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design and synthesis of liquid crystal copolyesters with high-frequency low dielectric loss and inherent flame retardancy

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Chinese Chemical Letters 2023年第5期34卷 621-625页

作者： Shi-Yu Zhang Teng Fu Yue Gong de-ming guo Xiu-Li Wang Yu-Zhong Wang State Key Laboratory of Polymer Materials Engineering The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric MaterialsNational Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)College of ChemistrySichuan UniversityChengdu 610064China

Ultra-low dielectric loss(Df)and low dielectric constant(Dk)materials are urgently required in highspeed and large-capacity transmission,in which the wholly aromatic liquid crystal polymer(LCP)has gained attention due to its excellent dielectric ***,the relationship between molecular structure and dielectric properties is still not *** this study,two copolyesters containing phenyl or naphthyl structures are synthesized,as well as the effects of benzene and naphthalene mesogens on dielectric properties are *** synthesized copolyesters containing naphthalene structure have good comprehensive properties with high thermal stability(T_(5%)=479℃ and T_g=195-216℃),inherent flame retardance(LOI=33.0-35.0 and UL-94 V-0 level at 0.8 mm),low Dk(2.9-3.0@10 GHz)and low Df(0.0027-0.0047@10 GHz).Naphthalene mesogen can reduce the dielectric loss more significantly than benzene at high frequency by reducing the density and mobility of polarizable groups,which leads to the effectively limited dipole polarization in ***,we proposed a new strategy for designing low Dk and low Df materials.

关键词： Liquid crystal polymer Low dielectric loss Low dielectric constant Naphthalene structure Flame retardant

A deep Learning Method for Computing Eigenvalues of the Fractional Schrödinger Operator

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Journal of Systems Science & Complexity 2024年第2期37卷 391-412页

作者： guo Yixiao ming Pingbing LSEC Institute of Computational Mathematics and Scientific/Engineering ComputingAcademy of Mathematics and Systems ScienceChinese Academy of SciencesBeijing 100190China School of Mathematical Sciences University of Chinese Academy of SciencesBeijing 100049China

The authors present a novel deep learning method for computing eigenvalues of the fractional Schrödinger *** proposed approach combines a newly developed loss function with an innovative neural network architecture that incorporates prior knowledge of the *** improvements enable the proposed method to handle both high-dimensional problems and problems posed on irregular bounded *** authors successfully compute up to the first 30 eigenvalues for various fractional Schrödinger *** an application,the authors share a conjecture to the fractional order isospectral problem that has not yet been studied.

关键词： Eigenvalue problem deep learning fractional Schrödinger operator isospectral problem

A bio-based epoxy resin derived from p-hydroxycinnamic acid with high mechanical properties and flame retardancy

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Chinese Chemical Letters 2022年第11期33卷 4912-4917页

作者： Xin Song Ze-Peng deng Chun-Bo Li Fei Song Xiu-Li Wang Li Chen de-ming guo Yu-Zhong Wang The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(MoE) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)State Key Laboratory of Polymer Materials EngineeringCollege of ChemistrySichuan UniversityChengdu 610064China

Recent advances in epoxy resins have been forward to achieving high mechanical performance,thermal stability,and flame ***,seeking sustainable bio-based epoxy precursors and avoiding introduction of additional flame-retardant agents are still of increasing *** we report the synthesis of p-hydroxycinnamic acid-derived epoxy monomer(HCA-EP)via a simple one-step reaction,and the HCA-EP can be cured with 4,4′-diaminodiphenylmethane(DDM)to prepare epoxy *** with the typical petroleum-based epoxy resin,bisphenol A epoxy resin,the HCA-EP-DDM shows a relatively high glass transition temperature(192.9℃)and impressive mechanical properties(tensile strength of 98.3 MPa and flexural strength of 158.9 MPa).Furthermore,the HCA-EP-DDM passes the V-1 flammability rating in UL-94 test and presents the limiting oxygen index of 32.6%.Notably,its char yield is as high as 31.6%under N_(2),and the peak heat rate release is 60%lower than that of bisphenol A epoxy *** findings provide a simple way of using p-hydroxycinnamic acid instead of bisphenol A to construct high-performance bio-based thermosets.

