检索结果-南通市图书馆

MAX-DOAS and in-situ measurements of aerosols and trace gases over Dongying,China:Insight into ozone formation sensitivity based on secondary HCHO

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2024年第1期135卷 656-668页

作者： Xiaojun Zheng Zeeshan Javed Cheng Liu Aimon Tanvir Osama Sandhu Haoran Liu Xiangguang Ji chengzhi xing Hua Lin Daolin Du Institute of Environment and Ecology School of the Environment and Safety EngineeringJiangsu UniversityZhenjiang 212013China Department of Precision Machinery and Precision Instrumentation University of Science and Technology of ChinaHefei 230026China Key Laboratory of Environmental Optics&Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Laboratory of Precision Scientific Instrumentation of Anhui Higher Education Institutes University of Science and Technology of ChinaHefei 230026China Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP3) Department of Environmental Science and EngineeringFudan UniversityShanghai 200433China National Agromet Center Pakistan Meteorological DepartmentIslamabad 44000Pakistan Institute of Physical Science and Information Technology Anhui UniversityHefei 230601China Information Materials and Intelligent Sensing Laboratory of Anhui Province Anhui UniversityHefei 230601China School of Environmental Science and Optoelectronic Technology University of Science and Technology of ChinaHefei 230026China

This study presents a comprehensive overview of the atmospheric pollutants including Sulfur dioxide(SO_(2)),Nitrogen dioxide(NO_(2)),Formaldehyde(HCHO),Particulate Matter PM;PM_(10):diameter≤10μm,and PM_(2.5):diameter≤2.5μm,and Ozone(O_(3)),over Dongying(Shandong Province)from March-April 2018 and September-October 2019 by employing ground-based Multiple Axis Differential Optical Absorption Spectroscopy(MAX-DOAS)observations along with the in-situ measurements attained by the national air quality monitoring platform.The concentrations of SO_(2)and NO_(2)were under the acceptable level,while both PM_(2.5),and PM_(10)were higher than the safe levels as prescribed by national and international air quality standards.The results depict that 21%of the total observation days were found to be complex polluted days(PM_(2.5)>35μg/m^(3) and O_(3)>160μg/m^(3)).The secondary HCHO was used for accurate analysis of O_(3)sensitivity.A difference of 11.40%and 10%during March-April 2018 and September-October 2019 respectively in O_(3)sensitivity was found between HCHO_(total)/NO_(2)and HCHO_(sec)/NO_(2).The results indicate that primary HCHO have significant contribution in HCHO.O_(3)formation predominantly remained to be in VOC-limited and transitional regime during March-April 2018 and September-October 2019 in Dongying.These results imply that concurrent control of both NO_(x) and VOCs would benefit in ozone reductions.Additionally,the criteria pollutants(PM,SO_(2),and NO_(2))depicted strong correlations with each other except for O_(3)for which weak correlation coefficient was obtained with all the species.This study will prove to be baseline for designing of air pollution control strategies.

关键词： MAX-DOAS Trace gases Ozone sensitivity Secondary HCHO Complex Pollution

Vertical distribution and temporal evolution of formaldehyde and glyoxal derived from MAX-DOAS observations:The indicative role of VOC sources

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2022年第12期34卷 92-104页

作者： Qianqian Hong Cheng Liu Qihou Hu Yanli Zhang chengzhi xing Jinping Ou Wei Tan Haoran Liu Xiaoqing Huang Zhenfeng Wu School of Environment and Civil Engineering Jiangnan UniversityWuxi 214122China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Lab of Environmental Optics&Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China Department of Precision Machinery and Precision Instrumentation University of Science and Technology of ChinaHefei 230026China Anhui Province Key Laboratory of Polar Environment and Global Change University of Science and Technology of ChinaHefei 230026China Guangdong Key Laboratory of Environmental Protection and Resources Utilization State Key Laboratory of Organic GeochemistryGuangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640China Guangdong-Hongkong-Macao Joint Laboratory of Collaborative Innovation for Environmental Quality Guangzhou 510632China Institute of Physical Science and Information Technology Anhui UniversityHefei 230601China

