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Carbon nanotube and conducting polymer composites for supercapacitors

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Progress in Natural Science:Materials international 2008年第7期18卷 777-788页

作者： Daniel Jewell George z. Chen School of Chemical and Environmental and Mining Engineering University of Nottingham University ParkNottingham NG7 2RD UK

Composites of carbon nanotubes and conducting polymers can be prepared via chemical synthesis, electrochemical deposition on pre- formed carbon nanotube electrodes, or by electrochemical co-deposition. The composites combine the large pseudocapacitance of the conducting polymers with the fast charging/discharging double-layer capacitance and excellent mechanical properties of the carbon nanotubes. The electrochemically co-deposited composites are the most homogeneous and show an unusual interaction between the polymer and nanotubes, giving rise to a strengthened electron delocalisation and conjugation along the polymer chains. As a result they exhibit excellent electrochemical charge storage properties and fast charge/discharge switching, making them promising electrode mate- rials for high power supercapacitors.

关键词： Supercapacitor Carbon nanotube Conducting polymer

Microstructure and mechanical behavior of laser aided additive manufactured low carbon interstitial Fe_(49.5)Mn_(30)Co_(10)Cr_(10)C_(0.5)multicomponent alloy

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Journal of Materials Science & Technology 2021年第18期77卷 38-46页

作者： Y.Chew z.G.zhu F.Weng S.B.Gao F.L.ng B.Y Lee G.J.Bi Singapore institute of Manufacturing Technology 73 Nanyang Drive637662Singapore School of Mechanical Aerospace Engineering Nanyang Technological University50 N any ang Avenue639798Singapore

Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe_(49.5)Mn_(30)Co_(10)Cr_(10)C_(0.5)interstitial multicomponent alloy using pre-alloyed *** room temperature yield strength(σ_y),ultimate tensile strength(σ_(UTS))and elongation(ε_(UTS))were 645 MPa,917 MPa and 27.0%*** asbuilt sample consisted of equiaxed and dendritic cellular structures formed by elemental *** cellular structures together with oxide particle inclusions were deemed to strengthen the *** other contributing components include dislocation strengthening,friction stress and grain boundary *** highε_(UTS)was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWiP and TRiP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa ***,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.instead,higher fraction of strain-induced hexagonal close-packed(HCP)εphase transformation of 21.2%were observed for fractured sample tested at-40℃,compared with 6.3%in fractured room temperature sample.

关键词： Multicomponent alloys Laser aided additive manufacturing Additive manufacturing Microstructure Mechanical property

Ground state energy of excitons in quantum dot treated variationally via Hylleraas-like wavefunction

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Chinese Physics B 2009年第4期18卷 1578-1585页

作者： S. Sakiroglu . Dogan A. Yιldιz K. Akgngr H. Epik Y. Ergn H. Sarι . Skmen Physics Department Dokuz Eyll University Physics Department Anadolu University Physics Department Cumhuriyet University

in this work, the effects of quantum confinement on the ground state energy of a correlated electron-hole pair in a spherical and in a disc-like quantum dot have been investigated as a function of quantum dot size. Under parabolic confinement potential and within effective mass approximation Ritz＇s variational method is applied to Hylleraas-like trial wavefunction. An efficient method for reducing the main effort of the calculation of terms like τekh exp （-λτeh） is introduced. The main contribution of the present work is the introduction of integral transforms which provide the calculation of expectation value of energy and the related matrix elements to be done analytically over single-particle coordinates instead of Hvlleraas coordinates.

关键词： exciton parabolic confinement variational method Hylleraas coordinates

Numerical Modeling and Analysis of Grooved Surface Applied to Film Cooling

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Journal of Bionic Engineering 2011年第4期8卷 464-473页

作者： L. Guo z. C. Liu Y. Y. Yan z. W. Han Faculty of Engineering University of Nottingham Nottingham NG7 2RD UK Department of internal Combustion Engine Jilin University Changchun 130022 P. R. China Key Laboratory of Bionic Engineering （Ministry of Education China） Jilin University Changchun 130022 P. R. China

in order to improve the efficiency of film cooling, numerical investigation was carried out to study the effects of different film-cooled plates on surface heat transfer. Both grooved and non-grooved surfaces were concerned. The modeling was per- formed using Fluent software with the adoption of Shear-Stress Transport （SST） k-ωmodel as the turbulence closure. The coolant was supplied by a single film cooling hole with an inclination angle of 30°. The Mach numbers for the coolant flow and the mainstream flow were fixed at 0 and 0.6, respectively. At three blowing ratios of 0.5, 1.0 and 1.5, the aerodynamic behaviour of the mixing process as well as the heat transfer performance of the film cooling were presented. The numerical results were validated using experimental data extracted from a benchmark test. Good agreements between numerical results and the ex- perimental data were observed. For the film cooling efficiency, it shows that both local and laterally averaged cooling effectiveness can be improved by the non-smooth surface at different blowing ratios. Using the grooved surface, the turbulence intensity upon the plate can be reduced notably, and the mixing between the two flows is weakened due to the reduced turbu lence level. The results indicate that the cooling effectiveness of film cooling can be enhanced by applying the grooved surface.

