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A survey on causal inference for recommendation

The Innovation 2024年第2期5卷 130-144页

作者： Huishi Luo Fuzhen Zhuang Ruobing Xie Hengshu Zhu deqing wang Zhulin An Yongjun Xu Institute of Artificial Intelligence Beihang UniversityBeijing 100191China Zhongguancun Laboratory Beijing 100094China WeChat Search Application Department TencentBeijing 100080China The Career Science Laboratory BOSS ZhipinBeijing 100028China SKLSDE School of Computer ScienceBeihang UniversityBeijing 100191China Institute of Computing Technology Chinese Academy of SciencesBeijing 100190China

Causal inference has recently garnered significant interest among recommender system(RS)researchers due to its ability to dissect cause-and-effect relationships and its broad applicability across multiple fields.It offers a framework to model the causality in RSs such as confounding effects and deal with counterfactual problems such as offline policy evaluation and data augmentation.Although there are already some valuable surveys on causal recommendations,they typically classify approaches based on the practical issues faced in RS,a classification that may disperse and fragment the uni-fied causal theories.Considering RS researchers’unfamiliarity with causality,it is necessary yet challenging to comprehensively review relevant studies from a coherent causal theoretical perspective,thereby facilitating a deeper integration of causal inference in RS.This survey provides a systematic review of up-to-date papers in this area from a causal theory standpoint and traces the evolutionary development of RS methods within the same causal strategy.First,we introduce the fundamental concepts of causal inference as the basis of the following review.Subsequently,we propose a novel theory-driven taxonomy,categorizing existing methods based on the causal theory employed,namely those based on the potential outcome framework,the structural causal model,and general counterfactuals.The review then delves into the technical details of how existing methods apply causal inference to address particular recommender issues.Finally,we highlight some promising directions for future research in this field.Representative papers and open-source resources will be progressively available at https://***/Chrissie-Law/Causal-Inference-forRecommendation.

关键词： survey details causal

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Efficient nonnegative tensor decomposition using alternating direction proximal method of multipliers

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Chinese Journal of Electronics 2024年

作者： deqing wang Guoqiang HU State Key Laboratory of Robotics Shenyang Institute of Automation Chinese Academy of Sciences Institutes for Robotics and Intelligent Manufacturing Chinese Academy of Sciences Key Laboratory of Marine Robotics College of Artificial Intelligence Dalian Maritime University

Nonnegative CANDECOMP/PARAFAC（NCP） tensor decomposition is a powerful tool for multiway signal processing. The optimization algorithm alternating direction method of multipliers（ADMM） has become increasingly popular for solving tensor decomposition problems in the block coordinate descent framework. However,the ADMM-based NCP suffers from rank deficiency and slow convergence for some large-scale and highly sparse tensor data. The proximal algorithm is preferred to enhance optimization algorithms and improve convergence properties. In this study, we propose a novel NCP algorithm using the alternating direction proximal method of multipliers（ADPMM） that consists of the proximal algorithm. The proposed NCP algorithm can guarantee convergence and overcome the rank deficiency. Moreover, we implement the proposed NCP using an inexact scheme that alternatively optimizes the subproblems. Each subproblem is optimized by a finite number of inner iterations yielding fast computation speed. Our NCP algorithm is a hybrid of alternating optimization and ADPMM and is named A2DPMM.The experimental results on synthetic and real-world tensors demonstrate the effectiveness and efficiency of our proposed algorithm.

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Tungsten oxide/nitrogen-doped carbon nanotubes composite catalysts for enhanced redox kinetics in lithium-sulfur batteries

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Chinese Journal of Chemical Engineering 2024年第3期67卷 58-67页

作者： deqing He Zihao Xie Qian Yang Wei wang Chao Su School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212100China State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 211816China

The sluggish redox kinetics of polysulfides in lithium-sulfur(Li-S)batteries are a significant obstacle to their widespread adoption as energy storage devices.However,recent studies have shown that tungsten oxide(WO_(3))can facilitate the conversion kinetics of polysulfides in Li-S batteries.Herein,we fabricated host materials for sulfur using nitrogen-doped carbon nanotubes(N-CNTs)and WO_(3).We used low-cost components and simple procedures to overcome the poor electrical conductivity that is a disadvantage of metal oxides.The composites of WO_(3) and N-CNTs(WO_(3)/N-CNTs)create a stable framework structure,fast ion diffusion channels,and a 3D electron transport network during electrochemical reaction processes.As a result,the WO_(3)/N-CNT-Li2S6 cathode demonstrates high initial capacity(1162 mA·h·g^(-1) at 0.5℃),excellent rate performance(618 mA·h·g^(-1) at 5.5℃),and a low capacity decay rate(0.093%up to 600 cycles at 2℃).This work presents a novel approach for preparing tungsten oxide/carbon composite catalysts that facilitate the redox kinetics of polysulfide conversion.

