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Photoluminescence,structural and antibacterial properties of co-dopedβ-Ca_(3)(PO_(4))_(2)-type phosphates Ca_(8)CuRE(PO_(4))_(7)(RE=Eu-Er)

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Journal of Rare Earths 2024年第9期42卷 1658-1668,I0002页

作者： Ivan v.Nikiforov Ekaterina v.Iliin Bogdan I.Lazoryak Sergey M.Aksenov Pavel v.Slukin dina v.deynek. Department of Chemistry Lomonosov Moscow State University119991MoscowRussia Laboratory of Arctic Mineralogy and Material Sciences Kola Science CentreRussian Academy of Sciences184209ApatityRussia Geological Institute Kola Science CentreRussian Academy of Sciences184209ApatityRussia State Scientific Center of Applied Microbiology and Biotechnology of Rospotrebnadzor 24 Block A142279ObolenskRussia

Novel Ca_(8)CuRE(PO_(4))_(7)where RE^(3+)=Eu^(3+),Tb^(3+),Dy^(3+),Ho^(3+)and Er^(3+)were synthesized by a solid-state method in *** structures of the samples were characterized by powder X-ray diffraction using Rietveld refinement to determine the occupation of crystal *** samples are found to have a centrosymmetric structure with space group R3c,as shown by dielectric *** synthesized Ca_(8)CuRE(PO_(4))_(7)samples have multifunctional *** Cu^(2+)ions provide antibacterial properties,while the rare earth elements ions exhibit luminescence properties,and theβ-Ca_3(PO_(4))_(2)-type host is *** photoluminescence properties of RE^(3+)ions were studied and compared with other simmilar Ca_(8)MRE(PO_(4))_(7)phosphates,where M is a divalent *** photoluminescence intensity quenching in terms of energy transfer from RE^(3+)to Cu^(2+)is *** bioactive properties were studied in relation to antibacterial activity against *** and *** syntesized Ca_(8)CuRE(PO_(4))_(7)samples demonstrate very high and stable inhibition of bacteria *** correlation between crystal structure and properties is *** combining multiple approaches to the directio nal design of such materials,several important properties within a single chemical compound to achieve biovisualization and bioactive properties simultaneously can be combined.

关键词： β-Ca_(3)(PO_(4))_(2) Whitlockite-type structure Bioactive phosphates TCP Photoluminescence Rare earths

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Wood anatomy chronologies of Scots pine in the foothills of the Western Sayan(Siberia)

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Journal of Forestry Research 2024年第3期35卷 13-27页

作者： Elena A.Babushkina Dmitry R.Dergunov Mikhail S.Zharkov Liliana v.Belokopytova dina F.Zhirnova Bao Yang Jingjing Liu Xiaomei Peng Eugene A.vaganov Khakass Technical Institute Siberian Federal UniversityAbakan 655017Russia Institute of Ecology and Geography Siberian Federal UniversityKrasnoyarsk 660036Russia Mathematical Methods and IT Department Siberian Federal UniversityKrasnoyarsk 660036Russia Key Laboratory of Desert and Desertification Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000People's Republic of China School of Geographic and Oceanographic Sciences Nanjing UniversityNanjing 210093People's Republic of China Department of Dendroecology V.N.Sukachev Institute of ForestSiberian Branch of the Russian Academy of ScienceKrasnoyarsk 660036Russia

Recent methodological advances in quantitative wood anatomy have provided new insights into the climatic responses of radial growth at the scale of cell structure of tree rings. This study considered long-term chronologies of tracheid measurements, indexed by a novel approach to separate their specific climatic responses from signal recorded in cell production(closely reflected in tree-ring width). To fill gaps in understanding the impact of climate on conifer xylem structure, Scots pine(Pinus sylvestris L.)trees > 200 years old were selected within the forest-steppe zone in southern Siberia. Such habitats undergo mild moisture deficits and the resulting climatic regulation of growth processes. Mean and maximum values of cell radial diameter and cell wall thickness were recorded for each tree *** a low level of climatogenic stress, components of cell chronologies independent of cambial activity were separated to obtain significant climatic signals revealing the timing of the specific stages of tracheid differentiation. Cell expansion lasted from mid-April to July and was impacted similarly to tree-ring width(stimulated by precipitation and stressed by heat), maximum cell size formed late June. A switch in the climatic responses of mean anatomical traits indicated transition to latewood in mid-July. Secondary wall deposition lasted until mid-September, suppressed by end of season temperatures. Generally, anatomical climatic responses were modulated by a less dry May and September compared with summer months.

