检索结果-南通市图书馆

interaction of edge dislocations with voids in tungsten

在线全文

学校读者我要写书评

暂无评论

Tungsten 2024年第3期6卷 633-646页

作者： Arseny kazakov Rita i.Babicheva Aleksandr Zinovev dmitry Terentyev Kun Zhou Elena A.Korznikova Sergey v.Dmitriev Research Laboratory for Metals and Alloys under Extreme impacts Ufa University of Science and Technology institute for Metals Superplasticity Problems of RAS School of Mechanical and Aerospace Engineering Nanyang Technological University institute for Nuclear Energy Technology Belgian Nuclear Research Center Technological Machines and Equipment Department Ufa State Petroleum Technological University institute of Mechanical Science Problems of RAS institute of Molecule and Crystal Physics UFRC of Russian Academy of Sciences

Tungsten is widely used as a material capable of withstanding extreme operating conditions and is one of the candidates for use in fusion and Generation Ⅳ fission *** modelling implemented to solve various material science problems is an indispensable approach for improving material *** work analyzes the interaction of an edge dislocation with a void in single-crystal tungsten with the help of molecular dynamics *** different approaches for studying the dynamics of dislocations in tungsten that differ in boundary conditions are *** interactions of the dislocation and void at different temperatures are investigated,and based on the obtained stress-strain curves,the dislocation obstacle strength for voids having various diameters is *** is shown that when applied to a crystal with small voids,the model with the fixed boundary conditions returns incorrect ***,the influence of the cell size for the model with periodic boundary conditions is analyzed,and the case of a non-central interaction of a dislocation with a void is *** obtained results improve our understanding of the mechanical response of irradiated materials.

关键词： Tungsten Molecular dynamics method Dislocations voids Boundary conditions

Suppressing filamentation instability due to laser beam self-filtering

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

High Power Laser Science and Engineering 2024年第3期12卷 51-61页

作者： dmitry Silin Efim Khazanov A.v.Gaponov-Grekhov institute of Applied Physics of the Russian Academy of Sciences Nizhny NovgorodRussia

The development of small-scale self-focusing in a nonlinear Kerr medium after preliminary self-filtering of a laser beam propagating in free space is studied *** is shown that,under definite conditions,due to self-filtering,filamentation instability(beam splitting into filaments)either occurs at significantly larger values of the B-integral,or does not occur at *** the latter case,there develops the honeycomb instability revealed in this *** instability is the formation of a random honeycomb structure in the beam *** is shown that self-filtering can significantly increase the permissible values of the B-integral,at which the beam quality remains acceptable.

关键词： filamentation instability honeycomb instability self-filtering small-scale self-focusing

Cluster Analysis of the Roma-BZCAT Blazars

在线全文

学校读者我要写书评

暂无评论

Research in Astronomy and Astrophysics 2024年第5期24卷 117-139页

作者： dmitry O.Kudryavtsev Yulia v.Sotnikova vladislav A.Stolyarov Timur v.Mufakharov valery v.vlasyuk Margarita L.Khabibullina Alexander G.Mikhailov Yulia v.Cherepkova Special Astrophysical Observatory of the Russian Academy of Sciences Nizhny Arkhyz 369167Russia Astrophysics Group Cavendish LaboratoryUniversity of CambridgeCambridge CB3 OHEUK kazan Federal University 18 Kremlyovskaya StKazan 420008Russia

Based on the collected multiwavelength data, namely in the radio(NvSS, FiRST, RATAN-600), iR(WiSE),optical(Pan-STARRS), Uv(GALEX), and X-ray(ROSAT, Swift-XRT) ranges, we have performed a cluster analysis for the blazars of the Roma-BZCAT catalog. Using two machine learning methods, namely a combination of PCA with k-means clustering and Kohonen's self-organizing maps(SOMs), we have constructed an independent classification of the blazars(five classes) and compared the classes with the known Roma-BZCAT classification(FSRQs, BL Lacs, galaxy-dominated BL Lacs, and blazars of an uncertain type) as well as with the high synchrotron peaked(HSP) blazars from the 3HSP catalog and blazars from the TevCat catalog. The obtained groups demonstrate concordance with the BL Lac/FSRQ classification along with a continuous character of the change in the properties. The group of HSP blazars stands out against the overall distribution. We examine the characteristics of the five groups and demonstrate distinctions in their spectral energy distribution shapes. The effectiveness of the clustering technique for objective analysis of multiparametric arrays of experimental data is demonstrated.

