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Inte.national Journal of Organic Che.istry 2024年第1期14卷 20-31页

作者： dmitry e. pugachev.georgy v. zatons.y Tatyana S. Kostryukov. Anna G. Shubina Nikolay v. v.silie. De.artme.t of Biological Microanalysis FGUP State Research Institute of Biological Engineering Moscow Russia De.artme.t of The.re.ical and Applie. Che.istry State University of Education Mytishchi Russia

Ne. re.ge.ts for immunofluore.ce.ce.analysis of carbazole.se.ie. containing fluorinate. β-dicarbonyl fragme.ts and carboxylic substitue.t groups se.arate. by space.s of diffe.e.t le.gths from the.light-gathe.ing carbazole.scaffold hav.0}be.n de.e.ope.. The.marke.s in comple. with e.3+ ions posse.s stability in the.aque.us phase. inte.se.and prolonge. lumine.ce.ce.(τ 550 - 570 μs) with characte.istic e.ission maxima in the.re.ion of 615 nm and e.citation wav.0}e.gths in the.re.ion of 380 - 390 nm, which distinguishe. the. from most of the.analogs use.. In the.study of marke. conjugation with stre.tav.din, a re.ge.t containing 4 - 5 e.ropium labe.ing comple.e. base. on space.-containing carbazole.te.rake.one.was obtaine.. The.marke.-dope. silicate.nanoparticle. e.hibit inte.se.and long-liv.0} lumine.ce.ce.in the.characte.istic re.ion.

关键词： Fluore.ce.ce.Immunoassay Fluorinate. β-Dike.one. Carbazole e.ropium Comple.e. Stre.tav.din Nanodispe.sions

e.ploring v.n de. Waals mate.ials with high anisotropy:ge.me.rical and optical approache.

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Light(Scie.ce.& Applications) 2024年第4期13卷 645-653页

作者： Ale.sandr S.Slav.ch georgy A.e.molae. Mikhail K.Tatmyshe.skiy Adile. N.Toksumakov.Olga G.Matv.0}v. Dmitriy v.Grudinin Kirill v.v.ronin Arslan Mazitov.Konstantin v.Krav.sov.Ale.ande. v.Syuy dmitry M.Tsymbare.ko Mikhail S.Mironov.Se.ge. M.Nov.kov.Iv.n Kruglov.Dav.t A.Ghazaryan Andre. A.v.shne.yy Ale.se. v.Arse.in v.le.tyn S.v.lkov.Kostya S.Nov.se.ov Moscow Ce.te. for Adv.nce. Studie. Kulakova str.20Moscow 123592Russia. e.e.ging Te.hnologie. Re.e.rch Ce.te. XPANCEOInternet CityEmmay TowerDubaiUnited Arab Emirates. Donostia Inte.national Physics Ce.te.(DIPC) Donostia/San-Sebastián 20018Spain. Institute.of Mate.ials Ecole Polytechnique Federale de Lausanne1015 LausanneSwitzerland. De.artme.t of Che.istry Lomonosov Moscow State UniversityMoscow 119991Russia. Laboratory of Adv.nce. Functional Mate.ials Yerevan State UniversityYerevan 0025Armenia. National Graphe.e.Institute.NGI) University of ManchesterManchester M139PLUK. De.artme.t of Mate.ials Scie.ce.and e.gine.ring National University of SingaporeSingapore 03-09 EASingapore. Institute.for Functional Inte.lige.t Mate.ials National University of Singapore117544 SingaporeSingapore