关键词： Quantitative wood anatomy Cell radial size Cell wall thickness Pinus sylvestris Climatic response

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开源硬件获得成功

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科技纵览 2024年第4期 6-9页

作者： dina GENKINA 不详

在2024年2月,OpenTitan联盟发布了首款包含开源内置硬件安全功能的商用硅芯片.这一里程碑标志着开放硬件运动的发展又推进了一步.自2010年RISC-v开源指令集架构发布并广泛应用以来,开放硬件的普及和应用一直在拓展和加深.

关键词：硬件安全 Open 硅芯片 RISC 指令集架构开源硬件发布里程碑

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Gas flaring cause shifts in mesophyll and stomatal functional traits of Betula pubescens Ehrh.

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林业研究:英文版 2023年第6期34卷 2079-2087页

作者： dina A.Ronzhina Svetlana v.Migalina Irek A.Yusupov Institute Botanic Garden Ural BranchRussian Academy of Sciences202a 8 Marta Str.EkaterinburgRussia 620144 Tyumen State University 6 Volodarskogo Str.TyumenRussia 625003

In petroleum-producing territories of West Siberia(Russia),oil well gas flares have a thermal effect on nearby plant *** communities can be used as models for studying plant acclimation to global *** the present study on the effect of the hydrothermal regime at the flare sites on mesophyll and stomatal functional traits of Betula pubescens,leaves were collected from trees at250 m(control site[CS]),200,150 and 100 m(maximum impact site[MIS])from a *** the CS to MIS site,the average annual air temperature increased by 0.5℃and bog water level decreased by 17 *** plants from the MIS,stomata were 16%smaller and density was 20%lower compared to those at the CS,resulting in lower maximum stomatal conductance in plants from the MIS(mean±SE:MIS 0.84±0.05 mol·m^(-2)s^(-1),CS 1.24±0.06 mol·m^(-2)s^(-1);F=12.6,Pvolume was 1.9 times lower at MIS than at *** numbers per cell also declined with distance from the flares,from 21(MIS)to18(CS;F=15.6,Pvolume was 24%higher at the CS,whereas the number of mesophyll cells and chloroplasts numbers per unit leaf area were 1.9 and 1.8 times higher at the MIS than at the CS,*** a result,leaves from the MIS had a large total mesophyll cell(Ames/A)and chloroplast(Achl/A)surface area per unit leaf area,resulting in a 46%increase in mesophyll conductance in plants from the ***,structural changes in leaf epidermis consisted of a decrease in stomatal size and number,could lower transpiration losses with higher temperatures and less *** compensate for the reduction in leaf conductance due to a decrease in stomatal conductance under these conditions,an increase in the number of mesophyll cells and chloroplasts per unit area provides a greater gas-exchange area and mesophyll conductance.

关键词： Leaf traits Mesophyll cell volume Chloroplast numbers Mesophyll conductance Stomatal conductance

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Structure and luminescence properties of color-tunable phosphor Sr_(2)La_(3)(SiO_(4))_(3)F:Tb^(3+),Sm^(3+)

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稀土学报:英文版 2023年第9期41卷 1288-1294,I0001页

