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Optimization, equilibrium, adsorption behavior and role of surface functional groups on graphene oxide-based nanocomposite towards diclofenac drug

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Journal of Environmental Sciences 2020年第7期32卷 137-150页

作者： Thuan Van Tran Duyen Thi Cam Nguyen Hanh TNLe dai-viet nvo Sonil Nanda Trinh Duy Nguyen Nguyen Tat Thanh Hi-Tech Institute Nguyen Tat Thanh UniversityHo Chi Minh City 755414Viet Nam Center of Excellence for Green Energy and Environmental Nanomaterials(CE@GrEEN) Nguyen Tat Thanh UniversityHo Chi Minh City 755414Viet Nam Institute of Hygiene and Public Health Ho Chi Minh City 700000Viet Nam Department of Chemical and Biochemical Engineering University of Western OntarioLondonOntarioCanada

Aquatic contamination of diclofenac(DCF),an emergent non-steroidal anti-inflammatory drug(NSAIDs),can result in adverse effects to many ecosystems through ***,introducing effective remediation techniques to sequester the pharmaceutical wastes is highly fundamental to prevent their accumulation in the ***,adsorption has been presented as a green and efficient ***,we report the characterization and application of the novel magnetic nanocomposite(GO@CoFe2O4)derived from cobalt-based ferrite(CoFe2O4)and graphene oxide(GO)for DCF *** the optimization procedure,the response surface methodology(RSM)was adopted to investigate the impacts of DCF concentration(1.6-18.4 mg/L),DCF dosage(0.08-0.92 g/L),and solution pH(2.6-9.4)to find the optimum conditions for DCF removal,at 10.5 mg/L,0.74 g/L,and pH 4,*** the adsorption experiments,the kinetic,isotherm,thermodynamic,and intraparticle diffusion models were systematically ***,we have elucidated the role of functional groups on the surface of GO@CoFe2O4 in enhancing the adsorption of DCF *** good removal efficiency(up to 86.1%),high maximum adsorption capacity(32.4 mg/g),GO@CoFe2O4 can be a potential candidate to eliminate DCF drug from water.

关键词： Diclofenac sodium Graphene oxide Magnetic nanocomposite Response surface methodology Pharmaceuticals adsorption

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A concise review on surface and structural modification of porous zeolite scaffold for enhanced hydrogen storage

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Chinese Journal of Chemical Engineering 2024年第6期70卷 33-53页

作者： B.A.Abdulkadir R.S.R.Mohd Zaki A.T.Abd Wahab S.N.Miskan Anh-Tam Nguyen dai-viet N.Vo H.D.Setiabudi Centre for Research in Advanced Fluid&Processes Universiti Malaysia Pahang Al-Sultan AbdullahLebuh Persiaran Tun Khalil YaakobGambangPahang 26300Malaysia Faculty of Chemical&Process Engineering Technology Universiti Malaysia Pahang Al-Sultan AbdullahLebuh Persiaran Tun Khalil YaakobGambangPahang 26300Malaysia Center of Excellence for Green Energy and Environmental Nanomaterials(CE@GrEEN) Nguyen Tat Thanh University300A Nguyen Tat ThanhDistrict 4Ho Chi Minh City 755414Viet Nam

Investigating zeolites as hydrogen storage scaffolds is imperative due to their porous nature and favorable physicochemical ***,the storage capacity of the unmodified zeolites has been rather unsatisfactory(0.224%-1.082%(mass))compared to its modified ***,the contemporary focus on enhancing hydrogen storage capacities has led to significant attention towards the utilization of modified zeolites,with studies exploring surface modifications through physical and chemical treatments,as well as the integration of various active *** enhanced hydrogen storage properties of zeolites are attributed to the presence of aluminosilicates from alkaline and alkaline-earth metals,resulting in increased storage capacity through interactions with the charge density of these ***,there is a great demand to critically review their role such as well-defined topology,pore structure,good thermal stability,and tunable hydrophilicity in enhanced hydrogen *** article aimed to critically review the recent research findings based on modified zeolite performance for enhanced hydrogen *** of the factors affecting the hydrogen storage capacities of zeolites that can affect the rate of reaction and the stability of the adsorbent,like pressure,structure,and morphology were studied,and ***,future perspectives,recommendations,and directions for modified zeolites were discussed.

