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Exploration of Strong Metal-Support Interaction in Heterogeneous Catalysts by in situ Transmission Electron Microscopy

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Chinese Journal of Chemistry 2024年第9期42卷 1004-1008页

作者： Yongjun Jiang Sheng dai Key Laboratoryfor Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center Institute of Fine ChemicalsSchool of Chemistry&Molecular EngineeringEast China Universityof Science and TechnologyShanghai 200237China

The phenomenon of strong metal-support interaction(SMSI)observed in supported metal catalysts,usually accompanied by the formation of the encapsulation layer on metal nanoparticles,has attracted extensive research attention due to its significance in heterogeneous ***,great progress has been made in recent years in investigating SMSI by in situ transmission electron microscopy(TEM),along with an enhanced comprehension of the underlying mechanisms governing SMSI *** emerging topic summarizes recent progress utilizing in situ TEM to study the interaction between metal and support and the relationship between the structure and performance of the supported catalyst under reaction conditions.A brief perspective about the use of in situ TEM for further study of SMSI is also presented,showing prospects in this field that will stimulate further upsurging research in promoting the catalytic efficiency of supported catalysts.

关键词： Heterogeneous catalysis In situ TEM Strong metal-support interaction Structure changes Interfaces Structural evolution

On-demand molecular design for efficient blue phosphorescence

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Science China Chemistry 2024年第7期67卷 2124-2126页

作者： Meiqi dai Dongpeng Yan Beijing Key Laboratory of Energy Conversion and Storage Materials Key Laboratory of RadiopharmaceuticalsMinistry of EducationCollege of ChemistryBeijing Normal UniversityBeijing 100875China

Blue luminescence(including both fluorescence and phosphorescence)is one of the core elements in solid-state lighting and full-color *** to now,ultralong room temperature phosphorescence(RTP)with a long lifetime over 0.1 s has been continuously *** ultralong phosphorescence emission bands are in the region of 500 to600 ***,high-energy blue phosphorescence remains an immense challenge[1].

关键词： blue lifetime bands

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Study on the optimal incident proton energy of ^(7)Li(p,n)^(7)Be neutron source for boron neutron capture therapy

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Nuclear Science and Techniques 2024年第3期35卷 170-180页

作者： Yi-Nan Zhu Zuo-Kang Lin Hai-Yan Yu Ye dai Zhi-Min dai Xiao-Han Yu Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Science Beijing 100049China

Boron neutron capture therapy(BNCT)is recognized as a precise binary targeted radiotherapy technique that effectively eliminates tumors through the^(10)B(n,α)^(7)Li nuclear *** various neutron sources,accelerator-based sources have emerged as particularly promising for BNCT ***^(7)Li(p,n)^(7)Be reaction is highly regarded as a potential neutron source for BNCT,owing to its low threshold energy for the reaction,significant neutron yield,appropriate average neutron energy,and additional *** study utilized Monte Carlo simulations to model the physical interactions within a lithium target subjected to proton bombardment,including neutron moderation by an MgF_(2)moderator and subsequent BNCT dose analysis using a Snyder head *** study focused on calculating the yields of epithermal neutrons for various incident proton energies,finding an optimal energy at 2.7 ***,the Snyder head phantom was employed in dose simulations to validate the effectiveness of this specific incident energy when utilizing a^(7)Li(p,n)^(7)Be neutron source for BNCT purposes.

关键词： Boron neutron capture therapy ^(7)Li(p,n)7Be neutron source Incident proton energy Monte Carlo simulation

SEMI-PROXIMAL POINT METHOD FOR NONSMOOTH CONVEX-CONCAVE MINIMAX OPTIMIZATION

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Journal of Computational Mathematics 2024年第3期42卷 617-637页

作者： Yuhong dai Jiani Wang Liwei Zhang LSEC ICMSECAMSSChinese Academy of SciencesBeijing 100190China School of Mathematical SciencesUniversity of Chinese Academy of SciencesBeijing 100049China Academy of Mathematics and Systems Science Chinese Academy of SciencesBeijing 100190China School of Mathematical Sciences Dalian University of TechnologyDalian 116024China

