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Investigation of 'chazi'(damaged-enamels)on Chenghua doucai Porcelains

science china(Technological sciences) 2009年第6期52卷 1722-1729页

作者： du feng1 & su baoru2.1 institute of chemistry & molecular engineering,qingdao {2. of science & Technology,qingdao,china 2.College of Information science & Technology,qingdao {2. of science & Technology,qingdao,china institute of chemistry & {2. engineering Qingdao University of Science & Technology Qingdao China College of Information science & Technology Qingdao University of Science & Technology Qingdao China

At the end of the 1950s,sun Yingzhou considered that the 'chazi'(damaged colour)on Chenghua doucai imperial porcelain as a defect was originally produced in firing process during Chenghua period(1465―1487).Researchers in china have accepted his *** any fragment with the 'chazi' has never been found in several tons of Chenghua imperial sherds excavated from Ming imperial kiln site in *** china,few scholars have questioned the formation of 'chazi',and further investigated *** researchers at the Research Laboratory in the British Museum,employing unde-structive EDXRF,have analyzed the chemical composition of the 'chazi'(damaged colour)on a Chen-ghua doucai stem cup in the museum,and they have confirmed that the 'chazi'(damaged colour)was caused by the fire of the Jianfu palace in the Forbidden City in *** on their research,the authors studied the colour chemical principle of the 'chazi's' formation *** to the ceramic technology principle,scientific reasoning for the 'chazi' was carried *** the help of the history of Qing court,the brainteaser of the 'chazi' was totally uncovered,the misunderstanding for the 'chazi' has also been *** research also suggests that employing modern science and technology is a direction to study Chinese ancient ceramic further.

关键词： Chenghua doucai porcelains court eunuchs the set on fire at the Jianfu palace ’chazi’(damaged-enamels) the British Museum colour chemical principle archaeology using science and technology

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Further study of sources of the imported cobalt-blue pigment used on Jingdezhen porcelain from late 13 to early 15 centuries

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science china(Technological sciences) 2008年第3期51卷 249-259页

作者： du feng1 & su baoru2.1 institute of chemistry & molecular engineering, qingdao {2. of science & Technology, qingdao 2.6000, china 2.College of Information science Technology, qingdao {2. of science & Technology, qingdao 2.6000, china institute of chemistry & {2. engineering Qingdao University of Science & Technology Qingdao 266000 China College of Information science Technology Qingdao University of Science & Technology Qingdao 266000 China

Based on the conclusion of modern scientific analysis: the cobalt-blue pigment applied on Jingdezhen official porcelain during Yuan Dynasty and prior to Xuande reign of Ming Dynasty (12.1―142.) contains high iron and low manganese con- tents, and the cobalt during Xuande and after Xuande periods (after 142.) of Ming Dynasty contains high manganese and low iron contents, in combination with the traditional archaeological method, the related historical textual records were in- vestigated and analyzed, the imported cobalt employed on Jingdezhen official porcelain was studied comprehensively, systematically and logically. In fact, 'su Ma Li Qing' (Samarra-blue) and 'su Bo Ni Qing' (sumatra-blue) are definitely different cobalt ores originated in different places, because of their very similar translitera- tions in Chinese, the confusion has appeared in ancient books for more than 400 years, which considered 'su Ma Li Qing' and 'su Bo Ni Qing' as the same co- balt-blue pigment. In this article the mistake was corrected, the possible producing places and the approximate eras of the two pigments imported to china and used at Jingdezhen were also suggested.

关键词： imported cobalt-blue pigments employed on official blue-and-white porcelain Yuan Dynasty early Ming Dy- nasty Mn/Fe content ratio su Ma Li Qing (Samarra-blue) su Bo Ni Qing (sumatra-blue) scientific archae- ological research transliteration

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Effect of nucleating agents on the electrical properties of cross-linked polyethylene under tensile stress

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High Voltage 2024年第2期9卷 429-439页

作者： Yunqi Xing Jiahao Liu Jingang su Junwei Zha Guochang Li Ze Guo Xiaozhen Zhao Mengjia feng State Key Laboratory of Reliability and Intelligence of Electrical Equipment Hebei University of TechnologyTianjinChina Electric Power Research institute of State Grid Hebei Electric Power supply Co. Ltd.ShijiazhuangChina Beijing Advanced Innovation Center for Materials Genome engineering School of Chemistry and Biological EngineeringUniversity of Science&Technology BeijingBeijingChina institute of Advanced Electrical Materials Qingdao University of Science and TechnologyQingdaoChina

