO_(3)representatives attractive for PCFC applications.

关键词： BaSnO_(3) protonic ceramic fuel cells(PCFCs) proton transport perovskite hydration electronic conductivity

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Equilibrium modeling of water-gas systems in Jurassic–Cretaceous reservoirs of the Arctic petroleum province, northern West Siberia

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Petroleum Exploration and Development 2022年第2期49卷 363-373页

作者： NOVIKOV dmitry Anatolievich Trofimuk Institute of Petroleum Geology and Geophysics of Siberian Branch of Russian Academy of Sciences(IPGG SBRAS) Avenue Kop-tyuga3Novosibirsk 630090Russia Novosibirsk State University Str.Pirogova1Novosibirsk 630090Russia

To reveal the equilibrium state of oil and gas and water in a petroliferous basin with a high content of saline water, calculations of water-gas equilibrium were carried out, using a new simulation method, for the Arctic territories of the West Siberian oil and gas bearing province. The water-bearing layers in this area vary widely in gas saturation and have gas saturation coefficients(C;) from 0.2 to 1.0. The gas saturation coefficient increases with depth and total gas saturation of the formation water. All the water layers with gas saturation bigger than 1.8 L/L have the critical gas saturation coefficient value of 1.0, which creates favorable conditions for the accumulation of hydrocarbons;and unsaturated formation water can dissolve gas in the existent pool. The gas saturation coefficient of formation water is related to the type of fluid in the reservoir. Condensate gas fields have gas saturation coefficients from 0.8 to 1.0, while oil reservoirs have lower gas saturation coefficient. Complex gas-water exchange patterns indicate that gas in the Jurassic–Cretaceous reservoirs of the study area is complex in origin.

关键词： water-gas system hydrocarbon accumulations Jurassic–Cretaceous oil reservoir West Siberia Arctic petroleum province

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Two-photon emission from a superlattice-based superconducting light-emitting structure

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Light(Science & Applications) 2024年第7期13卷 1331-1340页

作者： Shlomi Bouscher dmitry Panna Ronen Jacovi Fauzia Jabeen Christian Schneider Sven Höfling Alex Hayat Department of Electrical Engineering TechnionHaifa 32000Israel. Technische Physik Universität WürzburgAm HublandD-97074 WürzburgGermany. Institute of Physics Carl von Ossietzky Universität OldenburgD-26111 OldenburgGermany

Superconductor-semiconductor hybrid devices can bridge the gap between solid-state-based and photonics-based quantum systems,enabling new hybrid computing schemes,offering increased scalability and *** example for a hybrid device is the superconducting light-emitting diode(SLED).SLEDs have been theoretically shown to emit polarization-entangled photon pairs by utilizing radiative recombination of Cooper ***,the twophoton nature of the emission has not been shown experimentally *** demonstrate two-photon emission in a GaAs/AlGaAs *** electroluminescence spectra reveal unique two-photon superconducting features below the critical temperature(Tc),while temperature-dependent photon-pair correlation experiments(g(2)(τ,T))demonstrate temperature-dependent time coincidences below Tc between photons emitted from the *** results pave the way for compact and efficient superconducting quantum light sources and open new directions in light-matter interaction studies.

关键词： photon quantum utilizing

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Plasma-Assisted Chemistry in High-Speed Flow

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Plasma Science and Technology 2007年第6期9卷 760-765页

作者： Sergey B.LEONOV dmitry A.YARANTSEV Anatoly P.NAPARTOVICH Igor V.KOCHETOV Joint Institute for High Temperature Russian Academy of Science Izhorskaya str.13/19Moscow 125412Russia State

Fundamental problems related to the high-speed combustion are analyzed. The result of plasma-chemical modeling is presented as a motivation of experimental activity. Numerical simulations of the effect of uniform non-equilibrium discharge on the premixed hydrogen and ethylene-air mixture in supersonic flow demonstrate an advantage of such a technique over a heating. Experimental results on multi-electrode non-uniform discharge maintenance behind wallstep and in cavity of supersonic flow are presented. The model test on hydrogen and ethylene ignition is demonstrated at direct fuel injection to low-temperature high-speed airflow.