Formaldehyde(HCHO)and glyoxal(CHOCHO)are important oxidization intermediates of most volatile organic compounds(VOCs),but their vertical evolution in urban areas is not well understood.Vertical profiles of HCHO,CHOCHO,and nitrogen dioxide(NO_(2))were retrieved from ground-based Multi-Axis Differential Optical Absorption Spectroscopy(MAXDOAS)observations in Hefei,China.HCHO and CHOCHO vertical profiles prefer to occur at higher altitudes compared to NO_(2),which might be caused by the photochemistry-oxidation of longer-lived VOCs at higher altitudes.Monthly means of HCHO concentrations were higher in summer,while enhanced amounts of NO_(2)were mainly observed in winter.CHOCHO exhibited a hump-like seasonal variation,with higher monthly-averaged values not only occurred in warm months(July-August)but also in cold months(November-December).Peak values mainly occurred during noon for HCHO but emerged in the morning for CHOCHO and NO_(2),suggesting that HCHO is stronger link to photochemistry than CHOCHO.We further use the glyoxal to formaldehyde ratio(GFR)to investigate the VOC sources at different altitudes.The lowest GFR value is almost found in the altitude from 0.2 to 0.4 km,and then rises rapidly as the altitude increases.The GFR results indicate that the largest contributor of the precursor VOC is biogenic VOCs at lower altitudes,while at higher altitudes is anthropogenic VOCs.Our findings provide a lot more insight into VOC sources at vertical direction,but more verification is recommended to be done in the future.

关键词： Formaldehyde Glyoxal MAX-DOAS Vertical distribution VOC

Vertical distributions of tropospheric SO_(2) based on MAX-DOAS observations: Investigating the impacts of regional transport at different heights in the boundary layer

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2021年第5期33卷 119-134页

作者： Qianqian Hong Cheng Liu Qihou Hu chengzhi xing Wei Tan Ting Liu Jianguo Liu School of Environment and Civil Engineering Jiangnan UniversityWuxi214122China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen361021China Key Lab of Environmental Optics&Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei230031China Department of Precision Machinery and Precision Instrumentation University of Science and Technology of ChinaHefei230026China School of Earth and Space Sciences University of Science and Technology of ChinaHefei230026China Anhui Province Key Laboratory of Polar Environment and Global Change University of Science and Technology of ChinaHefei230026China

Information on the vertical distribution of air pollutants is essential for understanding their spatiotemporal evolution underlying urban atmospheric environment. This paper presents the SO_(2) profiles based on ground-based Multi-Axis Differential Optical Absorption Spectroscopy(MAX-DOAS) measurements from March 2018 to February 2019 in Hefei, East China. SO_(2) decrease rapidly with increasing heights in the warm season, while lifted layers were observed in the cold season, indicating accumulation or long-range transport of SO_(2) in different seasons might occur at different heights. The diurnal variations of SO_(2) were roughly consistent for all four seasons, exhibiting the minimum at noon and higher values in the morning and late afternoon. Lifted layers of SO_(2) were observed in the morning for fall and winter, implying the accumulation or transport of SO_(2) in the morning mainly occurred at the top of the boundary layer. The bivariate polar plots showed that weighted SO_(2) concentrations in the lower altitude were weakly dependent on wind, but in the middle and upper altitudes, higher weighted SO_(2) concentrations were observed under conditions of middlehigh wind speed. Concentration weighted trajectory(CWT) analysis suggested that potential sources of SO_(2) in spring and summer were local and transported mainly occurred in the lower altitude from southern and eastern areas;while in fall and winter, SO_(2) concentrations were deeply affected by long-range transport from northwestern and northern polluted regions in the middle and upper altitudes. Our findings provide new insight into the impacts of regional transport at different heights in the boundary layer on SO_(2) pollution.

