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Vanadium mineralization at Los Chihuidos sediment-hosted Cu-V deposit,Neuquén basin,Argentina:An approach to vanadium ore forming processes

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Geoscience Frontiers 2024年第1期15卷 225-246页

作者： Ana L.Rainoldi daniel beaufort Marta b.Franchini Adolfo Giusiano Sabine Petit Patricia Patrier M.Josefina Pons Dpto.de Geología Universidad Nacional del Sur(UNS)8000 Bahía BlancaArgentina Consejo Nacional de Investigaciones Científicas y Técnicas Centro Patagónico de Estudios MetalogenéticosArgentina Universitéde Poitiers IC2MPCNRS-UMR 7285HydrasaF-86022 Poitiers CedexFrance Universidad Nacional del Comahue Facultad de IngenieríaDepartamento de Geología y Petróleo8300 NeuquénArgentina Consultant Geologist 8300 NeuquénArgentina Universidad Nacional de Río Negro Instituto de Investigación en Paleobiología y GeologíaRío NegroArgentina

Vanadium mineralization at Los Chihuidos deposit of the Neuquén basin is linked to the development of a redox front system related to the inflow of hydrocarbons into the red sandstone of the Huincul *** of hydrocarbons with oxidized red beds and connate water generated redox reactions where hematite was dissolved due to iron reduction resulting in the discoloration of the red *** the contact between oxidized red sandstone and reduced white sandstone,precipitation of specific mineral phases resulted in the V ore with minor amounts of *** the implementation of the redox interface,abundant V-montmorillonite and V-hematite precipitated at the more oxidizing conditions and Cu-V-corrensite-type at the more reducing conditions of the redox *** the redox front advanced with fluids constantly migrating into the reservoir,more reducing conditions were stablished,promoting chloritization and minor illitization with V-Cu incorporation and continuous upgrading of the *** ore mineralogy consists of clay minerals including V-bearing montmorillonite,Cu-V-corrensite-type,V-di-trioctahedral chlorite and Cu-tri-trioctahedral chlorite with minor V-illite-smectite mixed-layer minerals and associated secondary *** over illitization was favored due to high amounts of Fe and Mg in detrital clasts and in connate fluids and by low K availability related to low amounts of detrital *** spatial transition of V and/or Cu bearing clay minerals observed through the mineralized redox front at Los Chihuidos deposit(kaolinite→smectite→illite/smectite→corrensite-type→di-trioctahedral-chlorite→tri-trioctahedral-chlorite)and the related variation of V-Cu concentrations in bulk rock are indicative of increasing pH and decreasing Eh of resident solutions from red to white sandstones during the hypogene mineralization *** influx of Cu-rich oxidized basinal brines precipitated main copper ore with Cu-sulfides in the white sandst

关键词： Clay minerals V-chlorite Redox front bleaching Hydrocarbons

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Evaluation of a hepatic biomarker of nutritional imbalance in juvenile red drum(Sciaenops ocellatus) fed 60% soybean meal-based diets using NMR-based metabolomics

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Animal Nutrition 2024年第1期16卷 45-61页

作者： Fabio Casu Aaron M.Watson Justin Yost T.Gibson Gaylord daniel W.bearden Michael R.Denson Marine Resources Research Institute South Carolina Department of Natural Resources bozeman Fish Technology Center United States Fish and Wildlife Service Marine biochemical Sciences Group Chemical Sciences Division National Institute of Standards and Technology Hollings Marine Laboratory

