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Chinese Chemical Letters 2024年第10期35卷 126-138页

作者： Qiyan Wu Ruixin Zhou Zhangyi Yao Tanyuan wang qing Li State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

Water splitting with proton exchange membrane water electrolyzers(PEMWE)is regarded as a promising pathway for sustainable hydrogen ***,oxygen evolution reaction(OER)is considered as the dominant factor during the whole process due to the sluggish *** the catalysts,Rubased catalysts draw special attention because of their excellent activity and relatively low ***,the limited stability impedes their further commercialization and tremendous efforts have been devoted to overcome this *** review firstly introduces the basic mechanisms of *** the evaluation protocols and techniques to investigate the stability of Ru-based catalysts are summarized.A detailed elucidation of the possible degradation mechanisms is also critically ***,effective strategies to design durable Ru-based catalysts for acidic OER are *** as heteroatom doping,phase and facet engineering,heterostructure building and support ***,promises,perspectives and challenges in developing highly durable Ru-based catalysts for acidic OER are outlined.

关键词： Acidic oxygen evolution Ru-based catalysts Stability Degradation mechanisms Optimization strategies

Flexible assistance strategy of lower limb rehabilitation exoskeleton based on admittance model

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Science China(Technological Sciences) 2024年第3期67卷 823-834页

作者： KOU JianGe wang YiXuan CHEN ZhenLei SHI Yan GUO qing XU Meng School of Automation Science and Electrical Engineering Beihang UniversityBeijing 100191China School of Aeronautics and Astronautics University of Electronic Science and Technology of ChinaChengdu 611731China Department of Musculoskeletal Tumor Senior Department of Orthopedicsthe Fourth Medical Centerof PLA GeneralHospitalBeijing 100853China

Exercise training based on exoskeleton is an effective rehabilitation method for stroke patients. However, some rehabilitation exoskeletons still have poor wearable performance and obvious human-robot impedance during training, which easily cause secondary injuries to the patients. In this study, a variable admittance control strategy is proposed to improve the operator's wearable comfort, which can adapt to different operators by regulating admittance parameters. The admittance controller has two feedback loops: the position inner-loop and the admittance outer-loop. Meanwhile, the exoskeleton Lagrange model is constructed with unknown friction disturbance. By using Lyapunov technique and backstepping with state observer, the joint position error of exoskeleton is convergence into a zero neighborhood. The effectiveness of the proposed admittance controller is verified by both simulation and experiment. The tracking error of hip and knee joint is less than 4 degrees while the human-robot interaction torque is constrained in a tolerable range of the operator.

关键词： human-robot interaction exoskeleton backstepping admittance control

Molecular Conformational Isomerization:An Efficient Way to Design Novel Emitters with Dual-Thermally Activated Delayed Fluorescence Characteristics and Their Optoelectronic and Bioimaging Applications

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CCS Chemistry 2024年第4期6卷 912-922页

作者： Yi-Zhong Shi Ya-Fang Xiao Hao Wu Shao-Li Zhang Xiao-chun Fan Ye Tian Chang-qing Ye Kai wang Jia Yu chun-Sing Lee Xiao-Hong Zhang School of Materials Science and Engineering Suzhou University of Science and TechnologySuzhou 215009 Institute of Functional Nano and Soft Materials(FUNSOM) Joint International Research Laboratory of Carbon-Based Functional Materials and DevicesSoochow UniversitySuzhou 215123Jiangsu Center of Super-Diamond and Advanced Films(COSDAF) Department of ChemistryCity University of Hong KongHong Kong SAR School of Biomedical Engineering The Second Affiliated HospitalGuangzhou Medical UniversityGuangzhou 510260 Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices Soochow UniversitySuzhou 215123Jiangsu Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow UniversitySuzhou 215123Jiangsu

