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Co-electrolysis of ethylene glycol and carbon dioxide for formate synthesis

Science China Chemistry 2024年第5期67卷 1539-1544页

作者： Dongfeng du Fusong Kang Shiru Yang bin Shao Jingshan Luo Institute of Photoelectronic Thin Film devices and Technology State Key Laboratory of Photovoltaic Materials and CellsKey Laboratory of Photoelectronic Thin Film Devices and Technology of TianjinMinistry of Education Engineering Research Center of Thin Film Photoelectronic TechnologyNankai UniversityTianjin 300350China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China Frontiers Science Center for New Organic Matter Nankai UniversityTianjin 300071China College of Electronic Information and Optical Engineering Tianjin Key Laboratory of Optoelectronic Sensor and Sensing Network TechnologyNankai UniversityTianjin 300350China

Co-electrolysis of waste plastics and carbon dioxide(CO_(2)) into value-added chemicals or fuels is a promising pathway for a sustainable society, but efficient and selective conversion remains a challenge. Herein, a gold-mediated nickel hydroxide(Au/Ni(OH)_(2)) is developed to oxidize waste plastic-derived ethylene glycol(EG) into formate. In-situ electrochemical experiments and theoretical results reveal that the introduction of Au favors the redox properties and EG adsorption behavior of Ni(OH)_(2). The Au/Ni(OH)_(2) catalyst shows an excellent formate selectivity of >90% at high current densities of above 100 m A cm^(-2). When coupled with sputtered bismuth(Bi) cathode for CO_(2) reduction, a high formate Faradic efficiency(FE) of 188.2% at 200 m A cm^(-2)and a good formate productivity of 7.33 mmol m^(-2)s^(-1)at 10 A are obtained in a flow cell and a zero-gap membrane electrode assembly(MEA) cell, respectively. This work demonstrates a promising strategy to convert waste plastics and CO_(2) into valuable products.

关键词： waste plastic upcycling ethylene glycol oxidation carbon dioxide reduction electrocatalysis formate synthesis

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Flow characteristics and bubble statistics during the fragmentation process of the ingested main cavity in plunging breaking waves

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Journal of Hydrodynamics 2024年第3期36卷 546-555页

作者： Wen-bin Zhang Wei-wen Zhao de-cheng Wan Computational Marine Hydrodynamics Lab(CMHL) School of Naval ArchitectureOcean and Civil EngineeringShanghai Jiao Tong UniversityShanghai200240China

Plunging breaking waves play an important role in the exchange of heat,momentum,and mass between the atmosphere and *** this paper,a series of direct numerical simulations is conducted to investigate the fragmentation process of the ingested main cavity in plunging breaking *** two-phase Navier-Stokes equations are solved using the finite-volume method based on adaptive refinement *** free surface is captured using a geometrical volume of fluid *** 2-D,3-D simulations are *** flow fields at different stages of wave breaking are presented and quantitative analysis for bubbles is *** 2-D instantaneous vorticity field and local velocity field are visualized to discuss the general flow characteristics during the fragmentation *** a 2-D parametric study is conducted to investigate the differences in the flow characteristics during the fragmentation process under different wave parameters including initial wave steepness(ε),Bond number(Bo),and Reynolds number(Re).3-D vortex structures are shown to further investigate the mechanisms behind the differences in the flow *** bubble size distributions under two different initial wave steepness are also discussed with their relationship to the fragmentation process of the ingested main *** research offers a significant understanding of the distinct procedures and fundamental dynamics involved in wave breaking,enhancing our comprehension of this intricate event.

关键词： Plunging breaking waves multiphase flow bubble statistics

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创新型城市研究的理论演进与反思

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地理科学 2014年第7期34卷 773-779页

作者：黄亮杜德斌华东师范大学科技创新与发展战略研究中心上海200062

通过对创新型城市研究的理论性追溯及其主要研究内容回顾,梳理出创新型城市研究的发展演进脉络。着重反思了当前创新型城市研究方面存在的薄弱环节,认为其突出表现为创新型城市研究的指标化困境以及对于城市创新外生力量源泉关注的不足... 详细信息

通过对创新型城市研究的理论性追溯及其主要研究内容回顾,梳理出创新型城市研究的发展演进脉络。着重反思了当前创新型城市研究方面存在的薄弱环节,认为其突出表现为创新型城市研究的指标化困境以及对于城市创新外生力量源泉关注的不足,并明确指出,个性化的城市创新路径选择以及有效利用国际创新资源是未来创新型城市研究与实践的主要突破方向。

关键词：创新型城市理论性追溯演进脉络理论反思

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百年来国际组织机构地理位置的时空演化:集聚模式与影响因素

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人文地理 2020年第5期35卷 85-93,160页

作者：侯纯光杜德斌华东师范大学全球创新与发展研究院上海200062 华东师范大学城市与区域科学学院上海200062 华东师范大学国家教育宏观政策研究院上海200062

