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Ideal Bi-Based Hybrid Anode Material for Ultrafast Charging of Sodium-Ion Batteries at Extremely Low Temperatures

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NANO-MICRO LETTERS 2025年第1期17卷 1-16页

作者： Bai, Jie Jia, jian Hui Wang, Yu Yang, Chun cheng jiang, Qing Jilin Univ Key Lab Automobile Mat Sch Mat Sci & Engn Minist Educ Changchun 130022 Peoples R China

Metallic nanoparticles with excellent size controllability and high loading rate are obtained via ultrafast high temperature shock *** Bi/CNRs-15 electrode exhibits an unprecedented rate performance (237.9 mAh g-1 at 2 A g-1) at - 60 degrees C, while the energy density of the full cell can reach to 181.9 Wh kg-1 at - 40 degrees C.A novel strategy of high-rate activation is proposed to obtain high capacity and superior stability at low temperature by creating new active sites for interfacial reaction. Sodium-ion batteries have emerged as competitive substitutes for low-temperature applications due to severe capacity loss and safety concerns of lithium-ion batteries at - 20 degrees C or lower. However, the key capability of ultrafast charging at ultralow temperature for SIBs is rarely reported. Herein, a hybrid of Bi nanoparticles embedded in carbon nanorods is demonstrated as an ideal material to address this issue, which is synthesized via a high temperature shock method. Such a hybrid shows an unprecedented rate performance (237.9 mAh g-1 at 2 A g-1) at - 60 degrees C, outperforming all reported SIB anode materials. Coupled with a Na3V2(PO4)3 cathode, the energy density of the full cell can reach to 181.9 Wh kg-1 at - 40 degrees C. Based on this work, a novel strategy of high-rate activation is proposed to enhance performances of Bi-based materials in cryogenic conditions by creating new active sites for interfacial reaction under large current.

关键词： Bi nanoparticles High temperature shock High-rate activation Ultrafast charging Low-temperature sodium-ion batteries

Observation of topological charge transformations in acoustic vortex using passive periodic systems

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 140-147页

作者： Di-Chao Chen Xie Liu Changqing Xu Da-jian Wu Ying cheng Xiao-Jun Liu School of Physics and Technology Nanjing Normal University Key Laboratory of Modern Acoustics School of Physics Nanjing University

Vortex transmutation utilizes a periodic system, which not only enables the alteration of the topological charge(TC) of unstable input vortices but also facilitates their transformation into stable structures. This approach is crucial for investigating the characteristics of vortices in various wave systems. Here, we achieve acoustic vortex TC transmutation by employing a welldesigned dual-structured plate external system(DPES). The interactions between the acoustic vortex and the finite-order discrete rotational symmetry lead to the transformation of its topological charge when complete rotational symmetry is broken to Nthorder discrete symmetry. Our results experimentally demonstrate the acoustic vortex TC transmutation based on passive artificial structures, enabling numerous applications in particle manipulation and information multiplexing as well as advancing our understanding and control over free-space acoustic vortices.

关键词： acoustic vortex topological charge transformation artificial structure

Dielectric-ion-conductive ZnNb2O6 layer enabling rapid desolvation and diffusion for dendrite-free Zn metal batteries

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Journal of Energy Chemistry 2025年第1期100卷 693-701页

作者： Haifeng Yang jian Wang Panpan Zhang Xiaomin cheng Qinghua Guan Jing Dong Bixian Chen Lujie Jia Jing Zhang Yongzheng Zhang Yunjian Liu Hongzhen Lin School of Materials Science and Engineering Jiangsu University i-Lab & CAS Key Laboratory of Nanophotonic Materials and Devices Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of Sciences Helmholtz Institute Ulm (HIU) Karlsruhe Institute of Technology (KIT) School of Materials Science and Engineering Xi'an University of Technology State Key Laboratory of Chemical Engineering East China University of Science and Technology

Rechargeable aqueous zinc-metal batteries （AZMBs） are promising candidates for large-scale energy storage systems due to their low cost and high ***,their performance and sustainability are significantly hindered by the sluggish desolvation kinetics at the electrode/electrolyte interface and the corresponding hydrogen evolution reaction where active water molecules tightly participate in the Zn（H2O）62+solvation ***,learnt from self-generated solid electrolyte interphase （SEI） in anodes,the dielectric but ion-conductive zinc niobate nanoparticles artificial layer is constructed on metallic Zn surface （ZNB@Zn）,acting as a rapid desolvation *** zincophilic and dielectric-conductive properties of ZNB layer accelerate interfacial desolvation/diffusion and suppress surface corrosion or dendrite formation,achieving uniform Zn plating/stripping behavior,as confirmed by electronic/optical microscopies and interface spectroscopical measurements together with theoretical ***,the as-prepared ZNB@Zn electrode exhibits excellent cycling stability of over 2000 h and robust reversibility （99.54%） even under high current density and depth of discharge ***,the assembled ZNB@Zn-based full cell displays high capacity-retention rate of 80.21%after 3000 cycles at 5 A g-1and outstanding rate performance up to 10 A *** large-areal pouch cell is stabilized for hundreds of cycles,highlighting the bright prospects of the dielectric but ion-conductive layer in further application of AZMBs.