关键词： methods data analysis-galaxies active-(galaxies:)BL Lacertae objects general

Expanded Porphyrin Exhibiting Off-Centered Out-of-Plane Coordination to Dysprosium

在线全文

学校读者我要写书评

暂无评论

CCS Chemistry 2024年第7期6卷 1731-1738页

作者： dmitry i.Nazarov Jorge Labella Alexey v.Kuzmin Maxim A.Faraonov Evgenii N.ivanov Salavat S.Khasanov Tomas Torres Mikhail K.islyaikin Dmitri v.Konarev Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS 142432 Chernogolovka Department of Organic Chemistry Universidad Autonoma de Madrid28049 Madrid institute of Solid-State Physics RAS 142432 Chernogolovka Research institute of Macroheterocycles Ivanovo State University of Chemistry and Technology15300 Ivanovo G.A.Krestov institute of Solution Chemistry of the Russian Academy of Sciences 153045 Ivanovo institute for Advanced Research in Chemical Sciences Universidad Autonoma de Madrid28049 Madrid iMDEA-Nanociencia 28049 Madrid

The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the development of advanced molecular *** this context,the use of expanded porphyrinoids remains elusive since their coordination chemistry is challenging to ***,taking inspiration from on-surface chemistry,we explored the coordination of Dy^(3+)to a six-membered porphyrinoid,namely,the hemihexaphyrazine ***,we observed the selective formation of a mono-nuclear off-centered,out-of-plane H_(2)Hhp-Dy^(3+)complex when performing the complexation under reductive *** this reaction,the oxidation state of the macrocycle did not *** X-ray diffraction analysis,we found that the coordination number of Dy in this complex was *** macrocycle cocrystallized with decamethylcobaltocene(Cp_(2)^(*)Co)molecules,giving rise to a wellordered solid-state packing,governed byπ-π*** a result of this organization,a small magnetic coupling between the neighboring molecules was *** in all,this work provides key insights into the coordination of magnetically active metals with expanded porphyrinoids,thus motivating the development of advanced spintronic devices.

关键词： porphyrins dysprosium macrocycle coordination chemistry magnetism

Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO_(2)

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第1期42卷 97-104,I0009页

作者： Sergey A.Lermontov Aleksey v.Maksimkin Nataliya A.Sipyagina Tarek Dayyoub Alena N.Malkova Evgeniy A.Kolesnikov Elena A.Straumal inna O.Gozhikova Saidkhodzha G.Nematulloev dmitry v.Telyshev institute of Physiologically Active Compounds of the Russian Academy of Sciences Chernogolovka 142432Russia institute for Bionic Technologies and Engineering I.M.Sechenov First Moscow State Medical University(Sechenov University)Moscow 19991Russia National University of Science and Technology"MiSiS"Moscow 119049 Russia institute of Biomedical Systems National Research University of Electronic TechnologyZelenogradMoscow 124498Russia

For the first time, a highly crystalline porous shish-kebab structure with a high degree of crystallinity was obtained by using a combination of two methods for the formation of porous polymeric materials. A treatment procedure using supercritical carbon dioxide(sc CO_(2))was carried out for oriented ultrahigh molecular weight polyethylene(UHMWPE) films, which provided special conditions for the crystallization of dissolved UHMWPE macromolecules on the surface of oriented UHMWPE crystals. The prepared porous materials were investigated by scanning electron microscopy(SEM) and differential scanning calorimetry(DSC). The particularity of the obtained porous shish-kebab is the absence of the amorphous phase between lamellar crystals(kebabs). The obtained pores had an oval shape, and they were oriented in the orientation direction of the UHMWPE macromolecules. The pore size ranged from 0.05 μm to 4 μm. Controlling the conditions for the crystallization of the UHMWPE macromolecules using supercritical CO_(2) gives the possibility to control the size of both lamellar disks and pores formed.

关键词： UHMWPE Supercritical CO_(2) Porous shish-kebab structure

Wood anatomy chronologies of Scots pine in the foothills of the Western Sayan(Siberia)

在线全文

学校读者我要写书评

暂无评论

Journal of Forestry Research 2024年第3期35卷 13-27页

作者： Elena A.Babushkina dmitry R.Dergunov Mikhail S.Zharkov Liliana v.Belokopytova Dina F.Zhirnova Bao Yang Jingjing Liu Xiaomei Peng Eugene A.vaganov Khakass Technical institute Siberian Federal UniversityAbakan 655017Russia institute of Ecology and Geography Siberian Federal UniversityKrasnoyarsk 660036Russia Mathematical Methods and iT Department Siberian Federal UniversityKrasnoyarsk 660036Russia Key Laboratory of Desert and Desertification Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000People's Republic of China School of Geographic and Oceanographic Sciences Nanjing UniversityNanjing 210093People's Republic of China Department of Dendroecology V.N.Sukachev Institute of ForestSiberian Branch of the Russian Academy of ScienceKrasnoyarsk 660036Russia