Minimax optimization problems are an important class of optimization problems arising from modern machine learning and traditional research *** there have been many numerical algorithms for solving smooth convex-concave minimax problems,numerical algorithms for nonsmooth convex-concave minimax problems are *** paper aims to develop an efficient numerical algorithm for a structured nonsmooth convex-concave minimax problem.A semi-proximal point method(SPP)is proposed,in which a quadratic convex-concave function is adopted for approximating the smooth part of the objective function and semi-proximal terms are added in each *** construction enables the subproblems at each iteration are solvable and even easily solved when the semiproximal terms are cleverly *** prove the global convergence of our algorithm under mild assumptions,without requiring strong convexity-concavity *** the locally metrical subregularity of the solution mapping,we prove that our algorithm has the linear rate of *** numerical results are reported to verify the efficiency of our algorithm.

关键词： Minimax optimization Convexity-concavity Global convergence Rate of con-vergence Locally metrical subregularity

Rockburst criterion and evaluation method for potential rockburst pit depth considering excavation damage effect

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第5期16卷 1649-1666页

作者： Jinhao dai Fengqiang Gong Lei Xu Engineering Research Center of Safety and Protection of Explosion & Impact of Ministry of Education (ERCSPEIME) Southeast UniversityNanjing211189China School of Civil Engineering Southeast UniversityNanjing211189China

Excavation-induced disturbances in deep tunnels will lead to deterioration of rock properties and formation of excavation damaged zone(EDZ).This excavation damage effect may affect the potential rockburst pit *** two diversion tunnels of Jinping II hydropower station for example,the relationship between rockburst pit depth and excavation damage effect is first *** results indicate that the rockburst pit depth in tunnels with severe damage to rock masses is relatively ***,the excavation-induced damage effect is characterized by disturbance factor D based on the Hoek-Brown criterion and wave velocity *** is found that the EDZ could be further divided into a high-damage zone(HDZ)with D=1 and weak-damage zone(WDZ),and D decays from one to zero *** this,a quantitative evaluation method for potential rockburst pit depth is established by presenting a three-element rockburst criterion considering rock strength,geostress and disturbance *** evaluation results obtained by this method match well with actual *** addition,the weakening of rock mass strength promotes the formation and expansion of potential rockburst *** potential rockburst pit depth is positively correlated with HDZ and WDZ depths,and the HDZ depth has a significant contribution to the potential rockburst pit depth.

关键词： Deep tunnel Rockburst Rockburst pit Excavation damage effect Hoek-Brown criterion

The Influence of the Sun and Moon on the Observation of Very High Energy Gamma-ray Sources Using EAS Arrays

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Research in Astronomy and Astrophysics 2024年第6期24卷 245-252页

作者： Tao Wen Songzhan Chen Benzhong dai School of Physics and Astronomy Yunnan UniversityKunming 650091China Key Laboratory of Particle Astrophysics Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China Tianfu Cosmic Ray Research Center Chengdu 610000China

With great advance of ground-based extensive air shower arrays,such as LHAASO and HAWC,many very high energy(VHE)gamma-ray sources have been discovered and are being monitored regardless of the day and the ***,the Sun and Moon would have some impacts on the observation of gamma-ray sources,which have not been taken into account in previous *** this paper,the influence of the Sun and Moon on the observation of very high energy gamma-ray sources when they are near the line of sight of the Sun or Moon is *** tracks of all the known VHE sources are scanned and several VHE sources are found to be very close to the line of sight of the Sun or Moon during some *** absorption of very high energy gamma rays by sunlight is estimated with detailed method and some useful conclusions are *** main influence is the block of the Sun and Moon on gamma rays and the shadow on the cosmic ray *** influence is investigated considering the detector angular resolution and some strategies on data analysis are proposed to avoid the underestimation of the gamma-ray emission.

