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Synthesis and photoluminescent performance of novel europium(Ⅲ) carboxylates with heterocyclic ancillary ligands

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Rare Metals 2022年第4期41卷 1342-1352页

作者： Priyanka Dhankhar Rekha Devi Sushma Devi Sangeeta Chahar Mandeep dalal V.B.Taxak S.P.Khatkar Priti Boora Department of Chemistry Maharshi Dayanand UniversityRohtak 124001India

Five novel europium(Ⅲ)complexes with 2-[4-(dibutylamino)-2-hydroxybenzoyl]benzoic acid(DAHB)as primary ligand and bathophenanthroline(batho),2,2’-bipyridyl(bipy),5,6-dimethyl-1,10-phenanthroline(dmph),1,10-phenanthroline(phen)as ancillary ligands were syn-thesized via solution precipitation *** structural formulae of synthesized complexes were speculated to be Eu(DABH)_(3)·2H_(2)O(C1),Eu(DABH)_(3)·batho(C2),Eu(DABH)_(3)·bipy(C3),Eu(DABH)_(3)·dmph(C4)and Eu(DABH)_(3)·phen(C5)by elemental analysis,infrared spectroscopy and proton nuclear magnetic resonance spec-troscopy(^(1)H-NMR).The photoluminescent properties and thermal stability of the complexes were investigated by photoluminescent spectroscopy and thermogravimetric analysis(TG-DTG),*** Commission Inter-nationale de I’Eclairage(CIE)color coordinates,Judd–Ofelt intensity parameter(Ω_(2)),total quantum yield,intrinsic quantum efficiency and energy transfer dynamics of com-plexes were also *** excitation spectra of com-plexes are extended up to visible *** complexes exhibit characteristic photoemission of Eu^(3+)metal ion with high color purity in red region attributed to efficient energy transfer from ligand to metal *** replacement of water molecules from coordination sphere of europium ion by ancillary ligands results in enhancement of luminescent properties of the C2–C5 complexes,indicating that ancillary ligands act as additional light harvesting centers in sensiti-zation *** thermal studies show that these complexes are suitable for meeting the requirement of temperature for fabrication of OLEDs devices.

关键词： Photoluminescence Europium Sensitization Aromatic carboxylic acid Energy transfer dynamics

Oxide ancillary ligand-based europium β-diketonate complexes and their enhanced luminosity

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Rare Metals 2021年第10期40卷 2873-2881页

作者： Devender Singh Shri Bhagwan Anuj dalal Kapeesha Nehra Raman Kumar Saini Kapoor Singh Anura Priyajith Simantilleke Sumit Kumar Ishwar Singh Department of Chemistry Maharshi Dayanand UniversityRohtak 124001India Centre de Fisica Universidade of MinhoBraga 4710057Portugal Department of Chemistry DCR University of Science and TechnologyMurthal 131039India

Ternary materials of europium complex with2,2,6,6-tetramethyl-3,5-heptanedione(tmhd) ligand and aqua ligand as ancillary ligands have been prepared and characterized for various optoelectronic *** of hydrated complex [Eu(tmhd)_(3)(H_(2)O)_(2)] proceeded with triphenylphosphine oxide(TPPO) and pyridine-N-oxide(PNO) ancillary ligands were studied to develop novel complexes. The prepared complexes show good thermal stability. A comparative investigation of preparedmaterials[Eu(tmhd)_(3)(H_(2)O)_(2)],[Eu(tmhd)_(3)(TPPO)_(2)] and [Eu(tmhd)_(3)(PNO)_(2)] was conducted for their luminescent behaviors in order to obtain the role of ancillary ligand in the enhancement of illumination amount generated from europium(Eu^(3+)) ion. Color coordinates of prepared ternary complexes such as[Eu(tmhd)_(3)(H_(2)O)_(2)]with(x = 0.54,y = 0.32),[Eu(tmhd)_(3)(TPPO)_(2)] with(x = 0.56, y = 0.32) and[Eu(tmhd)_(3)(PNO)_(2)] with(x = 0.57, y = 0.33) indicated that these materials exhibited bright red emission in visible region spectrum. The complexes show a proficient energy transport pathway from the ligands to the innermost Eu^(3+)by means of an ancillary ligand-sensitized luminescence process. Interaction between the metal and ligand results in a distinguished effect on quantum efficiency(η) as well as on Judd–Ofelt intensity factor(Ω_(2)) of the prepared materials.