关键词： Zeolites Hydrogen storage Surface modification Adsorption Active metal

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Combining SnO_(2-x)and g-C_(3)N_(4)nanosheets toward S-scheme heterojunction for high selectivity into green products of NO degradation reaction under visible light

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Journal of Materiomics 2022年第1期8卷 1-8页

作者： Pham Van viet Thanh-Dat Nguyen dai-Phat Bui Cao Minh Thi Faculty of Materials Science and Technology University of ScienceVNU-HCM227 Nguyen Van Cu StreetDistrict 5Ho Chi Minh City700000Viet Nam vietnam National University-Ho Chi Minh City Thu Duc DistrictHo Chi Minh City700000Viet Nam Ho Chi Minh City University of Technology(HUTECH) 475A Dien Bien Phu StreetBinh Thanh DistrictHo Chi Minh City700000Viet Nam

NOx emissions cause many negative impacts on the living *** photocatalysis of semiconductors is superior for nitric oxide(NO)degradation due to their low redox *** this report,we combine SnO_(2-x)/g-C_(3)N_(4)heterojunction photocatalyst toward the high selectivity into green products under visible light *** show that SnO_(2-x)/g-C_(3)N_(4)heterojunction degraded 40.8%of NO,which is 1.6 times higher than that of g-C_(3)N_(4).In addition,the selectivity coefficient of SnO_(2-x)/g-C_(3)N_(4)is higher 3 times than both pure SnO_(2-x)and g-C_(3)N_(4).Furthermore,SnO_(2-x)/g-C_(3)N_(4)expresses a superior stability for NO photocatalytic-degradation after five *** scavenger trapping test results,and electron spin resonance(ESR)analysis also provide more understanding of the charge transfer mechanism of ***_(2-x)/g-C_(3)N_(4)heterojunction shows a high removal efficiency of NO gas,making it an up-and-coming environmental treatment candidate.

关键词： G-C_(3)N_(4) NO removal Oxygen vacancies Photocatalysis S-scheme

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Mobile power generation system based on biomass gasifcation

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International Journal of Coal Science & Technology 2022年第3期9卷 171-184页

作者： Lu Ding Mingming Yang Kai Dong dai‑viet N.Vo Douglas Hungwe Jiahan Ye Alexander Ryzhkov Kunio Yoshikawa Institute of Clean Coal Technology East China University of Science and TechnologyShanghai 200237China Department of Environmental Science and Technology Tokyo Institute of Technology4259 Nagatsuta-choMidori-kuYokohama 226-8503Japan College of Chemistry Chemical Engineering and Material ScienceZaozhuang UniversityZaozhuang 277160China Institute of Environmental Technology and Sustainable Development Nguyen Tat Thanh UniversityHo Chi Minh City 755414Vietnam ZHE JIANG ECO ENVIRONMENTAL TECHNOLOGY CO. LTD.1188The Headquarters of the Free Port H Building 20FWuxing DistrictHuzhou CityZhejiang ProvinceChina Ural Federal University EkaterinburgRussia

Disaster-hit and/or un-electrifed remote areas usually have electricity accessibility issues and an abundance of plant-derived debris and wood from destroyed wooden structures;this can be potentially addressed by employing a decentralized ultrasmall biomass-fed gasifcation power generating *** paper presents an assessment of the technical viability of an ultra-small gasifcation system that utilizes densifed carbonized wood pellets/*** setup was run continuously for 100 h.A variety of biomass was densifed and carbonized by harnessing fugitive heat sources before charging into the *** briquettes and furnished blends exhibited inferior gasifcation performance compared to the carbonized *** the absence of tar blockage problems,steady-state conditions were achieved when pre-treated feedstock was *** steady-state conditions for carbonized pellets gasifcation operated at an equivalence ratio of 0.32,cold gas efciency and carbon conversion achieved 49.2%and 70.5%,*** efciency and maximum power output of 20.3%and 21 kW were realised,*** was found that the system could keep stable while the low heating valve of syngas was over 4 MJ/m^(3)on condition that avoiding tar blocking *** results indicate that the proposed compact ultra-small power generation system is a technically feasible approach to remedy power shortage *** addition,process simulation considering carbonized wood gasifcation combined power generation was formulated to produce syngas and *** pellets with the fow rate of 20 kg/h could generate a 15.18 kW power at the air fow rate of 40 Nm^(3)/h,which is in a good agreement with 15 kW in the 100 h *** is indicated that the gasifcation combined power generation cycle simulated by Aspen simulator could achieve reliable data to assist the complicated experiment operation.

关键词： Small-scale power generation Densifcation Carbonized pellet Carbonized briquette Gasifcation

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A novel memristive neural network with hidden attractors and its circuitry implementation

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Science China(Technological Sciences) 2016年第3期59卷 358-363页

作者： PHAM viet Thanh JAFARI Sajad VAIDYANATHAN sundarapandian VOLOS Christos WANG Xiong School of Electronics and Telecommunications Hanoi University of Science and Technology Ol Dai Co Viet Hanoi Vietnam Biomedical Engineering Department Amirkabir University of Technology Tehran 15875-4413 Iran Research and Development Centre Vel Tech University Avadi Chennai-600062 Tamil Nadu India Physics Department Aristotle University of Thessaloniki GR-54124 Greece Institute for Advanced Study Shenzhen University Shenzhen 518060 China

Neural networks have been applied in various fields from signal processing, pattern recognition, associative memory to artifi- cial intelligence. Recently, nanoscale memristor has renewed interest in experimental realization of neural network. A neural network with a memristive synaptic weight is studied in this work. Dynamical properties of the proposed neural network are investigated through phase portraits, Poincar6 map, and Lyapunov exponents. Interestingly, the memristive neural network can generate hyperchaotic attractors without the presence of equilibrium points. Moreover, circuital implementation of such memristive neural network is presented to show its feasibility.

