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Effect of Some Metal Ion Dopants on Electrochemical Properties of Ni(OH)_2 Film Electrode

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Chemical Research in Chinese Universities 2003年第4期19卷 494-498页

作者： ZhanG Heng-bin LIU han-san CAO Xue-jing SUN Chia-chung College of Chemistry State Key Laboratory of Theoretical and Computational ChemistryInstitute of Theoretical ChemistryJilin UniversityChangchun 130023P.R.China

The Ni(OH) 2 film electrodes doped respectively with alkali-earth metal aluminum, lead, partial transition metal and some rare-earth metal(altogether 17 kinds of metals) ions were prepared by cathode electrodeposition. The electrode reaction reversibility, the difficult extent of oxygen evolution, the proton diffusion coefficient, the discharge potential of middle value and the active material utilization of the Ni(OH) 2 film electrode were compared with those of the ones doped with the metal ions by means of cyclic voltammetry, potential step and constant current charge-discharge experiments. It was found that Ca 2+ , Co 2+ , Cd 2+ , Al 3+ etc. have obviously positive effect.

关键词： Film electrode Electrochemical properties Metal ion dopant

Effect of Palladium Nanoparticles on Photocatalytic Characteristics of N doped Titania Catalyst

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Journal of Materials Science & Technology 2015年第6期31卷 664-669页

作者： Jong-ho Lee Jeong-Il Youn Young-Jig Kim han-Jun Oh Department of Chemistry Hanseo University School of Advanced Materials Engineering Sungkyunkwan University Department of Materials Science Hanseo University

To improve the photocatalytic efficiency of TiO2nanotubular catalyst,N doped and Pd decorated titania nanotubes was successfully synthesized via anodizing,hydrazine hydrate treatment and photoreduction of Pd *** small Pd nanoparticles were precipitated on TiO2nanotubes through photoreduction of Pd ions,and its distribution is relatively *** X-ray photoelectron spectrometry（XPS） result,the N 1s spectrum represents two peaks with binding energy at 399.7 and 400.7 eV,which suggests that the nitrogen elements doped by hydrazine hydrate treatment are located in interstitial sites of the TiO2crystalline *** N doped TiO2nanotubes with Pd particles,a high photocurrent was detected due to increase of interface charge carrier separation ***,N doped and Pd decorated TiO2nanotubes exhibited much higher dye destruction efficiency and rate constant due to the synergistic effect of the N dopant and the Pd deposition on TiO2nanotubes.

关键词： Pd nanoparticle Titania nanotube Anodizing Dye dec

Challenges and opportunities for battery health estimation:Bridging laboratory research and real-world applications

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Journal of Energy Chemistry 2024年第2期89卷 434-436,I0011页

作者： Te han Jinpeng Tian C.Y.chung Yi-Ming Wei Center for Energy and Environmental Policy Research Beijing Institute of TechnologyBeijing 100081China School of Management and Economics Beijing Institute of TechnologyBeijing 100081China Department of Electrical and Electronic Engineering and Research Centre for Grid Modernization The Hong Kong Polytechnic UniversityKowloon 999077Hong KongChina

Addressing climate change demands a significant shift away from fossil fuels,with sectors like electricity and transportation relying heavily on renewable *** to this transition are energy storage systems,notably lithium-ion *** time,these batteries degrade,affecting their efficiency and posing safety *** and predicting battery aging is essential,especially estimating its state of health(SOH).Various SOH estimation methods exist,from traditional model-based approaches to machine learning approaches.

关键词： Energy storage systems State of health Multi-source data Scientific AI Data-sharing mechanism

Simulation of Storm Surge and Wave Due to Typhoon Isewan(5915)

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China Ocean Engineering 2015年第4期29卷 473-488页

作者： Jin-Hee YUK Kyeong Ok KIM han Soo LEE Byung ho ChoI Disaster Management HPC Technology Research Center Korea Institute of Science and Technology Information Marine Radionuclide Research Center Korea Institute of Ocean Science & Technology Graduate School of Science and Engineering Saitama University Department of Civil and Environmental Engineering Sungkyunkwan University

An integrally coupled wave-tide-surge model was developed and then applied to the simulation of the wave-typhoon surge for the typhoon Isewan （typhoon Vera （5915））, which is the strongest typhoon that has struck Japan and caused incalculable damage. An integrally coupled tide-surge-wave model using identical and homogeneous meshes in an unstructured grid system was used to correctly resolve the physics of wave-circulation interaction in both models. All model components were validated independently. The storm surge and wave properties such as the surge height, the significant wave height, wave period and direction were reproduced reasonably under the meteorological forcing, which was reprocessed to be close to the observations. The resulting modeling system can be used extensively for the prediction of the storm surge and waves and the usual barotropic forecast.