关键词： Ternary Eu^(3+)complexes Red emissive materials Photoluminescence Quantum efficiency Judd-Ofelt intensity Optoelectronic devices

Organ transplantation and drug eluting stents:Perioperative challenges

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World Journal of Transplantation 2016年第4期6卷 620-631页

作者： Aparna dalal Department of Anesthesiology Icahn School of Medicine

Patients listed for organ transplant frequently have severe coronary artery disease(CAD), which may be treated with drug eluting stents(DES). Everolimus and zotarolimus eluting stents are commonly used. Newer generation biolimus and novolimus eluting biodegradable stents are becoming increasingly popular. Patients undergoing transplant surgery soon after the placement of DES are at increased risk of stent thrombosis(ST) in the perioperative period. Dual antiplatelet therapy(DAPT) with aspirin and a P2Y12 inhibitor such as clopidogrel, prasugrel and ticagrelor is instated post stenting to decrease the incident of ST. Cangrelor has recently been approved by Food and Drug Administration and can be used as a bridging antiplatelet drug. The risk of ischemia vs bleeding must be considered when discontinuing or continuing DAPT for surgery. Though living donor transplant surgery is an elective procedure and can be optimally timed, cadaveric organ availability is unpredictable, therefore, discontinuation of antiplatelet medication cannot be optimally timed. The type of stent and timing of transplant surgery can be of utmost importance. Many platelet function point of care tests such as Light Transmittance Aggregrometry, Thromboelastography Platelet Mapping, VerifyN ow, Multiple Electrode Aggregrometry are used to assess bleeding risk and guide perioperative platelet transfusion. Response to allogenic platelet transfusion to control severe intraoperative bleeding may differ with the antiplatelet drug. In stent thrombosis is an emergency where management with either a drug eluting balloon or a DES has shown superior outcomes. Post-transplant complications often involved stenosis of an important vessel that may need revascularization. DES are now used for endovascular interventions for transplant orthotropic heart CAD, hepatic artery stenosis post liver transplantation, transplant renal artery stenosis following kidney transplantation, etc. Several antiproliferative drugs used

关键词： Drug eluting stents Cangrelor Stent thrombosis Organ transplant Antiplatelet medication Platelet function assays Mammalian target of rapamycin inhibitors Post-transplant immunosuppression Post-transplant endovascular inhibition Ticagrelor Thromboelastograms platelet mapping Novolimus Biolimus A9

BHGSO:Binary Hunger Games Search Optimization Algorithm for Feature Selection Problem

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Computers, Materials & Continua 2022年第1期70卷 557-579页

作者： R.Manjula Devi M.Premkumar Pradeep Jangir B.Santhosh Kumar dalal Alrowaili Kottakkaran Sooppy Nisar Department of Computer Science and Engineering Kongu Engineering CollegePerundurai638060Tamil NaduIndia Department of Electrical and Electronics Engineering Dayananda Sagar College of EngineeringBengaluru560078KarnatakaIndia Rajasthan Rajya Vidyut Prasaran Nigam Sikar332025RajasthanIndia Department of Computer Science and Engineering Guru Nanak Institute of TechnologyHyderabad501506TelanganaIndia Mathematics Department College of ScienceJouf UniversitySakakaP.O.Box:2014Saudi Arabia Department of Mathematics College of Arts and SciencesPrince Sattam bin Abdulaziz UniversityWadi Aldawaser11991Saudi Arabia

In machine learning and data mining,feature selection(FS)is a traditional and complicated optimization *** the run time increases exponentially,FS is treated as an NP-hard *** researcher’s effort to build a new FS solution was inspired by the ongoing need for an efficient FS framework and the success rates of swarming outcomes in different optimization *** paper presents two binary variants of a Hunger Games Search Optimization(HGSO)algorithm based on V-and S-shaped transfer functions within a wrapper FS model for choosing the best features from a large *** proposed technique transforms the continuous HGSO into a binary variant using V-and S-shaped transfer functions(BHGSO-V and BHGSO-S).To validate the accuracy,16 famous UCI datasets are considered and compared with different state-of-the-art metaheuristic binary *** findings demonstrate that BHGSO-V achieves better performance in terms of the selected number of features,classification accuracy,run time,and fitness values than other state-of-the-art *** results demonstrate that the BHGSO-V algorithm can reduce dimensionality and choose the most helpful features for classification *** proposed BHGSO-V achieves 95%average classification accuracy for most of the datasets,and run time is less than 5 *** low and medium dimensional datasets and less than 10 sec for high dimensional datasets.

关键词： Binary optimization feature selection machine learning hunger games search optimization

Study of Fixed Point Theorems for Higher Dimension in Partially Ordered Metric Spaces

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Applied Mathematics 2016年第5期7卷 399-412页

作者： Ibtisam Masmali Sumitra dalal College of Science Jazan University Jazan K.S.A

In this paper, we establish the existence and uniqueness of fixed points of operator , when n is an arbitrary positive integer and X is a partially ordered complete metric space. We have shown examples to verify our work. Our results generalize the recent fixed point theorems cited in [1]-[4] etc. and include several recent developments.