关键词： Epoxy resin Bio-based p-Hydroxycinnamic acid Mechanical performance Intrinsic flame retardancy

A Local Tb Theorem for Square Functions and Parabolic Layer Potentials

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Acta Mathematica Sinica,English Series 2024年第8期40卷 1941-1966页

作者： Zhi Dan WANG guo ming ZHANG School of Physical and Mathematical Sciences Nanjing Tech UniversityNanjing 211816P.R.China Frontiers Science Center for Nonlinear Expectations Ministry of EductionResearch Center for Mathematics and Interdisciplinary SciencesShandong UniversityQingdao266237P.R.China

In this paper,we give a locally parabolic version of Tb theorem for a class of vector-valued operators with off-diagonal decay in L^(2) and certain quasi-orthogonality on a subspace of L^(2),in which the testing functions themselves are also *** an application,we establish the boundedness of layer potentials related to parabolic operators in divergence form,defined in the upper half-space Rn+2+:={(x,t,λ)∈R^(n+1)×(0,∞)},with uniformly complex elliptic,L^(∞),t,λ-independent coefficients,and satisfying the de Giorgi/Nash estimates.

关键词： Local Tb theorems Calderon-Littlewood-Paley family Parabolic layer potentials Carleson measure estimates

On the Strong Approximation for a Simple Reentrant Line in Light Traffic Under First-buffer First-served Service Discipline

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Acta Mathematicae Applicatae Sinica 2024年第3期40卷 823-839页

作者： Kai-ming YANG Yong-jiang guo School of Science Beijing University of Posts and TelecommunicationsBeijing 100876China

For a 2-station and 3-class reentrant line under first-buffer first-served(FBFS)service discipline in light traffic,we firstly construct the strong approximations for performance measures including the queue length,workload,busy time and idle time *** on the obtained strong approximations,we use a strong approximation method to find all the law of the iterated logarithms(LILs)for the above four performance measures,which are expressed as some functions of system parameters:means and variances of interarrival and service times,and characterize the fluctuations around their fluid approximations.

关键词： reentrant line queueing network FBFS service discipline strong approximation LIL Brownian motion

Review on regulation of MnS in non-qquenched and tempered steel

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Journal of Iron and Steel Research(International) 2024年第4期31卷 779-789页

作者： guo-xing Qiu Qing Du Feng Lu de-jun Miao Yong-kun Yang Xiao-ming Li School of Metallurgical Engineering Xi'an University of Architecture and TechnologyXi'an 710055ShaanxiChina Laigang Technique Center Shandong Iron and Steel Group Co.Ltd.Jinan 271104ShandongChina

An overview of the current research status and control methods of MnS in non-quenched and tempered steel was *** a low-melting plastic inclusion,the morphology and distribution of MnS were influenced by various production ***,control of MnS is a systematic problem that must be integrated into the entire production *** on the production process,the factors affecting the morphology and distribution of MnS in steel were *** effects of oxygen activity,manganese,sulfur,and some alloys on MnS inclusion precipitation were summarized,mainly including MnS modification treatment and oxygen-sulfide composite precipitation *** is believed that MnS precipitates during the solidification process of steel,and controlling the solidification cooling rate could effectively regulate the size and morphology of MnS,avoiding the precipitation of ***,by changing the deformation rate,deformation amount,deformation temperature during the hot deformation process,and heating time and temperature during heat treatment,the distribution and morphology of MnS could be *** the fine control of the above process parameters,the number of II-MnS in steel could be effectively reduced,and their morphology could be improved,thereby enhancing the performance of non-quenched and tempered steel and promoting its wider ***,applying laboratory research results to industrial production is an important direction for future research efforts in this field.

关键词： MnS Non-quenched and tempered steel Control technology Process parameter Morphology Distribution

Ferrite features in simulated transition zone of EH36 shipbuilding steel submerged arc welded by CaF_(2)-SiO_(2)-MnO fluxes

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Journal of Iron and Steel Research(International) 2024年第4期31卷 790-796页

作者： ming Zhong Dong Hu Da-ming guo Somnath Basu Cong Wang Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819LiaoningChina School of Metallurgy Northeastern UniversityShenyang 110819LiaoningChina The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina department of Metallurgical Engineering and Materials Science Indian Institute of Technology BombayMumbai 400076MaharashtraIndia

Ferrite features in the simulated transition zone welded with CaF_(2)-SiO_(2)-MnO fluxes containing various MnO contents have been *** laser scanning microscopy has been applied to simulate the thermal cycling of the transition zone and the phase transformations during cooling have been in-situ *** has been found that the appearance temperature for ferrite side plate decreases with increasing Mn content in the weld metals caused by MnO content ***,growth rates for both ferrite side plate and acicular ferrite are significantly enhanced with a higher Mn content of weld ***,from the statistical fractions of salient microstructures,for all samples,the acicular ferrite,grain boundary ferrite,and polygonal ferrite take over more than 90%.It has also been demonstrated that with the increase in Mn content,the ferrite side plate fraction increases slightly from 5%to 10%and the acicular ferrite fraction shows a tendency of first increasing and then decreasing,which experiences the maximum with the flux containing 30 wt.%*** phenomenon is believed to be controlled by the O and Mn contents in weld metals synergistically.