关键词： Sulfur dioxide MAX-DOAS Vertical distribution Regional transport

Investigating the impact of Glyoxal retrieval from MAX-DOAS observations during haze and non-haze conditions in Beijing

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2019年第6期31卷 296-305页

作者： Zeeshan Javed Cheng Liu Muhammad Fahim Khokhar chengzhi xing Wei Tan Muhammad Ahmed Subhani Abdul Rehman Aimon Tanvir School of Earth and Space Sciences University of Science and Technology of China Center for Excellence in Regional Atmospheric Environment Institute of Urban Environment Chinese Academy of Sciences Key Lab of Environmental Optics & Technology Anhui Institute of Optics and Fine Mechanics Chinese Academy of Sciences Anhui Province Key Laboratory of Polar Environment and Global Change USTC Institute of Environmental Sciences and Engineering National University of Sciences and Technology

This study presents the Multi Axis Differential Optical Absorption Spectroscopy(MAXDOAS) measurements for Glyoxal(CHOCHO) in Beijing, China(39.95°N, 116.32°E). CHOCHO is the smallest compound of di-carbonyl group. As a primary sink of CHOCHO, its photolysis with NOx(oxides of nitrogen) results in the production of tropospheric ozone. Therefore,the focus of CHOCHO DOAS measurements is increasing in trend. We did the measurements from 09 May 2017 to 09 September 2017. The study was conducted to compare different retrieval settings in order to reveal best DOAS fit settings for CHOCHO;furthermore, effect of haze and non-haze days on CHOCHO concentration was examined.The root mean square of residual and Differential Slant Column density(dSCD) error was reduced when measurements were done with lower wavelength limit around 432–438 nm and upper intervals around 455–460 nm. Thus, lower wavelength intervals around432–438 nm and upper intervals around 457–460 nm were best for the retrieval of dSCDs for CHOCHO. Meteorological conditions like haze or non-haze days did not have significant effect on DOAS fit parameters. The CHOCHO vertical column densities range from 1.33 E +14 to 9.77 E + 14 molecules/cm2 during the study period with average of 6.16 E +14 molecules/cm2. The results indicated that during haze days CHOCHO concentration was higher because of lower rate of photolysis and atmospheric oxidation potential. Our results did not show any significant weekend effect on CHOCHO atmospheric concentration.

关键词： Glyoxal DOAS Retrieval settings Photolysis Haze days

Ground-Based Hyperspectral Stereoscopic Remote Sensing Network: A Promising Strategy to Learn Coordinated Control of O_(3) and PM_(2.5) over China

在线全文

学校读者我要写书评

暂无评论

Engineering 2022年第12期19卷 71-83页

作者： Cheng Liu chengzhi xing Qihou Hu Qihua Li Haoran Liu Qianqian Hong Wei Tan Xiangguang Ji Hua Lin Chuan Lu Jinan Lin Hanyang Liu Shaocong Wei Jian Chen Kunpeng Yang Shuntian Wang Ting Liu Yujia Chen Department of Precision Machinery and Precision Instrumentation University of Science and Technology of ChinaHefei 230026China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Lab of Environmental Optics and Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China Key Laboratory of Precision Scientific Instrumentation of Anhui Higher Education Institutes University of Science and Technology of ChinaHefei 230026China Anhui Province Key Laboratory of Polar Environment and Global Change University of Science and Technology of ChinaHefei 230026China School of Earth and Space Sciences University of Science and Technology of ChinaHefei 230026China School of Environmental Science and Optoelectronic Technology University of Science and Technology of ChinaHefei 230026China Institute of Physical Science and Information Technology Anhui UniversityHefei 230601China School of Environment and Civil Engineering Jiangnan UniversityWuxi 214122China

