检索结果-南通市图书馆

Science China Chemistry 2024年第1期67卷 323-329页

作者： daobin yang Shuncheng yang Hongqian Wang Lin Xie Pengyu Yan Ziyi Ge Zhejiang Engineering Research Center for Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China School of Materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

The construction of C-N bonds is of great importance in the fields of biology,medicine,chemistry and materials ***,the replacement of organic base from pyridine to piperidine in the Knoevenagel condensation process unexpectedly yields a series of novel organic molecules containing C-N ***,the synthesis method does not require any external transition-metals catalysis,and photo-/***,when the new compound 1b is added as a third component to a well-known binary system of PM6:Y6,the efficiency of the organic solar cell is significantly improved,resulting in an outstanding efficiency of 18.0%,which is one of the highest values reported to date for PM6:Y6-based ternary organic solar cells.

关键词： C-N bonds Knoevenagel condensation cross-coupling reaction third component organic solar cells

19.3% Efficiency ternary organic solar cells enabled by the alkyl side-chain effect of guest non-fullerene acceptors

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2024年第8期67卷 2686-2693页

作者： Hongqian Wang Sijian Wu daobin yang Xueliang Yu Shuncheng yang Pengfei Ding Pengyu Yan Zaifei Ma Jianfeng Zhang Ziyi Ge School of Materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China Zhejiang Engineering Research Center for Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Center for Advanced Low-dimension MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

The effect of side-chain engineering of conjugated molecules on the morphology and device performance in binary organic solar cells has been widely investigated. However, this relationship has hardly been studied in the guest components of ternary organic solar cells. In this study, a family of non-fullerene guest acceptors, namely XY-3, XY-5 and XY-7, with hydrogen substituent,straight and branched alkyl chains on the bithiophene units, respectively, were designed and synthesized to understand their effects on aggregation properties and device performance. The straight and branched alkyl chains on the bithiophene units result in sightly blue-shifted absorption compared to the hydrogen substituent and the XY-7 demonstrates the most appropriate phase separation scale and the most balanced charge transport. Consequently, the OSCs based on D18:e C9:XY-7 achieve a high shortcircuit current density(JSC) and fill factor(FF), while maintaining the enhancement of the open-circuit voltage(VOC) achieving an efficiency of 19.32%, exceeding those of D18:e C9, D18:e C9:XY-3, D18:e C9:XY-5(PCE:18.28%, 19.04%, 18.75%, respectively). These results highlight that the side-chain engineering of Y series non-fullerene acceptors as the guest acceptors has great potential in optimizing morphology properties and promoting photovoltaic performance.

关键词： organic solar cells side chain engineering ternary strategy non-fullerene energy losses

同方期刊数据库

Two star-shaped small molecule donors based on benzodithiophene unit for organic solar cells

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2022年第1期33卷 247-251页

作者： Jun Xu Jinsheng Zhang daobin yang Kuibao Yu Dandan Li Zihao Xia Ziyi Ge Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Nano Science and Technology Institute University of Science and Technology of ChinaSuzhou 215123China

Star-shaped small molecules have attracted great attention for organic solar cells(OSCs)because they have three-dimensional charge-transport characteristics,strong light absorption capacities and easily tunable energy ***,three-and four-armed star-shaped small molecule donors,namely BDT-3 Th and BDT-4 Th,respectively,have been successfully designed and synthesized,which used benzodithiophene(BDT)as the central *** two star-shaped intermediates(2 a and 2 b)could be simultaneously obtained by one-step of Suzuki coupling,and 1,2-dimethoxyethane played a key role in the Suzuki *** of them have excellent thermal stability,good solubility and broad ***-armed BDT-4 Th shows a slightly higher extinction coefficient,a deeper HOMO energy level and an obviously better phase separation morphology when blended with Y6 than three-armed BDT-3 *** a result,increased power conversion efficiency(PCE)of 5.83%is obtained in the BDT-4 Th:Y6-based OSC devices,which is obviously higher than that of the BDT-3 Th:Y6-based devices(PCE=3.78%).To the best of our knowledge,this is the highest PCE among the BDT-based star-shaped donors-based *** result provides an effective strategy to obtain star-shaped small molecule donor materials for high efficient organic solar cells.

