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Outer-surface Covering of Nanochannels with Hydrogel for Highly Sensitive and Specific Cr(VI)Detection Through Analyte-caused Charge Change in Hydrogel

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Chemical Research in Chinese Universities 2024年第2期40卷 326-332页

作者： LIU Huan SUN Xueting dai yu ZHANG Xiaojin XIA Fan Faculty of Materials Science and Chemistry China University of GeosciencesWuhan430074P.R.China

Nanochannels have made great progress and are a promising platform for detecting a series of ***,most nanochannels are modified on the inner wall,while ignoring the outer ***,we modified the outer surface of nanochannels with *** from other reported outer-surface modification methods,we directly cover nanochannels with hydrogel to form heterogeneous *** selected hydrogel hardly adsorbs other ions and shows specific adsorption for Cr(VI).The adsorption sites in hydrogel are homogeneous,and Cr(VI)adsorption onto hydrogel is endothermic and *** charge in hydrogel changes after Cr(VI)adsorption,and the resulting current changes can be used for the detection of Cr(VI)with the detection limit of 10−11 mol/*** platform is expected to be used for Cr(VI)detection in living organisms,especially within *** work provides a new approach for outer-surface modification of nanochannels and offers a new choice for nanochannel detection platforms.

关键词： Nanochannel Hydrogel Heterogeneous membrane Cr(VI)detection

An Efficient Optimization Design Framework for Low-Resistance Shape of Bionic Amphibious Robot

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China Ocean Engineering 2024年第1期38卷 117-128页

作者： ZHANG dai-yu ZHANG Man-yu WANG Zhi-dong ZHENG Wen-sheng LING Hong-jie HU Jun-ming School of Naval Architecture and Ocean Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

To realize the low-resistance shape optimization design of amphibious robots,an efficient optimization design framework is proposed to improve the geometric deformation flexibility and optimization *** the proposed framework,the free-form deformation parametric model of the flat slender body is established and an analytical calculation method for the height constraints is *** method is introduced to carry out the high-precision resistance calculation and a constrained Kriging-based optimization method is built to improve the optimization efficiency by circularly infilling the new sample points which satisfying the ***,the shape of an amphibious robot example is optimized to get the low-resistance shape and the results demonstrate that the presented optimization design framework has the advantages of simplicity,flexibility and high efficiency.

关键词： amphibious robot optimization method free-form deformation CFD-based hydrodynamic calculation

Cyclodextrin nanofilms with hydrophobic and hydrophilic channels for solvent permeation and molecular sieving

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Nano Research 2024年第7期17卷 6638-6644页

作者： Kai Zhang yu dai Yongli Shi Zhaoxin Zhang Linji Li Xiaojin Zhang Fan Xia Faculty of Materials Science and Chemistry China University of GeosciencesWuhan 430074China Henan Academy of Geology Zhengzhou 450052China

Nanofilms that can fast permeate solvents and accurately sieve molecules are of significant importance for separation.A promising strategy is to align the inner cavities of macrocycles into the channels within nanofilms,and control the channel size by selecting the ***,the channels outside the macrocycles are ***,we prepare nanofilms with hydrophobic channels(cyclodextrin inner cavity)and hydrophilic channels(cyclodextrin outer space)through interfacial polymerization of azobenzene-4,4’-dicarbonyl dichloride and amino-functionalizedβ-*** utilizing the significant geometric changes caused by the photoisomerization of azobenzene,nanofilms with adjustable hydrophilic channel sizes were *** nanofilms have high permeability to polar and non-polar solvents,and can distinguish molecules with almost the same molecular weight but different *** work expands the development of next-generation nanofilms generated through interfacial polymerization by incorporating rational molecular design.