Recent methodological advances in quantitative wood anatomy have provided new insights into the climatic responses of radial growth at the scale of cell structure of tree rings. This study considered long-term chronologies of tracheid measurements, indexed by a novel approach to separate their specific climatic responses from signal recorded in cell production(closely reflected in tree-ring width). To fill gaps in understanding the impact of climate on conifer xylem structure, Scots pine(Pinus sylvestris L.)trees > 200 years old were selected within the forest-steppe zone in southern Siberia. Such habitats undergo mild moisture deficits and the resulting climatic regulation of growth processes. Mean and maximum values of cell radial diameter and cell wall thickness were recorded for each tree *** a low level of climatogenic stress, components of cell chronologies independent of cambial activity were separated to obtain significant climatic signals revealing the timing of the specific stages of tracheid differentiation. Cell expansion lasted from mid-April to July and was impacted similarly to tree-ring width(stimulated by precipitation and stressed by heat), maximum cell size formed late June. A switch in the climatic responses of mean anatomical traits indicated transition to latewood in mid-July. Secondary wall deposition lasted until mid-September, suppressed by end of season temperatures. Generally, anatomical climatic responses were modulated by a less dry May and September compared with summer months.

关键词： Quantitative wood anatomy Cell radial size Cell wall thickness Pinus sylvestris Climatic response

Olefin Polymerization Behavior of Titanium(iv) Complexes with Fluorinated and Non-fluorinated Aliphatic Phenoxyimine Ligands

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第1期42卷 52-62,I0007页

作者： vladislav A.Tuskaev kasim F.Magomedov Svetlana Ch.Gagieva dmitry A.Kurmaev Yulia v.Nelyubina Evgenii K.Golubev Maria D.Evseeva viktor G.vasil'ev Galina G.Nikiforova Mikhail i.Buzin vyacheslav S.Bogdanov Boris M.Bulychev Department of Chemistry M.V.Lomonosov Moscow State UniversityMoscow 119992Russian Federation A.N.Nesmeyanov institute of Organoelement Compounds Russian Academy of SciencesMoscow119991Russian Federation Enikolopov institute of Synthetic Polymer Materials Russian Academy of SciencesMoscow 117393Russian Federation

A series of Ti(Ⅳ) dichloride and dialkoxide com plexes with phenoxyimine ligands containing fluorinated and nonfluorinated aliphatic imine fragments have been *** molecular structures of complexes 1 and 4 were established by single-crystal X-ray diffraction *** complexes adopt a distorted octahedral coordination structure around the titanium atom and two oxygen atoms are situated in trans position while two nitrogen atoms and two outgoing ligands(Cl or iPrO) are situated in cis *** of activators(MMAO-12 and combinations Et_nAiCl_(3-n)+Bu_(2)Mg) and outgoing ligand(Cl or iPrO) nature on the catalytic activity and properties of the resulting polymers was *** Ti complexes,despite the nature of the outgoing ligands(Cl or iPrO) in the presence of Al/Mg activators,was found to display a high ethylene polymerization activity in the range 1600-3830 kg_(polymer)·mol_(Ti)^(-1)·h^(-1)·atm^(-1) with a viscosity average molecular weight(M_v) value in the range 1.1×10~6-7.1×10~6 Dalton(Da).The resulting UHMWPE can be processed by a solventless method into high-strength and high-modulus oriented *** rheological characteristics of a polymer melt have been *** absence of a cross-over point did not allow to compare the values of the molecular weight distribution of polymers obtained on fluorinated and non-fluorinated pre-catalysts,however,the estimation of the entanglement density is in good agreement with the mechanical characteristics of oriented film *** activation with methylalumoxane,the activity of the com plexes decreased very significantly;however,a polymer with a molecular weight of about 12 million Da was *** the process of ethylene/octene-1 copolymerization,fluorine-containing precatalysts showed a clear advantage over non-fluorinated analogues both in activity and in comonomer content.