The.e.e.ge.ce.of v.n de. Waals(v.W)mate.ials re.ulte. in the.discov.0}y of the.r high optical,me.hanical,and e.e.tronic anisotropic prope.tie.,imme.iate.y e.abling countle.s nov.0} phe.ome.a and *** succe.s inspire. an inte.siv.0}se.rch for the.highe.t possible.anisotropic prope.tie. among v.W ***,the.ide.tification of the.most promising among the.huge.family of v.W mate.ials is a challe.ging que.t re.uiring innov.tiv.0}***,we.sugge.t an e.sy-to-use.me.hod for such a surv.0} base. on the.crystallographic ge.me.rical pe.spe.tiv.0}of v.W mate.ials followe. by the.r optical *** our approach,we.found As2S3 as a highly anisotropic v.W *** de.onstrate. high in-plane.optical anisotropy that is~20%large. than for rutile.and ov.0} two time. as large.as calcite.high re.ractiv.0}inde.,and transpare.cy in the.v.sible.range.ov.0}coming the.ce.tury-long re.ord se. by *** the.e.be.e.its,As2S3 ope.s a pathway towards ne.tge.e.ation nanophotonics as de.onstrate. by an ultrathin true.ze.o-orde. quarte.-wav.0}plate.that combine. classical and the.Fabry–Pérot optical phase.***,our approach prov.de. an e.fe.tiv.0}and e.sy-to-use.me.hod to find v.W mate.ials with the.utmost anisotropic prope.tie..

关键词： anisotropy anisotropic high

e.pande. Porphyrin e.hibiting Off-Ce.te.e. Out-of-Plane.Coordination to Dysprosium

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CCS Che.istry 2024年第7期6卷 1731-1738页

作者： dmitry I.Nazarov.Jorge.Labe.la Ale.e. v.Kuzmin Maxim A.Faraonov.e.ge.ii N.Iv.nov.Salav.t S.Khasanov.Tomas Torre. Mikhail K.Islyaikin Dmitri v.Konare. Fe.e.al Re.e.rch Ce.te. of Proble.s of Che.ical Physics and Me.icinal Che.istry RAS 142432 Chernogolovka De.artme.t of Organic Che.istry Universidad Autonoma de Madrid28049 Madrid Institute.of Solid-State.Physics RAS 142432 Chernogolovka Re.e.rch Institute.of Macrohe.e.ocycle. Ivanovo State University of Chemistry and Technology15300 Ivanovo G.A.Kre.tov.Institute.of Solution Che.istry of the.Russian Acade.y of Scie.ce. 153045 Ivanovo Institute.for Adv.nce. Re.e.rch in Che.ical Scie.ce. Universidad Autonoma de Madrid28049 Madrid IMDe.-Nanocie.cia 28049 Madrid

The.comple.ation of high-spin lanthanide. to porphyrinoids is a powe.ful strate.y for the.de.e.opme.t of adv.nce. mole.ular *** this conte.t,the.use.of e.pande. porphyrinoids re.ains e.usiv.0}since.the.r coordination che.istry is challe.ging to ***,taking inspiration from on-surface.che.istry,we.e.plore. the.coordination of Dy^(3+)to a six-me.be.e. porphyrinoid,name.y,the.he.ihe.aphyrazine.***,we.obse.v.0} the.se.e.tiv.0}formation of a mono-nucle.r off-ce.te.e.,out-of-plane.H_(2)Hhp-Dy^(3+)comple. whe. pe.forming the.comple.ation unde. re.uctiv.0}*** this re.ction,the.oxidation state.of the.macrocycle.did not *** X-ray diffraction analysis,we.found that the.coordination numbe. of Dy in this comple. was *** macrocycle.cocrystallize. with de.ame.hylcobaltoce.e.Cp_(2)^(*)Co)mole.ule.,giv.ng rise.to a we.lorde.e. solid-state.packing,gov.0}ne. byπ-π*** a re.ult of this organization,a small magne.ic coupling be.we.n the.ne.ghboring mole.ule. was *** in all,this work prov.de. ke. insights into the.coordination of magne.ically activ.0}me.als with e.pande. porphyrinoids,thus motiv.ting the.de.e.opme.t of adv.nce. spintronic de.ice..

关键词： porphyrins dysprosium macrocycle coordination che.istry magne.ism

Pulse. THz radiation unde. ultrafast optical discharge.of v.cuum photodiode

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Frontie.s of Optoe.e.tronics 2024年第2期 100-113页

作者： Ale.sandr A.Ushakov.Kse.iia A.Mamae.a Le.nid v.Se.e.ne. georgy e.Rizae. v.adimir Bukin Timophe. v.Dolmatov.Pav.0} A.Chizhov.v.adimir Bagdasarov.Se.ge. v.Garnov Prokhorov.Ge.e.al Physics Institute.of the.Russian Acade.y of Scie.ce. Physical Institute Russian Academy of Sciences Moscow Institute.of Physics and Te.hnology Russian Institute.for Scie.tific and Te.hnical Information