关键词： high-speed combustion electrical discharge nonequilibrium kinetics

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Flexible surface-enhanced Raman scattering-active substrates based on nanofibrous membranes

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Nano Research 2018年第9期11卷 4468-4488页

作者： Ekaterina S. Prikhozhdenko Daniil N. Bratashov dmitry A. Gorin Alexey M. Yashchenok Remote Controlled Theranostic Systems Lab Education and Research Institute of Nanostructures and Biosystems Saratov State University 83 As trakhanskaya Str. Saratov 410012 Russia Skoltech Center for Photonics and Quantum Materials Skolkovo Institute of Science and Technology Skolkovo Innovation Center 3 Nobel Str. Moscow 143026 Russia

Surface-enhanced Raman scattering （SERS） has emerged as an excellent analytical tool for the effective detection and fingerprint identification of various chemicals. Recently, significant progress has been made in the fabrication of SERS-active substrates using simple, inexpensive, and affordable methods. The full potential of universal SERS diagnostics will likely be realized with the development of approaches and devices capable of effectively detecting analytes on various surfaces as well as in multicomponent media. In addition, the combination of implantable or wearable SERS-active substrates and remote portable devices enables real-time diagnostics that ideally fit the concept of personalized medicine. In this paper, we summarize recent achievements in fabricating flexible SERS substrates made of cellulose paper, polymer membranes, and textile fibrous films. Emphasis is placed on the in-situ extraction and detection of various chemicals in real-world surfaces and complex media using flexible nanofibrous SERS platforms. The potential SERS applications and future perspectives in on-site diagnostics are also discussed.

关键词： paper electrospun membrane fabric surface-enhanced Ramanspectroscopy on-site diagnostics swabbing

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Complex analysis of the damage caused by geocryologic processes (as exemplified by effects on the Chara-China Railway track, Transbaikal region)

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Research in Cold and Arid Regions 2017年第3期9卷 335-338页

作者： Irina Chesnokova dmitry Sergeev Water Problems Institute Russian Academy of Sciences Institute of Environmental Geoscience Russian Academy of Sciences

The report presents an analysis of a unique data set demonstrating the influence of geocryological processes on the 75-km Chara-China Railway track(northern Transbaikal region).The originality of these investigations lies in the study of the influence of natural processes on the road in the absence of any repair works or protective and compensating measures for a long period of time(1998~2014).These conditions allowed assessment of the actual damage to the railroad.

关键词： geocryological processes permafrost conditions social-economic damage Chara-China Railway track

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Neutron irradiation effects on mechanical properties of ITER specification tungsten

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Tungsten 2021年第4期3卷 415-433页

作者： dmitry Terentyev Chih-Cheng Chang Chao Yin AZinovev Xin-Fu He Structural Materials Group Institute of Nuclear Materials ScienceBelgian Nuclear Research Center2400 MolBelgium Institute of Mechanics Materials and Civil EngineeringUCLouvain1348 Ottignies-Louvain-la-NeuveBelgium School of Nuclear Science and Technology University of Science and Technology of ChinaHefei 230026China China Institute of Atomic Energy Beijing 102413China

In this contribution,we present the results of recent neutron irradiation campaign performed in the material test reactor BR2(Belgium)on pure *** have applied various irradiation conditions and sample geometry to assess the effect of neu-tron irradiation on hardness,bending,tensile and fracture mechanical *** investigated material is a commercially pure tungsten plate fabricated according to the international thermonuclear experimental reactor(ITER)specification for the application in the divertor plasma-facing *** neutron irradiation covers a large span of temperatures and damage doses,ranging from 600 to 1200°C and 0.1-1 *** obtained mechanical properties were analyzed to deduce the shift of the ductile to brittle transition temperature(DBTT)applying bending,tensile and fracture toughness-testing ***,a correlation of the fracture toughness with the change of the hardness was *** obtained results are compared with the already published results on another ITER specification grade produced in the form of a *** presented and discussed results show that the performance of the compared grades in terms of the irradiation-induced embrittlement is similar,and that the irradiation in the high-temperature region(600-800°C)causes a considerable DBTT shift already at 0.2-0.5 dpa.