关键词： Fi catalysts Titanium(iv) (Co)polymerization Al/Mg co-catalyst Ultra-high molecular weight polyethylene

浓度梯度掺杂实现BiFeO_(3)薄膜自极化

在线全文

学校读者我要写书评

暂无评论

无机材料学报 2024年第1期39卷 99-106,I0006,I0007页

作者：戴乐刘洋高轩王书豪宋雅婷唐明猛 dmitry v karpinsky 刘丽莎汪尧进南京理工大学材料科学与工程学院南京210094 白俄罗斯国家科学院材料科学与应用研究中心白俄罗斯明斯克220072

BiFeO_(3)是一种非常有前途的无铅铁电材料,与大多数传统铁电材料相比,它具有更大的极化和更高的居里温度,为高温应用提供了可能。受到衬底强烈的夹持效应、较大的矫顽场和漏电流的影响,BiFeO_(3)薄膜难以被极化。自极化是解决这一问题... 详细信息

BiFeO_(3)是一种非常有前途的无铅铁电材料,与大多数传统铁电材料相比,它具有更大的极化和更高的居里温度,为高温应用提供了可能。受到衬底强烈的夹持效应、较大的矫顽场和漏电流的影响,BiFeO_(3)薄膜难以被极化。自极化是解决这一问题的可行方法。本研究采用溶胶-凝胶法在Pt(111)/Ti/SiO_(2)/Si衬底上生长了BiFeO_(3)薄膜,向上梯度薄膜(从衬底BiFeO_(3)过渡到薄膜表面Bi_(0.80)Ca_(0.20)FeO_(2.90))以及向下梯度薄膜(从衬底Bi_(0.80)Ca_(0.20)FeO_(2.90)过渡到薄膜表面BiFeO_(3))。通过细致地调控薄膜内部缺陷的定向分布形成内置电场,从而导致薄膜具有自极化特性。压电力显微镜结果表明:在BiFeO_(3)薄膜中,Ca的梯度方向可以调控自极化的方向。此外,类似二极管的单向导通特性验证了薄膜的自极化是由Ca的浓度梯度掺杂导致。X射线光电子能谱结果表明,氧空位的梯度分布导致的内置电场可能是造成自极化现象的原因。本研究为实现铁电薄膜的自极化提供了一种新的策略,并在以自极化的内置电场为驱动,提高光伏或光敏器件性能方面具有潜在的应用前景。

关键词：自极化梯度掺杂铁酸铋薄膜溶胶-凝胶法

Exploring van der Waals materials with high anisotropy:geometrical and optical approaches

在线全文

学校读者我要写书评

暂无评论

Light(Science & Applications) 2024年第4期13卷 645-653页

作者： Aleksandr S.Slavich Georgy A.Ermolaev Mikhail K.Tatmyshevskiy Adilet N.Toksumakov Olga G.Matveeva Dmitriy v.Grudinin Kirill v.voronin Arslan Mazitov Konstantin v.Kravtsov Alexander v.Syuy dmitry M.Tsymbarenko Mikhail S.Mironov Sergey M.Novikov ivan Kruglov Davit A.Ghazaryan Andrey A.vyshnevyy Aleksey v.Arsenin valentyn S.volkov Kostya S.Novoselov Moscow Center for Advanced Studies Kulakova str.20Moscow 123592Russia. Emerging Technologies Research Center XPANCEOInternet CityEmmay TowerDubaiUnited Arab Emirates. Donostia international Physics Center(DiPC) Donostia/San-Sebastián 20018Spain. institute of Materials Ecole Polytechnique Federale de Lausanne1015 LausanneSwitzerland. Department of Chemistry Lomonosov Moscow State UniversityMoscow 119991Russia. Laboratory of Advanced Functional Materials Yerevan State UniversityYerevan 0025Armenia. National Graphene institute(NGi) University of ManchesterManchester M139PLUK. Department of Materials Science and Engineering National University of SingaporeSingapore 03-09 EASingapore. institute for Functional intelligent Materials National University of Singapore117544 SingaporeSingapore

The emergence of van der Waals(vdW)materials resulted in the discovery of their high optical,mechanical,and electronic anisotropic properties,immediately enabling countless novel phenomena and *** success inspired an intensive search for the highest possible anisotropic properties among vdW ***,the identification of the most promising among the huge family of vdW materials is a challenging quest requiring innovative ***,we suggest an easy-to-use method for such a survey based on the crystallographic geometrical perspective of vdW materials followed by their optical *** our approach,we found As2S3 as a highly anisotropic vdW *** demonstrates high in-plane optical anisotropy that is~20%larger than for rutile and over two times as large as calcite,high refractive index,and transparency in the visible range,overcoming the century-long record set by *** these benefits,As2S3 opens a pathway towards nextgeneration nanophotonics as demonstrated by an ultrathin true zero-order quarter-wave plate that combines classical and the Fabry–Pérot optical phase ***,our approach provides an effective and easy-to-use method to find vdW materials with the utmost anisotropic properties.

关键词： anisotropy anisotropic high