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Effect of neutral polymeric bonding agent on tensile mechanical properties and damage evolution of NEPE propellant

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Defence Technology（防务技术） 2024年第2期32卷 357-367页

作者： M.Wubuliaisan Yanqing Wu Xiao Hou Kun Yang hongzheng Duan Xinmei Yin State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing100081PR China The Fourth Institute of china Aerospace Science and Technology Corporation Xi'an710025PR China School of Aerospace Engineering Beijing Institute of TechnologyBeijing100081PR China Science and Technology on Aerospace Chemical Power Laboratory Hubei Institute of Aerospace ChemotechnologyHubei441003PR China

Introducing Neutral Polymeric bonding agents(NPBA) into the Nitrate Ester Plasticized Polyether(NEPE)propellant could improve the adhesion between filler/matrix interface, thereby contributing to the development of new generations of the NEPE propellant with better mechanical properties. Therefore,understanding the effects of NPBA on the deformation and damage evolution of the NEPE propellant is fundamental to material design and applications. This paper studies the uniaxial tensile and stress relaxation responses of the NEPE propellant with different amounts of NPBA. The damage evolution in terms of interface debonding is further investigated using a cohesive-zone model(CZM). Experimental results show that the initial modulus and strength of the NEPE propellant increase with the increasing amount of NPBA while the elongation decreases. Meanwhile, the relaxation rate slows down and a higher long-term equilibrium modulus is reached. Experimental and numerical analyses indicate that interface debonding and crack propagation along filler-matrix interface are the dominant damage mechanism for the samples with a low amount of NPBA, while damage localization and crack advancement through the matrix are predominant for the ones with a high amount of NPBA. Finally, crosslinking density tests and simulation results also show that the effect of the bonding agent is interfacial rather than due to the overall crosslinking density change of the binder.

关键词： Solid propellant Bonding agent Mechanical properties Damage evolution Cohesive-zone model Interface debonding

3D reconstruction and defect pattern recognition of bonding wire based on stereo vision

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CAAI Transactions on Intelligence Technology 2024年第2期9卷 348-364页

作者： Naigong Yu hongzheng Li Qiao Xu Ouattara Sie Essaf Firdaous Faculty of Information Technology Beijing University of TechnologyBeijingChina Beijing Key Laboratory of Computing Intelligence and Intelligent System Beijing University of TechnologyBeijingChina Engineering Research Center of Digital Community Ministry of EducationBeijingChina College of Robotic UniversitéFélix Houphouët‐BoignyAbidjanCôte d’Ivoire

Non-destructive detection of wire bonding defects in integrated circuits(IC)is critical for ensuring product quality after ***-processing-based methods do not provide a detailed evaluation of the three-dimensional defects of the bonding ***,a method of 3D reconstruction and pattern recognition of wire defects based on stereo vision,which can achieve non-destructive detection of bonding wire defects is *** contour features of bonding wires and other electronic components in the depth image is analysed to complete the 3D reconstruction of the bonding *** to filter the noisy point cloud and obtain an accurate point cloud of the bonding wire surface,a point cloud segmentation method based on spatial surface feature detection(SFD)was *** can extract more distinct features from the bonding wire surface during the point cloud segmentation ***,in the defect detection process,a directional discretisation descriptor with multiple local normal vectors is designed for defect pattern recognition of bonding *** descriptor combines local and global features of wire and can describe the spatial variation trends and structural features of *** experimental results show that the method can complete the 3D reconstruction and defect pattern recognition of bonding wires,and the average accuracy of defect recognition is 96.47%,which meets the production requirements of bonding wire defect detection.

