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物理化学学报 2008年第8期24卷 1387-1392页

作者： ZCAN Muzaffer KARADA■ Faruk dehri lyas Department of Science and Technology Education Cukurova University Department of Physics Cukurova University Department of Chemistry Cukurova University Department of Chemistry Korkut Ata University Osmaniye 80000 Turkey

Interfacial behavior of cysteine (Cys) between mild steel and sulfuric acid solution as a corrosion inhibitor has been studied with electrochemical AC (alternating current) and DC (direct current) techniques at (25.0±0.1) ℃. The AC impedance results were evaluated using equivalent circuits in which a constant phase element (CPE) has been replaced with double layer capacitance (Cdl) to represent the frequency distribution of experimental data. Changes in impedance parameters (charge transfer resistance and double layer capacitance) indicated that cysteine molecules acted by accumulating at the metal/solution interface. The fractional coverage of the metal surface (θ) was determined using AC impedance results and it was found that the adsorption of cysteine on the mild steel surface followed a Langmuir isotherm model with a standard free energy of adsorption (△G0 ads) of -35.1 kJ·mol-1. To clarify the type of interaction between mild steel surface and cysteine molecules with a molecular orbital approach, electronic properties, such as, the highest occupied molecular orbital (HOMO) energy, the lowest unoccupied molecular orbital (LUMO) energy, and the frontier molecular orbital coefficients have been calculated. Energy gaps for the interaction of mild steel surface and cysteine molecules (ELUMO Fe-EHOMO Cys and ELUMO Cys-EHOMO Fe) were used to determine whether cysteine molecules acted as electron donors or electron acceptors when they interacted with the mild steel surface. The local reactivity was evaluated through the condensed Fukui indices. Theoretical calculations were carried out using the density functional theory (DFT) at B3LYP level with the 6-311++G(d,p) basis set for all atoms by Gaussian 03W program.

关键词：软钢防腐技术缓蚀剂半胱氨酸硫磺酸

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Second Order Sliding Mode Control for Discrete Decouplable Multivariable Systems via Input-output Models

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International Journal of Automation and computing 2015年第6期12卷 630-638页

作者： Houda Romdhane Khadija dehri Ahmed Said Nouri Numerical Control of Industrial Processes National Engineering School of Gabes University of Gabes

The problem of the chattering phenomenon is still the main drawback of the classical sliding mode control. To resolve this problem, a discrete second order sliding mode control via input-output model is proposed in this paper. The proposed control law is synthesized for decouplable multivariable systems. A robustness analysis of the proposed discrete second order sliding mode control is carried out. Simulation results are presented to illustrate the effectiveness of the proposed strategy.

关键词： Discrete second order sliding mode control decoupl

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