A 12-week feeding trial with juvenile red drum(Sciaenops ocellatus) fed high-soybean meal(SbM) diets was conducted to investigate a putative biomarker of nutritional imbalance, N-formimino-L-glutamate(FIGLU). Three fishmeal-free, 60% SbM pelleted diets(named b12, Fol, and Met, respectively) were tested to evaluate the effects on growth performance and tissue metabolite profiles of supplementation of vitamin b12(0.012 mg/kg), folate(10 mg/kg), methionine(1 g/kg) respectively, above basal supplementation levels. A fourth SbM-based diet(named b12/Fol/Met) was formulated with a combination of b12, folate, and methionine to attain the above-mentioned target concentrations. A fifth 60% SbM diet(named FWS) with methionine supplementation(1 g/kg above basal supplementation levels), enriched with taurine, lysine and threonine as well as minerals, was also tested. This diet contained formulation targets and additives which have allowed for replacing fishmeal with plant proteins in rainbow trout feeds. Control diets included a fishmeal-based diet(named FM), an unsupplemented basal 60% SbM diet(named SbM60), and a “natural” diet(named N) made up of equal parts of fish(cigar minnows), squid and shrimp as a positive reference for growth performance. Formulated feeds contained approximately 37% total crude protein, approximately 14% total crude lipid and were energetically balanced. Standard growth performance metrics were measured, and tissues(liver, muscle) were collected at week 12 to evaluate diet-induced metabolic changes using nuclear magnetic resonance(NMR)-based *** results show that the FWS diet outperformed all other SbM diets and the FM diet under all performance metrics(Pbut was detected in those fed the SbM diets and the FM diet. Fish fed the FWS diet and the Met diet showed lower hepatic levels of FIGLU compared with the other SbM-based diets(P<0.05), suggesting that among the different supplementatio

关键词： Aquaculture Metabolomics Nuclear magnetic resonance Red drum Soybean meal N-Formimino-L-glutamate

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Utilizing semantic-level computer vision for fracture trace characterization of hard rock pillars in underground space

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Geoscience Frontiers 2024年第2期15卷 366-391页

作者： Chuanqi Li Jian Zhou daniel Dias Laboratory 3SR CNRS UMR 5521Grenoble Alpes UniversityGrenoble 38000France School of Resources and Safety Engineering Central South UniversityChangsha 410083China

This study utilizes a semantic-level computer vision-based detection to characterize fracture traces of hard rock pillars in underground *** trace images captured by photogrammetry are used to establish the database for training two convolutional neural network(CNN)-based models,i.e.,U-Net(University of Freiburg,Germany)and DeepLabV3+(Google,USA)*** code technology,polyline approximation algorithm,and the circular window scanning approach are combined to quantify the main characteristics of fracture traces on flat and uneven surfaces,including trace length,dip angle,density,and *** extraction results indicate that the CNN-based models have better performances than the edge detection methods-based Canny and Sobel operators for extracting the trace and reducing noise,especially the DeepLabV3+***,the quantization results further prove the reliability of extracting the fracture *** a result,a case study with two types of traces(i.e.,on flat and uneven surfaces)demonstrates that the applied semantic-level computer vision detection is an accurate and efficient approach for characterizing the fracture trace of hard rock pillars.

关键词： Fracture trace Hard rock pillar Semantic-level computer vision Convolutional neural network(CNN) Underground space

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Acetabular cup size trends in total hip arthroplasty

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World Journal of Orthopedics 2024年第1期15卷 39-44页

作者： daniel Patrick McKenna Alex Price Timothy McAleese Darren Dahly Paul McKenna May Cleary Department of Trauma and Orthopaedics University Hospital WaterfordWaterford X91 ER8EIreland Department of Epidemiology and Public Health University College CorkCork T12 XF62Ireland

bACKGROUND Total hip arthroplasty(THA)is a common procedure for end stage *** learning curve for THA is complex and *** of the most difficult skills to master is acetabular *** wish to identify if experience in arthroplasty leads to preservation of more bone *** To investigate if increasing surgeon experience will predict an ever decreasing acetabular cup *** A retrospective case series of four attending orthopaedic surgeons was *** uncemented elective total hip arthroplasties since appointment were selected for *** size of acetabular cup used was noted and logistic regression was used to identify if a trend to smaller cups *** A total of 1614 subjects were included with a mean age of 64 *** cups were on average 0.18mm smaller per year(95%confidence interval-0.25 to-0.11,Pb,0.15 mm/year for surgeon C and 0.29 mm/year for surgeon *** of the four surgeons had a more pronounced trend to smaller cups for male subjects than their female *** We found increasing surgeon experience to be associated with an ever-decreasing acetabular cup *** acetabular cup size may act as a surrogate marker of surgical proficiency by virtue of decreased acetabular reaming.