关键词： Star-shaped molecules Benzodithiophene Suzuki coupling Donor materials Small molecules Organic solar cells

Stable Cycling of All-Solid-State Lithium Metal Batteries Enabled by Salt Engineering of PEO-Based Polymer Electrolytes

在线全文

学校读者我要写书评

暂无评论

Energy & Environmental Materials 2024年第2期7卷 71-78页

作者： Lujuan Liu Tong Wang Li Sun Tinglu Song Hao Yan Chunli Li daobin Mu Jincheng Zheng yang Dai Department of Chemical Engineering Shanghai University School of Material Science & Engineering Beijing Key Laboratory of Environmental Science and Engineering Beijing Institute of Technology Department of Physics Xiamen University

Poly（ethylene oxide）(PEO)-based polymer electrolytes show the prospect in all-solid-state lithium metal batteries;however,they present limitations of low room-temperature ionic conductivity,and interfacial incompatibility with high voltage ***,a salt engineering of 1,1,2,2,3,3-hexafluoropropane-1,3-disulfonimide lithium salt（LiHFDF）/LiTFSI system was developed in PEO-based electrolyte,demonstrating to effectively regulate Li ion transport and improve the interfacial stability under high *** show,by manipulating the interaction between PEO matrix and TFSI--HFDF-,the optimized solid-state polymer electrolyte achieves maximum Li+conduction of 1.24×10-4S cm-1at 40℃,which is almost 3 times of the ***,the optimized polymer electrolyte demonstrates outstanding stable cycling in the LiFePO4/Li and LiNi0.8Mn0.1Co0.1O2/Li（3.0-4.4 V,200 cycles） based all-solid-state lithium batteries at 40℃.

关键词： all-solid-state battery high voltage li-ion conductivity molecular interaction poly(ethylene oxide)

Facilitating prelithiation of silicon carbon anode by localized high-concentration electrolyte for high-rate and long-cycle lithium storage

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Carbon Energy 2024年第6期6卷 216-233页

作者： Yuanxing Zhang Borong Wu Jiaying Bi Xinyu Zhang daobin Mu Xin-Yu Zhang Ling Zhang Yao Xiao Feng Wu School of Materials Science and Engineering Beijing Institute of TechnologyBeijingChina Chongqing Innovation Center Beijing Institute of TechnologyChongqingChina College of New Energy Xi′an Shiyou UniversityXi′anChina Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhouChina Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjinChina

The commercialization of silicon-based anodes is affected by their low initial Coulombic efficiency(ICE)and capacity decay,which are attributed to the formation of an unstable solid electrolyte interface(SEI)***,a feasible and cost-effective prelithiation method under a localized highconcentration electrolyte system(LHCE)for the silicon-silica/graphite(Si-SiO_(2)/C@G)anode is designed for stabilizing the SEI layer and enhancing the *** thin SiO_(2)/C layers with-NH_(2) groups covered on nano-Si surfaces are demonstrated to be beneficial to the prelithiation process by density functional theory calculations and electrochemical *** SEI formed under LHCE is proven to be rich in ionic conductivity,inorganic substances,and flexible organic ***,faster Li+transportation across the SEI further enhances the prelithiation effect and the rate performance of Si-SiO_(2)/C@G *** also leads to uniform decomposition and high stability of the SEI with abundant organic *** a result,the prepared anode shows a high reversible specific capacity of 937.5 mAh g^(-1)after 400 cycles at a current density of 1 *** 811‖Li-SSGLHCE full cell achieves a high-capacity retention of 126.15 mAh g^(-1)at 1 C over 750 cycles with 84.82%ICE,indicating the great value of this strategy for Si-based anodes in large-scale applications.

关键词： localized high-concentration electrolytes prelithiation SEI layer silicon anode

Complete blood and urine paraprotein tests as response assessments in multiple myeloma patients treated with bortezomib,cyclophosphamide,and dexamethasone

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chronic Diseases and Translational Medicine 2024年第1期10卷 62-68页

作者： Xialu Lan Fujing Zhang Chen yang Wei Su Jianhua Du Shuangjiao Liu Miao Chen Bing Han daobin Zhou Junling Zhuang Department of Hematology Peking Union Medical College HospitalChinese Academy of Medical SciencesBeijingChina Department of Pathology Sun Yat-sen University Cancer CenterState Key Laboratory of Oncology in South ChinaCollaborative Innovation Center for Cancer MedicineGuangzhouChina Department of Laboratory Medicine Peking Union Medical College HospitalChinese Academy of Medical SciencesBeijingChina