国际组织机构在构建国家软实力、拓展国家利益、塑造全球治理机制具有不可替代的战略意义。论文基于国际协会联盟数据,运用矢量数据符号法和负二项回归模型对1918年至2017年成立的26457个国际组织机构地理位置的时空演化规律进行深入研... 详细信息

国际组织机构在构建国家软实力、拓展国家利益、塑造全球治理机制具有不可替代的战略意义。论文基于国际协会联盟数据,运用矢量数据符号法和负二项回归模型对1918年至2017年成立的26457个国际组织机构地理位置的时空演化规律进行深入研究,主要结论如下:①百年来国际组织机构累计数量呈几何数量级增长了1200倍,整体呈缓慢上升又陡然下降的演化趋势;②国际组织机构的空间分布极不均衡,具有等级扩散的演化规律,优先选择区域中心国家的中心城市;③国际组织机构具有永久中立国、强国和区域中心国三种集聚模式;④回归显示国家的经济、文化和科技影响力及历史性组织文化遗产在0.01水平上与国际组织机构地理布局呈显著的正相关关系。

关键词：国际组织机构地理位置空间扩散集聚模式多边机制

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Eu-MOF-Based Fluorescent Ratiometric Sensor by detecting 3,4,5-Trihydroxybenzoic for Fingerprint Visualization on Porous Objects

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Photonic Sensors 2024年第1期14卷 85-98页

作者： Muwen LIANG Yabin ZHAO Yaping LUO bin du Wei HU bing LIU Xihui MU Zhaoyang TONG department of Investigation People's Public Security University of ChinaBejing 100038China State Key Laboratory of NBC Protection for Civilian Beijing 102205China

Latent fingerprints(LFPs)at the crime scene are served as important clues to locate the trajectory of criminal behavior and portray the characteristics of the ***,visualizing LFPs is of considerable *** this work,the europium metal-organic framework(Eu-MOF)sensor was successfully constructed for sensitive detection of gallic acid(3,4,5-trihydroxybenzoic acid,GA)and visualization of the sweat *** boric-acid-modified Eu-MOF was prepared by using the simple one-pot solvothermal method using Eu as the metal i ion center and 3,5-dicarboxybenzeneboronic acid(BBDC)as the organic *** sensor showed desirable photoluminescent performance through the chelating of BBDC with Eu3+.The sensor exhibited the satisfactory linear relationship to GA in the range of 1 nM to 20 nM with a low detection limit of 0.34 nM under the optimized *** prepared sensor with ideal selectivity to GA was successfully applied for visualizing LFPs on porous substrates with the high contrast and superior *** the good performance of the sensor,all fingerprint images obtained from 1200 samples presented clear friction ridges and met the identification ***,the sensor had less impact on the subsequent deoxyribonucleic acid(DNA)detection,displaying a promising perspective for applications in extracting physical evidence of site investigation.

关键词： Europium metal-organic framework(Eu-MOF) photoluminescence 3,4,5-trihydroxybenzoic latent fingerprints(LFPs)development

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跨国公司研发全球化的空间组织研究

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经济地理 2005年第5期25卷 620-623页

作者：祝影杜德斌上海大学国际工商与管理学院中国上海201800 华东师范大学资源与环境科学学院中国上海200062

随着跨国公司全球战略目标的逐步深化,跨国公司研发全球化的组织形态也不断发生调整和变化,在理论上相继出现母国绝对集中式研发、母国相对集中式研发、多中心分散式研发、轴心型混合式研发、网络化整合研发五种类型。在一定的研发组织... 详细信息

随着跨国公司全球战略目标的逐步深化,跨国公司研发全球化的组织形态也不断发生调整和变化,在理论上相继出现母国绝对集中式研发、母国相对集中式研发、多中心分散式研发、轴心型混合式研发、网络化整合研发五种类型。在一定的研发组织形式引导下,跨国公司全球范围内的研发活动会产生集聚、扩散等地理现象,从地理特征和空间关联两个层面诠释着跨国公司研发全球化的空间形态,相对应的研发全球地理分布呈现出由孤岛中心、开放中心、多心分散、中心边缘向网络化结构发展的趋势,并通过各个分支机构之间的各种要素流诠释着跨国公司研发全球化的空间格局。

关键词：研发全球化组织演化空间组织跨国公司

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芬兰科技创新之路及对我国西部大开发的启示

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经济地理 2007年第4期27卷 538-542页

作者：王勇杜德斌华东师范大学城市与区域经济系中国上海200062

在全球信息科技革命浪潮中,芬兰通过重视发展教育和对科技人才的培养、加大研发投入对科技自主创新的支持,迅速地从上世纪初落后的农业国而快速发展成为1960年代经济、科技高度发达的高福利制国家,同时在2003年之后又超过美国成为世界... 详细信息

在全球信息科技革命浪潮中,芬兰通过重视发展教育和对科技人才的培养、加大研发投入对科技自主创新的支持,迅速地从上世纪初落后的农业国而快速发展成为1960年代经济、科技高度发达的高福利制国家,同时在2003年之后又超过美国成为世界最具竞争力的经济体,被誉为"芬兰奇迹"。当前,我国西部地区与芬兰经济腾飞前有许多相似之处。文章主要分析了芬兰走科技创新之路的前提,阐述了其高科技发展战略及相应举措,重点探讨了主要科技创新领域的发展现状,最后,结合我国当前的西部大开发提出了一些启示。