关键词： Li-S batteries Composites Ion diffusion channels 3D electron transport network Redox kinetics

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Innovation leading development:a glimpse into three-dimensional bioprinting in Israel

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Bio-Design and Manufacturing 2024年第3期7卷 358-382页

作者： Lujing Gao Zixuan Liu Daniel Dikovsky Jiqian wang deqing Mei Lihi Adler-Abramovich Ehud Gazit Kai Tao State Key Laboratory of Heavy Oil Processing and Centre for Bioengineering and Biotechnology College of Chemistry and Chemical EngineeringChina University of Petroleum(East China)Qingdao 266580China Future Science Research Institute Hangzhou Global Scientific and Technological Innovation CentreHangzhou 311200China Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials Hangzhou 311200China Redefine Meat Ltd. Rehovot 7670110Israel State Key Laboratory of Fluid Power and Mechatronic Systems School of Mechanical EngineeringZhejiang UniversityHangzhou 310058China Key Laboratory of Advanced Manufacturing Technology of Zhejiang Province School of Mechanical EngineeringZhejiang UniversityHangzhou 310058China Department of Oral Biology The Maurice and Gabriela Goldschleger School of Dental MedicineFaculty of Medical&Health SciencesTel Aviv UniversityTel Aviv 6997801Israel The Center for Nanoscience and Nanotechnology Tel Aviv UniversityTel Aviv 6997801Israel Department of Materials Science and Engineering Iby and Aladar FleischmanTel Aviv UniversityTel Aviv 6997801Israel The Shmunis School of Biomedicine and Cancer Research George S.Wise Faculty of Life SciencesTel Aviv UniversityTel Aviv 6997801Israel

Three-dimensional(3D)printing has attracted increasing research interest as an emerging manufacturing technology for devel-oping sophisticated and exquisite architecture through hierarchical printing.It has also been employed in various advanced industrial areas.The development of intelligent biomedical engineering has raised the requirements for 3D printing,such as flexible manufacturing processes and technologies,biocompatible constituents,and alternative bioproducts.However,state-of-the-art 3D printing mainly involves inorganics or polymers and generally focuses on traditional industrial fields,thus severely limiting applications demanding biocompatibility and biodegradability.In this regard,peptide architectonics,which are self-assembled by programmed amino acid sequences that can be flexibly functionalized,have shown promising potential as bioinspired inks for 3D printing.Therefore,the combination of 3D printing and peptide self-assembly poten-tially opens up an alternative avenue of 3D bioprinting for diverse advanced applications.Israel,a small but innovative nation,has significantly contributed to 3D bioprinting in terms of scientific studies,marketization,and peptide architectonics,including modulations and applications,and ranks as a leading area in the 3D bioprinting field.This review summarizes the recent progress in 3D bioprinting in Israel,focusing on scientific studies on printable components,soft devices,and tissue engineering.This paper further delves into the manufacture of industrial products,such as artificial meats and bioinspired supramolecular architectures,and the mechanisms,physicochemical properties,and applications of peptide self-assembly.Undoubtedly,Israel contributes significantly to the field of 3D bioprinting and should thus be appropriately recognized.

关键词： Israel 3D bioprinting Biomanufacturing Peptide self-assembly Integration of industry,education and research

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Enhancing lithium-sulfur battery performance with In_(2)O_(3)-In_(2)S_(3)@NSC heterostructures:Synergistic effects of double barrier and catalytic transformation

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Journal of Materials Science & Technology 2024年第2期169卷 105-114页

作者： deqing He Chunyu Zhu Yutao Huo Zhonghao Rao School of Energy and Environmental Engineering Hebei University of TechnologyTianjin 300401China Hebei Key Laboratory of Thermal Science and Energy Clean Utilization Hebei University of TechnologyTianjin 300401China School of Low-carbon Energy and Power Engineering China University of Mining and TechnologyXuzhou 221116China

The sluggish redox reaction kinetics of lithium polysulfides(LiPSs)are considered the main obstacle to the commercial application of lithium-sulfur(Li-S)batteries.To accelerate the conversion by catalysis and inhibit the shuttling of soluble LiPSs in Li-S batteries,a solution is proposed in this study.The solution involves fabrication of N,S co-doped carbon coated In_(2)O_(3)/In_(2)S_(3)heterostructure(In_(2)O_(3)-In_(2)S_(3)@NSC)as a multifunctional host material for the cathode.The In_(2)O_(3)-In_(2)S_(3)@NSC composite can reduce the Gibbs free energy for the conversion reactions of LiPSs,which results in superior performance.The synergy between different components in In_(2)O_(3)-In_(2)S_(3)@NSC and the unique 3D structure facilitate ion and electron transport in Li-S batteries.The In_(2)O_(3)-In_(2)S_(3)@NSC/Li 2 S 6 cathode exhibits excellent rate capacity,with a capacity of 599 mAh g−1 at 5.5 C,and good cycle stability,with a capacity of 436 mAh g^(−1)after 1000 cycles at 1 C.Overall,this study proposes a promising solution to improve the energy storage properties of Li-S batteries,which could potentially facilitate the commercialization of Li-S batteries.