Background: This study assessed the effect of standardized efficacy markers on prognosis in patients with newly diagnosed multiple myeloma(MM)during the induction phase of treatment with bortezomib,cyclophosphamide,and dexamethasone(BCD).Methods :We retrospectively analyzed clinical data in 197 newly diagnosed MM patients treated with BCD as front-line regimen at Peking Union Medical College Hospital from January 1,2013 to December 31,***: There were 107 patients with International Staging System(ISS)III and 51 with paraprotein of light *** these,77 completed nine cycles of the BCD *** the number of treatment cycles increased,the proportions of serum and urine immunofixation electrophoresis(IFE)tests elevated from 40.39%to 62.22%and 16.75%to 37.78%,*** than 90%of intact immunoglobulin chain MM patients were evaluated for blood M protein per cycle,but that of urinary M protein was less than 60%.The detection rate of urinary M protein in light chain MM was more than 70%per *** with a very good partial response(VGPR)had longer progression-free survival(PFS)than those with uncertain VGPR(32 vs.26 months,p=0.0336).Of the 141 patients who completed at least four cycles without undergoing autologous hematopoietic stem cell transplantation,those who were regularly assessed at every other cycle showed more favorable PFS than those who visited irregularly(27 vs.22 months,p=0.059).Conclusion: Urinary M protein detection rate is significantly lower than that in serum,leading to an overestimation of efficacy,premature reduction of treatment intensity,and shortened *** response assessments are critical to treatment decisions and clinical diagnoses.

关键词： bortezomib light chain subtype multiple myeloma response assessment

Microscopic and spectroscopic analysis of atmospheric iron-containing single particles in Lhasa,Tibet

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2024年第7期141卷 40-50页

作者： Junyu Chen daobin Zhang Yiran Fu Jinhu Wang Xiaomei Cui Ci-ren Qu-zong Qiangying Zhang Chan Jin Bu Duo School of Ecology and Environment Tibet UniversityLhasa 850000China Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China Institute of Tibetan Plateau Research Chinese Academy of SciencesBeijing 100101China

The Tibetan Plateau,known as the“Third Pole”,is currently in a state of perturbation caused by intensified human *** this study,56 samples were obtained at the five sampling sites in typical area of Lhasa city and their physical and chemical properties were investigated by TEM/EDS,STXM,and NEXAFS *** careful examination of 3387single particles,the results showed that Fe should be one of the most frequent metal *** Fe-containing single particles in irregular shape and micrometer size was about7.8%and might be mainly from local ***,the Fe was located on the subsurface of single particles and might be existed in the form of iron ***,the core-shell structure of iron-containing particles were about 38.8%and might be present as single-,dual-or triple-core shell structure and multi-core shell structure with the Fe/Si ratios of 17.5,10.5,2.9 and 1.2,***,iron and manganese were found to coexist with identical distributions in the single particles,which might induce a synergistic effect between iron and manganese in catalytic ***,the solid spherical structure of Fe-containing particles without an external layer were about 53.4%.The elements of Fe and Mn were co-existed,and might be presented as iron oxide-manganese oxide-silica ***,the ferrous and ferric forms of iron might be *** information can be valuable in expanding our understanding of Fe-containing particles in the Tibetan Plateau atmosphere.

关键词： Fe-containing single particle Irregular shape Core-shell structure Solid spherical structure Transmission electron microscopy Synchrotron X-ray microscopy

Lithiophilic Li-Si alloy-solid electrolyte interface enabled by high-concentration dual salt-reinforced quasi-solid-state electrolyte

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第8期95卷 216-230,I0005页

作者： Yuanxing Zhang Ling Zhang Zhiguang Zhao Yuxiang Zhang Jingwen Cui Chengcai Liu daobin Mu Yuefeng Su Borong Wu Feng Wu School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Chongqing Innovation Center Beijing Institute of TechnologyChongqing 401120China Collaborative Innovation Center of Electric Vehicles in Beijing Beijing 100081China

Solid polymer electrolytes(SPEs)are urgently required to achieve practical solid-state lithium metal batteries(LMBs)and lithium-ion batteries(LIBs),Herein,we proposed a mechanism for modulating interfacial conduction and anode interfaces in high-concentration SPEs by *** electrolyte exhibits superior ionic conductivity and remarkable interface compatibility with salt-rich clusters:(1)polymer-plastic crystal electrolyte(P-PCE,TPU-SN matrix)dissociates ion pairs to facilitate Li+transport in the electrolyte and regulates Li^(+)diffusion in the *** crosslinking structure of the matrix compensates for the loss of mechanical strength at high-salt concentrations;(2)dual-anion TFSI^(-)_(n)-DFBOP^(-)_(m)in the Li^(+)solvation sheath facilitates facile Li^(+)desolvation and formation of salt-rich clusters and is conducive to the formation of Li conductive segments of TPU-SN matrix;(3)theoretical calculations indicate that the decomposition products of LiDFBOP form SEI with lower binding energy with LiF in the SN system,thereby enhancing the interfacial electrochemical redox kinetics of SPE and creating a solid interface SEI layer rich in *** a result,the optimized electrolyte exhibits an excellent ionic conductivity of9.31×10^(-4)S cm^(-1)at 30℃and a broadened electrochemical stability up to 4.73 *** designed electrolyte effectively prevents the formation of Li dendrites in Li symmetric cells for over 6500 h at0.1 mA cm^(-2).The specific Li-Si alloy-solid state half-cell capacity shows 711.6 mAh g^(-1)after 60 cycles at 0.3 A g^(-1).Excellent rate performance and cycling stability are achieved for these solid-state batteries with Li-Si alloy anodes and NCM 811 *** 811‖Prelithiated silicon-based anode solid-state cell delivers a discharge capacity of 195.55 mAh g^(-1)and a capacity retention of 97.8%after 120 *** 811‖Li solid-state cell also delivers capacity retention of 84.2%after 450 cycles.