With the coming of the“14th Five-Year Plan,”the coordinated control of particulate matter with an aerodynamic diameter no greater than 2.5 lm(PM_(2.5))and O_(3) has become a major issue of air pollution prevention and control in China.The stereoscopic monitoring of regional PM_(2.5) and O_(3) and their precursors is crucial to achieve coordinated control.However,current monitoring networks are currently inadequate for monitoring the vertical profiles of both PM_(2.5) and O_(3) simultaneously and support air quality control.The University of Science and Technology of China(USTC)has established a nationwide ground-based hyperspectral stereoscopic remote sensing network based on multi-axis differential optical absorption spectroscopy(MAX-DOAS)since 2015.This monitoring network provides a significant opportunity for the regional coordinated control of PM_(2.5) and O_(3) in China.One-year vertical profiles of aerosol,NO_(2) and HCHO monitored from four MAX-DOAS stations installed in four megacities(Beijing,Shanghai,Shenzhen,and Chongqing)were used to characterize their vertical distribution differences in four key regions,Jing–Jin–Ji(JJJ),Yangtze River Delta(YRD),Pearl River Delta(PRD),and Sichuan Basin(SB),respectively.The normalized and yearly averaged aerosol vertical profiles below 400 m in JJJ and PRD exhibit a box shape and a Gaussian shape,respectively,and both show exponential shapes in YRD and SB.The NO_(2) vertical profiles in four regions all exhibit exponential shapes because of vehicle emissions.The shape of the HCHO vertical profile in JJJ and PRD was Gaussian,whereas an exponential shape was shown in YRD and SB.Moreover,a regional transport event occurred at an altitude of 600–1000 m was monitored in the southwest–northeast pathway of the North China Plain(NCP)by five MAX-DOAS stations(Shijiazhuang(SJZ),Wangdu(WD),Nancheng(NC),Chinese Academy of Meteorological Sciences(CAMS),and University of Chinese Academy of Sciences(UCAS))belonging to the above network.The aerosol optical depths(AOD)in these five st

关键词： MAX-DOAS Stereoscopic monitoring Regional transport Ozone production Control strategy

First observation of tropospheric nitrogen dioxide from the Environmental Trace Gases Monitoring Instrument onboard the GaoFen-5 satellite

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Light(Science & Applications) 2020年第1期9卷 1389-1397页

作者： Chengxin Zhang Cheng Liu Ka Lok Chan Qihou Hu Haoran Liu Bo Li chengzhi xing Wei Tan Haijin Zhou Fuqi Si Jianguo Liu School of Earth and Space Sciences University of Science and Technology of ChinaHefei 230026China Department of Precision Machinery and Precision Instrumentation University of Science and Technology of ChinaHefei 230026China Key Laboratory of Environmental Optics and Technology Anhui Institute of Optics and Fine MechanicsChinese Academy of SciencesHefei 230031China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Laboratory of Precision Scientific Instrumentation of Anhui Higher Education Institutes University of Science and Technology of ChinaHefei 230026China Remote Sensing Technology Institute(IMF) German Aerospace Center(DLR)OberpfaffenhofenGermany

The Environmental Trace Gases Monitoring Instrument(EMI)is the first Chinese satellite-borne UV–Vis spectrometer aiming to measure the distribution of atmospheric trace gases on a global scale.The EMI instrument onboard the GaoFen-5 satellite was launched on 9 May 2018.In this paper,we present the tropospheric nitrogen dioxide(NO2)vertical column density(VCD)retrieval algorithm dedicated to EMI measurement.We report the first successful retrieval of tropospheric NO_(2) VCD from the EMI instrument.Our retrieval improved the original EMI NO_(2) prototype algorithm by modifying the settings of the spectral fit and air mass factor calculations to account for the on-orbit instrumental performance changes.The retrieved EMI NO_(2) VCDs generally show good spatiotemporal agreement with the satellite-borne Ozone Monitoring Instrument and TROPOspheric Monitoring Instrument(correlation coefficient R of ~0.9,bias<50%).A comparison with ground-based MAX-DOAS(Multi-Axis Differential Optical Absorption Spectroscopy)observations also shows good correlation with an R of 0.82.The results indicate that the EMI NO_(2) retrieval algorithm derives reliable and precise results,and this algorithm can feasibly produce stable operational products that can contribute to global air pollution monitoring.

关键词： measurement dioxide satellite

Comparison of mixing layer height inversion algorithms using lidar and a pollution case study in Baoding, China

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2019年第5期31卷 81-90页

作者： Xiangguang Ji Cheng Liu Zhouqing Xie Qihou Hu Yunsheng Dong Guangqiang Fan Tianshu Zhang chengzhi xing Zhuang Wang Zeeshan Javed Jianguo Liu School of Environmental Science and Optoelectronic Technology University of Science and Technology of China Key Lab of Environmental Optics and Technology Anhui Institute of Optics and Fine Mechanics Hefei Institutes of Physical Science Chinese Academy of Sciences School of Earth and Space Sciences University of Science and Technology of China Center for Excellence in Regional Atmospheric Environment Institute of Urban Environment Chinese Academy of Sciences Anhui Province Key Laboratory of Polar Environment and Global Change University of Science and Technology of China