关键词： film cooling non-smooth surface cooling effectiveness grooved structure blowing ratio

固定化微生物技术修复镉污染红黏土的室内试验研究

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长江科学院院报 2024年第6期41卷 106-113页

作者：陈筠黄洋向川龙钰贵州理工学院交通工程学院林同棪国际工程咨询(中国)有限公司贵阳职业技术学院城乡规划建设分院贵州大学资源与环境工程学院

为了探究固定化微生物技术对镉(Cd)污染红黏土物理力学性质和环境污染的修复效应,以活性炭为载体,菌种选取巴氏芽孢杆菌,开展基本物理试验、无侧限抗压强度试验、毒性浸出试验和重金属形态提取试验。试验结果表明:巴氏芽孢杆菌对镉离子... 详细信息

为了探究固定化微生物技术对镉(Cd)污染红黏土物理力学性质和环境污染的修复效应,以活性炭为载体,菌种选取巴氏芽孢杆菌,开展基本物理试验、无侧限抗压强度试验、毒性浸出试验和重金属形态提取试验。试验结果表明:巴氏芽孢杆菌对镉离子有较强的耐受性;对比单加微生物或活性炭,固定化微生物技术的修复效果更显著;14%活性炭微生物土样的无侧限抗压强度为229.7 kPa,较镉污染土提升174.7%;修复21 d后,10%活性炭微生物土样的镉离子浸出浓度降低到0.002 mg/L,较镉污染土样降低99.8%;修复后,土中的镉从弱酸态向可还原态和残渣态转化。总的来说,固定化微生物技术对镉污染红黏土具有良好的修复效果,活性炭的掺量以10%为宜。研究成果可为贵州省镉污染红黏土的治理提供参考。

关键词：红黏土巴氏芽孢杆菌固定化微生物技术镉污染土壤修复电镜扫描

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非对称T形截面钢柱z向加载受力研究

城市建筑 2024年第16期21卷 190-192页

作者：姜川湖北交通职业技术学院

为研究一种工程应用中的复杂T字异形截面钢柱受力性能,文章采用ABAQUS软件建立了T字异形截面钢柱的有限元模型,通过分析构件的破坏形式、侧向刚度变化、骨架曲线、延性性能等关键参数的变化,探究在不同加载方式下该异形截面钢柱的受力... 详细信息

为研究一种工程应用中的复杂T字异形截面钢柱受力性能,文章采用ABAQUS软件建立了T字异形截面钢柱的有限元模型,通过分析构件的破坏形式、侧向刚度变化、骨架曲线、延性性能等关键参数的变化,探究在不同加载方式下该异形截面钢柱的受力性能。分析结果表明:该类T形截面柱在沿z轴方向进行加载时,其耗能性能相对较弱,延性相对较差,结构塑性区域主要发生在距离柱脚一定高度处。

关键词：钢结构 T形截面有限元模拟滞回性能

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Gene replacement therapy in Bietti crystalline corneoretinal dystrophy:an open-label,single-arm,exploratory trial

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Signal Transduction and Targeted Therapy 2024年第5期9卷 2275-2284页

作者： Jinyuan Wang Jinlu zhang Shicheng Yu Hongyan Li Shaohong Chen Jingting Luo Haibo Wang Yuxia Guan Haihan zhang Shiyi Yin Huili Wang Heping Li Junle Liu Jingyuan zhu Qiong Yang Ying Sha chuan zhang Yuhang Yang Xuan Yang Xifang zhang Xiuli zhao Likun Wang Liping Yang Wenbin Wei Beijing Tongren Eye Center Beijing Key Laboratory of Intraocular Tumor Diagnosis and TreatmentBeijing Ophthalmology&Visual Sciences Key LabMedical Artificial Intelligence Research and Verification Key Laboratory of the Ministry of Industry and Information TechnologyBeijing Tongren HospitalCapital Medical University100730 BeijingChina School of Clinical Medicine Tsinghua University100084 BeijingChina Chigenovo Co. Ltd.102206 BeijingChina Department of Ophthalmology Peking University Third HospitalBeijing Key Laboratory of Restoration of Damaged Ocular NervePeking University Third Hospital100191 BeijingChina Department of Ophthalmology The Third People’s Hospital of Dalian116091 DalianChina Department of Biomedical informatics School of Basic Medical SciencesPeking University Health Science Center100191 BeijingChina institute of Systems Biomedicine Department of PathologySchool of Basic Medical SciencesPeking University Health Science Center100191 BeijingChina

