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Room temperature synthesis of two-dimensional multi layer magnets based on α-Co^(Ⅱ) layered hydroxides

Nano Materials Science 2022年第1期4卷 36-43页

作者： Victor Oestreicher christian dolle Diego Hunt Michael Fickert Gonzalo Abellan Instituto de Ciencia Molecular(ICMol).Universidad de Valencia Catedritico Jose Beltran 2PaternaValencia46980Spain Departamento de Física de la Materia Condensada GIy A.Instituto de Nanociencia y NanotecnologíaCNEA-CAC-CONICET.Av.Gral.PazSan MartinBuenas Aires1650Argentina Chair of Organic ChemistryⅡand Joint Institute of Advanced Materials and Processes(ZMP).Friedrich-Alexander-Universitát Erlangen-Nürnberg(FAU) Nikolaus-Fiebiger Strasse 1091058 Erlangen and Dr.-Mack Strasse 81Furth 90762Germany

Research on two-dimensional(2D) materials is one of the most active fields in materials science and nanotechnology. Among the members of the 2D family, layered hydroxides(LHs) represent an exceptional case of study due to their unparalleled chemical versatility which allows the modulation of their physicochemical properties at will. Nowadays, LHs based on earth-abundant metals are key materials in the areas of energy storage and conversion, hybrid materials or magnetism. α-Co hydroxides(Simonkolleite-like structures) are promising phases with tuneable electronic and magnetic properties by ligand modification. However, even in the simple case of α-Co^(Ⅱ) hydroxychlorides, the preparation of well-defined large 2D crystals is not straightforward, hindering the development of fundamental studies. Herein, we present the synthesis of 2D hexagonal crystals with outstanding sizethickness relationship(diameter > 5 μm and thickness of 20 ± 7 nm) by a simple homogeneous synthesis taking place at room temperature. In structural terms, no differences are observed between our layered materials and those obtained hydrothermally. However, dynamic susceptibility measurements alert about different arrangements of the magnetic sublattices, which have been rationalized with structural DFT calculations. This work provides an extremely easy bottom-up method to obtain high-quality 2D crystals based on α-CoIIhydroxides,paving the way for the development of fundamental studies and applications.

关键词： Two-dimensional(2D)materials Layered hydroxides Hexagonal morphology Bottom-up synthesis Magnetism

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Electrospun carbon nanofibre-assisted patterning of metal oxide nanostructures

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Microsystems & Nanoengineering 2022年第3期8卷 263-276页

作者： Monsur Islam christian dolle Ahsana Sadaf Peter G.Weidler Bharat Sharma Yolita M.Eggeler Dario Mager Jan G.Korvink Institute of Microstructure Technology Karlsruhe Institute of TechnologyHermann-von-Helmholtz-Platz 176344 Eggenstein-LeopoldshafenGermany Microscopy of Nanoscale Structures&Mechanisms(MNM) Laboratory for Electron Microscopy(LEM)Karlsruhe Institute of TechnologyEngesserstr.7D-76131 KarlsruheGermany Institut fur Funktionlle Grenzflachen Karlsruhe Institute of TechnologyHermann-von-Helmholtz-Platz 176344 Eggenstein-LeopoldshafenGermany

This work establishes carbon nanofibre-mediated patterning of metal oxide nanostructures,through the combination of electrospinning and vapor-phase transport *** of a suitable precursor with subsequent carbonization results in the patterning of catalyst gold nanoparticles embedded within carbon *** vapor-phase transport growth,these nanofibres allow preferential growth of one-dimensional metal oxide nanostructures,which grow radilly outward from the nanofibril axis,ielding a hairy caterpilr-ike *** synthesis of metal oxide caterpilars is demonstrated using zinc oxide,indium oxide,and tin *** and substrate temperatures play the most crucial role in determining the morphology of the metal oxide caterpillars,whereas the distribution of the nanofibres also has a significant impact on the overall *** the current methodology with near-field electrospinning further facilitates user-defined custom patterning of metal oxide caterpllr-like structures.

关键词： fibre carbon patterning

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