关键词： neural network memristor hyperchaos hidden attractor equilibrium

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An Application of Random Process for Controlled Object Identification with Traffic Delay Problem

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Journal of Mathematics and System Science 2015年第2期5卷 86-91页

作者： Vu Tien viet 47 - dai An - Van Quan Ha Dong district Ha Noi city Vietnam

In the article proposed an effective method estimating transfer function model of controlled plant including dead-time delay, based on stochatstic time series of input-output signals. The model structure is modified with parameters optimized until the model error becomes ＂white-noise＂ series that with inough smal auto-correlation function.

关键词：交通延误对象标识随机过程应用受控传递函数模型自相关函数时间延迟

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Influence of sintering behavior on the microstructure and electrical properties of BaTiO_(3) lead-free ceramics from hydrothermal synthesized precursor nanoparticles

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Journal of Advanced Dielectrics 2021年第2期11卷 42-51页

作者： Do viet On Le dai Vuong Truong Van Chuong Dao Anh Quang Ho Van Tuyen Vo Thanh Tung Department of Physics College of Sciences Hue UniversityHue CityVietnam Faculty of Chemical and Environmental Engineering Hue Industrial College Hue CityVietnam Institute of Research and Development Duy Tan University Da Nang CityVietnam Faculty of Natural Sciences Duy Tan University Da Nang CityVietnam

BaTiO_(3) nanoparticles were synthesized by hydrothermal method using amorphous phase TiO_(2) precursor as the *** microstructure and phase structure were determined using XRD,SEM and Raman spectroscopy analysis *** results showed that BaTiO_(3) nanoparticles have tetragonal structure,average size of about 100 nm was obtained at Ba/Ti ratio of 1.5,synthesis temperature of 200℃ and reaction time of 12 *** components of the BaTiO_(3) lead-free ceramic system are fabricated by conventional solid-phase reaction from the average size BaTiO_(3) particles about 100 nm obtained by hydrothermal *** effects of sintering behavior on dielectric,ferroelectric and piezoelectric properties of BT high-density ceramic were *** BaTiO_(3) ceramic composition sintered at 1300℃ has a relative density of 97%,the value of the electromechanical coefficient kp=0.40,k33=0.42,the large piezoelectric coefficient d_(33)=300 pC/N,d_(31)=−125 pC/N.

关键词： BaTiO_(3)nanoparticles lead-free ceramics piezoelectric ferroelectric properties

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Electrochemical Immunosensor for Detection of Atrazine Based on Polyaniline/Graphene

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Journal of Materials Science & Technology 2016年第6期32卷 539-544页

作者： Nguyen Van Chu Nguyen Hai Binh Cao Thi Thanh Nguyen Van Tu Nguyen Le Huy Nguyen Tuan Dzung Phan Ngoc Minh Vu Thi Thu Tran dai Lam Institute of Materials Science Vietnam Academy of Science and Technology18 Hoang Quoc VietCau Giay.HanoiViet Nam School of Chemical Engineering.Hanoi University of Science and Technology 1 Dai Co VietHanoiViet Ham Institute for Tropical Technology.vietnam Academy of Science and Technology 18 Hoang Quoc VietHanoiViet Nam Center for High Technology Development Vietnam Academy of Science and Technology18 Hoang Quoc VietHanoiViet Nam University of Science and Technology of Hanoi.18 Hoang Quoc viet HanoiViet Ham Graduate University of Science and Technology.vietnam Academy of Science and Technology 18 Hoang Quoc Viet.HanoiViet Nam

In this study, a novel layer-by-layer polyaniline/graphene （PANi/Gr） structure for electrochemical detec- tion of atrazine was developed. Gr film was synthesized by thermal chemical vapor deposition （CVD） method and transferred onto the PANi-predeposited microelectrode. The properties of PANi/Gr film were thoroughly investigated by high-resolution transmission electron microscopy and Raman techniques. The most attractive feature of this system is a suitable microenvironment, which could provide an amplifi- cation of the conductive signal, thus may contribute to enhancing electron transfer and subsequently improve the sensitivity in electrochemical measurements. With low detection limit （- 43 × 10 -12 g/L）, ac-ceptable stability and good reproducibility, the proposed electrochemical immunosensor could be advantageously extended for multiplexed detection of other agents of environmental pollution.