关键词： Zn metal battery Dielectric artificial layer Rapid ion diffusion Zincophilic diffusion Active water inhibition

Marginal-restraint mandrel-free spinning process for thin-walled ellipsoidal heads

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Advances in Manufacturing 2020年第2期8卷 189-203页

作者： Yong-cheng Lin Jia-Yang Chen dao-Guang He Xin-He Li jian Yang School of Mechanical and Electrical Engineering Central South UniversityChangsha 410083People's Republic of China State Key Laboratory of High Performance Complex Manufacturing Changsha 410083People's Republic of China Light Alloy Research Institute Central South UniversityChangsha 410083People's Republic of China

Metal sheet spinning is an advanced near-net forming technology for the manufacture of thin-walled ellipsoidal *** exact control of dimensional accuracy,however,is a considerable problem for spinning thinwalled parts with large diameter-to-thickness *** this work,a marginal restraint mandrel-free spinning process with two passes is proposed for the fabrication of thinwalled ellipsoidal heads without wrinkling.A finite element model is established and verified to study the influences of spinning parameters on the dimensional precision of thin-walled ellipsoidal *** is found that the spinning parameters considerably influence the deviations of wall thickness and contour characteristics.A small forming angle or small roller fillet radius during the first pass spining,as well as the small angle between passes or high feed ratio during the second pass spinning,can improve the wall thickness ***,as the forming angle or feed ratio is increased during the first pass spinning,the contour precision initially increases and then *** the second pass spinning,the contour precision can be improved at a small angle between passes,whereas it deteriorates at a larger roller installation *** optimized spinning parameters are obtained and verified by experiments.

关键词： Alloy Thin-walled ellipsoidal heads Spinning Finite element model Dimensional precision

Resistance of Cement-based Grouting Materials with Nano-SiO2 Emulsion to Chloride Ion Penetration

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期 114-119页

作者：黎水平 cheng jian WEI Chao YUAN Bin YU chengxiao College of Architectural Science and Engineering Yangzhou University

The chloride penetration resistance of cement-based grout materials was improved by nano-silica *** of mixtures containing different nano-silica particles or emulsions were exposed in sodium chloride solutions of specific concentrations with different test *** properties of the mixes were assessed in terms of weight loss and compressive strength.X-ray diffraction （XRD） and scanning electron microscopy （SEM） of mixes were performed to analysis the phase evolution and *** results demonstrated that the introduction of nano-SiO2emulsion significantly decreased the compressive strength loss and calcium hydroxide （CH） crystal content of hydration production,and then enhanced the resistance of cement-based grouting materials to chloride ion *** improvement derives from the filling and pozzolanic effects of nano-SiO2particles,which were incorporated via an emulsion and attributed to a well dispersion in grouting matrix.

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Molecular simulation study of the microstructures and properties of pyridinium ionic liquid[HPy][BF_(4)]mixed with acetonitrile

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原子与分子物理学报 2025年第4期42卷 27-32页

作者： XU jian-Qiang MA Zhao-Peng cheng Si LIU Zhi-Cong ZHU Guang-Lai Department of Physics School of Physics and Electronic InformationAnhui Normal UniversityWuhu 241002China

The microstructures and thermodynamic properties of mixed systems comprising pyridinium ionic liquid[HPy][BF_(4)]and acetonitrile at different mole fractions were studied using molecular dynamics simulation in this *** following properties were determined:density,self-diffusion coefficient,excess molar volume,and radial distribution *** results show that with an increase in the mole fraction of[HPy][BF_(4)],the self-diffusion coefficient ***,the excess molar volume initially decreases,reaches a minimum,and then *** rules of radial distribution functions(RDFs)of characteristic atoms are *** increasing the mole fraction of[HPy][BF_(4)],the first peak of the RDFs of HA1-F decreases,while that of CT6-CT6 rises at first and then *** indicates that the solvent molecules affect the polar and non-polar regions of[HPy][BF_(4)]differently.

