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Photoelectrocatalytic hydrogen evolution and synchronous degradation of organic pollutants by pg-C_(3)N_(4)/β-FeOOH S-scheme heterojunction

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Science China(Technological Sciences) 2024年第4期67卷 1238-1252页

作者： LI XiBao HAN Tao ZHOU YingTang XIE Yu LUO YiDan HUANG JunTong CHEN Zhi deng fang School of Materials Science and Engineering Nanchang Hangkong UniversityNanchang 330063China National-Local Joint Engineering Research Center of Heavy Metal Pollutants Control and Resource Utilization Nanchang Hangkong UniversityNanchang 330063China Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control National Engineering Research Center for Marine AquacultureMarine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316022China

Crafting photoelectrocatalytic materials with robust oxidation-reduction properties for simultaneous hydrogen evolution and pollutant degradation poses a formidable challenge.In this study,a pg-C_(3)N_(4)/β-FeOOH S-scheme heterostructure with a special energy band structure was developed by anchoring porous pg-C_(3)N_(4)on needle shapedβ-FeOOH.Functioning as a hole extraction layer,needle-leaf-likeβ-FeOOH can facilitate efficient hole migration and enhance charge transport.Remarkably,the optimized 0.2-pg-C_(3)N_(4)/β-FeOOH could degrade 78%of ofloxacin(OFLO)in 90 min.The organic pollutants could absorb a large number of holes,which prompted a greater proportion of photogenerated electrons to actively participate in the hydrogen evolution reaction at the cathode.Consequently,the hydrogen production of 0.2-pg-C_(3)N_(4)/β-FeOOH reached 1452.88μmol cm^(-2)h^(-1),exhibiting a notable increase of 61.81-165.12μmol cm^(-2)h^(-1)compared with that in the absence of pollutants.Experimental and theoretical calculation results underscore that this investigation is grounded in a distinctive electron and hole dual channel transfer mechanism.These findings offer novel insights for the future development of S-scheme heterojunction photoelectrocatalytic materials capable of concurrently degrading pollutants and promoting hydrogen evolution.

关键词： photoelectrocatalysis hydrogen evolution degradation synchronous S-scheme heterojunction

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Timing theory integrated nursing combined behavior change integrated theory of nursing on primiparous influence

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World Journal of Clinical Cases 2024年第2期12卷 293-301页

作者： Yan-Xia He Yang Lv Ting-Ting Lan fang deng Yuan-Yuan Zhang Department of Obstetrics and Gynecology Wuhan Children’s HospitalWuhan 430015Hubei ProvinceChina Center for Reproductive Medicine Department of Obstetrics and GynecologySichuan Provincial People's HospitalSchool of MedicineUniversity of Electronic Science and Technology of ChinaChengdu 610072Sichuan ProvinceChina

BACKGROUND The comprehension and utilization of timing theory and behavior change can offer a more extensive and individualized provision of support and treatment alternatives for primipara.This has the potential to enhance the psychological well-being and overall quality of life for primipara,while also furnishing healthcare providers with efficacious interventions to tackle the psychological and physiological obstacles encountered during the stages of pregnancy and postpartum.AIM To explore the effect of timing theory combined with behavior change on selfefficacy,negative emotions and quality of life in patients with primipara.METHODS A total of 80 primipara cases were selected and admitted to our hospital between August 2020 and May 2022.These cases were divided into two groups,namely the observation group and the control group,with 40 cases in each group.The nursing interventions differed between the two groups,with the control group receiving routine nursing and the observation group receiving integrated nursing based on the timing theory and behavior change.The study aimed to compare the pre-and post-nursing scores of Chinese Perceived Stress Scale(CPSS),Edinburgh Postpartum Depression Scale(EPDS),Self-rating Anxiety Scale(SAS),breast milk knowledge,self-efficacy,and SF-36 quality of life in both groups.RESULTS After nursing,the CPSS,EPDS,and SAS scores of the two groups was significantly lower than that before nursing,and the CPSS,EPDS,and SAS scores of the observation group was significantly lower than that of the control group(P=0.002,P=0.011,and P=0.001 respectively).After nursing,the breastfeeding knowledge mastery,selfefficacy,and SF-36 quality of life scores was significantly higher than that before nursing,and the breastfeeding knowledge mastery(P=0.013),self-efficacy(P=0.008),and SF-36 quality of life(P=0.011)scores of the observation group was significantly higher than that of the control group.CONCLUSION The integration of timing theory and behavior change integrated theory has been found to be a