关键词： Electrochemical immunosensor Polyaniline Graphene Atrazine

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One-step hydrothermal synthesis of Sn-doped α-Fe_(2)O_(3) nanoparticles for enhanced photocatalytic degradation of Congo red

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Journal of Semiconductors 2022年第12期43卷 22-31页

作者： Van Nang Lam Thi Bich Vu Quang Dat Do Thi Thanh Xuan Le Tien dai Nguyen T-Thanh-Bao Nguyen Hoang Tung Do Thi Tu Oanh Nguyen Department of Natural Sciences Hoa Lu UniversityNinh NhatNinh Binh CityViet Nam Institute of Theoretical and Applied Research Duy Tan UniversityHanoi 100000Viet Nam Faculty of Natural Sciences Duy Tan UniversityDa Nang 550000Vietnam Institute of Physics Vietnam Academy of Science and Technology10 Dao TanBa DinhHanoiVietnam Institute of Materials Science Vietnam Academy of Science and Technology18 Hoang Quoc VietCaugiayHanoiVietnam

We report on the synthesis of Sn-doped hematite nanoparticles(Sn-α-Fe_(2)O_(3) NPs)by the hydrothermal *** prepared Sn-α-Fe_(2)O_(3) NPs had a highly pure and well crystalline rhombohedral phase with an average particle size of 41.4 *** optical properties of as-synthesizedα-Fe_(2)O_(3) NPs show a higher bandgap energy(2.40-2.57 eV)than that of pure bulkα-Fe_(2)O_(3)(2.1 eV).By doping Sn intoα-Fe_(2)O_(3) NPs,the Sn-doped hematite was observed a redshift toward a long wavelength with in-creasing Sn concentration from 0%to 4.0%.The photocatalytic activity of Sn-dopedα-Fe_(2)O_(3) NPs was evaluated by Congo red(CR)dye *** degradation efficiency of CR dye using Sn-α-Fe_(2)O_(3) NPs catalyst is higher than that of pureα-Fe_(2)O_(3) *** highest degradation efficiency of CR dye was 97.8%using 2.5%Sn-dopedα-Fe_(2)O_(3) NPs catalyst under visible-light *** results suggest that the synthesized Sn-dopedα-Fe_(2)O_(3) nanoparticles might be a suitable approach to develop a photocatalytic degradation of toxic inorganic dye in wastewater.

关键词： α-Fe_(2)O_(3)nanoparticles Sn Congo red photocatalytic properties photodegradation

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Dynamic covalent nano-networks comprising antibiotics and polyphenols orchestrate bacterial drug resistance reversal and inflammation alleviation

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Bioactive Materials 2023年第9期27卷 288-302页

作者： Yuanfeng Li Yin-Zi Piao Hua Chen Keqing Shi Juqin dai Siran Wang Tieli Zhou Anh-Tuan Le Yaran Wang Fan Wu Rujiang Ma Linqi Shi Yong Liu Translational Medicine Laboratory The First Affiliated Hospital of Wenzhou Medical UniversityWenzhouZhejiang325035China Wenzhou Institute University of Chinese Academy of SciencesOujiang LaboratoryZhejiang Lab for Regenerative MedicineVision and Brain HealthWenzhouZhejiang325001China Key Laboratory of Functional Polymer Materials of Ministry of Education Institute of Polymer ChemistryCollege of ChemistryNankai UniversityTianjin300071China Department of Clinical Laboratory The First Affiliated Hospital of Wenzhou Medical UniversityWenzhouZhejiang325035China Nano Institute Phenikaa UniversityYen NghiaHa DongHa NoiViet Nam

New antimicrobial strategies are urgently needed to meet the challenges posed by the emergence of drug-resistant bacteria and bacterial *** work reports the facile synthesis of antimicrobial dynamic covalent nano-networks(aDCNs)composing antibiotics bearing multiple primary amines,polyphenols,and a cross-linker acylphenylboronic ***,the iminoboronate bond drives the formation of aDCNs,facilitates their stability,and renders them highly responsive to stimuli,such as low pH and high H2O2 ***,the representative A1B1C1 networks,composed of polymyxin B1(A1),2-formylphenylboronic acid(B1),and quercetin(C1),inhibit biofilm formation of drug-resistant Escherichia coli,eliminate the mature biofilms,alleviate macrophage inflammation,and minimize the side effects of free *** bacterial eradication and inflammation amelioration efficiency of A1B1C1 networks are also observed in a peritoneal infection *** facile synthesis,excellent antimicrobial performance,and biocompatibility of these aDCNs potentiate them as a much-needed alternative in current antimicrobial pipelines.

关键词： Biofilms Dynamic covalent bonds On-demand drug release Resistance reversal Biosafety

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