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Acta Geochimica 2016年第2期35卷 156-171页

作者： Minfang Wang Xubo Zhang daohui pi Xiaonan Guo Faculty of Earth Resources China University of GeosciencesWuhan 430074 China State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074China The Second Geological Survey of Henan Province Xuchang 461000China

The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust.

关键词： Zircon U-Pb Strontium isotope XinhuaPb-Zn-(Ag) deposit Yunkai Area - South China

Rare Earth Element Geochemistry of Phosphatic Rocks in Neoproterozoic Ediacaran Doushantuo Formation in Hushan Section from the Yangtze Gorges Area, South China

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Journal of Earth Science 2016年第2期27卷 204-210页

作者： Hong Xin Shaoyong Jiang Jinghong Yang Heping Wu daohui pi State Key Laboratory for Mineral Deposits Research Department of Earth Sciences Nanjing University State Key Laboratory of Geological Processes and Mineral Resources Collaborative Innovation Center for Exploration of Strategic Mineral Resources Faculty of Earth Resources China University of Geosciences

Phosphatic rocks are widely distributed in Neoproterozoic Ediacaran Doushantuo Formation in Yangtze Gorges Area, South China. In this study, rare earth element geochemistry of eight phosphatic rock samples from the Hushan Section has been studied. All the samples display typical hat-shaped REE patterns, moderate negative Ce anomalies（Ce/Ce＊=0.55 to 0.67）, slightly positive Eu anomalies（Eu/Eu＊=1.05 to 1.22） and low Y/Ho ratios（38.2±5.6）. The hat-shaped REE patterns indicate diagenetic alteration of the primary REE signatures, which coincides with detrital siliciclastic sources of REE based on the Y/Ho ratios. The degree of Negative Ce anomalies and positive Eu anomalies may have recorded the redox features of diagenetic fluids, suggesting an anoxic environment during the phosphogenesis processes in Neoproterozoic Ediacaran Doushantuo Formation, South China. The geochemical comparison between the Lower Phosphorite Layer and Upper Phosphorite Layer at Hushan indicates a greater degree of diagenesis occurred in the Upper Layer than the Lower one. Besides the terrigenous sources of REE, organic materials could have also played a role on the REE characteristics.

关键词： phosphatic rocks rare earth element Ediacaran Doushantuo Formation YangtzeGorges area.

Trace Elements Characteristics of Black Shales from the Ediacaran Doushantuo Formation, Hubei Province, South China： Implications for Redox and Open vs. Restricted Basin Conditions

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Journal of Earth Science 2018年第2期29卷 342-352页

作者： Bi Zhu Shaoyong Jiang daohui pi Lu Ge Jinghong Yang Institute of Isotope Hydrology School of Earth Sciences and Engineering Hohai University Nanjing 210098 China State Key Laboratory of Geological Processes and Mineral Resources Faculty of Earth Resources Collaborative Innovation Center for Exploration of Strategic Mineral Resources China University of Geosciences Wuhan 430074 China State Key Laboratory for Mineral Deposits Research School of Earth Sciences and Engineering Nanjing University Nanjing 210093 China

In the present study, we carried out trace element analyses of black shales of the Edia- caran Doushantou Formation from two sections （Jiulongwan, Baiguoyuan） in Hubei Province, South China. Mo-U characteristics of black shales from the two sections and compiled Mo-U data of Dou- shantuo black shales from sections of a variety of sedimentary facies described the temporal/spatial variability in the redox conditions of paleo-seawater during deposition of the Donshantuo Formation. Changes in Mo-U patterns of the Doushantuo Member II （DST2） shales of open marine environments are consistent with a shift from a predominately oxic to a predominately anoxic ocean during their deposition. Mo-U patterns of the DST2 black shales from intra-shelf sections reflect basin restriction may have happened in the intra-shelf basin and are compatible with the redox-stratified model of the intra-shelf basin. Mo-U patterns of black shales of the Doushantuo Member IV （DST4） reveal that the shales from intra-shelf sections have more pronounced Mo enrichment and more significant enrich- ment of Mo over U than the slope shales, indicating the operation of a Mn particulate shuttle in the intra-shelf basin. High Mo/TOC ratios of the DST4 at the intra-shelf sections, in combination with similar Mo-TOC patterns of the DST4 from both intra-shelf and slope sections, indicate the intra- shelf basin was well connected to the open ocean during deposition of the DST4.

