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Effect of low-speed waterjet pressure on the rock-breaking performance of unsubmerged cavitating abrasive waterjet

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Petroleum Science 2024年第4期21卷 2638-2649页

作者： Chen-Xing Fan deng Li Yong kang Hai-Tao Zhang Hubei Key Laboratory of Waterjet Theory and New Technology Wuhan University School of Power and Mechanical Engineering Wuhan University

Unsubmerged cavitating abrasive waterjet(UCAWj) has been shown to artificially create a submerged environment that produces shear cavitation, which effectively enhances rock-breaking performance. The shear cavitation generation and collapse intensity depend on the pressure difference between the intermediate high-speed abrasive waterjet and the coaxial low-speed waterjet. However, the effect of the pressure of the coaxial low-speed waterjet is pending. For this purpose, the effect of low-speed waterjet pressure on rock-breaking performance at different standoff distances was experimentally investigated,and the effects of erosion time and ruby nozzle diameter on erosion performance were discussed. Finally,the micromorphology of the sandstone was observed at different locations. The results show that increased erosion time and ruby nozzle diameter can significantly improve the rock-breaking performance. At different standoff distances, the mass loss increases first and then decreases with the increase of low-speed waterjet pressure, the maximum mass loss is 10.4 g at a low-speed waterjet pressure of0.09 MPa. The surface morphology of cavitation erosion was measured using a 3D profiler, the increase in both erosion depth and surface roughness indicated a significant increase in the intensity of the shear cavitation collapse. At a low-speed waterjet pressure of 0.18 MPa, the cavitation erosion surface depth can reach 600 μm with a roughness of 127 μm.

关键词： Rock-breaking Coaxial low-speed waterjet pressure Abrasive waterjet Cavitation Unsubmerged environment

Computer vision-aided DEM study on the compaction characteristics of graded subgrade filler considering realistic coarse particle shapes

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Railway Engineering Science 2024年第2期32卷 194-210页

作者： Taifeng Li kang Xie Xiaobin Chen Zhixing deng Qian Su Railway Engineering Research Institute China Academy of Railway Sciences Corporation LimitedBeijing 100081China Department of Civil Engineering Central South UniversityChangsha 410075China School of Civil Engineering Southwest Jiaotong UniversityChengdu 610031China

The compaction quality of subgrade filler strongly affects subgrade *** main objective of this research is to analyze the macro-and micro-mechanical compaction characteristics of subgrade filler based on the real shape of coarse ***,an improved Viola-jones algorithm is employed to establish a digitalized 2D particle database for coarse particle shape evaluation and discrete modeling purposes of subgrade *** indexes of 2D subgrade filler are then computed and statistically ***,numerical simulations are performed to quantitatively investigate the effects of the aspect ratio(AR)and interparticle friction coefficient(μ)on the macro-and micro-mechanical compaction characteristics of subgrade filler based on the discrete element method(DEM).The results show that with the increasing AR,the coarse particles are narrower,leading to the increasing movement of fine particles during compaction,which indicates that it is difficult for slender coarse particles to inhibit the migration of fine ***,the average displacement of particles is strongly influenced by the AR,indicating that their occlusion under power relies on particle *** dis-placement and velocity of fine particles are much greater than those of the coarse particles,which shows that compaction is primarily a migration of fine *** the cyclic load,the interparticle friction coefficientμhas little effect on the internal structure of the sample;under the quasi-static loads,however,the increase inμwill lead to a significant increase in the porosity of the *** study could not only provide a novel approach to investigate the compaction mechanism but also establish a new theoretical basis for the evaluation of intelligent subgrade compaction.