关键词： bonding wire defect detection point cloud point cloud segmentation

Long-term efficacy and safety of Huangqi(Radix Astragali Mongolici)-based Traditional chinese Medicine in diabetic peripheral neuropathy:a Meta-analysis of randomized controlled trials

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Journal of Traditional chinese Medicine 2024年第2期44卷 229-242页

作者： PING Jing HAO hongzheng WU Zhenqi ZOU Meijuan LI Zuojing CHENG Gang School of Life Sciences and Biopharmaceutics Shenyang Pharmaceutical UniversityShenyang 110000China Department of Endocrinology Affiliated Hospital of Liaoning University of Traditional Chinese MedicineShenyang 110000China Department of Research Administration Affiliated Hospital of Liaoning University of Traditional Chinese MedicineShenyang 110000China School of Pharmacy Shenyang Pharmaceutical UniversityShenyang 110000China

OBJECTIVE:To assess the long-term effectiveness of Huangqi(Radix Astragali Mongolici,HQ)-based Traditional chinese Medicine(TCM)in the treatment of diabetic peripheral neuropathy(DPN).METHODS:Nine databases were searched to retrieve available randomized controlled trials that compared HQbased TCM and Western Medicines in the treatment of *** methodological quality of the included studies was assessed using the Cochrane bias risk tool,and RevMan 5.4 was used for data *** effect estimates of interest were risk ratio(RR),mean difference(MD)or standardized mean difference(SMD)with 95%confidence interval(CI).RESULTS:The results from 48 available studies assessing 3759 patients demonstrated that cases administered HQ-based TCM[RR=1.30,95%CI(1.21,1.40),P<0.00001]or HQ-based TCM combined with Western Medicines[RR=1.25,95%CI(1.19,1.31),P<0.00001]exhibited higher total efficacy rates than individuals who received Western Medicine *** results showed that the HQ-based TCM group had decreased Toronto Clinical Scoring System scores[MD=-1.50,95%CI(-1.83,-1.17),P<0.00001],and reduced serum interleukin 6[SMD=-0.57,95%CI(-0.87,-0.27),P=0.0002]and tumor necrosis factors-αlevels[SMD=-0.60,95%CI(-0.95,-0.25),P=0.0009].In addition,both HQ-based TCM and HQbased TCM combined with Western Medicine increased nerve conduction velocity and decreased glycaemia compared with Western Medicine *** terms of blood lipids,oxidative stress and adverse drug reactions,there were no significant differences between the HQ-based TCM groups and the Western Medicine control ***:The current Meta-analysis revealed that HQ-based TCM yields higher efficacy and safety than Western Medicine alone for the treatment of DPN,although further well-designed RCTs are required to validate these findings.

关键词： Huangqi(Radix Astragali Mongolici) medicine chinese traditional diabetic peripheral neuropathy Meta-analysis

Near-infrared non-fused electron acceptors for efficient organic photovoltaics

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chinese Chemical Letters 2024年第4期35卷 436-441页

作者： Wenxiang Ma Xinyu He Tianyi Chen De-Li Ma hongzheng Chen Chang-Zhi Li State Key Laboratory of Silicon and Advanced Semiconductor Materials Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China

Developing narrow-bandgap organic semiconductors is important to facilitate the advancement of organic photovoltaics(OPVs). Herein, two near-infrared non-fused ring acceptors(NIR NFRAs), PTBFTT-F and PTBFTT-Cl have been developed with A-π_A-π_D-D-π_D-π_A-A non-fused structures. It is revealed that the introduction of electron deficient π-bridge(π_A) and multiple intramolecular noncovalent interactions effectively retained the structural planarity and intramolecular charge transfer of NFRAs, extending strong NIR photon absorption up to 950 nm. Further, the chlorinated acceptor, with the enlarged π-surface compared to the fluorinated counterpart, promoted not only molecular stacking in solid, but also the desirable photochemical stability in ambient, which are helpful to thereby improve the exciton and charge dynamics for the corresponding OPVs. Overall, this work provides valuable insights into the design of NIR organic semiconductors.

关键词： Organic photovoltaic Near-infrared Non-fused electron acceptor Noncovalent interaction Stability

Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells

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chinese Chemical Letters 2024年第6期35卷 254-257页

作者： Kangrong Yan Ziqiu Shen Yanchun Huang Benfang Niu hongzheng Chen Chang-Zhi Li State Key Laboratory of Silicon and Advanced Semiconductor Materials Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China