关键词： Doushantuo Formation Mo-U eovariation Mo/TOC South China.

Organic Carbon Isotope Geochemistry of the Neoproterozoic Doushantuo Formation,South China

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Acta Geologica Sinica(English Edition) 2006年第5期80卷 670-683页

作者： GUO Qingjun LIU Congqiang Harald STRAUSS Tatiana GOLDBERG ZHU Maoyan pi daohui WANG Jian State Key Laboratory of Environmental Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang Guizhou 550002 China Geologisch-Palaontologisches Institut Universitat Miinster Corrensstrasse 24 48149 Miinster Germany School of Earth Sciences James Cook University Townsville QLD 4811 Australia Nanjing Institute of Geology and Palaeontology Chinese Academy of Sciences Nanjing Jiangsu 210008 China Guizhou Phosphorite Ore Company Weng＇an Guizhou

The Neoproterozoic Doushantuo Formation on the Yangtze Platform, South China, documents a sedimentary succession with different sedimentary facies from carbonate platform to slope and to deep sea basin, and hosts one of the world-class phosphorite deposits. In these strata, exquisitely preserved fossils have been discovered： the Weng＇an biota. This study presents carbon isotope geochemistry which is associated paired carbonate and organic matter from the Weng＇an section of a carbonate platform （shelf of the Yangtze Platform, Guizhou Province） from the Songtao section and Nanming section of a transition belt （slope of the Yangtze Platform, Guizhou Province） and from the Yanwutan section （basin area of the Yangtze Platform, Hunan Province）. Environmental variations and bio-events on the Yangtze Platform during the Late Neoproterozoic and their causal relationship are discussed. Negative carbon isotope values for carbonate and organic carbon （mean δ^13Corg = -35.0‰） from the uppermost Nantuo Formation are followed by an overall increase in δ^13C up-section. Carbon isotope values vary between -9.9‰ and 3.6‰ for carbonate and between -35.6‰ and -21.5‰ for organic carbon, respectively. Heavier δ^13Ccarb values suggest an increase in organic carbon burial, possibly related to increasing productivity （such as the Weng＇an biota）. The δ^13C values of the sediments from the Doushantuo Formation decreased from the platform via the slope to basin, reflecting a reduced environment with minor dissolved inorganic carbon possibly due to a lower primary productivity. It is deduced that the classical upwelling process, the stratification structure and the hydrothermal eruption are principally important mechanisms to interpret the carbon isotopic compositions of the sediments from the Doushantuo Formation.

关键词： Late Neoproterozoic Doushantuo Formation organic carbon isotopic composition the Yangtze Platform

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广西东平锰矿床地质地球化学特征及矿床成因

地球科学 2024年第2期49卷 656-668页

作者：周皓宇皮道会黄钦丁大庆凌泽安徽省地质矿产勘查局313地质队安徽六安237010 中国地质大学资源学院湖北武汉430074 中国冶金地质总局广西地质勘查院广西南宁530022 中国冶金地质总局矿产资源研究院北京101300 辽宁省第四地质大队有限责任公司辽宁阜新123000

三叠纪是中国南方一个最重要的成锰时代,在华南板块和周围赋存许多大中型的锰矿床.东平锰矿位于中国广西桂西南成矿带.以东平锰矿为研究对象,通过显微薄片观察、电子探针分析及全岩地球化学分析等方法,探讨了锰矿的物质来源和矿床成因.... 详细信息

三叠纪是中国南方一个最重要的成锰时代,在华南板块和周围赋存许多大中型的锰矿床.东平锰矿位于中国广西桂西南成矿带.以东平锰矿为研究对象,通过显微薄片观察、电子探针分析及全岩地球化学分析等方法,探讨了锰矿的物质来源和矿床成因.通过矿相学的研究工作,我们发现东平锰矿里广泛赋存有黄铁矿、黄铜矿、闪锌矿、方铅矿、辉砷钴矿、硫镍钴矿等一些硫或砷化物.锰矿石样品中Al/(Al+Fe+Mn)、Y/Ho比值和Fe-Mn-(Ni+Cu+Co)×10、lgU-lgTh投图等表明锰矿的成矿物质来源与热水活动有关;正Ce异常及V/(V+Ni)等指示锰最初是在氧化环境中富集.综合以上研究,我们认为东平锰矿的锰质来源主要与热液活动有关;热液来源的锰最初以氧化物或者氢氧化物的方式沉淀,在成岩过程中转变为锰碳酸盐.