关键词： Pyridinium ionic liquids Thermodynamic properties Molecular dynamics simulation Radial distribution functions

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Chinese Chemical Letters 2024年第8期35卷 25-35页

作者： Yatian Deng dao Wang Jinglan cheng Yunkun Zhao Zongbao Li Chunyan Zang jian Li Lichao Jia School of Materials Science and Engineering State Key Lab of Material Processing and Die&Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074China College of Science Qiongtai Normal UniversityHaikou 571127China Kunming Sino-Platinum Metals Catalyst Co. Ltd.Kunming 650106China State Key Laboratory of Advanced Electromagnetic Technology Huazhong University of Science and TechnologyWuhan 430074China

Catalyst with high performance has drawn increasing attention recently due to its significant advantages in chemical reactions such as speeding up the reaction,lowering the reaction temperature or pressure,and proceeding without itself being *** the superior catalytic performance of precious metal catalysts,transition metal oxides offer a promising route for substitution of precious metals in catalysis arising from their low cost,intrinsic activity and sufficient ***-type oxide SmMn_(2)O_(5) exhibits a unique crystal structure containing double crystalline fields,and nowadays is used widely as the catalyst in different chemical reactions,including the reactions of vehicle emissions reduction and oxygen evolution reaction,gas sensors,and metal-air batteries,promoting attention in catalytic perfor-mance *** our knowledge,there is no review article covering the comprehensive informa-tion of SmMn2 O 5 and its *** we review the recent progress in understanding of the crys-tal structure of SmMn_(2)O_(5) and its basic physical *** then summarize the catalytic sources of SmMn_(2)O_(5) and reaction mechanisms,while the strategies to improve catalytic performance of SmMn_(2)O_(5) are further ***,we provide a perspective on how to make further progress in catalytic applications.

关键词： Catalyst SmMn_(2)O_(5) Mullite-type oxide Catalytic oxidation Oxygen reduction reaction Oxygen evolution reaction Reaction mechanisms

Antitumor Effects of Ethanol Extract from Ventilago leiocarpa Benth on Sarcoma 180 Tumor-Bearing Mice and Possible Immune Mechanism

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Chinese Journal of Integrative Medicine 2021年第12期27卷 905-911页

作者： cheng dao-Hai LIU Ying WANG Li Department of Pharmacy First Affiliated Hospital of Guangxi Medical UniversityNanning(530021)China Department of Pharmacology Guangxi Institute of Chinese Medicine&Pharmaceutical ScienceNanning(530022)China Guangxi Key Laboratory of Traditional Chinese Medicine Quality Standards Nanning(530022)China

Objective To explore the antitumor effects of ethanol extract from Ventilago leiocarpa Benth(EEVLB)on sarcoma 180(S180)tumor-bearing mice and the potential *** Sixty mice were randomly assigned to 6 groups according to a random number table:normal group,model group,5-fluorouracil(5-FU)group(0.02 g·kg^(−1)),and high-,medium-,low-dose EEVLB groups(100,84,and 56 g of raw material·kg^(−1)body weight,respectively),with 10 mice each *** treatments were given once daily for 10 consecutive *** of EEVLB on inhibiting tumor growth and immune function in mice were evaluated among all groups after the treatments by detecting tumor inhibition rate,organ index,serum levels of interleukin(IL)-2,-6,-10,CD3^(+)CD4^(+)T lymphocytes,CD4^(+)/CD8^(+)ratio,caspase-3 and *** EEVLB with different concentrations achieved inhibition of tumor growth in vivo,wherein the high-dose group showed the most significant reduction in tumor weight and increased apoptosis of tumor cells(P<0.05).In addition,both net weight gain and spleen index of mice showed uptrend in EEVLB treatment groups(P<0.05).Besides,serum levels of IL-2 and IL-6,percentages of CD3^(+)CD4^(+)T lymphocytes and ratio of CD4^(+)/CD8^(+)in peripheral blood were elevated in high-and medium-dose EEVLB groups compared with the model group(P<0.05).Also,upregulation of caspase-3 and downregulation of Bcl-2 were observed at protein levels in the high-dose EEVLB group(P<0.01).Conclusions EEVLB exhibits promising antitumor activity in *** effect might be due to activation of apoptotic signaling pathway,increase of cytokine levels and enhancement of immune function in tumor-bearing mice.

关键词： Ventilago leiocarpa Benth Chinese folk medicine Yao medicine antitumor effect immune function caspase-3 Bcl-2

Performance of Gaussian waveform in OvTDM

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The Journal of China Universities of Posts and Telecommunications 2009年第1期16卷 32-37页

作者： YANG Xun WANG jian LI dao-ben Key Laboratory of Information Processing and Intelligent Technology Beijing University of Posts and Telecommunications Beijing 100876 China

Waveforms play a key role in overlapping time division multiplexing （OvTDM） system. The OvTDM has been proved to be a novel transmission technique that can utilize time diversity to improve the bit error ratio （BER） performance in Rayleigh channel. According to the resulted law, the BER performance of Gaussian waveform in OvTDM also improves with the increase in the waveform parameter monotonically, and the rectangular waveform is the worst case of Gaussian waveform. In contrast, the spectrum effectiveness of Gaussian waveform OvTDM decreases with the increase in the waveform parameter. In the study, it is obtained that waveforms can achieve the best performance when the smallest correlation coefficient between neighbor symbols is e^-1 .

关键词： OvTDM inter symbol interference (ISI) Gaussian waveform rectangular waveforrn BER spectrum effectiveness