关键词： n-Tupled Coincidence Points n-Tupled Coincidence Fixed Points Compatible Maps Fixed Points and Partially Ordered Metric Spaces

Homotopy Perturbation Method for the Generalized Hirota-Satsuma Coupled KdV Equation

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Applied Mathematics 2012年第12期3卷 1983-1989页

作者： dalal A. Maturi Department of Mathematics Faculty of Science King AbdulAziz University Jeddah Saudi Arabia

In this paper, we consider the homotopy perturbation method (HPM) to obtain the exact solution of Hirota-Satsuma Coupled KdV equation. The results reveal that the proposed method is very effective and simple and can b... 详细信息

关键词： Homotopy Perturbation Method Generalized Hirota-Satsuma Coupled KdV Equation

Face transplantation:Anesthetic challenges

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World Journal of Transplantation 2016年第4期6卷 646-649页

作者： Aparna dalal Department of Anesthesiology Icahn School of Medicine at Mount Sinai

Face transplantation is a complex vascular composite allotransplantation(VCA) surgery. It involves multiple types of tissue, such as bone, muscles, blood vessels, nerves to be transferred from the donor to the recipient as one unit. VCAs were added to the definition of organs covered by the Organ Procurement and Transplantation NetworkFinal Rule and National Organ Transplant Act. Prior to harvest of the face from the donor, a tracheostomy is usually performed. The osteotomies and dissection of the midface bony skeleton may involve severe hemorrhagic blood loss often requiring transfusion of blood products. A silicon face mask created from the facial impression is used to reconstruct the face and preserve the donor's dignity. The recipient airway management most commonly used is primary intubation of an existing tracheostoma with a flexometallic endotracheal tube. The recipient surgery usually averages to 19-20 h. Since the face is a very vascular organ, there is usually massive bleeding, both in the dissection phase as well as in the reperfusion phase. Prior to reperfusion, often, after one sided anastomosis of the graft, the contralateral side is allowed to bleed to get rid of the preservation solution and other additives. Intraoperative product replacement should be guided by laboratory values and point of care testing for coagulation and hemostasis. In face transplantation, bolus doses of pressors or pressor infusions have been used intraoperatively in several patients to manage hypotension. This article reviews the anesthetic considerations for management for face transplantation, and some of the perioperative challenges faced.

关键词： Face transplantation Vascular composite allotransplantation Organ harvest Facial reconstruction

Split liver transplantation:What's unique?

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World Journal of Transplantation 2015年第3期5卷 89-94页

作者： Aparna R dalal Department of Anesthesiology Icahn School of Medicine at Mount Sinai

The intraoperative management of split liver transplantation(SLT) has some unique features as compared to routine whole liver transplantations. Only the liver has this special ability to regenerate that confers benefits in survival and quality of life for two instead of one by splitting livers. Primary graft dysfunction may result from small for size syndrome. Graft weight to recipient body weight ratio is significant for both trisegmental and hemiliver grafts. Intraoperative surgical techniques aim to reduce portal hyperperfusion and decrease venous portal pressure. Ischemic preconditioning can be instituted to protect against ischemic reperfusion injury which impacts graft regeneration. Advancement of the technique of SLT is essential as use of split cadaveric grafts expands the donor pool and potentially has an excellent future.

关键词： Graft to recipient body weight ratio Split liver transplantation Small for size syndrome Hemiliver grafts Portal hyperperfusion

Monitoring Trace Metals in Some Cultured Freshwater Fish Species in Saudi Arabia

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Journal of Food Science and Engineering 2013年第9期3卷 481-488页

作者： Aljabryn dalal Hamad Nutrition and Food Science Department Princess Nora University Riyadh 11471 Saudi Arabia

Three species of freshwater fishes, Oreochromis niloticus, Clarias lazera and Cyprinus carpio, were collected in marketing size from some fish farms in Al-Kharj region, Riyadh area, Saudi Arabia and examined throughout the year 2012 for the following trace metals contents： chromium （Cr）, lead （Pb）, cobalt （Co）, nickel （Ni）, copper （Cu）, zinc （Zn）, iron （Fe） and cadmium （Cd）. The results showed no detection of Cd in all examined species, however, the mean values of other tested metals were within the standard permissible levels except for Pb which showed higher mean levels ranged from 2.05 ± 0.65 mg/kg to 5.30 ± 0.60 mg/kg in O. niloticus, 0.15 ± 0.13 mg/kg to 6.40 ± 0.10 mg/kg in C. lazera and 1.7 ± 0.20 mg/kg in C. carpio compared to the maximum permissible limits recorded by Saudi Arabia Standards Organization （SASO） for fish and shellfish. Consequently, from the public health point of view, efficient routine examination of cultured fishes to control trace metals during culture processes and before marketing is recommended.

关键词： Heavy metals fresh water Saudi Arabia fish farming.