during the operation of high-voltage cables,external stress and residual stress can affect the aggregated structure of in{2.lating materials and lead to significant deterioration in their electrical *** investigate the evolution characteristics of the electrical properties of cross-linked polyethylene(XLPE)under mechanical stress,this paper ex-plains the relationship between the aggregated structure of XLPE and its electrical properties and proposes a method for improving in{2.lation performance under me-chanical *** re{2.lts show that metallocene polyethylene used as a nucleating agent can promote crystallisation through heterogeneous nucleation and increase Young's modulus by non-uniform nucleation,increasing crystallinity and reducing interplanar spacing,re{2.lting in more complete crystal forms and reduced damage to the aggregated structure during the tensile *** nucleating agent modification,the XLPE crystallisation becomes more uniform,and interfacial adhesion forces *** weakened interface damage process between the amorphous and crystalline regions under tensile stress effectively inhibits the process of molecular chain polarisation turning and reduces trap *** modified XLPE crystal structure shows a tendency towards densification and enhanced molecular chain interactions,which can reduce the damage to the aggregated structure under tensile stress,while the reduced free volume inside the material and the shortened average free path of carriers can weaken the damage of high-energy electrons to molecular chains,thereby inhibiting the process of electrical tree *** re{2.lts show that nucleating agents have great potential for maintaining the stable operation of XLPE cables under mechanical stress.

关键词： stress electrical damage

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Theoretical Study on Xe…N non-Covalent Interactions:Three Hybridization N with XeO_(3) and XeOF_(2.

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Chinese Journal of Chemical Physics 2022年第2期35卷 322-330,I0007-I0010,I0002,I0003页

作者： su-jun Ji Zhi-ling Ding Hang Yin Dao-yuan Zheng Jin-feng Zhao institute of molecular {2.s and engineering Institute of Frontier and Interdisciplinary ScienceShandong UniversityQingdao 266237China State Key Laboratory of molecular Reaction Dynamics Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China

The interactions of complexes of XeOF_(2. and XeO_(3) with a series of different hybridization N-containing donors are studied by means of DFT and MP_(2. *** aerogen bonding interaction energies range from 6.5 kcal/mol to19.9 kcal/mol between XeO_(3) or XeOF_(2. and typical N-containing *** sequence of interaction for N-containing hy-bridization is sp^(3)>sp^(2.>sp,and XeO_(3)is higher than XeOF_(2..For some donors of sp^(2.and sp^(3) hybridization,the steric effect plays a minor role in the interaction with the evidence of reduced density gradient *** dominant stable part is the electrostatic *** complex of XeO_(3),the weight of polarization is larger than dispersion,while the situation is opposite for XeOF_(2.*** for the sum of the maximum value of {2. electrostatic potential on Xe atom and minimum value of {2. electrostatic potential on N atom,the other five interaction parameters including the potential energy density at bond critical point,the equilibrium distances,interaction energies with the basis set superposition error correction,localized {2. orbital energy decomposition analysis interaction energies,and the electron charge density,show great linear correlation coefficients with each other.

关键词： Aerogen bonding Localized molecular orbital energy decomposition analysis Noncovalent interaction Energy component analysis

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Evidence for particle acceleration approaching PeV energies in the W51 complex

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science Bulletin 2024年第18期69卷 2833-2841页