Single-molecule luminophores with dual-thermally activated delayed fluorescence(TADF)properties are receiving increasing ***,how to achieve these goals requires more in-depth ***,we demonstrate a novel example emitter,10-(5-(2-(pyridin-3-yl)-[4,5′-bipyrimidin]-6-yl)pyridin-2-yl)-10Hphenoxazine(PmPy-PXZ),enabling dual-TADF properties due to its key feature of conformational *** a pyridine bridge can greatly reduce the steric hindrance and facilitate dual-stable conformations in the ground state,where the quasi-axial(QA)forms ***,unlike previously reported TADF molecules with dual confirmations,both theoretical and experimental measurements show that not only the quasi-equatorial(QE)forms but also the QA forms exhibit distinct TADF characteristics,which can be attributed to an additional higher reverse intersystem crossing *** is the first time that dual-TADF properties of single molecules have been achieved based on conformational *** applications in“self-doping”organic light-emitting diode and biomedical imaging have further been *** these results show the good potential of such dual-band TADF emitters based on molecular conformational isomerization.

关键词： dual-thermally activated delayed fluorescence conformational isomerization organic light-emitting diode biomedical imaging self-doping

Cryptococcus splenic abscess in primary biliary cholangitis: a case report

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World Journal of Emergency Medicine 2024年第4期15卷 319-321页

作者： Yuxin Dong qing Tang Lijun wang Songtao Shou Department of Emergency Medicine Tianjin Medical University General HospitalTianjin 300052China

Chronic liver diseases,including primary biliary cholangitis(PBC),are recognized as immunosuppressive conditions due to the impaired functionality of hepatic sinusoidal Kupffer cells.[1]PBC is specifically characterized by cholangitis and progressive liver pathology,which may eventually lead to *** compromised liver function and reduced efficacy of Kupffer cells in patients with PBC weaken their cell-mediated immune responses,increasing their susceptibility to opportunistic pathogens such as Cryptococcus.[2]Cryptococcosis is an infectious disease caused by pathogenic encapsulated yeasts of the genus Cryptococcus,which is distributed worldwide and exhibits diverse clinical presentations.[3]Most case reports on cryptococcal infections are associated with HIV infection or other conditions that compromise the immune system.[4]Case reports related to primary biliary cholangitis are ***,this case report underscores a rare cryptococcal infection in a patient with primary biliary cholangitis,emphasizing the need to consider opportunistic infections in those with compromised liver function and immune dysregulation.

关键词： cholangitis impaired diseases

Predicting plant disease epidemics using boosted regression trees

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Infectious Disease Modelling 2024年第4期9卷 1138-1146页

作者： chun Peng Xingyue Zhang Weiming wang School of Mathematics and Statistics Huaiyin Normal UniversityHuaian223300PR China Ecole Polytechnique Federale de Lausanne Rte Cantonale1015LausanneSwitzerland

Plant epidemics are often associated with weather-related *** is difficult to identify weather-related predictors for models predicting plant *** the article by Shah et al.,to predict Fusarium head blight(FHB)epidemics of wheat,they explored a functional approach using scalar-on-function regression to model a binary outcome(FHB epidemic or non-epidemic)with respect to weather time series spanning 140 days relative to *** scalar-on-function models fit the data better than previously described logistic regression *** this work,given the same dataset and models,we attempt to reproduce the article by Shah et *** a different approach,boosted regression *** fitting,the classification accuracy and model statistics are surprisingly good.

关键词： Plant disease epidemics Scalar-on-function model Boosted regression trees

Privacy Protection for Blockchain-Based Healthcare IoT Systems: A Survey

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IEEE/CAA Journal of Automatica Sinica 2024年第8期11卷 1757-1776页

作者： Minfeng Qi Ziyuan wang qing-Long Han Jun Zhang Shiping Chen Yang Xiang School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyHawthorn3122VictoriaAustralia Faculty of Data Science City University of MacaoMacaoChina CSIRO Data61 SydneyNew South WalesAustralia

To enable precision medicine and remote patient monitoring,internet of healthcare things(IoHT)has gained significant interest as a promising *** the widespread use of IoHT,nonetheless,privacy infringements such as IoHT data leakage have raised serious public *** the other side,blockchain and distributed ledger technologies have demonstrated great potential for enhancing trustworthiness and privacy protection for IoHT *** this survey,a holistic review of existing blockchain-based IoHT systems is conducted to indicate the feasibility of combining blockchain and IoHT in privacy *** addition,various types of privacy challenges in IoHT are identified by examining general data protection regulation(GDPR).More importantly,an associated study of cutting-edge privacy-preserving techniques for the identified IoHT privacy challenges is ***,several challenges in four promising research areas for blockchain-based IoHT systems are pointed out,with the intent of motivating researchers working in these fields to develop possible solutions.