关键词： astroparticle physics Sun:general methods:observational Sun:UV radiation

Reduction of unactivated alkyl chlorides enabled by light-induced single electron transfer

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Science China Chemistry 2024年第2期67卷 471-481页

作者： Lei dai Zhao-Fei Zhang Xiang-Yu Chen School of Chemical Sciences University of the Chinese Academy of SciencesBeijing100049China Institute of Chemistry Chinese Academy of SciencesBeijing100190China Binzhou Institute of Technology Weiqiao-UCAS Science and Technology ParkBinzhou256606China

Alkyl chlorides are abundant and easily accessible starting ***,due to the high reduction potentials associated with unactivated alkyl chlorides,achieving their single electron reduction remains a persistent *** challenge has spurred the exploration of efficient activation methods to overcome this *** recent years,photocatalysis has emerged as a mild and potent tool for the single electron reduction of unactivated alkyl chlorides,opening up new possibilities in this *** the rapid advancements in this area,a comprehensive review that provides a conceptual understanding of this emerging field,with a specific focus on reaction design and catalytic mechanisms,would be timely and highly ***,we present an overview of various synthetic techniques for photoinduced single electron reduction of unactivated alkyl ***,we also discuss the limitations of the present methods and future directions that lie ahead in this field.

关键词： photocatalysis unactivated alkyl chlorides single electron transfer radical reactions

Study on a conical bearing for acceleration-sensitive equipment

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Earthquake Engineering and Engineering Vibration 2024年第1期23卷 103-128页

作者： Pang Hui Xu Wen dai Junwu Jiang Tao Key Laboratory of Earthquake Engineering and Engineering Vibration Institute of Engineering MechanicsChina Earthquake AdministrationHarbin 150080China Key Laboratory of Earthquake Disaster Mitigation Ministry of Emergency ManagementHarbin 150080China School of Civil Engineering and Transportation Beihua UniversityJilin 132013China

Seismic isolation effectively reduces seismic demands on building structures by isolating the superstructure from ground vibrations during ***,isolation strategies give less attention to acceleration-sensitive systems or ***,as the isolation layer’s displacement grows,the stiffness and frequency of traditional rolling and sliding isolation bearings increases,potentially causing self-centering and resonance *** a result,a new conical pendulum bearing has been selected for acceleration-sensitive equipment to increase self-centering capacity,and additional viscous dampers are incorporated to enhance system ***,the theoretical formula for conical pendulum bearings is supplied to analyze the device’s dynamic parameters,and shake table experiments are used to determine the proposed device’s isolation efficiency under various *** to the test results,the newly proposed devices have remarkable isolation performance in terms of minimizing both acceleration and displacement ***,a numerical model of the isolation system is provided for further research,and the accuracy is demonstrated by the aforementioned experiments.

关键词： seismic isolation acceleration-sensitive equipment the conical pendulum bearing shake table tests isolation performance,numerical model

Prenatal cadmium exposure impairs neural tube closure via inducing excessive apoptosis in neuroepithelium

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Journal of Environmental Sciences 2024年第4期138卷 572-584页

作者： Shiyong Zhu Xuenan Li Xueyan dai Jinlong Li College of Veterinary Medicine Northeast Agricultural UniversityHarbin 150030China Key Laboratory of the Provincial Education Department of Heilongjiang for Common Animal Disease Prevention and Treatment Northeast Agricultural UniversityHarbin 150030China Heilongjiang Key Laboratory for Laboratory Animals and Comparative Medicine Northeast Agricultural UniversityHarbin 150030China

Birth defects have become a public health *** hazardous environmental factors exposure to embryos could increase the risk of birth ***,a toxic environmental factor,can cross the placental barrier during *** woman may be subjected to cadmium before taking precautionary protective ***,the link between birth defects and cadmium remains *** exposure can induce excessive apoptosis in neuroepithelium during embryonic development *** exposure activated the p53 via enhancing the adenosine 5‘-monophosphate(AMP)-activated protein kinase(AMPK)and reactive oxygen species'(ROS)*** cadmium decreases the level of Paired box 3(Pax3)and murine double minute 2(Mdm2),disrupting the process of p53 *** p53 accumulation induced excessive apoptosis in neuroepithelium during embryonic development *** apoptosis led to the failure of neural tube *** study emphasizes that environmental materials may increase the health risk for *** caused the failure of neural tube closure during early embryotic *** women may be exposed by cadmium before taking precautionary protective actions,because of cadmium concentration-containing foods and environmental tobacco *** suggests that prenatal cadmium exposure is a threatening risk factor for birth defects.

关键词： Cadmium Neural tube closure Excessive apoptosis p53 Embryogenesis