关键词： Timing theory Behavior change Primipara Bad mood Quality of life

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Clinical nursing value of predictive nursing in reducing complications of pregnant women undergoing short-term massive blood transfusion during cesarean section

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World Journal of Clinical Cases 2024年第1期12卷 51-58页

作者： Li Cheng Li-Ping Li Yuan-Yuan Zhang fang deng Ting-Ting Lan Department of Obstertrics Wuhan Third HospitalWuhan 430000Hubei ProvinceChina Department of Gynaecology Wuhan No.1 HospitalWuHan 430030Hubei ProvinceChina Center for Reproductive Medicine Department of Obstetrics and GynecologySichuan Provincial People's HospitalSchool of MedicineUniversity of Electronic Science and Technology of ChinaChengdu 610072Sichuan ProvinceChina

BACKGROUND Cesarean hemorrhage is one of the serious complications,and short-term massive blood transfusion can easily cause postoperative infection and physical stress response.However,predictive nursing intervention has important clinical significance for it.AIM To explore the effect of predictive nursing intervention on the stress response and complications of women undergoing short-term mass blood transfusion during cesarean section(CS).METHODS A clinical medical record of 100 pregnant women undergoing rapid mass blood transfusion during sections from June 2019 to June 2021.According to the different nursing methods,patients divided into control group(n=50)and observation group(n=50).Among them,the control group implemented routine nursing,and the observation group implemented predictive nursing intervention based on the control group.Moreover,compared the differences in stress res-ponse,complications,and pain scores before and after the nursing of pregnant women undergoing rapid mass blood transfusion during CS.RESULTS The anxiety and depression scores of pregnant women in the two groups were significantly improved after nursing,and the psychological stress response of the observation group was significantly lower than that of the control group(P<0.05).The heart rate and mean arterial pressure(MAP)of the observation group during delivery were lower than those of the control group,and the MAP at the end of delivery was lower than that of the control group(P<0.05).Moreover,different pain scores improved significantly in both groups,with the observation group considerably less than the control group(P<0.05).After nursing,complications such as skin rash,urinary retention,chills,diarrhea,and anaphylactic shock in the observation group were 18%,which significantly higher than in the control group(4%)(P<0.05).CONCLUSION Predictive nursing intervention can effectively relieve the pain,reduce the incidence of complications,improve mood and stress response,and serve as a reference value for the nursing of women underg

关键词： Predictive care Rapid mass blood transfusion Cesarean section Stress response Complications

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Achieving laparoscopic anatomic resection for hepatocellular carcinoma by fluorescence guided positive staining of hepatic cone unit

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Hepatobiliary & Pancreatic Diseases International 2024年第4期23卷 406-411页

作者： Jun-fang deng Chuan-Hui Peng Yu Zhang Xiao-Feng Xu Rong-Liang Tong Zheng-Long Zhai Di-Yu Chen Cheng Zhang Li-Ming Wu Jian Wu Division of Hepatobiliary Pancreatic Surgery the First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003China

Laparoscopic anatomical liver resection has been increasingly reported worldwide,but how to demarcate the resection planes is technically challenging[1].Positive staining technique with intraoperative indocyanine green(ICG)-fluorescence imaging has been introduced as an effective tool for real-time intraoperative guidance[2].Liver anatomy is complex.Generally,liver is composed of 9 segments,each is composed of two to three subsegments,and each subsegment contains several hepatic cone units.A hepatic cone unit is dominated by a tertiary or quaternary hepatic pedicles[3].

关键词： hepatic resection anatomy

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Photovoltaic,thermoelectric and electromagnetic generation technologies applied in power systems for mobile unmanned systems

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Science China(Technological Sciences) 2023年第3期66卷 599-629页

作者： DING Ning WANG XiangYang XIAN XiaoYang CAI YeYun LIU DaoMing deng fang Key Laboratory of Intelligent Control and Decision of Complex Systems School of AutomationBeijing Institute of TechnologyBeijing 100081China Beijing Institute of Technology Chongqing Innovation Center Chongqing 401120China