关键词： Blockchain internet of healthcare things(IoHT) privacy-preserving techniques(PPTs).

Water–soluble and polarity–sensitive near–infrared fluorescent probe for long–time specific cancer cell membranes imaging and C. Elegans label

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Chinese Chemical Letters 2024年第4期35卷 321-323页

作者： Lixian Fu Yiyun Tan Yue Ding Weixia qing Yong wang Henan International Joint Laboratory of Medicinal Plants Utilization College of Chemistry and Molecular SciencesHenan UniversityKaifeng 475004China School of Basic Medical Science Henan UniversityKaifeng 475004China

A novel D–π –A structure and near–infrared fluorescent probe(DCITT) with high polarity sensitivity and membrane targeting was reported. The fluorescent spectra of DCITT were polarity dependent and Stokes shift was greater than 300 nm. Due to its high fluorescence quantum yield, low cytotoxicity and photostability, DCITT could be used as a labeling probe in multicellular organisms. In particular, DCITT effectively distinguished tumor cells from normal cells because it could specifically light up the cancer cells membrane based on strong red fluorescence for a long time. On this basis, a polar–sensitive cell membrane probe is developed to differentiate tumor cells from normal cells, which provides an idea and method for the early diagnosis of tumor at cellular level.

关键词： NIR–fluorescent probe Polarity–sensitive Bioimaging Targeting cell membrane Differentiate tumor and normal cells

Pressure transient characteristics of non-uniform conductivity fractured wells in viscoelasticity polymer flooding based on oil-water two-phase flow

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Petroleum Science 2024年第1期21卷 343-351页

作者： Yang wang Jia Zhang Shi-Long Yang Ze-Xuan Xu Shi-qing Cheng National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing102249China

Polymer flooding in fractured wells has been extensively applied in oilfields to enhance oil *** contrast to water,polymer solution exhibits non-Newtonian and nonlinear behavior such as effects of shear thinning and shear thickening,polymer convection,diffusion,adsorption retention,inaccessible pore volume and reduced effective ***,the flux density and fracture conductivity along the hydraulic fracture are generally non-uniform due to the effects of pressure distribution,formation damage,and proppant *** this paper,we present an oil-water two-phase flow model that captures these complex non-Newtonian and nonlinear behavior,and non-uniform fracture characteristics in fractured polymer *** hydraulic fracture is firstly divided into two parts:high-conductivity fracture near the wellbore and low-conductivity fracture in the far-wellbore section.A hybrid grid system,including perpendicular bisection(PEBI)and Cartesian grid,is applied to discrete the partial differential flow equations,and the local grid refinement method is applied in the near-wellbore region to accurately calculate the pressure distribution and shear rate of polymer *** combination of polymer behavior characterizations and numerical flow simulations are applied,resulting in the calculation for the distribution of water saturation,polymer concentration and reservoir *** with the polymer flooding well with uniform fracture conductivity,this non-uniform fracture conductivity model exhibits the larger pressure difference,and the shorter bilinear flow period due to the decrease of fracture flow ability in the far-wellbore *** field case of the fall-off test demonstrates that the proposed method characterizes fracture characteristics more accurately,and yields fracture half-lengths that better match engineering reality,enabling a quantitative segmented characterization of the near-wellbore section with high fracture conductivity and th

关键词： Polymer flooding Non-Newtonian fluid Non-uniform fracture conductivity Two-phase flow Pressure transient analysis