关键词： Subgrade filler particles Deep learning particle Shape analysis Particle library Compaction characteristics Discrete element method(DEM)

3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery

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Chinese Chemical Letters 2024年第8期35卷 425-432页

作者： Hengying Xiang Nanping deng Lu Gao Wen Yu Bowen Cheng Weimin kang State Key Laboratory of Separation Membranes and Membrane Processes Tiangong UniversityTianjin 300387China School of Textile Science and Engineering Tiangong UniversityTianjin 300387China

Satisfactory ionic conductivity,excellent mechanical stability,and high-temperature resistance are the prerequisites for the safe application of solid polymer electrolytes(SPEs)in all-solid-state lithium metal batteries(ASSLMBs).In this study,a novel poly(m-phenylene isophthalamide)(PMIA)-core/poly(ethylene oxide)(PEO)-shell nanofiber membrane and the functional Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)ceramic nanopar-ticle are simultaneously introduced into the PEO-based SPEs to prepare composite polymer electrolytes(CPEs).The core PMIA layer of composite nanofibers can greatly improve the mechanical strength and thermal stability of the CPEs,while the shell PEO layer can provide the 3D continuous transport channels for lithium *** addition,the introduction of functional LLZTO nanoparticle not only reduces the crys-tallinity of PEO,but also promotes the dissociation of lithium salts and releases more Li^(+)ions through its interaction with the Lewis acid-base of anions,thereby overall improving the transport of lithium ***,the optimized CPEs present high ionic conductivity of 1.38×10^(−4)S/cm at 30℃,signifi-cantly improved mechanical strength(8.5 MPa),remarkable thermal stability(without obvious shrinkage at 150℃),and conspicuous Li dendrites blocking ability(>1800 h).The CPEs also both have good com-patibility and cyclic stability with LiFePO_(4)(>2000 cycles)and high-voltage LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NMC811)(>500 cycles)*** addition,even at low temperature(40℃),the assembled LiFePO4/CPEs/Li bat-tery still can cycle *** novel design can provide an effective way to exploit high-performance solid-state electrolytes.

关键词： Composite polymer electrolytes Core-shell structured nanofiber Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)ceramic nanoparticle All-solid-state lithium metal batteries Outstanding thermal stability and electrochemical performance

Advanced preparation and application of bimetallic materials in lithium-sulfur batteries:A review

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journal of Energy Chemistry 2024年第1期88卷 469-512,I0011页

作者： Yongbing jin Nanping deng Yanan Li Hao Wang Meiling Zhang Weimin kang Bowen Cheng State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International joint Research on Separation Membranes School of Textile Science and EngineeringTiangong UniversityTianjin 300387China

Lithium-sulfur(Li-S)batteries are considered highly promising as next-generation energy storage systems due to high theoretical capacity(2600 Wh kg^(-1))and energy density(1675 mA h g^(-1))as well as the abundant natural reserves,low cost of elemental sulfur,and environmentally friendly ***,several challenges impede its commercialization including low conductivity of sulfur itself,the severe“shuttle effect”caused by lithium polysulfides(LiPSs)during charge–discharge processes,volume expansion effects and sluggish reaction *** a solution,polar metal particles and their compounds have been introduced as the main hosts for sulfur cathode due to their robust catalytic activity and adsorption capability,effectively suppressing the“shuttle effect”of Li *** alloys and their compounds with multi-functional properties exhibit remarkable electrochemical performance more readily when compared to single-metal ***-designed bimetallic materials demonstrate larger specific surface areas and richer active sites,enabling simultaneous high adsorption capability and strong catalytic *** synergistic effect of the“adsorption-catalysis”sites accelerates the adsorptiondiffusion-conversion process of Li PSs,ultimately achieving a long-lasting Li-S ***,the latest progress and performance of bimetallic materials in cathodes,separators,and interlayers of Li-S batteries are systematically ***,the principles and challenges of Li-S batteries are briefly ***,various mechanisms for suppressing“shuttle effects”of Li PSs are emphasized at the ***,the performance parameters of various bimetallic materials are comprehensively summarized,and some improvement strategies are proposed based on these ***,the future prospects of bimetallic materials are discussed,with the hope of providing profound insights for the rational design and manufacturing of high-performance bimetallic materia

关键词： Bimetallic materials Lithium-sulfur batteries Effectively suppress shuttle effect of LiPSs Significantly improve reaction kinetics Exceptionally long lifespan

Construction of ZnO@CDs@Co_(3)O_(4) sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO_(2) reduction

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Chinese Chemical Letters 2024年第4期35卷 147-152页

作者： Xiuzheng deng Yi Ke jiawen Ding Yingtang Zhou Hui Huang Qian Liang Zhenhui kang Advanced Catalysis and Green Manufacturing Collaborative Innovation Center CNPC-CZU Innovation AllianceSchool of Petrochemical EngineeringChangzhou UniversityChangzhou 213164China Institute of Functional Nano&Soft Materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow UniversitySuzhou 215123China Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control National Engineering Research Center for Marine AquacultureMarine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316004China