关键词： Li-S battery Multifunctional host material Synergy Heterostructures Energy storage properties

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Two types of coumarins-specific enzymes complete the last missing steps in pyran- and furanocoumarins biosynthesis

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Acta Pharmaceutica Sinica B 2024年第2期14卷 869-880页

作者： Yucheng Zhao Yuedong He Liangliang Han Libo Zhang Yuanzheng Xia Fucheng Yin Xiaobing wang deqing Zhao Sheng Xu Fei Qiao Yibei Xiao Lingyi Kong Department of Resources Science of Traditional Chinese Medicines School of Traditional Chinese Pharmacyand State Key Laboratory of Natural MedicinesChina Pharmaceutical UniversityNanjing 210009China College of Bioscience and Biotechnology Hunan Agricultural UniversityChangsha 410128China Jiangsu Key Laboratory of Bioactive Natural Product Research and State Key Laboratory of Natural Medicines Department of Natural Medicinal ChemistryChina Pharmaceutical UniversityNanjing 210009China Key Laboratory of Crop Gene Resources and Germplasm Enhancement in Southern China Ministry of AgricultureTropical Crops Genetic Resources InstituteChinese Academy of Tropical Agricultural SciencesHaikou 517317China Institute of Botany Jiangsu Province and Chinese Academy of SciencesNanjing 210014China Department of Pharmacology School of Pharmacyand State Key Laboratory of Natural MedicinesChina Pharmaceutical UniversityNanjing 210009China

Pyran-and furanocoumarins are key representatives of tetrahydropyrans and tetrahydrofurans,respectively,exhibiting diverse physiological and medical bioactivities.However,the biosynthetic mechanisms for their core structures remain poorly understood.Here we combined multiomics analyses of biosynthetic enzymes in Peucedanum praeruptorum and in vitro functional verification and identified two types of key enzymes critical for pyran and furan ring biosynthesis in plants.These included three distinct P.praeruptorum prenyltransferases(PpPT1e3)responsible for the prenylation of the simple coumarin skeleton 7 into linear or angular precursors,and two novel CYP450 cyclases(PpDC and PpOC)crucial for the cyclization of the linear/angular precursors into either tetrahydropyran or tetrahydrofuran scaffolds.Biochemical analyses of cyclases indicated that acid/base-assisted epoxide ring opening contributed to the enzyme-catalyzed tetrahydropyran and tetrahydrofuran ring refactoring.The possible acid/base-assisted catalytic mechanisms of the identified cyclases were theoretically investigated and assessed using site-specific mutagenesis.We identified two possible acidic amino acids Glu303 in PpDC and Asp301 in PpOC as vital in the catalytic process.This study provides new enzymatic tools in the epoxide formation/epoxide-opening mediated cascade reaction and exemplifies how plants become chemically diverse in terms of enzyme function and catalytic process.

关键词： Tetrahydropyrans Tetrahydrofurans Baldwin rules Coumarins CYP450cyclase

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PSLDA:a novel supervised pseudo document-based topic model for short texts

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Frontiers of Computer Science 2022年第6期16卷 71-80页

作者： Mingtao SUN Xiaowei ZHAO Jingjing LIN Jian JING deqing wang Guozhu JIA School of Economics and Management Beihang UniveristyBeijing100191China School of Computer Science Beihang UniversityBeijing100191China School of Instrumentation and Optoelectronic Engineering Beihang UniversityBeijing100191China

Various kinds of online social media applications such as Twitter and Weibo,have brought a huge volume of short texts.However,mining semantic topics from short texts efficiently is still a challenging problem because of the sparseness of word-occurrence and the diversity of topics.To address the above problems,we propose a novel supervised pseudo-document-based maximum entropy discrimination latent Dirichlet allocation model(PSLDA for short).Specifically,we first assume that short texts are generated from the normal size latent pseudo documents,and the topic distributions are sampled from the pseudo documents.In this way,the model will reduce the sparseness of word-occurrence and the diversity of topics because it implicitly aggregates short texts to longer and higher-level pseudo documents.To make full use of labeled information in training data,we introduce labels into the model,and further propose a supervised topic model to learn the reasonable distribution of topics.Extensive experiments demonstrate that our proposed method achieves better performance compared with some state-of-the-art methods.