关键词： Prelithiation Li-Si alloy anode Solid-state electrolyte SEI layer

在线全文

学校读者我要写书评

暂无评论

细长轴工件切削颤振的研究

现代制造工程 2012年第12期 13-16页

作者：杨道斌王民费仁元国家知识产权局专利局专利审查协作北京中心北京100190 北京工业大学机电学院北京100124

对细长轴工件切削加工中的颤振效应进行分析,通过激振实验,对细长轴工件切削系统的主切削抗力方向的动态特性进行实验研究,得出结论:细长轴工件使得整个切削系统的一阶固有频率降低,二阶固有频率提高。综合考虑,整个切削系统建立了两自... 详细信息

对细长轴工件切削加工中的颤振效应进行分析,通过激振实验,对细长轴工件切削系统的主切削抗力方向的动态特性进行实验研究,得出结论:细长轴工件使得整个切削系统的一阶固有频率降低,二阶固有频率提高。综合考虑,整个切削系统建立了两自由度模型,分析了细长轴工件切削系统的切削颤振以及稳定性条件。

关键词：细长轴工件切削系统动态特性颤振稳定性

Coupling of BiOCl Ultrathin Nanosheets with Carbon Quantum Dots for Enhanced Photocatalytic Performance

在线全文

学校读者我要写书评

暂无评论

Transactions of Tianjin University 2024年第3期30卷 211-220页

作者： Pin Song Xiaoyu Fang Wei Jiang Yuyang Cao daobin Liu Shiqiang Wei Jun Du Lang Sun Lei Zhao Song Liu Yuzhu Zhou Jun Di Chade Lv Bijun Tang Jiefu yang Tingting Kong Yujie Xiong Key Laboratory of Functional Molecular Solids Ministry of EducationAnhui Engineering Research Center of Carbon NeutralityCollege of Chemistry and Materials ScienceAnhui Normal UniversityWuhu 241000China National Synchrotron Radiation Laboratory CAS Center for Excellence in NanoscienceSchool of Chemistry and Materials ScienceUniversity of Science and Technology of ChinaHefei 230029China School of Chemistry and Chemical Engineering National Special Superfi ne Powder Engineering Research CenterNanjing University of Science and TechnologyNanjing 210094China MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001China School of Materials Science&Engineering Nanyang Technological UniversitySingapore 639798Singapore

Over the past few decades,photocatalysis technology has received extensive attention because of its potential to mitigate or solve energy and environmental pollution *** novel materials with outstanding photocatalytic activities has become a research hotspot in this *** this study,we prepared a series of photocatalysts in which BiOCl nanosheets were modified with carbon quantum dots(CQDs)to form CQDs/BiOCl composites by using a simple solvothermal *** photocatalytic performance of the resulting CQDs/BiOCl composite photocatalysts was assessed by rhodamine B and tetracycline degradation under visible-light *** with bare BiOCl,the photocatalytic activity of the CQDs/BiOCl composites was significantly enhanced,and the 5 wt%CQDs/BiOCl composite exhibited the highest photocatalytic activity with a degradation efficiency of 94.5%after 30 min of ***,photocatalytic N_(2)reduction performance was significantly improved after introducing *** 5 wt%CQDs/BiOCl composite displayed the highest photocatalytic N_(2)reduction performance to yield NH_3(346.25μmol/(g h)),which is significantly higher than those of 3 wt%CQDs/BiOCl(256.04μmol/(g h)),7 wt%CQDs/BiOCl(254.07μmol/(g h)),and bare BiOCl(240.19μmol/(g h)).Our systematic characterizations revealed that the key role of CQDs in improving photocatalytic performance is due to their increased light harvesting capacity,remarkable electron transfer ability,and higher photocatalytic activity sites.

关键词： Carbon quantum dots BiOCl Rhodamine B Tetracycline Photocatalysis