作者： Haikun Liu Kun Nie Yuanyuan Zhang Lefu Mei dina v.deynek. Xiaoxue Ma Department of Energy and Chemical Engineering Dongguan University of TechnologyDongguan 523808China State Key Laboratory of New Textile Materials&Advanced Processing Technology and Hubei Key Laboratory for New Textile Materials and Applications School of Materials Science and EngineeringKey Laboratory of Polyphenylene Sulfide Fiber and Application in Textile IndustryWuhan Textile UniversityWuhan430200China Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral MaterialsSchool of Materials Sciences and TechnologyChina University of GeosciencesBeijing 100083China School of Materials Sciences and Technology Dongguan University of TechnologyDongguan 523808China School of Materials Science and Engineering Xi'an Jiaotong UniversityXi'an 710049China Department of Chemistry Lomonosov Moscow State UniversityMoscow 119991Russia Laboratory of Arctic Mineralogy and Material Sciences Kola Science CentreRussian Academy of Sciences14 Fersman Str.184209ApatityRussia

A series of single-phase and color-tunable phosphors Sr_(2)La_(3)(SiO_(4))_(3)F:0.15Tb^(3+),xSm^(3+)(SLSOF:0.15Tb^(3+),xSm^(3+)) was prepared using solid-state *** X-ray diffraction(XRD) was used to characterize the phase of the as-prepared *** synthesized phosphors have apatite-type structure without other ***^(3+) and Tb^(3+) ions substitute La^(3+) into the lattice and form a single-phase solid *** elements are evenly distributed in the sample according to the scanning electron microscopy(SEM) *** crystal structure of the host phosphor was refined by the Rietveld *** optical properties were studied in detail by investigation of the luminescence and diffuse spectra,fluorescence decay curves and energy transfer *** phosphor color can be changed from green(0.29,0.48) to yellow/orange and red(0.57,0.42) via adjusting the doping ratio of Sm^(3+).The SLSOF:0.15Tb^(3+),xSm^(3+)phosphors can emit typical multicolor light such as green,yellow,orange and red with gradually increasing Sm^(3+)doping *** results indicate the occurrence of the energy transfer which results in the color-tunable properties of the phosphors.

关键词： Apatite Calcination Phosphor Optical property Luminescence Rare earths

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Effective regulation of electronic structures and luminescence properties of LiGd_(9)(SiO_(4))6-x(GeO_(4))xO_(2):Dy^(3+)phosphors by tetrahedral substitution

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Journal of Rare Earths 2023年第5期41卷 673-681,I0002页

作者： Yuanyuan Zhang Lefu Mei Haikun Liu Sergey M.Aksenov dina v.deynek. Deliang Chen School of Materials Sciences and Technology Dongguan University of TechnologyDongguan 523808China School of Materials Science and Engineering Xi'an Jiaotong UniversityXi'an 710049China Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral MaterialsSchool of Materials Sciences and TechnologyChina University of GeosciencesBeijing 100083China Department of Energy and Chemical Engineering Dongguan University of TechnologyDongguan 523808China Laboratory of Arctic Mineralogy and Material Sciences Kola Science CentreRussian Academy of Sciences14 Fersman StrApatity184209Russia Laboratory of Nature-Inspired Technologies and Environmental Safety of the Arctic Kola Science CentreRussian Academy of SciencesApatity18420 Russia Department of Chemistry Lomonosov Moscow State UniversityMoscow119991Russia School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China

A series of Dy^(3+)-activated phosphors with the general formula LiGd_(9)(SiO_(4))6-x(GeO_(4))xO_(2):Dy^(3+)(0≤x≤3)characterized by an apatite-type structure were successfully synthesized via a simple solid-state technique involving a partial substitution of[SiO_(4)]^(4-)with[GeO_(4)]^(4-)*** effects of homovalent[GeO_(4)]^(4-)-[SiO_(4)]^(4-)substitution on the crystal structure,electronic structure,luminescence properties and thermal performance of LiGd_(9)(SiO_(4))6-x(GeO_(4))xO_(2):Dy^(3+)phosphors were studied in *** phases and microstructure were performed by using X-ray diffraction(XRD)Rietveld refinement method and scanning electron microscopy(SEM)*** substitution of smaller[SiO_(4)]^(4-)ions by larger[GeO_(4)]^(4-)ones makes their unit cell parameters increase gradually,and their band gaps *** photoluminescence spectra of LiGd_(9)(SiO_(4))6-x(GeO_(4))xO_(2):Dy^(3+)(0≤x≤3)exhibit obvious emission peaks located at 477,573 and 675 nm within a visible wavelength region,resulting in an excellent white ***,the I573nm/I477nm values of LiGd_(9)(SiO_(4))6-x(GeO_(4))xO_(2):Dy^(3+)(0≤x≤3)become larger with the partial substitution of[SiO_(4)]^(4-)by[GeO_(4)]^(4-),and their CIE chromaticity coordinates exhibit a yellow shift.