关键词： Hip Arthroplasty Acetabulum Cup Learning

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Tribologically induced nanostructural evolution of carbon materials: A new perspective

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Friction 2024年第1期12卷 144-163页

作者： Guilherme Oliveira NEVES Nicolás ARAYA Diego berti SALVARO Thiago de Souza LAMIM Renan Oss GIACOMELLI Cristiano bINDER Aloisio Nelmo KLEIN Josédaniel biasoli de MELLO Laboratório de Materiais Universidade Federal de Santa CatarinaSanta Catarina 88040-900Brazil Departamento de Ingeniería Mecánica Facultad de IngenieríaUniversidad del Bío-BíoConcepcion 4070-386Chile Universidad de Concepción Concepcion 4070-386Chile SENAI Innovation Institute for Laser Processing Santa Catarina 89218-153Brazil Universidade Federal de Uberlândia Minas Gerais 38408-100Brazil

Carbon-based solid lubricants are excellent options to reduce friction and wear,especially with the carbon capability to adopt different allotropes *** the macroscale,these materials are sheared on the contact along with debris and contaminants to form tribolayers that govern the tribosystem *** a recently developed advanced Raman analysis on the tribolayers,it was possible to quantify the contactinduced defects in the crystalline structure of a wide range of allotropes of carbon-based solid lubricants,from graphite and carbide-derived carbon particles to multi-layer graphene and carbon *** addition,these materials were tested under various dry sliding conditions,with different geometries,topographies,and solid-lubricant application *** of the initial tribosystem conditions and allotrope level of atomic ordering,there is a remarkable trend of increasing the point and line defects density until a specific saturation limit in the same order of magnitude for all the materials tested.

关键词： carbon nanostructures tribology Raman spectroscopy defects quantification tribolayer solid lubrication

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Evolution of heart transplant donor characteristics in the 21st century: A United States single center’s experience

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World Journal of Transplantation 2024年第3期14卷 22-29页

作者： Alexander M Spring Christiana Gjelaj Shivank Madan Snehal R Patel Omar Saeed Sandhya Murthy Yogita Rochlani daniel b sim. Sasha Vukelic Stephen J Forest Jamil F borgi daniel J Goldstein Ulrich P Jorde Montefiore-Einstein Center for Heart and Vascular Care Montefiore Medical CenterAlbert Einstein College of MedicineBronxNY 10467United States Division of Cardiothoracic Surgery Tulane UniversityNew OrleansLA 70112United States

Despite a record setting number of heart transplants performed annually,the national donor shortage continues to plague transplant teams across the United *** we describe the barriers to adaptation of numerous“non-traditional”orthotopic heart transplant donor characteristics including donors with hepatitis C virus,those meeting criteria for donation after cardiac death,donors with coronavirus disease 19 infection,donors with the human immunodeficiency virus,and grafts with left ventricular systolic *** center’s objective was to increase our transplant volume by expanding our donor pool from“traditional”donors to these“non-traditional”*** detail how medical advances such as certain laboratory studies,pharmacologic interventions,and organ care systems have allowed our center to expand the donor pool thereby increasing transplantation volume without adverse effects on outcomes.

关键词： Orthotopic heart transplantation Hepatitis C virus COVID-19 Left ventricular systolic dysfunction Human immunodeficiency virus Donation after cardiac death

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Anti-N-methyl-D-aspartate receptor-associated encephalitis: A review of clinicopathologic hallmarks and multimodal imaging manifestations

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World Journal of Radiology 2024年第1期16卷 1-8页

作者： bryce David beutler Alastair E Moody Jerry Mathew Thomas benjamin Phillip Sugar Mark b Ulanja daniel Antwi-Amoabeng Lucas Anthony Tsikitas Department of Radiology University of Southern CaliforniaKeck School of MedicineLos AngelesCA 90033United States Department of Anesthesiology University of UtahSalt Lake CityUT 84132United States Department of Internal Medicine Christus Ochsner St.Patrick HospitalLake CharlesLA 70601United States

Anti-N-methyl-D-aspartate receptor-associated encephalitis(NMDARE)is a rare immune-mediated neuroinflammatory condition characterized by the rapid onset of neuropsychiatric symptoms and autonomic *** mechanism of pathogenesis remains incompletely understood,but is thought to be related to antibodies targeting the GluN1 subunit of the NMDA receptor with resultant downstream dysregulation of dopaminergic *** adults are most frequently affected;the median age at diagnosis is 21 *** is a strong female predilection with a female sex predominance of 4:*** often develops as a paraneoplastic process and is most commonly associated with ovarian ***,NMDARE has also been described in patients with small cell lung cancer,clear cell renal carcinoma,and other benign and malignant *** is based on correlation of the clinical presentation,electro-encephalography,laboratory studies,and *** tomography,positron emission tomography,and magnetic resonance imaging are essential to identify an underlying tumor,exclude clinicopathologic mimics,and predict the likelihood of long-term functional *** imaging may be of value for prognostication and to assess the response to *** may involve high-dose corticosteroids,intravenous immunoglobulin,and plasma ***,we review the hallmark clinicopathologic features and imaging findings of this rare but potentially devastating condition and summarize diagnostic criteria,treatment regimens,and proposed pathogenetic mechanisms.