关键词： nanofilm β-cyclodextrin azobenzene interfacial polymerization solvent permeation molecular sieving

Design, performance and application of a line-imaging velocity interferometer system for any reflector coupled with a streaked optical pyrometer system at the Shenguang-Ⅱ upgrade laser facility

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High Power Laser Science and Engineering 2024年第1期12卷 52-59页

作者： Dawei yuan Shaojun Wang Huigang Wei Haochen Gu yu dai Jiayong Zhong yutong Li Gang Zhao Jie Zhang Key Laboratory of Optical Astronomy National Astronomical ObservatoriesChinese Academy of SciencesBeijingChina Institute of Frontiers in Astronomy and Astrophysics of Beijing Normal University BeijingChina Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijingChina Key Laboratory for Laser Plasmas(MOE)and School of Physics and Astronomy Shanghai Jiao Tong UniversityShanghaiChina Department of Astronomy Beijing Normal UniversityBeijingChina Collaborative Innovation Center of IFSA Shanghai Jiao Tong UniversityShanghaiChina School of Physical Sciences University of Chinese Academy of SciencesBeijingChina Songshan Lake Materials Laboratory DongguanChina

The velocity interferometer system for any reflector(VISAR) coupled with a streaked optical pyrometer(SOP) system is used as a diagnostic tool in inertial confinement fusion(ICF) experiments involving equations of state and shock *** validate the process of adiabatically compressing the fuel shell through precise tuning of shocks in experimental campaigns for the double-cone ignition(DCI) scheme of ICF, a compact line-imaging VISAR with an SOP system is designed and implemented at the Shenguang-II upgrade laser facility. The temporal and spatial resolutions of the system are better than 30 ps and 7 μm, respectively. An illumination lens is used to adjust the lighting spot size matching with the target size. A polarization beam splitter and λ/4 waveplate are used to increase the transmission efficiency of our system. The VISAR and SOP work at 660 and 450 nm, respectively, to differentiate the signals from the scattered lights of the drive lasers. The VISAR can measure the shock velocity. At the same time, the SOP system can give the shock timing and relative strength. This system has been used in different DCI campaigns, where the generation and propagation processes of multi-shock are carefully diagnosed.

关键词： double-cone ignition streaked optical pyrometer velocity interferometer system for any reflector

Continuous-flow electrosynthesis of urea and oxalic acid by CO_(2)-nitrate reduction and glycerol oxidation

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Chinese Journal of Catalysis 2024年第8期63卷 270-281页

作者： Shuanglong Zhou yue Shi yu dai Tianrong Zhan Jianping Lai Lei Wang Key Laboratory of Eco-Chemical Engineering Key Laboratory of Optic-electric Sensing and Analytical Chemistry of Life ScienceTaishan Scholar Advantage and Characteristic Discipline Team of Eco-Chemical Process and TechnologyCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042ShandongChina

Urea and oxalic acid are critical component in various chemical manufacturing ***,achieving simultaneous generation of urea and oxalic acid in a continuous-flow electrolyzer is a ***,we report a continuous-flow electrolyzer equipped with 9-square centime-ter-effective area gas diffusion electrodes(GDE)which can simultaneously catalyze the glycerol oxidation reaction in the anode region and the reduction reaction of CO_(2)and nitrate in the cathode region,producing oxalic acid and urea at both the anode and cathode,*** current density at low cell voltage(0.9 V)remained above 18.7 mA cm^(-2)for 10 consecutive electrolysis cycles(120 h in total),and the Faraday efficiency of oxalic acid(67.1%)and urea(70.9%)did not *** and theoretical studies show that in terms of the formation of C-N bond at the cathode,Pd-sites can provide protons for the hydrogenation process of CO_(2)and NO3-,Cu-sites can promote the generation of*COOH and Bi-sites can stabilize**** addition,in terms of glycerol oxidation,the introduction of Cu and Bi into Pd metallene promotes the oxidation of hydroxyl groups and the cleavage of C-C bond in glycerol molecules,respectively.