关键词： Apatite Structure substitution Electronic structure White emitting Rare earths

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Improving Date Fruit Classification Using Cycle GAN-Generated Dataset

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Computer Modeling in Engineering & Sciences 2022年第4期131卷 331-348页

作者： dina M.Ibrahim Nada M.Elshennawy Department of Information Technology College of ComputerQassim UniversityBuraydah51452Saudi Arabia Computers and Control Engineering Department Faculty of EngineeringTanta UniversityTanta37133Egypt

Dates are an important part of human *** are high in essential nutrients and provide a number of health *** fruits are also known to protect against a number of diseases,including cancer and heart *** fruits have several sizes,colors,tastes,and *** are a lot of challenges facing the date *** of the most significant challenges is the classification and sorting of *** there is no public dataset for date fruits,which is a major limitation in order to improve the performance of convolutional neural networks(CNN)models and avoid the overfitting *** this paper,an augmented date fruits dataset was developed using Deep Convolutional Generative Adversarial Networks(DCGAN)and CycleGAN approach to augment our collected date fruit *** augmentation is required to address the issue of a restricted number of images in our datasets,as well as to establish a balanced *** are three types of dates in our proposed dataset:Sukkari,Ajwa,and *** dataset augmentation,we train our created dataset using ResNet152v2 and CNN models to assess the classification process for our three categories in the *** train these two models,we start with the original ***,the models were trained using the DCGAN-generated dataset,followed by the CycleGAN-generated *** resulting results demonstrated that when using the ResNet152v2model,the CycleGAN-generated dataset had the highest classification performance with 96.8%accuracy,followed by the CNN model with 94.3%accuracy.

关键词： Dates fruits data augmentation DCGAN CycleGAN,deep learning convolution neural networks

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New approaches to diagnostics and treatment of cholangiocellular cancer based on photonics methods

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Frontiers of Optoelectronics 2020年第4期13卷 352-359页

作者： Dmitry v.YAKOvLEv dina S.FARRAKHOvA Artem A.SHIRYAEv Kanamat T.EFENDIEv Maxim v.LOSCHENOv Liana M.AMIRKHANOvA Dmitry O.KORNEv vladimir v.LEvKIN Igor v.RESHETOv victor B.LOSCHENOv Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry Russian Academy of SciencesMoscow 117997Russia Prokhorov General Physics Institute of Russian Academy of Sciences Moscow 119991Russia University Clinical Hospital No.1 Oncology CenterI.M.Sechenov First Moscow State Medical University(Sechenov University)Ministry of Health of the Russian FederationMoscow 119991Russia Department of Laser Micro- Nano-and BiotechnologyInstitute of Engineering Physics for BiomedicineNational Research Nuclear University MEPhIMoscow 115409Russia

Cholangiocellular cancer(CCC)is an oncological disease of the bile ducts characterized by a high mortality *** date,the use of standard methods for the diagnosis and treatment of CCC has not been able to reduce mortality from this *** work presents the results of fluorescence diagnostics(FD),which consists in using a modified optical fiber and photodynamic therapy(PDT)using a therapeutic laser instead of a low-intensity *** technique was tested on 43 patients in a clinical *** results obtained indicate a direct correlation between spectroscopic and video FD ***,a direct correlation was found between the photobleaching of a chlorin e6-based photosensitizer,with the commercial names of PhotoIon Radachlorin and Photoran and stricture *** findings demonstrate the possibility of using a therapeutic laser with a wavelength of 660 nm for both diagnosis and treatment of bile ducts cancer,which results in a significant reduction of the operation time without decreasing its effectiveness.