作者： LHAASO Collaboration Zhen Cao F.Aharonian Axikegu Y.X.Bai Y.W.Bao D.Bastieri X.J.Bi Y.J.Bi W.Bian A.V.Bukevich Q.Cao W.Y.Cao Zhe Cao J.Chang J.F.Chang A.M.Chen E.S.Chen H.X.Chen Liang Chen Lin Chen Long Chen M.J.Chen M.L.Chen Q.H.Chen S.Chen S.H.Chen S.Z.Chen T.L.Chen Y.Chen N.Cheng Y.D.Cheng M.Y.Cui S.W.Cui X.H.Cui Y.D.Cui B.Z.Dai H.L.Dai Z.G.Dai Danzengluobu X.Q.Dong K.K.duan J.H.Fan Y.Z.Fan J.Fang J.H.Fang K.Fang C.F.feng H.feng L.feng S.H.feng X.T.feng Y.feng Y.L.feng S.Gabici B.Gao C.D.Gao Q.Gao W.Gao W.K.Gao M.M.Ge L.S.Geng G.Giacinti G.H.Gong Q.B.Gou M.H.Gu F.L.Guo X.L.Guo Y.Q.Guo Y.Y.Guo Y.A.Han M.Hasan H.H.He H.N.He J.Y.He Y.He Y.K.Hor B.W.Hou C.Hou X.Hou H.B.Hu Q.Hu S.C.Hu D.H.Huang T.Q.Huang W.J.Huang X.T.Huang X.Y.Huang Y.Huang X.L.Ji H.Y.Jia K.Jia K.Jiang X.W.Jiang Z.J.Jiang M.Jin M.M.Kang I.Karpikov D.Kuleshov K.Kurinov B.B.Li C.M.Li Cheng Li Cong Li D.Li F.Li H.B.Li H.C.Li Jian Li Jie Li K.Li S.D.Li W.L.Li W.L.Li X.R.Li Xin Li Y.Z.Li Zhe Li Zhuo Li E.W.Liang Y.F.Liang S.J.Lin B.Liu C.Liu D.Liu D.B.Liu H.Liu H.D.Liu J.Liu J.L.Liu M.Y.Liu R.Y.Liu S.M.Liu W.Liu Y.Liu Y.N.Liu Q.Luo Y.Luo H.K.Lv B.Q.Ma L.L.Ma X.H.Ma J.R.Mao Z.Min W.Mitthumsiri H.J.Mu Y.C.Nan A.Neronov L.J.Ou P.Pattarakijwanich Z.Y.Pei J.C.Qi M.Y.Qi B.Q.Qiao J.J.Qin A.Raza D.Ruffolo A.Sáiz M.Saeed D.Semikoz L.Shao O.Shchegolev X.D.Sheng F.W.Shu H.C.Song Yu.V.Stenkin V.Stepanov Y.su D.X.sun Q.N.sun X.N.sun Z.B.sun J.Takata P.H.T.Tam Q.W.Tang R.Tang Z.B.Tang W.W.Tian C.Wang C.B.Wang G.W.Wang H.G.Wang H.H.Wang J.C.Wang Kai Wang Kai Wang L.P.Wang L.Y.Wang P.H.Wang R.Wang W.Wang X.G.Wang X.Y.Wang Y.Wang Y.D.Wang Y.J.Wang Z.H.Wang Z.X.Wang Zhen Wang Zheng Wang D.M.Wei J.J.Wei Y.J.Wei T.Wen C.Y.Wu H.R.Wu Q.W.Wu S.Wu X.F.Wu Y.S.Wu S.Q.Xi J.Xia G.M.Xiang D.X.Xiao G.Xiao Y.L.Xin Y.Xing D.R.Xiong Z.Xiong D.L.Xu R.F.Xu R.X.Xu W.L.Xu L.Xue D.H.Yan J.Z.Yan T.Yan C.W.Yang C.Y.Yang F.Yang F.F.Yang L.L.Yang M.J.Yang R.Z.Yang W.X.Yang Y.H.Yao Z.G.Yao L.Q.Yin N.Yin X.H.You Z.Y.You Y.H.Yu Q.Yuan H.Yue H.D.Zeng T.X.Zeng W.Zeng M.Zha B.B.Zhang F.Zhang H.Zhang 不详 Key Laboratory of Particle Astrophysics&Experimental Physics Division&Computing Center Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China university of Chinese Academy of sciences Beijing 100049China TIANFU Cosmic Ray Research Center ChengduChina dublin institute for Advanced Studies 31 Fitzwilliam Place2 DublinIreland Max-Planck-Institut for Nuclear Physics P.O.Box 103980Heidelberg 69029Germany School of Physical science and Technology&School of Information science and Technology Southwest Jiaotong UniversityChengdu 610031China School of Astronomy and Space science Nanjing UniversityNanjing 210023China Center for Astrophysics Guangzhou UniversityGuangzhou 510006China Tsung-Dao Lee institute&School of Physics and Astronomy Shanghai Jiao Tong UniversityShanghai 200240China institute for Nuclear Research of Russian Academy of sciences Moscow 117312Russia Hebei Normal university Shijiazhuang 050024China university of science and Technology of{2. Hefei 230026China State Key Laboratory of Particle Detection and Electronics China Key Laboratory of Dark Matter and Space Astronomy&Key Laboratory of Radio Astronomy Purple Mountain ObservatoryChinese Academy of SciencesNanjing 210023China Research Center for Astronomical Computing Zhejiang LaboratoryHangzhou 311121China Key Laboratory for Research in Galaxies and Cosmology Shanghai Astronomical ObservatoryChinese Academy of SciencesShanghai 200030China School of Physics and Astronomy Yunnan UniversityKunming 650091China Key Laboratory of Cosmic Rays(Tibet university) Ministry of EducationLhasa 850000China National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China School of Physics and Astronomy(Zhuhai)&School of Physics(Guangzhou)&Sino-French institute of Nuclear engineering and Technology(Zhuhai) Sun Yat-sen UniversityZhuhai 519000&Guangzhou 510275GuangdongChina institute of Frontier and Interdisciplinary science Shandong UniversityQingdao 266237China APC UniversitéParis Cité

Theγ-ray emission from the W51 complex is widely acknowledged to be attributed to the interaction between the cosmic rays(CRs)accelerated by the shock of supernova remnant(SNR)W51C and the dense molecular clouds in the adjacent star-forming region,***,the maximum acceleration capability of W51C for CRs remains *** on observations con{2.cted with the Large High Altitude Air Shower Observatory(LHAASO),we report a significant detection ofγrays emanating from the W51 complex,with energies from 2.to 2.0 *** LHAASO measurements,for the first time,extend theγ-ray emission from the W51 complex beyond 100 TeV and reveal a significant spectrum bending at tens of *** combining the"π^(0)-decay bump"featured data from Fermi-LAT,the broadbandγ-ray spectrum of the W51 region can be well-characterized by a simple pp-collision *** observed spectral bending feature suggests an exponential cutoff at~400 TeV or a power-law break at~2.0 TeV in the CR proton spectrum,most likely providing the first evidence of SNRs serving as CR accelerators approaching the PeV ***,two young star clusters within W51B could also be theoretically viable to pro{2.ce the most energeticγrays observed by *** findings strongly support the presence of extreme CR accelerators within the W51 complex and provide new insights into the origin of Galactic CRs.

关键词： UHE c-ray Cosmic rays SNR W51C Star clusters

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