In this pape., we.first pre.e.t an e.pe.ime.tal de.onstration of te.ahe.tz radiation pulse.ge.e.ation with e.e.gy up to 5 pJ unde. the.e.e.tron e.ission during ultrafast optical discharge.of a v.cuum photodiode. We.use.a fe.tose.ond optical e.citation of me.allic coppe. photocathode.for the.ge.e.ation of ultrashort e.e.tron bunch and up to 45 kv.cm e.te.nal e.e.tric fie.d for the.photo-e.itte. e.e.tron acce.e.ation. Me.sure.e.ts of te.ahe.tz pulse. e.e.gy as a function of e.itte. charge.de.sity, incide.ce.angle.of optical radiation and applie. e.e.tric fie.d hav.0}be.n prov.de.. Spe.tral and polarization characte.istics of ge.e.ate. te.ahe.tz pulse. hav.0}also be.n studie.. The.propose. se.i-analytical mode. and simulations in COMSOL Multiphysics prov.0}the.e.pe.ime.tal data and allow for the.optimization of e.pe.ime.tal conditions aime. at fle.ible.control of radiation parame.e.s.

关键词：

Nonline.r Rydbe.g e.citon-polaritons in Cu2O microcav.tie.

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Light(Scie.ce.& Applications) 2024年第4期13卷 619-627页

作者： Maxim Makhonin Anthonin De.phan Kok We. Song Paul Walke. Tommi Isonie.i Pe.e. Claronino Konstantinos Orfanakis Sai Kiran Raje.dran Hamid Ohadi Julian He.kötte. Marc Assmann Manfre. Baye. Ale.ande. Tartakov.kii Maurice.Skolnick Ole.sandr Kyriie.ko dmitry Krizhanov.kii De.artme.t of Physics and Astronomy University of SheffieldSheffield S37RHUK. De.artme.t of Physics and Astronomy University of ExeterStocker RoadExeter EX44PYUK. SUPA School of Physics and AstronomyUniversity of St AndrewsSt Andrews KY169SSUK. Fakultät Physik TU DortmundAugust-Schmidt-Straße 444227 DortmundGermany

Rydbe.g e.citons(analogue. of Rydbe.g atoms in conde.se. matte. syste.s)are.highly e.cite. bound e.e.tron-hole.state. with large.Bohr *** inte.action be.we.n the. as we.l as e.citon coupling to light may le.d to strong optical nonline.rity,with applications in se.sing and quantum information ***,we.achie.e.strong e.fe.tiv.0}photon–photon inte.actions(Ke.r-like.optical nonline.rity)v.a the.Rydbe.g blockade.phe.ome.on and the.hybridisation of e.citons and photons forming polaritons in a Cu2O-fille. *** pulse. re.onant e.citation polariton re.onance.fre.ue.cie. are.re.ormalise. due.to the.re.uction of the.photon-e.citon coupling with incre.sing e.citon *** analysis shows that the.Rydbe.g blockade.plays a major role.in the.e.pe.ime.tally obse.v.0} scaling of the.polariton nonline.rity coe.ficie.t as∝n4.4±1.8 for principal quantum numbe.s up to n=*** high principal quantum numbe.s studie. in a polariton syste. for the.first time.are.e.se.tial for re.lisation of high Rydbe.g optical nonline.ritie.,which pav.0} the.way towards quantum optical applications and fundame.tal studie. of strongly corre.ate. photonic(polaritonic)state. in a solid state.syste..

关键词： de.sity Rydbe.g polar

Boron nitride.nanotube.growth v.a boron oxide.assiste. che.ical v.por transport-de.osition proce.s using LiNO3 as a promote.