Bietti crystalline corneoretinal dystrophy is an inherited retinal disease caused by mutations in CYP4V2,which results in blindness in the working-age population,and there is currently no available ***,we report the results of the first-in-human clinical trial(NCT04722107)of gene therapy for Bietti crystalline corneoretinal dystrophy,including 12 participants who were followed up for 180-365 *** open-label,single-arm exploratory trial aimed to assess the safety and efficacy of a recombinant adeno-associated-virus-serotype-2/8 vector encoding the human CYP4V2 protein(rAAV2/8-hCYP4V2).Participants received a single unilateral subretinal injection of 7.5×10^(10)vector genomes of rAAV2/***,73 treatment-emergent adverse events were reported,with the majority(98.6%)being of mild or moderate intensity and considered to be procedure-or corticosteroid-related;no treatment-related serious adverse events or local/systemic immune toxicities were *** with that measured at baseline,77.8%of the treated eyes showed improvement in best-corrected visual acuity(BCVA)on day 180,with a mean±standard deviation increase of 9.0±10.8 letters in the 9 eyes analyzed(p=0.021).By day 365,80%of the treated eyes showed an increase in BCVA,with a mean increase of 11.0±10.6 letters in the 5 eyes assessed(p=0.125).importantly,the patients’improvement observed using multifocal electroretinogram,microperimetry,and Visual Function Questionnaire-25 further supported the beneficial effects of the *** conclude that the favorable safety profile and visual improvements identified in this trial encourage the continued development of rAAV2/8-hCYP4V2(named zVS101e).

关键词： cor dystrophy crystalline

Thermodynamic Characterization of Planar Shapes and Curves, and the Query of Temperature in Black Holes

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Journal of Applied Mathematics and Physics 2021年第8期9卷 2004-2037页

作者： Güngö r Gündüz Orta Doğ u Teknik Ü niversitesi Ankara Turkey

The purpose of this research is to characterize shapes in thermodynamic terms, namely, in terms of total energy, dissipative energy, entropy, and temperature. As case studies, polygons and some well-known curves were taken, and they were characterized using physical terms. The relation between entropy and curvature was elucidated, and the black hole surface gravity and temperature were criticized and reinterpreted from this point of view. Particular energy attributions were evaluated by comparing the position of any edge of a polygon (i.e. its angle with the horizontal axis) with a broken crystal surface. Energies of all edges were added up at all positions between 0˚ - 360˚. in regular polygons, the total energy decreases with the increase of the number of edges. Entropy increases in the reverse order, and the increase of the number of edges increases entropy. it implies that the circle has the lowest energy but the highest surface entropy. in curves (circle, sine-curve, spiral, and exponential curve), the total energy, dissipative energy, and entropy all depend on amplitude and also on specific variables. Black hole entropy expressed in terms of the surface area is a configurational entropy and not thermal entropy;therefore, it does not involve a varying temperature term. The surface gravity of a black hole is connected to acceleration and thus to curvature. To relate it with the temperature needs to be reinterpreted, because, surface gravity behaves like an attractive force not exactly like temperature. Hawking radiation is still possible, but the black hole does not get warmer as it evaporates. Material loss from the black hole gets faster as its radius decreases due to the curvature effect, i.e. by a mechanism similar to the Gibbs-Thomson effect.

关键词： Polygons Curves Viscoelasticity Energy Entropy Temperature Black Hole

Fourier transform technique in variational treatment of two-electron parabolic quantum dot

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Chinese Physics B 2009年第8期18卷 3508-3516页

作者： S.Sakiroglu A.Yιldιz .Dogan K.Akgngr H.Epik Y.Ergn H.Sarι .Skmen Physics Department Dokuz Eyll University Physics Department Anadolu University Physics Department Cumhuriyet University

in this work, we propose an efficient method of reducing the computational effort of variational calculation with a Hylleraas-like trial wavefunction. The method consists of introducing integral transforms for the terms as r12^κ exp （-λτ12） which provide the calculation of the expectation value of energy and the relevant matrix elements to be done analytically over single-electron coordinates instead of Hylleraas coordinates. We have used this method to calculate the ground state energy of a two-electron system in a spherical dot and a disk-like quantum dot separately. Under parabolic confinement potential and within effective mass approximation size and shape effects of quantum dots on the ground state energy of two electrons have been investigated. The calculation shows that our results even with a small number of basis states are in good agreement with previous theoretical results.

关键词： two-electron quantum dot parabolic confinement variational method Hylleraas coor- dinates