关键词： Anti-N-methyl-D-aspartate receptor-associated encephalitis Autoimmune encephalitis Encephalitis Ovarian teratoma Paraneoplastic syndrome Teratoma

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The transition from backarc extension to Andean growth:Insights from geochronologic,sedimentologic,and structural studies of Mesozoic and Cenozoic sedimentary and volcanic rocks in south-central Chile(36°S)

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Geoscience Frontiers 2024年第5期15卷 93-117页

作者： Alfonso Encinas Nicolás Henríquez daniel Castro Darío Orts Diego Kietzmann Franco Iovino Paulo Vásquez Andrés Folguera Victor Valencia Facundo Fuentes Departamento de Ciencias de la Tierra Facultad de Ciencias QuímicasUniversidad de ConcepciónVíctor Lamas 1290Concepción 4030000Chile Universidad Nacional de Río Negro.Instituto de Investigación en Paleobiología y Geología.General Roca Río NegroArgentina Instituto de Investigación en Paleobiología y Geología(IIPG).CONICET.Av.J.A.Roca 1242 8332 General RocaRío NegroArgentina Universidad de buenos Aires Facultad de Ciencias Exactas y NaturalesDepartamento de Ciencias GeológicasCiudad UniversitariaPabellón IIIntendente Güiraldes 2160C1428EHA Ciudad Autónoma de Buenos AiresArgentina CONICET-Universidad de buenos Aires Instituto de Geociencias BásicasAmbientales y Aplicadas de Buenos Aires(IGeBA)Ciudad UniversitariaPabellón IIIntendente Güiraldes 2160C1428EHA Ciudad Autónoma de Buenos AiresArgentina Instituto de Estudios Andinos‘‘Don Pablo Groeber”(IDEAN) CONICET-Universidad de Buenos AiresBuenos AiresArgentina Facultad de Ciencias Exactas y Naturales Universidad de Buenos AiresBuenos AiresArgentina Washington State University School of the EnvironmentPullmanUSA Yacimientos Petrolíferos Fiscales(YPF)S.A. Buenos AiresArgentina

Many studies propose a significant shift in the tectonic and paleogeographic evolution of the Andes in south-central Chile and Argentina during the Late *** has been proposed that the preceding Jurassic-Early Cretaceous extensional regime that resulted in a low-relief volcanic arc and the backarc Neuquén basin came to an end,giving way to shortening and Andean growth from the Late Cretaceous ***,there are disagreements regarding the timing and nature of this transition to Andean *** address these issues,we conducted geochronologic(U-Pb and^(40)Ar/&(39)Ar),sedimentologic,and structural studies on Mesozoic-Cenozoic sedimentary and volcanic rocks in the Río Maule area(Principal Cordillera,Chile,36°S).From our findings and prior analyses,we propose the following tectono-stratigraphic evolution of the region.(1)Marine deposition of the Tithonian-Hauterivian baños del Flaco Formation took place in an extensional backarc basin.(2)After a~40 Myr hiatus,fluvial deposits of the Colimapu Formation and volcanic rocks of the Plan de los Yeuques Formation accumulated during the *** the Colimapu Formation displays evidence of syndepositional shortening,the Plan de los Yeuques Formation exhibits synextensional growth *** to other studies,our results suggest that the Chilean part of the Principal Cordillera was largely a zone of active deposition rather than an elevated fold-thrust belt during the Late *** propose that sedimentation occurred within a series of relatively stable intermontane subbasins generated by shortening,followed by extension.(3)After a~20 Myr hiatus,middle Eocene to early Miocene(Lutetian-Aquitanian)accumulation of a thick succession of andesitic lavas and minor clastic sediments of the Abanico Formation occurred in an intraarc extensional basin.(4)Finally,major shortening and uplift of previously deposited Mesozoic-Cenozoic rocks took place throughout the *** phase constitu