关键词：东平锰矿床地球化学物质来源成矿模式

鄂西白果园地区层状斜长角闪岩的发现及其地质意义

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地质科技情报 2014年第5期33卷 53-58页

作者：闫浩皮道会黄志伟中国地质大学资源学院武汉430074

对鄂西白果园地区新发现的层状斜长角闪岩进行了岩石学、地球化学和年代学研究。结果表明:该斜长角闪岩的原岩为洋中脊玄武岩,形成于超俯冲带环境,时代为中元古代晚期,可与庙湾岩组对比。该斜长角闪岩的发现证实扬子板块北缘在罗迪尼亚(... 详细信息

对鄂西白果园地区新发现的层状斜长角闪岩进行了岩石学、地球化学和年代学研究。结果表明:该斜长角闪岩的原岩为洋中脊玄武岩,形成于超俯冲带环境,时代为中元古代晚期,可与庙湾岩组对比。该斜长角闪岩的发现证实扬子板块北缘在罗迪尼亚(Rodinia)超大陆中可能与澳大利亚比邻。

关键词：年代学地球化学斜长角闪岩白果园鄂西

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上扬子地块东缘凹子岗锌矿床成矿流体特征

大地构造与成矿学 2016年第3期40卷 465-477页

作者：熊索菲姚书振皮道会曾国平何谋惷谭满堂中国地质大学(武汉)资源学院湖北武汉430074 中国地质大学(武汉)紧缺矿产资源勘查协同创新中心湖北武汉430074 中国地质调查局武汉地调中心湖北武汉430200

凹子岗锌矿床位于上扬子地块东缘,该矿床经历了两个成矿期：沉积成岩期和热液期,形成两种不同岩相学特征的闪锌矿。流体包裹体岩相学研究显示,存在盐水包裹体（W型）、烃类包裹体（G型）和含石盐子矿物多相包裹体（S型）。有机流体活动... 详细信息

凹子岗锌矿床位于上扬子地块东缘,该矿床经历了两个成矿期：沉积成岩期和热液期,形成两种不同岩相学特征的闪锌矿。流体包裹体岩相学研究显示,存在盐水包裹体（W型）、烃类包裹体（G型）和含石盐子矿物多相包裹体（S型）。有机流体活动与成矿存在耦合关系,其中烃类包裹体（G型）赋存于白云石和自形粗粒闪锌矿中,具有黄色荧光效应,激光拉曼测试显示其成分为沥青质、CH4、C3H8和H2O;此外,沥青与闪锌矿密切共生。显微测温结果显示热液期流体包裹体均一温度集中于160-180℃,盐度集中于8%~14%NaCl（eqv）,部分可达30%NaCl（eqv）左右。成矿流体除含有机质外,还含有NaCl、KCl、CaCl2、MgCl2、H2O,为多元共存的流体体系,成矿压力为22~84 MPa。

关键词：凹子岗锌矿床流体包裹体有机流体鄂西成矿带地球化学

中上扬子地块周缘主要金属成矿系统及成矿谱系

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地学前缘 2020年第2期27卷 218-231页

作者：姚书振宫勇军胡新露周宗桂沈传波皮道会熊索菲谭满堂中国地质大学(武汉)资源学院湖北武汉430074 中国地质大学(武汉)紧缺矿产资源勘查协同创新中心湖北武汉430074 中国地质调查局武汉地质调查中心湖北武汉430205

中上扬子地块周缘巨型成矿带是多旋回多阶段构造演化背景下成矿作用的产物。主要的成矿系统包括沉积-热水沉积成矿系统类、后生盆地流体成矿系统类、岩浆热液成矿系统类三大类。南华纪沉积-热水沉积锰成矿系统、震旦纪沉积-热水沉积铅... 详细信息