To promote the practices of perovskite photovoltaics,it requires to develop efficient perovskite solar cells(PVSCs)standing long-time operation under the adverse ***,we demonstrate that the tailor-made conjugated polymers as conductive adhesives stabilized the originally redox-reactive heterointerface between perovskite and metal oxide,facilitating the access of efficient and stable inverted *** was revealed that bithiophene and phenyl alternating conjugated polymers with partial glycol chains atop of the metal oxide layer has resulted in effective organic-inorganic hybrid hole transporting bilayers,which allow maintaining efficient hole extraction and transport,meanwhile preventing halide migration to directly contact with the nickel oxide(NiO_(x))*** a result,the corresponding inverted PVSCs with the organic-inorganic hole transporting bilayers have achieved an excellent power conversion efficiency of 23.22%,outperforming 20.65% of bare NiO_(x)-based ***,the encapsulated PVSCs with organic-inorganic bilayers exhibited the excellent photostability with 91% of the initial efficiency after 1000-h one-sun equivalent illumination in ambient ***,this work provides new insights into stabilizing the vulnerable heterointerface for perovskite solar cells.

关键词： Perovskite solar cells Conjugated polymer Hole transporting bilayer Charge extraction Heterointerface degradation

A Review of Anode Materials for Dual‑Ion Batteries

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Nano-Micro Letters 2024年第11期16卷 618-674页

作者： hongzheng Wu Shenghao Luo Hubing Wang Li Li Yaobing Fang Fan Zhang Xuenong Gao Zhengguo Zhang Wenhui Yuan School of Chemistry and Chemical Engineering Guangdong ProvinceSouth China University of TechnologyGuangzhou 510641People’s Republic of China Zhuhai Modern Industrial Innovation Research Institute of South china University of Technology Zhuhai 519125Guangdong ProvincePeople’s Republic of China School of Environment and Energy Guangdong ProvinceSouth China University of TechnologyGuangzhou 510641People’s Republic of China

Distinct from"rockingchair"lithium-ion batteries(LIBs),the unique anionic intercalation chemistry on the cathode side of dual-ion batteries(DIBs)endows them with intrinsic advantages of low cost,high voltage,and ecofriendly,which is attracting widespread attention,and is expected to achieve the next generation of large-scale energy storage *** the electrochemical reactions on the anode side of DIBs are similar to that of LIBs,in fact,to match the rapid insertion kinetics of anions on the cathode side and consider the compatibility with electrolyte system which also serves as an active material,the anode materials play a very important role,and there is an urgent demand for rational structural design and performance optimization.A review and summarization of previous studies will facilitate the exploration and optimization of DIBs in the ***,we summarize the development process and working mechanism of DIBs and exhaustively categorize the latest research of DIBs anode materials and their applications in different battery ***,the structural design,reaction mechanism and electrochemical performance of anode materials are briefly ***,the fundamental challenges,potential strategies and perspectives are also put *** is hoped that this review could shed some light for researchers to explore more superior anode materials and advanced systems to further promote the development of DIBs.

关键词： Dual-ion batteries Anode Carbonaceous materials Metallic materials Organic materials Optimization strategies

Cl- ions accelerating interface charge transfer in a Si/In2S3 Faradaic junction photocathode for solar seawater splitting

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Science china Chemistry 2024年第9期67卷 2923-2929页

作者： Jun Luo Ruotong Bao hongzheng Dong Ye Fu Dongjian Jiang Bo Wang Yuzhan Zheng Qiong Wang Wenjun Luo Zhigang Zou Eco-materials and Renewable Energy Research Center (ERERC) Jiangsu Key Laboratory for Nano Technology National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences Nanjing University National Laboratory of Solid State Microstructures and Department of Physics Nanjing University

Photoelectrocatalytic seawater splitting is a promising low-cost method to produce green hydrogen in a large scale. The effects of Cl-ions in seawater on the performance of a photoanode have been reported in previous studies. However, few researches have been done on the roles of Cl-ions in a photocathode. Herein, for the first time, we find that Cl-ions in the electrolyte improve the photocurrent of a Si/In2S3photocathode by 50% at-0.6 VRHE. An in-situ X-ray photoelectron spectroscopy（XPS） characterization combined with the time-of-flight secondary-ion mass spectrometry by simulating photoelectrochemical conditions was used to investigate the interface charge transfer mechanism. The results suggest that there is an In2+3S3–x（OH）2xlayer on the surface of In2S3in the phosphate buffer solution（PBS） electrolyte, which plays a role as an interface charge transfer mediator in the Si/In2S3photocathode. The In2+3S3–x（OH）2xsurface layer becomes In2+3S3–x（Cl）2xin the PBS electrolyte with NaCl and accelerates the charge transfer rate at the In2S3/electrolyte interface. These results offer a new concept of regulating interface charge transfer mediator to enhance the performance of photoelectrocatalytic seawater splitting for hydrogen production.