Unmanned systems are increasingly adopted in various fields,becoming an indispensable technology in daily life.Power systems are the lifeblood of unmanned systems,and affect the working time and task complexity.However,traditional power systems,such as batteries and fuels have a fixed capacity.Therefore,once the power supply is exhausted and cannot be replenished in time,the unmanned systems will stop working.Hence,researchers have increasingly begun paying attention to renewable energy generation technologies.The principles,advantages,and limitations of renewable energy generation technologies are different,and their application effects in different unmanned systems are also uneven.This paper presents a comprehensive study of the application and development status of photovoltaic,thermoelectric,and magnetoelectric generation technologies in four kinds of unmanned systems,including space,aviation,ground,and water,and then summarizes the adaptability and limitations of the three technologies to different systems.Moreover,future development directions are predicted to enhance the reliability of renewable energy generation technologies in unmanned systems.This is the first study to conduct a comprehensive and detailed study of renewable energy generation technologies applied in unmanned systems.The present work is critical for the development of renewable energy generation technologies and power systems for unmanned systems.

关键词： unmanned system renewable energy generation technology photovoltaic generation thermoelectric generation electromagnetic generation

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毫米波通信的低复杂度时变信道估计算法

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控制工程 2024年第4期31卷 738-744页

作者：邓芳刘兵无锡科技职业学院物联网技术学院江苏无锡214028

当毫米波通信系统工作于时变信道场景中时,为解决通信用户快速位移导致的方位角计算误差和信道估计算法精度下降等问题,通常要消耗大量计算资源。因此,基于用户在快时变信道场景下的信号传输特征,首先在确定毫米波传输信号方位时采用对... 详细信息

当毫米波通信系统工作于时变信道场景中时,为解决通信用户快速位移导致的方位角计算误差和信道估计算法精度下降等问题,通常要消耗大量计算资源。因此,基于用户在快时变信道场景下的信号传输特征,首先在确定毫米波传输信号方位时采用对角加载方法,根据高斯白噪声先验信息得到对角加载方法的参数;然后采用对角带矩阵分解方法对所得到的信道干扰矩阵模型进行处理,从而降低信道估计与均衡算法的复杂度。仿真结果表明,所提算法能够使工作在时变信道条件下的通信系统以低于常规算法的运算复杂度处理系统中的干扰,且不降低传输性能。

关键词：发射角(angle of departure,AoD) 移动通信计算复杂度

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Two-dimensional RGO-bridge S-scheme phosphorus-doped g-C_(3)N_(4)/Bi_(5)O_(7)Ivan der Waals heterojunctions for efficient visible-light photocatalytic treatment of real pharmaceutical wastewater

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中国科学:技术科学英文版 2023年第10期66卷 3011-3024页

作者： WANG ZhenZhou XU XiWei deng fang DIONYSIOU Dionysios D LI XiBao PENG JunLong LUO XuBiao ZOU JianPing LUO ShengLian National-Local Joint Engineering Research Center of Heavy Metal Pollutants Control and Resource Utilization Nanchang Hangkong UniversityNanchang 330063China Environmental Engineering and Science Program Department of Chemical and Environmental Engineering(DChEE)University of CincinnatiCincinnati 45221-0012USA

The design of van der Waals heterojunctions with S-scheme charge transfer pathway is expected to be an effective strategy for improvement of photocatalytic performance.Herein,two-dimensional(2D)phosphorus-doped g-C_(3)N_(4)/Bi_(5)O_(7)Ivan der Waals heterojunctions with reduced graphene oxide as electron bridge(PCN/RGO/Bi_(5O)_(7)I)were successfully synthesized via hydrothermal method.The van der Waals interaction endowed 2D PCN/RGO/Bi_(5O)_(7)I with intimate contact interface,lattice match,tunable band structure,and internal electric field,which efficiently promoted interfacial charge separation and enhanced redox ability of photogenerated charge carriers.As a result,the S-scheme PCN/RGO/Bi_5O_7I van der Waals heterojunctions exhibited superior photocatalytic performance in ciprofloxacin degradation and real pharmaceutical wastewater treatment.The optimized 12%PCN/RGO/Bi_5O_7I displayed the highest photocatalytic activity with 92%removal of ciprofloxacin.Importantly,the COD removal efficiency and extent of mineralization of real pharmaceutical wastewater reached 66.9%and 59.8%,respectively,and the biodegradability of pharmaceutical wastewater was significantly improved.The photocatalytic mechanism of the S-scheme PCN/RGO/Bi_(5)O_(7)I van der Waals heterojunctions based on the analysis of reactive species,work function,and internal electric field was presented.This study provides fresh insights into plausible design of S-scheme van der Waals heterojunction to enhance photocatalytic redox ability.