中上扬子地块周缘巨型成矿带是多旋回多阶段构造演化背景下成矿作用的产物。主要的成矿系统包括沉积-热水沉积成矿系统类、后生盆地流体成矿系统类、岩浆热液成矿系统类三大类。南华纪沉积-热水沉积锰成矿系统、震旦纪沉积-热水沉积铅锌成矿系统、震旦纪一寒武纪沉积-热水沉积银钒多金属成矿系统、二叠纪沉积-热水沉积锰成矿系统主要发育在古大陆边缘且形成于大地构造挤压向拉张的转换期,大型、超大型矿床定位受大陆边缘构造网络系统的制约,成矿的有利环境是拉张断裂控制的裂陷槽,同生断裂系统和深部含矿流体的持续补给是关键的控矿要素。印支一燕山早期后生盆地流体Pb-Zn成矿系统是本区主要的成矿系统且发育在盆山结合带,大型、超大型矿床定位主要受断裂、层位与岩性联合控制。燕山期岩浆热液型Pb-Zn多金属成矿系统受侵入接触构造体系控制,Pb-Zn矿体主要发育在外带;燕山期岩浆热液型Au多金属成矿系统主要发育在盆山结合带,大型、超大型矿床定位受断裂、褶皱构造和隐伏花岗岩的联合控制。本文初步构建了中上扬子地块周缘主要金属矿床成矿谱系。

关键词：铅锌多金属成矿系统锰成矿系统金多金属成矿系统成矿谱系中上扬子地块

滇东南发现新元古代岩浆岩:SHRIMP锆石U-Pb年代学和岩石地球化学证据

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岩石学报 2006年第4期22卷 916-926页

作者：刘玉平叶霖李朝阳宋彪李铁胜郭利果皮道会中国科学院地球化学研究所矿床地球化学重点实验室贵阳550002 中国科学院广州地球化学研究所广州510640 中国地质科学院北京离子探针中心北京100037 中国科学院地质与地球物理研究所北京100029

滇东南老君山地区出露了一套穹隆状变形-变质岩系,新近完成的1:5万都龙幅、麻栗坡县幅区域地质矿产调查报告,将其分解为晚志留纪南温河花岗岩、新元古界新寨岩组和古元古界猛硐岩群。首次对猛硐岩群的石英角闪斜长片麻岩进行了SHRIMP锆... 详细信息

滇东南老君山地区出露了一套穹隆状变形-变质岩系,新近完成的1:5万都龙幅、麻栗坡县幅区域地质矿产调查报告,将其分解为晚志留纪南温河花岗岩、新元古界新寨岩组和古元古界猛硐岩群。首次对猛硐岩群的石英角闪斜长片麻岩进行了SHRIMP锆石U-Pb定年,结合阴极发光图像分析,获得两组岩浆锆石的结晶年龄分别为761±12Ma和829±10Ma,指示滇东南老君山地区存在新元古代岩浆活动,同时从同位素年代学上,表明猛硐岩群是一套前寒武纪的变质沉积-岩浆杂岩。此外,还获得一些年龄为≈1．83Ga的残留锆石,表明该区存在古元古代的结晶基底。石英角闪斜长片麻岩及共存的斜长角闪岩,它们的原岩具有大陆裂谷背景下玄武质-玄武安山质岩浆系列的地球化学特征,可能与新元古代Rodinia超大陆聚合-裂解过程中的岩浆活动有关,本区在新元古代可能位于南华裂谷与康滇裂谷的交汇部位。

关键词：新元古代岩浆活动 SHRIMP锆石U-Pb定年地球化学滇东南

Boosting Oxygen Evolution Reaction Performance on NiFe‑Based Catalysts Through d‑Orbital Hybridization

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Nano-Micro Letters 2025年第1期17卷 281-292页

作者： Xing Wang Wei pi Sheng Hu Haifeng Bao Na Yao Wei Luo State Key Laboratory of New Textile Materials and Advanced Processing Technology Key Laboratory of New Textile Materials and Applications of Hubei ProvinceSchool of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200People’s Republic of China College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072People’s Republic of China

Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based *** introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in ***,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this *** and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER *** critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.

关键词： NiFe-based catalysts d-orbital coupling Oxygen evolution reaction Anion exchange membrane electrolyzer