关键词： solar hydrogen production interface charge transfer mechanism coupled electron and ion transfer in-situ XPS characterization In2+3S3–x(OH)2x surface layer

Natural variation in MORE GRAINS 1 regulates grain number and grain weight in rice

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Journal of Integrative Plant Biology 2024年第7期66卷 1440-1458页

作者： Yingchun Han Qianfeng Hu Nuo Gong Huimin Yan Najeeb Ullah Khan Yanxiu Du hongzheng Sun Quanzhi Zhao Wanxi Peng Zichao Li Zhanying Zhang Junzhou Li Henan Key Laboratory of Rice Molecular Breeding and High Efﬁciency Production College of AgronomyHenan Agricultural UniversityZhengzhou 450046China Beijing Key Laboratory of Crop Genetic Improvement College of Agronomy and BiotechnologyChina Agricultural UniversityBeijing 100193China Rice Industrial Technology Research Institute Guizhou UniversityGuiyang 550025China School of Forestry Henan Agricultural UniversityZhengzhou 450046China

Grain yield is determined mainly by grain number and grain *** this study,we identified and characterized MORE GRAINS1(MOG1),a gene associated with grain number and grain weight in rice(Oryza sativa L.),through map-based *** of MOG1 increased grain yield by 18.6%-22.3%under field *** determined that MOG1,a bHLH transcription factor,interacts with OsbHLH107 and directly activates the expression of LONELY GUY(LOG),which encodes a cytokinin-activating enzyme and the cell expansion gene EXPANSIN-LIKE1(EXPLA1),positively regulating grain number per panicle and grain *** variations in the promoter and coding regions of MOG1 between Hap-LNW and Hap-HNW alleles resulted in changes in MOG1 expression level and transcriptional activation,leading to functional *** analysis revealed that Hap-HNW,which results in a greater number and heavier grains,has undergone strong selection but has been poorly utilized in modern lowland rice *** summary,the MOG1-OsbHLH107 complex activates LOG and EXPLA1 expression to promote cell expansion and division of young panicles through the cytokinin pathway,thereby increasing grain number and grain *** findings suggest that Hap-HNW could be used in strategies to breed high-yielding temperate japonica lowland rice.

关键词： grain number grain weight MOG1 natural variation rice

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人类永久生存的历史唯物主义立法

理论探索 2024年第3期 26-32页

作者：吴宏政吉林大学长春130012

按照马克思的观点,动物“只是按照它所属的那个种的尺度和需要来构造”,因而不需要自己给自己立法,动物天然置身于自然法则之中而获得了物种永久生存的保证。人类因为可以按照“任何一个种的尺度去生产”,这等于没有固定的“尺度”,因... 详细信息

按照马克思的观点,动物“只是按照它所属的那个种的尺度和需要来构造”,因而不需要自己给自己立法,动物天然置身于自然法则之中而获得了物种永久生存的保证。人类因为可以按照“任何一个种的尺度去生产”,这等于没有固定的“尺度”,因而需要自己为自己的永久生存完成立法。西方的法哲学和历史哲学试图为人类物种作出种种生存立法,但这些立法基于唯心论世界观抽掉了人类物种的“自然生命”基础,所以仅仅为人类物种的生存完成了抽象立法。这一抽象立法把人类物种的“精神生命”从“自然生命”中剥离出来,因而无法保证人类物种的永久生存。马克思从唯物论世界观出发,揭示了世界历史进程中人类社会形态及其文明形态的演进规律,把公有制的社会生产关系确立为人类物种的永久生存之法,最终完成了对人类物种实现自己永久生存的历史唯物主义立法。

关键词：人类永久生存历史唯物主义生存立法抽象立法