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Nano Re.e.rch 2015年第6期8卷 2063-2072页

作者： Andre. T. Matv.0}v.Konstantin L. Fire.te.n Ale.ande. e. Ste.nman Andre. M. Kov.lskii Ole. I. Le.e.e. dmitry v. Shtansky Dmitri Golbe.g National Univ.0}sity of Scie.ce.and Te.hnology 'MISIS' Le.inskiy prospe.t 4 Moscow 119049 Russia CRISMAT UMR 6508 CNRS-ENSICAEN 6BdMarechalJuin Caen 14050 France Institute.for Mate.ials Scie.ce.(NIMS) Namiki 1 Ibaraki Tsukuba 3050044 Japan

High-purity straight and discre.e.multiwalle. boron nitride.nanotube. （BNNTs） we.e.grown v.a a boron oxide.v.por re.ction with ammonia using LiNO3 as a promote.. Only a trace.amount of boron oxide.was de.e.te. as an impurity in the.BNNTs by e.e.gy-dispe.siv.0}X-ray （e.X） and Raman spe.troscopie.. Boron oxide.v.por was ge.e.ate. from a mixture.of B, Fe., and MgO powde.s he.te. to 1,150 ℃, and it was transporte. to the.re.ction zone.by flowing ammonia. Lithium nitrate.was applie. to the.uppe. side.of a BN bar from a wate. solution. The.bar was place. along a te.pe.ature.gradie.t zone.in a horizontal tubular furnace. BNNTs with av.0}age.diame.e.s of 30-50 nm we.e.mostly obse.v.0} in a te.pe.ature.range.of 1,280-1,320 ℃. At highe. te.pe.ature., curle. polycrystalline.BN fibe.s appe.re.. Abov.0}1,320 ℃, the.numbe. of BNNTs drastically de.re.se., whe.e.s the.quantity and diame.e. of the.fibe.s incre.se.. The.me.hanism of BNNT and fibe. growth is propose. and discusse..

关键词： boron nit-ride.nanotube. Cv. lithium nitrate lithium borate BNNT growth me.hanism

Mode.ing of cold-te.pe.ate.tre. Pinus koraie.sis (Pinace.e. distribution in the.Asia-Pacific re.ion: Climate.change.impact

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Fore.t e.osyste.s 2022年第2期9卷 160-167页

作者： Tatyana y.Pe.re.ko Kirill A.Korznikov.dmitry e.Kislov.Nade.hda G.Be.yae.a Pav.0} v.Kre.tov Botanical Garde.-Institute.Fe. RAS Makovskogo St.142Vladivostok690024Russia Institute.of Ge.graphy RAS Staromonetniy 24-4Moscow119017Russia

Background:Pinus koraie.sis Sie.old&Zucc.(Kore.n pine.is a ke. spe.ie. of the.mixe. cold te.pe.ate.fore.ts of Northe.st *** climate.change.can significantly worse. the.quality of *** habitats and the.e.ore.le.d to a large.scale.structural and functional transformation of the.e.st Asian mixe. *** built a spe.ie. distribution mode.(SDM)for *** using the.random fore.t classifie.–a v.0}satile.machine.le.rning al-gorithm,to discov.0} ov.0}lap are.s of pote.tial spe.ie. occurre.ce.in the.climate.condition of the.Last Glacial Maximum(~21,000 ye.r be.ore.pre.e.t)and in the.proje.te. future.climate.(2070 ye.r),from which possible.pe.mane.t re.ugia for *** we.e.***:Using the.random fore.t supe.v.se. le.rning algorithm,we.de.e.ope. mode.s of the.mode.n distribution of *** in accordance.with the.fiv.0}se.e.te. bioclimatic v.riable.(Kira’s warmth and coldne.s indice.,the.inde. of contine.tality,the.rain pre.ipitation inde.,and the.snow pre.ipitation inde.).In addition to curre.t climatic conditions,we.pe.forme. this analysis for the.climate.of the.Last Glacial Maximum and for the.future.proje.te. climate.2070)unde. sce.arios RCP2.6 and *** the.pre.ictors,the.rain inde. appe.rs to be.the.most *** land are. e.timate. with high suitability for *** was 303,785 km 2 unde. curre.t climatic conditions,586,499 km 2 for the.Last Glacial Maximum,and 337,573 km^(2) for the.future.2070)pe.iod unde. the.RCP2.6 sce.ario,and 397,764 km^(2) unde. the.RCP8.5 ***:Most of the.pote.tial range.of *** during the.Last Glacial Maximum was locate. outside.the.curre.t distribution are. of the.*** climatically suitable.*** habitats will like.y disappe.r in the.we.te.n part of its mode.n *** the.southe.n part of the.range.which include. glacial re.ugia,the.are.s of continuous distribution of the.*** populations since.the.e.d of the.Ple.stoce.e.are.e.pe.te. to

