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Chemical Research in Chinese Universities 1998年第3期14卷 8-13页

作者： TOnG Ming-liang WU Yu-luan CHEn Xiao-ming SUn Zi-ming david n.hendrickson Department of Chemistry Zhongshan UniversityGuangzhou510275 Department of Chemistry-0358 University of California at San DiegoLa JollaCA92093USA

Six novel pentanuclear complexes [Cu 3Ln 2(ClCH 2CO 2) 12 (H 2O) 8]·2H 2O (Ln=La, Pr, Sm, Gd, Dy, or Er) were synthesized by the reaction of chloroacetic acid with Cu and Ln ions in aqueous solutions. The X ray crystallography established the structure of the Gd complex, which contains a pair of quadruply acetato bridged CuGd dinuclear subunits, and each of them is linked to the central Cu atom by a single acetato bridge. The coordination sphere of each Gd atom is completed by three aqua ligands [Gd-O=0.242 8(5)-0.244 4(4) nm] to form an 8 coordinated distorted square antiprism. The central Cu atom is coordinated by two oxygen atoms from the two bridging acetato groups and two oxygen atoms from the two monodentate acetato groups in a slightly distorted square planar fashion, while each terminal Cu atom is coordinated by the four acetato oxygen atoms at the basal plane and an aqua ligand at the apical position to form a square pyramid. The variable temperature (4 320 K) magnetic susceptibility data of the Gd complex were measured, and fitted to the Curie Weiss law with C =16.38 K cm 3·mol -1 and θ =-1.55 K, indicating very weak antiferromagnetic interaction.

关键词： Heterometallic complex Copper(Ⅱ) Lanthanoid(Ⅲ) Antiferromagnetic interaction

Making bridges between preclinical and clinical insights into age-related cognitive decline

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neural Regeneration Research 2025年第8期20卷 2321-2322页

作者： david VC Brito Clévio nóbrega Algarve Biomedical Center-Research Institute(ABC-RI) Campus GambelasFaroPortugal Algarve Biomedical Center-(ABC) Campus GambelasFaroPortugal Faculty of Medicine and Biomedical Sciences(FMCB) University of AlgarveGambelas CampusFaroPortugal

With people living longer,the societal impact of age-related cognitive decline is becoming more pronounced(Crimmins,2015).Thus,it is increasingly important to comprehend the cognitive shifts linked to aging-whether th... 详细信息

关键词： bridges becoming insight

Silk-based nerve guidance conduits with macroscopic holes modulate the vascularization of regenerating rat sciatic nerve

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neural Regeneration Research 2025年第6期20卷 1789-1800页

作者： Carina Hromada Patrick Heimel Markus Kerbl LászlóGál Sylvia nürnberger Barbara Schaedl James Ferguson nicole Swiadek Xavier Monforte Johannes C.Heinzel Antal nógrádi Andreas H.Teuschl-Woller david Hercher Department Life Science Engineering University of Applied Sciences Technikum WienViennaAustria Austrian Cluster for Tissue Regeneration ViennaAustria Ludwig Boltzmann Institute for Traumatology The Research Center in Cooperation with AUVAViennaAustria University Clinic of Dentistry Medical University of ViennaViennaAustria Department of Plastic Reconstructive and Aesthetic SurgeryLandesklinikum Wiener Neustadt2700 Wiener NeustadtAustria Department of Anatomy Histology and EmbryologyAlbert Szent-Györgyi Medical SchoolUniversity of SzegedSzegedHungary Medical University of Vienna Department of Orthopedics and Trauma SurgeryDevision of Trauma SurgeryViennaAustria Department of Hand- PlasticReconstructive and Burn SurgeryBG Unfallklinik TuebingenUniversity of TuebingenTuebingenGermany