关键词： typhoon Isewan storm surge wave tide coupled wave-tide-surge model

Zn-doped nickel iron(oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation

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Journal of Energy Chemistry 2023年第6期81卷 82-92,I0004页

作者： So Jung Kim Heechae Choi Jeong ho Ryu Kang Min Kim Sungwook Mhin Arpan Kumar Nayak Junghwan Bang Minyeong Je Ghulam Ali Kyung Yoon chung Kyeong-han Na Won-Youl Choi Sunghwan Yeo Jin Uk Jang HyukSu han Department of Energy Engineering Konkuk University120 Neungdong-roGwangjin-guSeoul 05029Republic of Korea Theoretical Materials&Chemistry Group Institute of Inorganic ChemistryUniversity of CologneGreinst.650939CologneGermany Materials Lab Geobuk-ro 25-50Incheon 22793Republic of Korea Department of Materials Science and Engineering Korea National University of Transportation50 Daehak-roChungjuChungbuk 27469Republic of Korea Korea Institute of Industrial Technology 137-41 Gwahakdanji-roGangneung-siGangwon 25440Republic of Korea Department of Advanced Materials Engineering Kyonggi UniversitySuwon 16227Republic of Korea Korea Institute of Industrial Technology 156 Gaetbeol-roYeonsu-guIncheon 406-840Republic of Korea U.S.-Pakistan Center for Advanced Studies in Energy(USPCASE) National University of Sciences and Technology(NUST)H-12IslamabadPakistan Energy Storage Research Center Korea Institute of Science and TechnologyHwarang-ro 14-gil 5Seongbuk-guSeoul 02792Republic of Korea Division of Energy and Environment Technology KIST SchoolKorea University of Science and TechnologySeoul 02792Republic of Korea Department of Metal and Materials Engineering Gangneung-Wonju National University 7 JukheongilGangneungGangwon 25457Republic of Korea Smart Hydrogen Energy Center Gangneung-Wonju National University7 JukheongilGangneungGangwon 25457Republic of Korea Innovative Fuel Development Division Korea Atomic Energy Research InstituteDaedeok-daero 989-111Yuseong-guDaejeon 305-353Republic of Korea

Electrochemical water splitting to produce hydrogen fuel is a promising renewable energy-conversion ***-scale electrolysis of freshwater may deplete water resources and cause water scarcity ***,seawater electrolysis is a potential solution to the future energy and water *** seawater electrolysis,it is critical to develop cost-effective electrocatalysts to split seawater without chloride ***,we present zinc-doped nickel iron(oxy)hydroxide nanocubes passivated by negatively charged polyanions(NFZ-PBA-S)that exhibits outstanding catalytic activity,stability,and selectivity for seawater *** dopants and polyanion-rich passivated surface layers in NFZ-PBA-S could effectively repel chlorine ions and enhance corrosion resistance,enabling its excellent catalytic activity and stability for seawater oxidation.

关键词： Seawater splitting Oxygen evolution reaction Electrocatalyst Layered double hydroxide Sulfidation

Dual in-situ observation of tribochemical and morphological evolution of single-layer WS_(2)and multi-layer WS_(2)/C coatings

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Friction 2024年第7期12卷 1580-1598页

作者： Yuzhen LIU Jae-ho han Shusheng XU Young Chan JUNG Dae-Eun KIM State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Department of Mechanical Engineering Yonsei UniversitySeoul03722Republic of Korea Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai Yantai 264000China Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering Yantai 264000China

The outstanding tribological performance of transition metal dichalcogenides(TMDs)is attributed to their unique sandwich microstructure and low interlayer shear *** advantageous structure allows TMDs to demonstrate exceptional friction reduction ***,the incorporation of TMDs and amorphous carbon(a-C)in multi-layer structures shows excellent potential for further enhancing tribological and anti-oxidation *** carbon,known for its high ductility,chemical inertness,and excellent wear resistance,significantly contributes to the overall performance of these multi-layer *** gain an in-depth understanding of the tribological mechanism and evolution of TMDs’multi-layer coatings,a dual in-situ analysis was carried out using a tribometer equipped with a 3D laser microscope and a Raman *** innovative approach allowed for a comprehensive evolution of the tribological,topographical,and tribochemical characteristics of both single-layer WS_(2)and multi-layer WS_(2)/C coatings in real *** findings from the dual in-situ tribotest revealed distinct failure characteristics between the single-layer WS_(2)coating and the multi-layer WS_(2)/C *** single-layer WS_(2)coating predominantly experienced failure due to mechanical removal,whereas a combination of mechanical removal and tribochemistry primarily influenced the failure of the multi-layer WS_(2)/C *** tribological evolution process of these two coatings can be classified into four stages on the basis of their tribological behavior:the running-in stage,stable friction stage,re-deposition stage,and lubrication failure *** stage represents a distinct phase in the tribological behavior of the coatings and contributes to our understanding of their behavior during sliding.