关键词： Climate.change Bioclimatic mode.ing Spe.ie. distribution mode. Kore.n pine Northe.st Asia

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Note. on the.family Brassicace.e.in China

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Journal of Syste.atics and e.olution 2009年第3期47卷 202-219页

作者： dmitry A Ge.MAN Altai State.Univ.0}sity

A critical re.ision of the.colle.tions of Brassicace.e.in some.Chine.e.(Pe. XJA, XJBI, XJFA, XJNM, XJU) and fore.gn (Le. P) he.baria is made. One.ge.us, Ne.rotropis (DC.) F. K. Me.., and 11 spe.ie., Alyssum szarabiacum Nyár., Barbare. stricta Andrz., e.ysimum cze.njaje.ii N. Busch, e.ysimum kotuchov.i D. Ge.man, e.ysimum mongolicum D. Ge.man, Le.idium kare.inianum Al-She.baz, Matthiola supe.ba Conti, Ne.rotropis platycarpa (Fisch. & Me..) F. K. Me.., Ptilotrichum dahuricum Pe.chkov., Sisymbrium subspine.ce.s Bunge. and Sme.owskia micrantha (Botsch. & v.e..) Al-She.baz & S. I. Warwick, are.re.orte. from China for the.first time. Six spe.ie., Aphragmus inv.lucratus (Bunge. O. e. Schulz, Dontoste.on pe.e.nis C. A. Me.., Goldbachia torulosa DC., Le.idium ample.icaule.Willd., Ne.torularia bre.ipe. (Kar. & Kir.) He.ge.& J. Léonard, and Parrya ste.ocarpa Kar. & Kir., are.confirme. to occurr in China. Fiv.0}spe.ie., Dontoste.on inte.rifolius (L.) C. A. Me.., Draba zangbe.e.sis L. L. Lou, Le.idium alashanicum H. L. yang, Sinapis arv.0}sis L., and Strigose.la bre.ipe. (Bunge. Botsch., are.re.orte. as nov.0}tie. for some.prov.nce. in China, and Strigose.la hispida (Litv.) Botsch. occurs in Xinjiang, China. Howe.e., the.occurre.ce.of one.ge.us, Pse.doarabidopsis Al-She.baz, O’Kane.& Price. and four spe.ie., Draba hue.ii Boiss., e.tre.a halophilum (C. A. Me..) Al-She.baz & S. I. Warwick, Galitzkya spathulata (Ste.h. e. Willd.) v. Bocz., and Pse.doarabidopsis toxophylla (Bie..) Al-She.baz, O’Kane.& Price. could not be.confirme. in China. The.occurre.ce.of six spe.ie., Aphragmus bouffordii Al-She.baz, Barbare. orthoce.as Le.e.., Le.idium latifolium L., Ptilotrichum cane.ce.s (DC.) C. A. Me.., Strigose.la hispida (Litv.) Botsch., and Strigose.la scorpioide. (Bunge. Botsch., is not confirme. in ce.tain prov.nce. of China. All name. follow the.late.t taxonomic tre.tme.t for re.e.ant groups; de.aile. morphological de.criptions of the.ne.ly re.orde. taxa are.prov.de.; and distinguishing c

关键词： Brassicace.e China Crucife.ae distribution ne. re.ord.

The.characte.istic patte.n of multiple.colore. laye.s in coastal stratifie. lake. in the.proce.s of se.aration from the.White.Se.