关键词：芬兰科技创新研发西部大开发可持续发展和谐社会

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Effect of Al content in molten steel on interaction between MgO-C refractory and SPHC steel

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Journal of Iron and Steel Research International 2024年第4期31卷 838-848页

作者： Fu-bin Gao Fu-ming Wang Xiang Zhang Tian-yu du Xin-hua Wangg School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China Handan Iron and Steel Company Hegang GroupHandan 056015HebeiChina The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

The effect of Al content in molten steel on the interaction between SPHC steel(0.005-0.068 wt.%Al,and 19×10^(-4)-58×10^(-4)wt.%O)and MgO-C refractory(11.63 wt.%C)was ***-metallic inclusions in the steel were examined at various periods(0,5,15,30,45,and 60 min)as well as the MgO-C interface after 60 min of corrosion at 1600℃.The results show that when MgO-C refractory comes into contact with SPHC steel,the refractory interface consists of three layers arranged from the innermost to the outermost,including the original refractory layer,the dense MgO layer,and the iron infiltration *** carbon in the MgO-C refractories and the Al content in the molten steel undergo a reaction with the MgO in the refractories,resulting in an increase in Mg concentration in the *** Al content in the molten steel from 0.005 to 0.068 wt.%causes a spinel layer to appear at the interface,and the disappearance time of Al_(2)O_(3) inclusions in the steel decreases from 60 to 30 min,while the average MgO content in inclusions ***,controlling the Al content in the molten steel and the smelting duration can help regulate the formation of spinel inclusionsinthe steel.

关键词： MgO-C refractory SPHC steel Inclusion-Spinel Al-killed steel Interfacial reaction

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Nano-frictional mechano-reinforcing porous nanowires scaffolds

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Friction 2024年第5期12卷 968-980页

作者： Licheng HUA Conghu HU Jingkang ZHANG Jin LI Chenjie GU bin HUANG Guangyong LI Jianke du Wanlin GUO Smart Materials and Advanced Structures Laboratory School of Mechanical Engineering&MechanicsNingbo UniversityNingbo315211China Key Laboratory for Intelligent Nano Materials and devices of Ministry of Education Nanjing University of Aeronautics and AstronauticsNanjing210016China Key Laboratory of Impact and Safety Engineering Ministry of EducationSchool of mechanical Engineering and MechanicsNingbo UniversityNingbo315211China department of Microelectronics and Engineering Ningbo UniversityNingbo315211China

Artificial biomaterials with dynamic mechano-responsive behaviors similar to those of biological tissues have been drawing great *** this study,we report a TiO_(2)-based nanowire(TiO_(2)NWs)scaffolds,which exhibit dynamic mechano-responsive behaviors varying with the number and amplitude of nano-deformation *** is found that the elastic and adhesive forces in the TiO_(2)NWs scaffolds can increase significantly after multiple cycles of *** nanofriction experiments show the triboelectric effect of increasing elastic and adhesive forces during the nano-deformation cycles of TiO_(2)NWs *** properties allow the TiO_(2)NW scaffolds to be designed and applied as intelligent artificial biomaterials to simulate biological tissues in the future.

关键词： TiO_(2)NWs scaffolds nano-deformation mechano-reinforcing triboelectric effect intelligent artificial biomaterials

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Dielectric and energy storage properties of PbO–SrO–Nb_(2)O_(5)–Na_(2)O–Si thin films by annealing

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Rare Metals 2024年第1期43卷 351-355页

作者： Fei-Hu Tan Qing-Meng Zhang Feng Wei Hong-bin Zhao Xiao Zhang Jun du State Key Laboratory of Advanced Materials for Smart Sensing General Research Institute for Nonferrous MetalsBeijing 100088China Advanced Electronic Materials Institute General Research Institute for Nonferrous MetalsBeijing 100088China

Dielectric and energy storage properties of PbOSrO-Na_(2)O-Nb_(2)O_(5)-SiO_(2)(PSNNS) thin films with annealing temperature from 700 to 850 ℃ were investigated by measuring their capacitance-electric filed curve and hysteresis *** results show that the highest dielectric constant and energy density are 81.2 and 17.0 J·cm^(-3),respectively,which is obtained in the sample with annealing temperature of 800 ℃.Annealed from 700 to800 ℃,the dielectric constant and energy storage performance of PSNNS films are continuously ***,with annealing temperature up to 850 ℃,their dielectric constant decreases,which might be related with the removal of interfacial defects as a function of annealing *** is one of the causes of space charge phenomenon,resulting in the increase in dielectric ***,the micro structure analysis by X-ray diffraction(XRD) and transmission electron microscope(TEM) indicates that the change of crystallization phase and interfacial polarization takes responsibility to the results.

关键词： Thin film Pulse laser deposition Annealing temperature Energy storage density

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