关键词： Submerged arc welding Transition zone Phase transformation Microstructure

Distribution of oxide inclusions in H13 castings under super-gravity field with multi-stage rotation speeds

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Journal of Iron and Steel Research(International) 2024年第1期31卷 121-133页

作者： Shao-ying Li Xiao-jun Xi Xing-ming Zhao Han-jie guo Jing guo School of Metallurgical and Ecological Engineering University of Science and Technology Beijing(USTB)Beijing100083China Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials Beijing100083China Beijing Beiye Functional Materials Corporation Beijing100192China Shandong Tianwu Forming Technology Co. Ltd.Liaocheng252024ShandongChina

The 42 kg industrial H13 castings were prepared by different super-gravity fields with multi-rotation speeds,and the distribution of oxide inclusions in the castings was *** addition,the inward movement Reynolds number and inward movement time of oxide inclusions as well as the solidification time of molten steel at different positions in the castings were calculated to clarify the removal mechanism of oxide inclusions in super-gravity *** results show that the large size(i.e.,greater than 10μm)oxide inclusions are mainly concentrated in the inner and outer parts of the super-gravity castings with constant rotation speed(500 r min^(-1))and five-stage rotation speeds(500,600,750,850,and 950 r min^(-1)),respectively,while there are no large oxide inclusions in the super-gravity castings with three-stage rotation speeds(500,600,and 750 r min^(-1)).Although an increase in the particle size of inclusion and the rotation speed in super-gravity field is conducive to the increase in the inward movement Reynolds number of oxide inclusions and reduction in the inward movement time of oxide inclusions,it will reduce the local solidification time of molten *** the range of the rotation speed studied,the super-gravity field with three-stage rotation speeds has the best effect on the removal of inclusions in H13 molten steel.

关键词： Distribution Oxide inclusion H13 casting Super-gravity field Rotation speed

Experimental Study of Local Scour Around Four Piles Under Different Attack Angles and Gap Ratios

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China Ocean Engineering 2024年第4期38卷 612-624页

作者： LIU ming-ming TANG guo-qiang JIN Xin GENG Shao-yang School of Architecture and Engineering Liaocheng UniversityLiaocheng 252000China Water-Sediment Regulation and Sand Effective Utilization Special Laboratory of Shandong Provincial Education department Liaocheng UniversityLiaocheng 252000China State Key Laboratory of Coastal and Offshore Engineering Dalian University of TechnologyDalian 116024China College of Electronic Engineering Chengdu University of Information TechnologyChengdu 610225China College of Energy Chengdu University of TechnologyChengdu 610059China

In an effort to investigate and quantify the patterns of local scour,researchers embarked on an in-depth study using a systematic experimental *** research focused on the effects of local scour around a set of four piles,each subjected to different hydromechanical *** particular,this study aimed to determine how different attack angles—the angles at which the water flow impinges on the piles,and gap ratios—the ratios of the spacing between the piles to their diameters,influence the extent and nature of scour.A comprehensive series of 35 carefully designed experiments were orchestrated,each designed to dissect the nuances in how the gap ratio and attack angle might contribute to changes in the local scour observed at the base of pile *** these experimental trials,a wealth of local scour data were collected to support the *** data included precise topographic profiles of the sediment bed around the pile groups,as well as detailed scour time histories showing the evolution of scour at strategic feature points throughout the test *** analysis of the experimental data provided interesting *** study revealed that the interplay between the gap ratio and the attack angle had a pronounced influence on the scouring dynamics of the pile *** of the key observations was that the initial phases of scour,particularly within the first hour of water flow exposure,were characterized by a sharp increase in the scour depth occurring immediately in front of the *** this initial rapid development,the scour depth transitioned to a more gradual change *** contrast,the scour topography around the piles continuously *** suggests that sediment displacement and the associated sculpting of the seabed around pile foundations are sustained and progressive processes,altering the underwater landscape over *** results of this empirical investigation have significant implications for the design and constructio

关键词： local scour piles gap ratio attack angle