关键词： S-scheme heterojunction van der Waals heterostructure photocatalytic degradation ciprofloxacin energy consumption

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企业股权网络结构与股价暴跌风险——来自中国市场的证据

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系统工程理论与实践 2024年第3期44卷 836-852页

作者：何琳洁谢志华邓芳常璐湖南师范大学商学院长沙410081 北京工商大学商学院北京100048

与传统的企业股权关系相比,日益复杂的交叉持股形成的股权网络使企业能够更好地获得信息和资源,从而缓解企业各类风险.但股权网络结构对企业股价暴跌风险的影响机理尚不明晰.本文采取社会网络分析方法,基于2007–2021年中国市场数据,考... 详细信息

与传统的企业股权关系相比,日益复杂的交叉持股形成的股权网络使企业能够更好地获得信息和资源,从而缓解企业各类风险.但股权网络结构对企业股价暴跌风险的影响机理尚不明晰.本文采取社会网络分析方法,基于2007–2021年中国市场数据,考察了上市企业股权网络结构特征对股价暴跌风险的影响机制.研究发现,在中国市场上,居于股权网络结构的战略位置,能够为企业带来协同治理优势.居于网络核心位置的企业,可以凭借信息与资源优势,以及声誉机制等治理手段,部分消除控股股东与管理者之间的信息不对称,治理管理者窖藏坏消息行为,从而削弱企业未来股价暴跌风险.这一结论经过一系列稳健性检验后仍然成立.进一步研究表明,产权制度和区域经济发展差异并不影响股权网络结构对企业股价暴跌风险的抑制作用,但在非国有企业和经济欠发达地区的企业,该治理效果更为明显.本文的研究结果证实企业股权网络结构形成的社会关系有助于改善企业内部治理环境,拓展丰富了企业股价暴跌风险影响因素的研究,对防范企业股价暴跌风险具有重要的实践意义.

关键词：股权网络结构股价暴跌风险网络中心性

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Adaptive Observer Based Backstepping Controller Design for Dynamic Ship Positioning

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China Ocean Engineering 2017年第5期31卷 639-645页

作者： deng fang WANG Long-jin JIAO Dong-mei College of Mechanical & Electrical Engineering Qingdao University of Science & Technology

Modified adaptive observer based backstepping control system for dynamic positioning of ship is proposed. As an improvement, the adaptive observer takes the first-order wave frequency model and the bias term which represent the slowly varying environmental disturbances and the unmodeled dynamics. Thus, the wave-frequency motions are filtered out, and only the reconstructed low-frequency motions are sent as inputs of the controller. Furthermore, as the ship dynamics parameters are unknown, the adaptive estimation law is designed for both the unknown ship dynamics and the unmeasured state variables. Based on the estimated states and parameters, backstepping controller considering the integral action is designed. Global exponential stability （GES） for the total system is proved using Lyapunov direct method. Simulation results show a good performance of the observer and control system.

关键词： Dynamic positioning backstepping control adaptive observer parameter estimation

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An Improved Sensor Fault Diagnosis Scheme Based on TA-LSSVM and ECOC-SVM

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Journal of Systems Science & Complexity 2018年第2期31卷 372-384页

作者： GU Xiaodan deng fang GAO Xin ZHOU Rui School of Automation Beijing Institute of Technology Beijing 100081 China Department of Information Equipment Equipment Institute of PLA Beijing 101416 China School of Automation Beijing Institute of Technology Beijing 100081 China.

即时监视传感器的运作的状态并且差错的精确诊断是必要的。这份报纸为传感器建议一个改进差错诊断计划，它包括差错察觉和差错鉴定。第一，趋势分析与最少的广场结合了支持向量机器(TA-LSSVM ) 方法被建议并且实现了检测差错。第二，改... 详细信息

即时监视传感器的运作的状态并且差错的精确诊断是必要的。这份报纸为传感器建议一个改进差错诊断计划，它包括差错察觉和差错鉴定。第一，趋势分析与最少的广场结合了支持向量机器(TA-LSSVM ) 方法被建议并且实现了检测差错。第二，改正产量代码支持向量机器(ECOC-SVM ) 的一个改进错误基于差错鉴定方法被建议区分不同传感器失败模式。表明建议计划的有效性，实验与一个 MTi 系列传感器，和比较与另外的差错鉴定方法被做的一些被进行。试验性的结果证明建议差错诊断计划与察觉提供必要改进即时性质和更好的鉴定精确性。

关键词：监视传感器诊断鉴定方法支持向量 MTi 精确性试验性即时

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