关键词： supervised topic model short text pseudo-document

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From VIB‑to VB‑Group Transition Metal Disulfides:Structure Engineering Modulation for Superior Electromagnetic Wave Absorption

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Nano-Micro Letters 2024年第2期16卷 218-257页

作者： Junye Cheng Yongheng Jin Jinghan Zhao Qi Jing Bailong Gu Jialiang Wei Shenghui Yi Mingming Li Wanli Nie Qinghua Qin deqing Zhang Guangping Zheng Renchao Che Department of Materials Science Shenzhen MSU-BIT UniversityShenzhen 517182People’s Republic of China School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081People’s Republic of China School of Materials Science and Engineering Qiqihar UniversityQiqihar 161006People’s Republic of China Department of Mechanical Engineering Hong Kong Polytechnic UniversityHung HomKowloonHong KongPeople’s Republic of China Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative MaterialsFudan UniversityShanghai 200438People’s Republic of China Zhejiang Laboratory Hangzhou 311100People’s Republic of China

The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various fields,such as catalysis,energy storage,sensing,etc.In recent years,a lot of research work on TMDs based functional materials in the fields of electromagnetic wave absorption(EMA)has been carried out.Therefore,it is of great significance to elaborate the influence of TMDs on EMA in time to speed up the application.In this review,recent advances in the development of electromagnetic wave(EMW)absorbers based on TMDs,ranging from the VIB group to the VB group are summarized.Their compositions,microstructures,electronic properties,and synthesis methods are presented in detail.Particularly,the modulation of structure engineering from the aspects of heterostructures,defects,morphologies and phases are systematically summarized,focusing on optimizing impedance matching and increasing dielectric and magnetic losses in the EMA materials with tunable EMW absorption performance.Milestones as well as the challenges are also identified to guide the design of new TMDs based dielectric EMA materials with high performance.

关键词： Transition metal disulfides Electromagnetic wave absorption Impedance matching Structure engineering modulation

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On-Surface Synthesis of Electron-Deficient Bisanthene Tetraimide

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CCS Chemistry 2024年第3期6卷 672-681页

作者： Ye Liu Liangliang Chen Hailong Li Xi-Sha Zhang Qigang Zhong Zhengming Hao Minghui Wu Yan-Ying Huang Lina wang Minchong Sheng Miao Xie Haiming Zhang deqing Zhang Lifeng Chi Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices Institute of Functional Nano&Soft Materials(FUNSOM)Soochow UniversitySuzhouJiangsu 215123 CAS Key Laboratory for Organic Solids Institute of ChemistryChinese Academy of SciencesBeijing 100190 Institute of Applied Physics Justus Liebig University GiessenGiessen 35392

Imide-based conjugated molecules have emerged as a highly promising class of building blocks for constructing n-type semiconducting materials with lowlying lowest unoccupied molecular orbitals and exceptional stability.Although imides,such as naphthalene diimides,perylene diimides and their lateral fused analogs,have been synthesized extensively,the design and synthesis of largerπ-extended molecules incorporating more than two imide groups are desirable but still very challenging.Herein,we report the synthesis of an unprecedented electron-deficient bisanthene tetraimide(ATI)containing a bisantheneconjugated core and four five-membered imide groups,which was successfully achieved via a combined approach of solution and on-surface synthesis.The chemical structures,electronic states,formation mechanism and aromaticity of ATI were systematically investigated by scanning tunneling microscopy,noncontact atomic force microscopy,scanning tunneling spectroscopy,and density functional theory calculations.

关键词： on-surface synthesis electron-deficient bisanthene tetraimide dehydrocyclization low lowest unoccupied molecular orbital level

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推动新能源发电高质量发展:成效、问题与对策建议

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价格理论与实践 2024年第3期 44-49页

作者：王德卿中共中央党校(国家行政学院)

新能源发电高质量发展是实现“碳达峰“”碳中和”目标的重要环节,是促进人与自然和谐共生的重要保障,是推动经济高质量发展的题中之义,有助于优化能源结构、保障能源安全。现阶段我国新能源发电存在的问题,突出表现为两个矛盾现象,即:... 详细信息

新能源发电高质量发展是实现“碳达峰“”碳中和”目标的重要环节,是促进人与自然和谐共生的重要保障,是推动经济高质量发展的题中之义,有助于优化能源结构、保障能源安全。现阶段我国新能源发电存在的问题,突出表现为两个矛盾现象,即:新能源发电装机规模屡创新高但发电量占比并未对应提升、电力供应紧张与“弃光弃风”同时发生。分析其原因在于用电需求分布与发电供给分布不匹配、发电波动与消纳波动不匹配、配套建设与发展速度不匹配。基于此,应从建设与要素分布特征相适应的电网系统、打造灵活互补的综合能源系统、扩大和健全新能源电力交易市场等方面着手,增强新能源发电的均衡性、稳定性和经济性,推动新能源发电高质量发展。

关键词：新能源发电电网系统综合能源电力市场

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