关键词： Tungsten Neutron irradiation Embrittlement

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Microscopic theory of exciton and trion polaritons in doped monolayers of transition metal dichalcogenides

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npj Computational Materials 2022年第1期8卷 891-900页

作者： Yaroslav Vladimirovich Zhumagulov Salvatore Chiavazzo dmitry Romanovich Gulevich Vasili Perebeinos Ivan Andreevich Shelykh Oleksandr Kyriienko University of Regensburg Regensburg93040Germany Department of Physics and Engineering ITMO UniversitySt.Petersburg197101Russia Department of Physics and Astronomy University of ExeterStocker RoadExeterEX44QLUnited Kingdom Department of Electrical Engineering University at BuffaloThe State University of New YorkBuffaloNY14260USA Science Institute University of IcelandDunhagi-3IS-107ReykjavikIceland

We study a doped transition metal dichalcogenide (TMDC) monolayer in an optical *** the microscopic theory,we simulate spectra of quasiparticles emerging due to the interaction of material excitations and a high-finesse optical mode,providing a comprehensive analysis of optical spectra as a function of Fermi energy and predicting several modes in the strong light-matter coupling *** addition to exciton-polaritons and trion-polaritons,we report polaritonic modes that become bright due to the interaction of excitons with free *** large doping,we reveal strongly coupled modes corresponding to excited trions that hybridize with a cavity *** also demonstrate that the increase of carrier concentration can change the nature of the system’s ground state from the dark to the bright *** results offer a unified description of polaritonic modes in a wide range of free electron densities.

关键词： polar transition theory

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Guest Editorial

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High Voltage 2017年第2期2卷 47-48页

作者： Shao, Tao Tarasenko, Victor F. Tu, Xin Levko, dmitry Wuhan University of Hydraulic and Electrical Engineering Wuhan China Laboratory of Optical Radiation IHCE China School of Chemistry University of Manchester United Kingdom Department of Aerospace Engineering and Engineering Mechanics University of Texas Austin TX United States

Much attention is being focused on research of plasmas due to their unique features and great potential for application in different areas,including surface modification,plasma medicine,and plasma *** the various topics related to plasma,we selected two as the main topics of this Special Issue,namely Nanosecond-Pulse Discharges,and Plasma-Assisted Oxidation.

关键词： Oxidation potential Issue

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Some Identities of the Higher-Order Type 2 Bernoulli Numbers and Polynomials of the Second Kind

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Computer Modeling in Engineering & Sciences 2021年第9期128卷 1121-1132页

作者： Taekyun Kim Dae SanKim dmitry V.Dolgy Si-Hyeon Lee Jongkyum Kwon Department of Mathematics Kwangwoon UniversitySeoul139-701Korea Department of Mathematics Sogang UniversitySeoul121-742Korea Kwangwoon Glocal Education Center Kwangwoon UniversitySeoul139-701Korea Department of Mathematics Education Gyeongsang National UniversityJinju52828Korea

We introduce the higher-order type 2 Bernoulli numbers and polynomials of the second *** this paper,we investigate some identities and properties for them in connection with central factorial numbers of the second kind and the higher-order type 2 Bernoulli *** give some relations between the higher-order type 2 Bernoulli numbers of the second kind and their conjugates.

关键词： Bernoulli polynomials of the second kind higher-order type 2 Bernoulli polynomials of the second kind higher-order conjugate type 2 Bernoulli polynomials of the second kind

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