关键词： Andes South-central Chile backarc basin Foreland basin Fold-thrust belt

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brain-derived neurotrophic factor signaling in the neuromuscular junction during developmental axonal competition and synapse elimination

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Neural Regeneration Research 2025年第2期20卷 394-401页

作者： Josep Tomàs Víctor Cilleros-Mañé Laia Just-borràs Marta balanyà-Segura Aleksandra Polishchuk Laura Nadal Marta Tomàs Carolina Silvera-sim.n Manel M.Santafé Maria A.Lanuza Unitat d’Histologia i Neurobiologia(UHNeurob) Facultat de Medicina i Ciències de la SalutUniversitat Rovira i VirgiliReusSpain

During the development of the nervous system,there is an overproduction of neurons and *** competition between neighboring nerve endings and synapses performing different activity levels leads to their elimination or *** have extensively studied the involvement of the brain-derived neurotrophic factor-Tropomyosin-related kinase b receptor neurotrophic retrograde pathway,at the neuromuscular junction,in the axonal development and synapse elimination process versus the synapse *** purpose of this review is to describe the neurotrophic influence on developmental synapse elimination,in relation to other molecular pathways that we and others have found to regulate this *** particular,we summarize our published results based on transmitter release analysis and axonal counts to show the different involvement of the presynaptic acetylcholine muscarinic autoreceptors,coupled to downstream serine-threonine protein kinases A and C(PKA and PKC)and voltage-gated calcium channels,at different nerve endings in developmental *** dynamic changes that occur sim.ltaneously in several nerve terminals and synapses converge across a postsynaptic site,influence each other,and require careful studies to individualize the mechanisms of specific *** describe an activity-dependent balance(related to the extent of transmitter release)between the presynaptic muscarinic subtypes and the neurotrophin-mediated Trkb/p75NTR pathways that can influence the timing and fate of the competitive interactions between the different axon *** downstream displacement of the PKA/PKC activity ratio to lower values,both in competing nerve terminals and at postsynaptic sites,plays a relevant role in controlling the elimination of supernumerary ***,calcium entry through L-and P/Q-subtypes of voltage-gated calcium channels(both channels are present,together with the N-type channel in developing nerve terminals)contributes to red

关键词： acetylcholine release adenosine receptors axonal competition brain-derived neurotrophic factor calcium channels motor end-plate muscarinic acetylcholine receptors postnatal synapse elimination serine kinases tropomyosin-related kinase receptorb

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Identification of four novel DC-SIGN ligands on Mycobacterium bovis bCG

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Protein & Cell 2010年第9期1卷 859-870页

作者： Maria V.Carroll Robert b.sim.Fabiana bigi Anne Jäkel Robin Antrobus daniel A.Mitchell Department of Pharmacology University of OxfordMansfield RoadOxford OX13QTUK Institute of biotechnology CICVyA-INTALos Reseros y Las Cabañas1712 CastelarArgentina Cambridge Institute of Medical Research Addenbrooke’s HospitalHills RoadCambridge CB20XYUK CSRI-UHCW Walsgrave Campus University of WarwickCoventryCV22DXUK

Dendritic-cell-specific intercellular adhesion molecule-3-grabbing non-integrin(DC-SIGN;CD209)has an important role in mediating adherence of Mycobacteria species,including *** and *** bCG to human dendritic cells and macrophages,in which these bacteria can survive ***-SIGN is a C-type lectin,and interactions with mycobacterial cells are believed to occur via mannosylated structures on the mycobacterial *** studies suggest more varied modes of binding to multiple mycobacterial *** we identify,by affinity chromatography and mass-spectrometry,four novel ligands of *** bCG that bind to *** novel ligands are chaperone protein DnaK,60 kDa chaperonin-1(Cpn60.1),glyceraldehyde-3 phosphate dehydrogenase(GAPDH)and lipoprotein *** published work strongly suggests that these are on the cell *** these ligands,lprG appears to bind DC-SIGN via typical proteinglycan interactions,but DnaK and Cpn60.1 binding do not show evidence of carbohydrate-dependent *** was also identified as a ligand for DC-SIGNR(L-SIGN;CD299)and the *** orthologue of lprG has been found previously to interact with human toll-like receptor ***,these findings offer new targets for combating mycobacterial adhesion and within-host survival,and reinforce the role of DCSIGN as an important host ligand in mycobacterial infection.

关键词： DC-SIGN Mycobacteria lectins

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