关键词： Urea Oxalic acid CO_(2) C-N bond Metallene

Polysulfide modified PtCu intermetallic nanocatalyst with enrichment realizes efficient electrooxidation ethanol to CO_(2)

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Nano Research 2024年第4期17卷 2320-2327页

作者： Shuanglong Zhou Zheng Lv Liang Zhao Dan Zhang Zuocao Wang yu dai Bin Li Olga Starostenko Jianping Lai Lei Wang Key Laboratory of Eco-chemical Engineering Ministry of EducationTaishan scholar advantage and characteristic discipline team of Eco-chemical process and technologyLaboratory of Inorganic Synthesis and Applied ChemistryCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China College of Foreign Languages Qingdao City UniversityQingdao 266106China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine Kyiv 02160Ukraine Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection College of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdao 266042China

The main problem faced by ethanol oxidation reaction(EOR)includes low activity,poor selectivity,and *** the study,we found that polysulfide modified on the surface of PtCu intermetallic(IM)/C can simultaneously enrich hydroxyl and ethanol,which could effectively improve the catalytic activity,CO_(2) selectivity,and durability of *** mass activity and the specific activity of the product in 1 M KOH electrolyte reached 17.83 A·mgPt^(-1) and 24.67 mA·cm^(-2).The CO_(2) selectivity of polysulfide modified product achieved 93.5%,which was 30 folds higher than Pt/*** addition,the catalyst showed high catalytic *** mechanism study demonstrates that the surface modified polysulfide could significantly boost the enrichment effect of ethanol and hydroxyl species,accelerating C–C bond cleavage and CO oxidation.

关键词： Pt CO_(2) selectivity enrichment effect ethanol oxidation reaction(EOR) electrocatalyst

Development and validation of a prediction model for early screening of people at high risk for colorectal cancer

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World Journal of Gastroenterology 2024年第5期30卷 450-461页

作者： Ling-Li Xu Yi Lin Li-yuan Han yue Wang Jian-Jiong Li Xiao-yu dai Department of General Surgery Ningbo No.2 HospitalNingbo 315000Zhejiang ProvinceChina Center for Health Economics Faculty of Humanities and Social SciencesUniversity of NottinghamNingbo 315100Zhejiang ProvinceChina Department of Global Health Ningbo Institute of Life and Health IndustryUniversity of Chinese Academy of SciencesNingbo 315000Zhejiang ProvinceChina School of Public Health Medical College of Soochow UniversitySuzhou 215123Jiangsu ProvinceChina

BACKGROUND Colorectal cancer(CRC)is a serious threat *** early screening is suggested to be the most effective method to prevent and control CRC,the current situation of early screening for CRC is still not *** China,the incidence of CRC in the Yangtze River Delta region is increasing dramatically,but few studies have been ***,it is necessary to develop a simple and efficient early screening model for *** To develop and validate an early-screening nomogram model to identify individuals at high risk of *** Data of 64448 participants obtained from Ningbo Hospital,China between 2014 and 2017 were retrospectively *** cohort comprised 64448 individuals,of which,530 were excluded due to missing or incorrect *** 63918,7607(11.9%)individuals were considered to be high risk for CRC,and 56311(88.1%)were *** participants were randomly allocated to a training set(44743)or validation set(19175).The discriminatory ability,predictive accuracy,and clinical utility of the model were evaluated by constructing and analyzing receiver operating characteristic(ROC)curves and calibration curves and by decision curve ***,the model was validated internally using a bootstrap resampling *** Seven variables,including demographic,lifestyle,and family history information,were *** logistic regression analysis revealed that age[odds ratio(OR):1.03,95%confidence interval(CI):1.02-1.03,P<0.001],body mass index(BMI)(OR:1.07,95%CI:1.06-1.08,P<0.001),waist circumference(WC)(OR:1.03,95%CI:1.02-1.03 P<0.001),lifestyle(OR:0.45,95%CI:0.42-0.48,P<0.001),and family history(OR:4.28,95%CI:4.04-4.54,P<0.001)were the most significant predictors of high-risk *** lifestyle was a protective factor,whereas family history was the most significant risk *** area under the curve was 0.734(95%CI:0.723-0.745)for the final validation set ROC curve and 0.735(95%CI:0.728-0.742)for the training s

关键词： Colorectal cancer Early screening model High-risk population Nomogram model Questionnaire survey Dietary habit Living habit