关键词： cholangiocellular cancer(CCC) fluorescent diagnostics(FD) photodynamic therapy(PDT) chlorin e6 PhotoIon spectroscopic method video fluorescent method photobleaching cancer bile ducts tumor intraoperation diagnostics photosensitizer(PS)

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Computational analysis of apatite-type compounds for band gap engineering: DFT calculations and structure prediction using tetrahedral substitution

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Rare Metals 2021年第12期40卷 3694-3700页

作者： Hai-Kun Liu Li-Bing Liao Yuan-Yuan Zhang Sergey MAksenov Ning Liu Qing-Feng Guo dina v.deynek. Tian-Yi Wang Le-Fu Mei Cheng-Hua Sun Science and Technology Innovation Institute Dongguan University of TechnologyDongguan 523808China School of Chemical Engineering and Energy Technology Dongguan University of TechnologyDongguan 523808China Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral MaterialsSchool of Materials Sciences and TechnologyChina University of GeosciencesBeijing 100083China School of Materials Sciences and Technology Dongguan University of TechnologyDongguan 523808China

Mineral apatite compounds have attracted significant interest due to their chemical stability and adjustable hexagonal structure,which makes them suitable as new photovoltaic functional *** band gap of natural apatite is ~5.45 ev,and such a large value limits their applications in the field of catalysis and energy *** this research,we designed a method to narrow the band gap via the tetrahedral substitution effect in apatite-based *** density functional theory(DFT) and experimental investigation of the electronic and optical properties revealed that the continuous incorporation of [MO_(4)]^(4-) tetrahedrons(M=Si,Ge,Sn,and Mn) into the crystal lattice can significantly reduce the band *** particular,this phenomenon was observed when the[MnO_(4)]^(4-) tetrahedron replaces the [PO_(4)]^(4-) tetrahedron because of the formation of a Mn 3 d-derived conduction band minimum(CBM) and interacts with other elements,leading to band broadening and obvious reduction of the band *** approach allowed us to propose a novel scheme in the band gap engineering of apatite-based compounds toward an entire spectral range modification.

关键词： Apatite Density functional theory(DFT) Band gap engineering Structure prediction Tetrahedral substitution

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The role of vISTA in the tumor microenvironment

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Journal of Cancer Metastasis and Treatment 2022年第1期8卷 365-378页

作者： dina Rabadi Alia A.Sajani Randolph J.Noelle J.Louise Lines Department of Biological Sciences Dartmouth CollegeHanoverNH 03755USA Department of Microbiology and Immunology Norris Cotton Cancer CenterGeisel School of Medicine at DartmouthLebanonNH 03756USA

v-domain Ig Suppressor of T cell Activation(vISTA)is a negative immune checkpoint that is expressed on multiple immune cell subsets and has been characterized in T cells,macrophages,and myeloid-derived suppressor *** the only immune checkpoint expressed on naïve T cells,vISTA contributes to the maintenance of T cell quiescence and *** also regulates multiple myeloid cell activities such as chemotaxis,differentiation,and *** the context of cancer,antagonistic monoclonal antibody targeting of vISTA has been shown to aid anti-tumor ***,combination therapies that include other immune checkpoints such as PD-1 or CTLA-4 with vISTA blockade may enhance therapeutic efficacy in a variety of *** therapy may help overcome adaptive resistance to individual checkpoint therapies,thereby improving patient outcomes and ***,we summarize the role of vISTA in myeloid cells and T cells within the tumor *** discuss the proposed counter-receptors for vISTA,vISTA antibodies currently in development,and the potential for combination therapies with checkpoint inhibitors such as PD-1 and CTLA-4.

关键词： vISTA cancer MDSC immune checkpoint

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