Photocatalytic conversion of CO_(2) into small-molecule chemical feedstocks can meet the growing demand for energy and alleviate the global warming. Herein, a p-n ZnO@CDs@Co_(3)O_(4) heterojunction with sandwich structure was constructed by calcination method of self-assembled ZIF-8@CDs@ZIF-67. The ZnO@CDs@Co_(3)O_(4) with well-defined interfacial structure exhibited the significantly enhanced photocatalytic CO_(2) reduction activity, and the optimal catalyst indicated the(CO + CH_(4)) evolution rate of 214.53μmol g^(-1)h^(-1) under simulated solar light, which was superior to ZnO, Co_(3)O_(4) and binary ZnO@Co_(3)O_(4).The internal cavity, exposed active sites, multiple interfaces and constructed p-n heterojunction can facilitate the light harvesting and photoexcited electron transfer. Besides, after introduction of CDs placed in the middle layer between ZnO and Co_(3)O_(4), CDs with excellent photoelectric property further promoted charge separation and migration. This work represents an appealing strategy to construct well-defined photocatalysts for boosting CO_(2) photoreduction.

关键词： Metal-organic framework Photocatalytic CO_(2) reduction Carbon dots p-n heterojunction Sandwich heterostructure

Regulating electrochemical performances of lithium battery by external physical field

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Rare Metals 2024年第6期43卷 2391-2417页

作者： Shi-kang Wang Shuai Wu Yi-Cheng Song Hassanien Gomaa Cui-Hua An Qi-Bo deng Ning Hu School of Mechanical Engineering School of Materials Science and EngineeringHebei University of TechnologyTianjin 300401China Shanghai Key Laboratory of Mechanics in Energy Engineering Shanghai 200444China Department of Chemistry Faculty of ScienceAl-Azhar UniversityAssiut 71524Egypt Tianjin Key Laboratory of Power Transmission and Safety Technology for New Energy Vehicles Tianjin 300401China State Key Laboratory of Reliability and Intelligence Electrical Equipment Key Laboratory of Advanced Intelligent Protective Equipment TechnologyMinistry of EducationHebei University of TechnologyTianjin 300130China

Lithium batteries have always played a key role in the field of new energy ***,non-controllable lithium dendrites and volume dilatation of metallic lithium in batteries with lithium metal as anodes have limited their ***,a large number of studies have shown that the electrochemical performances of lithium batteries can be enhanced through the regulation of external physical ***,it significantly hinders the growth of lithium dendrites and promoting the reaction *** review summarizes recent innovations in the investigation of various physical fields of lithium *** application of magnetic field in the synthesis of lithium battery electrode materials is *** influence factors and regulation mechanism of various physical fields on the electrochemical performance of lithium batteries are reviewed *** addition,the current research status and existing challenges,along with future directions for the evolution of lithium batteries,are minutely discussed and *** strategies for the further evolution of lithium batteries have also been provided.

关键词： Lithium battery External field assist Reaction kinetics Lithium dendrite

Tailoring the Microstructure and Mechanical Property of Mg-Zn Matrix Composite via the Addition of Al Element

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Acta Metallurgica Sinica(English Letters) 2024年第3期37卷 438-452页

作者： Chong Wang Fuyuan Liu Xuejian Wang Enyu Guo Zelong Du Kunkun deng Zongning Chen Huijun kang Guohao Du Tongmin Wang Key Laboratory of Solidification Control and Digital Preparation Technology(Liaoning Province) School of Materials Science and EngineeringDalian University of TechnologyDalian 116024China School of Mechanical Engineering Guizhou UniversityGuiyang 550025China Ningbo Institute of Dalian University of Technology Ningbo 315000China Shanxi Key Laboratory of Advanced Magnesium-Based Materials College of Materials Science and EngineeringTaiyuan University of TechnologyTaiyuan 030024China Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute CASShanghai 201204China