关键词： In-situ analysis multi-layer coating tribology tribochemistry

AI-infused Semantic Model to Enrich and Expand Programming Question Generation

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Journal of Artificial Intelligence and Technology 2022年第2期2卷 47-54页

作者： I-han Hsiao Cheng-Yu chung Santa Clara University Santa ClaraCAUSA Arizona State University TempeAZUSA

Creating practice questions for programming learning is not *** requires the instructor to diligently organize heterogeneous learning resources,that is,conceptual programming concepts and procedural programming ***’s programming question generation(PQG)is still largely relying on the demanding creation task performed by the instructors without advanced technological *** this work,we propose a semantic PQG model that aims to help the instructor generate new programming questions and expand the assessment *** PQG model is designed to transform conceptual and procedural programming knowledge from textbooks into a semantic network by the Local Knowledge Graph(LKG)and Abstract Syntax Tree(AST).For any given question,the model queries the established network to find related code examples and generates a set of questions by the associated LKG/AST semantic *** conduct analysis to compare instructor-made questions from 9 undergraduate introductory programming courses and textbook *** results show that the instructormade questions had much simpler complexity than the textbook *** disparity of topic distribution intrigued us to further research the breadth and depth of question quality and also to investigate the complexity of the questions in relation to the student ***,we report a user study results on the proposed Artificial Intelligent-infused semantic PQG model in examining the machine-generated questions’quality.

关键词： Assessment Programming Semantic Modeling Automatic Question Generation

Study of cerium-promoted rhodium alumina catalyst as a steam reforming catalyst for treatment of spent solvents

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Journal of Rare Earths 2014年第9期32卷 831-836页

作者： Hee-Chul Yang Min-Woo Lee ho-Sang Hwang Jei-Kwon Moon Dong-Yong chung Korea Atomic Energy Research Institute

This study attempted to develop an appropriate catalyst used for the steam reforming of gasified spent solvents. Rh2O3/ CeOE-Al2O3 catalysts with various CeO2 loadings were prepared and heated at different temperatures of 500 and 800 ℃, and their surface properties were studied using X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS）, transmission electron microscopy （TEM）, temperature programmed reduction （TPR） and Bmmauer-Emmett-Teller （BET） analyses. Rhodium existed in the form of Rh2O3, regardless of the sample composition as well as the heating temperature. In the tested range of cerium addition （up to 12 times the rhodium mass）, no significant changes in BET surface areas and binding energy corresponding to Rh 3d5/2 were observed. Instead, the addition of cerium led to a greatly enhanced dispersion of rhodium nanoparticles, and no agglomeration of rhodium was observed for samples heated even at 800 ℃. honeycomb monolith rhodium catalysts promoted with cerium were fabricated and tested for the steam reforming of a gasified spent solvent, mainly consisting of butylene （C4H8）. The test results suggested that a cerium-promoted rhodium catalyst could be used as an appropriate reforming catalyst for treating low-quality non-methane hydrocarbons without the formation of coke at high temperatures of up to 900 ℃.

关键词： cerium rhodium catalyst steam reforming spent resin rare earths

Anion storing,oxygen vacancy incorporated perovskite oxide composites for high-performance aqueous dual ion hybrid supercapacitors

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Journal of Energy Chemistry 2024年第7期94卷 646-655页

作者： Taehun Kang Puritut Nakhanivej Kyung Jae Wang Yu Chen Yongchul G chung ho Seok Park School of Chemical Engineering Sungkyunkwan University(SKKU)2066Seobu-roJangan-guSuwonGyeonggi-do 16419Republic of Korea Warwick Manufacturing Group(WMG) University of WarwickCoventry CV47ALUnited Kingdom School of Chemical Engineering Pusan National UniversityGeumjeong-guBusanGyeongsangnam-do 46241Republic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan University2066SeoburoJangan-guSuwon 440-746Republic of Korea SKKU Advanced Institute of Nano Technology(SAINT) Sungkyunkwan University2066SeoburoJangan-guSuwon 440-746Republic of Korea Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences and Technology(SAIHST)Sungkyunkwan UniversitySuwon 16419Republic of Korea

Dual ion storage hybrid supercapacitors(HsCs)are considered as a promising device to overcome the limited energy density of existing supercapacitors while preserving high power and long ***,the development of high-capacity anion-storing materials,which can be paired with fast charg-ing capacitive electrodes,lags behind cation-storing ***,we demonstrate the surface faradaic OH-storage mechanism of anion storing perovskite oxide composites and their application in high-performance dual ion *** oxygen vacancy and nanoparticle size of the reduced LaMnO_(3)(r-LaMnO_(3))were controlled,while r-LaMnO_(3) was chemically coupled with ozonated carbon nanotubes(oCNTs)for the improved anion storing capacity and cycle *** taken by in-situ and ex-situ spectroscopic and computational analyses,OH-ions are inserted into the oxygen vacancies coordi-nating with octahedral Mn with the increase in the oxidation state of Mn during the charging process or vice *** OH-storing r-LaMnO_(3)/oCNT composite with Na*storing MXene,the as-fabricated aqueous dual ion HSCs achieved the cycle performance of 73.3%over 10,000 cycles,delivering the max-imum energy and power densities of 47.5 w h kg^(-1) and 8 kw kg^(-1),respectively,far exceeding those of previously reported aqueous anion and dual ion storage *** research establishes a foundation for the unique anion storage mechanism of the defect engineered perovskite oxides and the advancement of dual ion hybrid energy storage devices with high energy and power densities.

关键词： Anion storage Dual ion storage Defect engineered perovskites Hybrid supercapacitors Nanocomposites