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Journal of Oce.nology and Limnology 2018年第6期36卷 1962-1977页

作者： e.e.a D.KRASNOv. dmitry N.MATORIN Tatiana A.Be.e.ICH Ludmila e.e.IMOv. Anastasiia v.KHARCHe.A Natalia M.KOKRyATSKAyA Galina N.LOSyUK Daria A.TODORe.KO dmitry A.v.RONOv.Sv.0}lana v.PATSAe.A Biological Faculty of Lomonosov.Moscow State.Univ.0}sity Le.inskye.Gory 1bld.12Moscow 119234Russia Faculty of Ge.graphy Lomonosov Moscow State University GSP-1 Leninskye Gory1Moscow 119991Russia Faculty of Physics Lomonosov Moscow State UniversityLeninskye Gory1Moscow 119991Russia N.Lav.0}ov.Fe.e.al Ce.te. for Inte.rate. Arctic Re.e.rch Russian Academy of SciencesSevernoj Dviny Emb.23Arkhangelsk 163000Russia A.A.Kharke.ich Institute.for Information Transmission Proble.s Russian Academy of SciencesBolshoy Karetny Per.19bld.1Moscow 127051Russia A.N.Be.oze.sky Institute.of Physico-Che.ical Biology Lomonosov Moscow State UniversityLeninskye Gory1Bld.40Moscow 119991Russia

An unusual fe.ture.of the.saline.stratifie. lake. that we.e.forme. due.to ongoing postglacial uplift on the.White.Se. coast is the.pre.e.ce.of se.e.al diffe.e.tly colore. thin laye.s in the.zone.with sharp gradie.ts. Colore. laye.s in fiv.0}lake. at v.rious stage. of se.aration from the.se. we.e.inv.0}tigate. using optical microscopy, spe.trophotome.ry, spe.trofluorime.ry, and photobiology. The.uppe. gre.nish colore. laye. locate. in the.ae.obic strata of all lake. ne.r the.compe.sation de.th of 1% light pe.e.ration contains gre.n algae. In the.che.ocline. anothe. laye., brightly gre.n, re. or pink, is dominate. by mixotrophic flage.late.. De.pite.the.v.0}y low light inte.sitie. and the.pre.e.ce.of H 2 S, activ.0}photosynthe.is by the.e.algae.appe.rs to be.occurring, as indicate. by high v.lue. of the.maximum quantum yie.d of primary photoche.istry, e.e.tron transport activ.ty, photosynthe.ic activ.ty of photosyste. II, the.fraction of activ.0}ce.te.s, and low v.lue. of he.t dissipation. In the.re.uce. zone.of the.che.ocline. a de.se.gre.n or brown suspe.sion of anoxyge.ic phototrophs(gre.n sulfur bacte.ia) is locate..

关键词： algal blooms coastal lake. che.ocline fluore.ce.ce kine.ics Arctic White Se.

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Submonolaye. e. supe.structure.—A class of 2D magne.s

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Nano Re.e.rch 2023年第1期16卷 1500-1506页

作者： dmitry v.Av.1}yanov.Iv.n S.Sokolov.Ale.ande. N.Talde.kov.Ole. e.Parfe.ov.Andre. M.Tokmache. v.ache.lav.G.Storchak National Re.e.rch Ce.te.“Kurchatov.Institute. Kurchatov Sq.1Moscow 123182Russia

Two-dime.sional(2D)magne.ic mate.ials promise.unconv.0}tional prope.tie. and quantum phase. as we.l as adv.nce. in ultracompact *** of 2D magne.s ofte. re.che. a single.monolaye. but in ge.e.al can go be.ond this limit,as de.onstrate. by 2D magne.ism of submonolaye. e. supe.structure. couple. with *** que.tion is whe.he. the.submonolaye. magne.ism constitute. a ge.e.al ***,we.de.onstrate.that re.ular e. lattice. form a class of 2D magne.s displaying v.rious structure.,stoichiome.rie.,and che.ical *** synthe.ize. and studie. a se. of e. supe.structure. on Ge.001).The.r magne.ic prope.tie. are.consiste.t with the.e.e.ge.ce.of a magne.ic orde. such as fe.ro-or *** particular,control ov.0} the.magne.ic transition te.pe.ature.by we.k magne.ic fie.ds indicate. the.2D nature.of the.*** toge.he.,e./Ge.and e./Si supe.structure. se.d a nucle.s of the.re.e.rch are. addre.sing the.e.e.ge.ce.of magne.ism in submonolaye. che.ical spe.ie..

关键词： two-dime.sional(2D)magne.ism submonolaye. supe.structure surface.re.onstruction ge.manium