Rhegmatogenous retinal detachment in highly myopic eyes with implantable collamer lens

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International Journal of Ophthalmology(English edition) 2024年第2期17卷 392-396页

作者： Jun Li Chong-Lin Chen Jia-qing Li Xiao-Ling Liang chun Zhang State Key Laboratory of Ophthalmology Zhongshan Ophthalmic CenterSun Yat-sen UniversityGuangdong Provincial Key Laboratory of Ophthalmology and Visual ScienceGuangzhou 510060Guangdong ProvinceChina

AIM:To investigate the clinical characteristics,treatment methods and outcomes of rhegmatogenous retinal detachment(RRD)in highly myopic eyes with implantable collamer lens(ICL).METHODS:High myopia patients who received treatment for nontraumatic RRD after ICL implantation surgery at the Retinal Department of Zhongshan Ophthalmic Center from Jan 2018 to Dec 2022 were *** ophthalmologic examinations including visual acuity measurement and digital fundus photography were performed in each ***:A total of nine RRD eyes from nine patients who received V4c-ICL implantation were *** mean time from ICL implantation surgery to the diagnosis of RRD was 32.44±22.56mo(range,1-60mo).At the initial visit for RRD,giant retinal tear(GRT),horseshoe tear,simple round hole,and horseshoe tear combined with round hole were detected in 3,3,2,and 1 eye(s),respectively,with maculaoff in *** patients received surgical treatment,and one patient was treated by retinal laser photocoagulation *** ICL was preserved in 7 *** the last followup,the mean best corrected visual acuity(BCVA)improved significantly from 1.76±1.06 logMAR at presentation to 0.81±1.01 logMAR(P=0.035),and no case of recurrent retinal detachment was ***:The morphological presentation of retinal breaks is diverse in this *** ICL can be preserved in most cases during the course of retinal detachment repair surgery in our data,companied with acceptable visual and anatomical outcomes.

关键词： high myopia implantable collamer lens rhegmatogenous retinal detachment

Effect of ceramic work rolls on surface roughness of rolled SUS304 ultra-thin strips

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Journal of Iron and Steel Research International 2024年第7期31卷 1704-1718页

作者： Peng-cheng Li Tao wang Chen-chen Zhao Qi Liu qing-xue Huang College of Mechanical and Vehicle Engineering Taiyuan University of TechnologyTaiyuan 030024ShanxiChina Engineering Research Center of Advanced Metal Composites Forming Technology and Equipment of Ministry of Education Taiyuan University of TechnologyTaiyuan 030024ShanxiChina National Key Laboratory of Metal Forming Technology and Heavy Equipment Taiyuan University of TechnologyTaiyuan 030024ShanxiChina

Surface morphology and roughness are important parameters of surface quality of cold-rolled ultra-thin strip *** order to study the effect of Si_(3)N_(4) ceramic work rolls on the surface roughness of SUS304 ultra-thin strip,ABAQUS finite element model calculation,3D laser profilometry,and other methods were adopted based on the physical characteristics of Si_(3)N_(4) ceramic roll and 9Cr2MoV steel roll,like anti-flattening performance and oil *** surface morphology and roughness of SUS304 ultra-thin strip rolled by different material work rolls under oil lubrication conditions were *** results showed that under the rolling force of 10 kN,the maximum flattening amount of Si_(3)N_(4) ceramic roll was reduced by 35.14%compared to that of 9Cr2MoV steel *** reduction rate of SUS304 ultra-thin strip rolled by ceramic roll was 34.19%,while that rolled by steel roll was only 22%;Si_(3)N_(4) ceramic roll can further increase the number of alternating convex peaks and concave valleys in the rolled thin strip,reduce the profile steepness,reduce surface roughness,and enhance the planarization effect of surface micro-convex bodies,with improving surface quality and surface ***,the mechanism of Si_(3)N_(4) ceramic roll significantly improving the surface roughness of rolled SUS304 ultra-thin strip was proposed.

关键词： Ceramic work roll-Steel roll SUS304 ultra-thin strip Reduction Surface roughness