Peripheral nerve injuries induce a severe motor and sensory deficit. Since the availability of autologous nerve transplants for nerve repair is very limited, alternative treatment strategies are sought, including the use of tubular nerve guidance conduits(tnGCs). However, the use of tnGCs results in poor functional recovery and central necrosis of the regenerating tissue, which limits their application to short nerve lesion defects(typically shorter than 3 cm). Given the importance of vascularization in nerve regeneration, we hypothesized that enabling the growth of blood vessels from the surrounding tissue into the regenerating nerve within the tnGC would help eliminate necrotic processes and lead to improved regeneration. In this study, we reported the application of macroscopic holes into the tubular walls of silk-based tnGCs and compared the various features of these improved silk^(+) tnGCs with the tubes without holes(silk^(–) tnGCs) and autologous nerve transplants in an 8-mm sciatic nerve defect in rats. Using a combination of micro-computed tomography and histological analyses, we were able to prove that the use of silk^(+) tnGCs induced the growth of blood vessels from the adjacent tissue to the intraluminal neovascular formation. A significantly higher number of blood vessels in the silk^(+) group was found compared with autologous nerve transplants and silk^(–), accompanied by improved axon regeneration at the distal coaptation point compared with the silk^(–) tnGCs at 7 weeks postoperatively. In the 15-mm(critical size) sciatic nerve defect model, we again observed a distinct ingrowth of blood vessels through the tubular walls of silk^(+) tnGCs, but without improved functional recovery at 12 weeks postoperatively. Our data proves that macroporous tnGCs increase the vascular supply of regenerating nerves and facilitate improved axonal regeneration in a short-defect model but not in a critical-size defect model. This study suggests that further optimizatio

关键词： axon regeneration blood vessel functional recovery macroporous nerve lesion peripheral nerve repair sciatic nerve silk-based nerve guidance conduit vascularization

A methodological framework for improving air quality monitoring network *** to environment management

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Journal of Environmental Sciences 2021年第4期33卷 138-147页

作者： david Galán-Madruga Department of Atmospheric Pollution National Center for Environment HealthHealth Institute Carlos IIICtra.Majadahonda a Pozuelo km 2228220 MadridSpain

This work aims to provide a methodology framework which allows to improve the performance and efficiency of an air quality monitoring network(AQMn).It requires to be constituted by a minimum and reliable number of measurement ***,the AQMn efficiency should be assessed over time,as a consequence of the possible emergence of new emission sources of air pollutants,which could lead to variations on their spatial distribution within the target ***_(10)particles data monitored by the Community of Madrid's(Spain)AQMn between 2008 and 2017 were used to develop a methodology to optimize the AQMn *** annual spatial distribution of average PM_(10)levels over the studied period monitored by all current stations vs those more representative was provided by a geographic information system(GIS),and the percentage of similarity between both postulates was quantified using simple linear regression(>95%).As one innovative tool of this study,the practical application of the proposed methodology was validated using PM_(10)particles data measured by AQMn during 2007 and 2018,reaching a similitude degree higher than 95%.The influence of temporal variation on the proposed methodological framework was around 20%.The proposed methodology sets criteria for identifying non-redundant stations within AQMn,it is also able to appropriately assess the representativeness of fixed monitoring sites within an AQMn and it complements the guidelines set by European legislation on air pollutants monitoring at fixed stations,which could help to tackle efforts to improve the air quality management.

关键词： Air quality Ambient air monitoring network PM_(10)particles Redundant stations Optimization Environment management

Infrastructure Beijing Fends Against Olympie White Elephants

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China International Business 2006年第11期 44-45页

作者： david hendrickson

The 2008 Games will leave behind a vast stadium and venue network, but how prepared is the city to deal with these facilities once the Olympics has rolled on？

关键词：北京 2008年奥运会投资

Online Trading C2C Operators Fight for number One

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China International Business 2006年第5期 29-31页

作者： david hendrickson

Taobao and eBay-Eachnet, the country＇s leading customer-to-customer Intemetcompanies, are engaged in a fierce battle for dominance in a fast growing market.

关键词：网上购物阿里巴巴网站淘宝网中国电子商务

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Class in Session

China International Business 2006年第3期 I0006-I0006,I0008-I0009页

作者： david hendrickson

China＇s insatiable demand for high-level business education is grabbing the attention of the global academic community and transforming how elite institutions do business. But will it last and to what end？

关键词：商业教育 MBA 中国 UIBE EMBA

Investors Labor Over IPR

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China International Business 2006年第7期 37-39页

作者： david hendrickson

IPR tops the list of concerns for overseas flower companies firms in the China market. Subsidiaries and joint ventures could be the answer.

关键词：知识产权保护中国商机海外花卉公司

Dateline 2050 Economy

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China International Business 2006年第7期 24-25页

作者： david hendrickson

John Hawksworth, head of Macroeconomics at Pricewaterhouse-Coopers, recently authored a comparative study of the world economy in 2050. He offers CIB his assessment of China＇s economy by mid-century and what it is li... 详细信息

关键词：中国经济 2050年经济全球化金融市场

Disney Eyes Mainland Location

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China International Business 2006年第5期 25-27页

作者： david hendrickson

With its focus on China＇s vast pool of potential consumers, Disney is looking at the possibility of eventually opening a theme park in Shanghai

关键词：迪斯尼公司娱乐业中国市场经营战略上海