LASSO-LSSVM与激光诱导击穿光谱技术结合提高铝合金中Mn成分检测精度研究

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光谱学与光谱分析 2024年第4期44卷 977-982页

作者：戴宇佳高勋刘子源浙江农林大学光机电工程学院浙江杭州311300 长春理工大学物理学院吉林长春130022

铝合金作为一种重要的航空航天装备材料,其元素含量是决定铝合金材料质量和性能的关键因素,其组成成分的多样性对铝合金的铸造、冶炼以及回收分类有较大的影响,其中Mn是铝合金中的重要元素,能够止铝合金的再结晶过程,提高再结晶温度。... 详细信息

铝合金作为一种重要的航空航天装备材料,其元素含量是决定铝合金材料质量和性能的关键因素,其组成成分的多样性对铝合金的铸造、冶炼以及回收分类有较大的影响,其中Mn是铝合金中的重要元素,能够止铝合金的再结晶过程,提高再结晶温度。铝合金成分的定量测定是合金成分在线检测的重要组成部分。信号波动(激光能量波动、等离子体不稳定性、样品不均匀性等)和自吸收效应对激光诱导击穿光谱(LIBS)技术测定铝合金中微量元素有一定影响。为了消除自吸收效应和信号波动所引起的偏差,提出了一种利用LIBS技术结合LASSO-LSSVM机器学习法检测铝合金材料中微量元素含量的新方法。利用最小绝对收缩和选择算子(LASSO)模型对光谱特征向量进行选择,降低光谱数据的维度从而与训练样本相匹配,降低了过拟合风险,有效提取表征LIBS光谱最重要的特征。利用最小二乘支持向量机(LSSVM)模型对LASSO所选择的特征光谱进行训练,分析结果与内标法和偏最小二乘回归(PLSR)相比,LASSO-LSSVM回归模型的精度和准确性都有所提高,其中,Mn元素回归曲线的相关系数(R^(2))从74.62%提高到99.29%,平均相对误差(ARE)从22.38%降低到3.56%,训练集均方根误差(RMSEC)从0.66 wt%降低到0.040 wt%,测试集均方根误差(RMSEP)从0.58 wt%降低到0.042 wt%。LASSO-LSSVM回归模型适用于复杂、不确定性较高的高维光谱数据,能够大大降低输入光谱数据的维数和冗余信息,因此,该模型减少了LSSVM的过拟合问题。研究结果表明,LIBS技术和LASSO-LSSVM回归模型的结合可以有效改善LIBS技术对于铝合金材料的定量分析性能,是一种简单、可靠、高精度检测合金含量的新方法。

关键词：激光诱导击穿光谱铝合金 LASSO-LSSVM 定量分析

肥胖成因的新视角:代谢性炎症诱导食物奖赏异常

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生物化学与生物物理进展 2024年第6期51卷 1327-1340页

作者：代玉玺何玉秀陈巍河北师范大学体育学院石家庄050024 河北省人体运动生物信息测评重点实验室石家庄050024

近年来,肥胖已成为全球亟待解决的重要公共卫生问题。越来越多的研究发现,食物奖赏在肥胖的形成与发展过程中发挥重要作用。最近的研究表明,由于能量过剩引发的代谢性炎症可能通过多种生理途径干扰正常的奖赏信号传递,从而促进肥胖的发... 详细信息

近年来,肥胖已成为全球亟待解决的重要公共卫生问题。越来越多的研究发现,食物奖赏在肥胖的形成与发展过程中发挥重要作用。最近的研究表明,由于能量过剩引发的代谢性炎症可能通过多种生理途径干扰正常的奖赏信号传递,从而促进肥胖的发展。基于这一观点,推测产生肥胖的原因可能与代谢性炎症诱导食物奖赏异常有关。因此,深入探讨肥胖、食物奖赏和代谢性炎症之间的关系,总结代谢性炎症诱导食物奖赏异常的可能机制,可为预防和治疗肥胖提供新的思路和理论支持。

关键词：肥胖食物奖赏代谢性炎症