The semi-solid stir casting method is adopted to prepare 10 wt%SiC_(p)/Mg-6Zn-0.5Ca-xAl(x=0,1,3 and 5 wt%)composites,and the microstructure evolution and mechanical property of composites with various Al content are *** results show that the addition of 3 wt%Al improves the distribution of SiC_(p),whereas the SiC_(p) cluster occurs again with Al content greater than 3%.An abnormal phenomenon of twinning is observed in the cast composites in this *** SiC_(p)/Mg-6Zn-0.5Ca composite possesses the highest twin content of~23%,for which tension twins(TTW)and compression twins(CTW)account for~19%and~3%,*** CTW is only observed in ZXA600 *** addition of Al has an inhibiting effect for the generation and growth of *** content of twin decreases firstly and then increases with increase of Al *** lowest twin content is obtained as Al increases to 3 wt%.It is found the existence of twin is detrimental to the mechanical property of ***-cast SiC_(p)/Mg-6Zn-0.5Ca-3Al composite with the lowest twin content exhibits the optimal mechanical property of yield strength,ultimate tensile strength and elongation for 100 MPa,188 MPa and 4.4%,*** outstanding mechanical property is attributed to the uniform distribution of SiC_(p),the low twin content and the well-distributed fine second phases.

关键词： Mg matrix composite Synchrotron tomography Twinning Liquid melt processing Mechanical property

Design,preparation,application of advanced array structured materials and their action mechanism analyses for high performance lithium-sulfur batteries

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journal of Energy Chemistry 2024年第2期89卷 266-303,I0007页

作者： Nanping deng Xiaofan Feng Yongbing jin Zhaozhao Peng Yang Feng Ying Tian Yong Liu Lu Gao Weimin kang Bowen Cheng State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International joint Research on Separation Membranes School of Textile Science and EngineeringTiangong UniversityTianjin 300387China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China

Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage *** widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,*** various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li *** many novel array structured materials are applied to battery for tackling thorny problems mentioned *** this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are ***,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery ***,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are *** hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.

关键词： Array structured materials Preparation methods and structural designs Action mechanism analyses Advanced Li-S batteries Excellent electrochemical performances and safety

Sm-like 5 knockdown inhibits proliferation and promotes apoptosis of colon cancer cells by upregulating p53,CDKN1A and TNFRSF10B

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World journal of Gastrointestinal Oncology 2024年第6期16卷 2716-2726页

作者： Cai-j.ng Mo Xiao-Yuan deng Ru-Lan Ma Kun Zhu Lei Shi kang Li Department of Surgical Oncology The First Affiliated Hospital of Xi’an Jiaotong UniversityXi’an 710061Shaanxi ProvinceChina Department of Infectious Diseases The First Affiliated Hospital of Xi’an Jiaotong UniversityXi’an 710061Shaanxi ProvinceChina

BACKGROUND The role of Sm-like 5(LSM5)in colon cancer has not been *** this study,we investigated the role of LSM5 in progression of colon cancer and the potential underlying mechanism *** To determine the role of LSM5 in the progression of colon cancer and the potential underlying mechanism *** The Gene Expression Profiling Interactive Analysis database and the Human Protein Atlas website were used for LSM5 expression analysis and prognosis ***-time quantitative polymerase chain reaction and Western blotting were utilized to detect the expression of mRNAs and proteins.A lentivirus targeting LSM5 was constructed and transfected into colon cancer cells to silence LSM5 *** and apoptosis assays were also conducted to evaluate the growth of the colon cancer *** GeneChip assay and bioinformatics analysis were performed to identify the potential underlying mechanism of LSM5 in colon *** LSM5 was highly expressed in tumor tissue and colon cancer cells.A high expression level of LSM5 was related to poor prognosis in patients with colon *** of LSM5 suppressed proliferation and promoted apoptosis in colon cancer *** of LSM5 also facilitates the expression of p53,cyclin-dependent kinase inhibitor 1A(CDKN1A)and tumor necrosis factor receptor superfamily 10B(TNFRSF10B).The inhibitory effect of LSM5 knockdown on the growth of colon cancer cells was associated with the upregulation of p53,CDKN1A and *** LSM5 knockdown inhibited the proliferation and facilitated the apoptosis of colon cancer cells by upregulating p53,CDKN1A and TNFRSF10B.

关键词： Sm-like 5 Colon cancer Proliferation Apoptosis Knockdown