Beijing–Tianjin–Hebei area is suffering from atmospheric pollution from a long time. The understanding of the air pollution mechanism is of great importance for officials to design strategies for the environmental governance. Mixing layer height(MLH) is a key factor influencing the diffusion of air pollutants. It plays an important role on the evolution of heavy pollution events. Light detection and ranging(lidar), is an effective remote-sensing tool, which can retrieve high spatial and temporal evolution process within mixing layer(ML), especially the variation of MLH. There are many methods to retrieve MLH, but each method has its own applicable limitations. The Mie-lidar data in Beijing was firstly used to compare three different algorithms which are widely used under different pollution levels.We find that the multi-layer structure near surface may cause errors in the detection of mixing layer. The MLH retrieved based on image edge detection was better than another two methods especially under heavy polluted episode. Then we applied this method to investigate the evolution of the mixing layer height during a pollution episode in December2016. MLH at Gucheng county showed the positive correlation with the concentration of particulate matters during the start of this pollution episode. The elevated pollution level in Gucheng was not associated with MLH's decrease, and the significantly increased particulate matters raised the boundary layer, which trapped the pollutants near the surface.

关键词： Mixing layer Beijing–Tianjin–Hebei area Severe haze

Vertical distributions of wintertime atmospheric nitrogenous compounds and the corresponding OH radicals production in Leshan, southwest China

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2021年第7期33卷 44-55页

作者： chengzhi xing Cheng Liu Qihou Hu Qingyan Fu Shanshan Wang Hua Lin Yizhi Zhu Shuntian Wang Weiwei Wang Zeeshan Javed Xiangguang Ji Jianguo Liu Key Lab of Environmental Optics&Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China Department of Precision Machinery and Precision Instrumentation University of Science and Technology of ChinaHefei 230026China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Laboratory of Precision Scientific Instrumentation of Anhui Higher Education Institutes University of Science and Technology of ChinaHefei 230026China Anhui Province Key Laboratory of Polar Environment and Global Change USTCHefei 230026China Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP3) Department of Environmental Science and EngineeringFudan UniversityShanghai 200433China Shanghai Institute of Eco-Chongming(SIEC) No.3663 Northern Zhongshan RoadShanghai 200062China School of Environmental Science and Optoelectronic Technology University of Science and Technology of ChinaHefei 230026China Chongqing Key Laboratory of Catalysis and New Environmental Materials College of Environment and ResourcesChongqing Technology and Business UniversityChongqing 400067China Shanghai Environmental Monitoring Center Shanghai 200235China School of Environmental Science and Engineering Nanjing University of Information Science and TechnologyNanjing 210044China

Ground-based multi-axis differential optical absorption spectroscopy(MAX-DOAS)observations were operated from 02 to 21 December 2018 in Leshan,southwest China,to measure HONO,NO_(2) and aerosol extinction vertical distributions,and these were the first MAX-DOAS measurement results in Sichuan Basin.During the measurement period,characteristic ranges for surface concentration were found to be 0.26-4.58 km^(−1) and averaged at 0.93 km^(−1) for aerosol extinction,0.49 to 35.2 ppb and averaged at 4.57 ppb for NO_(2) and 0.03 to 7.38 ppb and averaged at 1.05 ppb for HONO.Moreover,vertical profiles of aerosol,NO_(2) and HONO were retrieved from MAX-DOAS measurements using the Heidelberg Profile(HEIPRO)algorithm.By analysing the vertical gradients of pollutants and meteorological information,we found that aerosol and HONO are strongly localised,while NO_(2) is mainly transmitted from the north direction(city center direction).Nitrogen oxides such as HONO and NO_(2) are important for the production of hydroxyl radical(OH)and oxidative capacity in the troposphere.In this study,the averaged value of OH production rate from HONO is about 0.63 ppb/hr and maximum value of ratio between OH production from HONO and from(HONO+O_(3))is>93%before12:00 in Leshan.In addition,combustion emission contributes to 26%for the source of HONO in Leshan,and we found that more NO_(2) being converted to HONO under the conditions with high aerosol extinction coefficient and high relative humidity is also a dominant factor for the secondary produce of HONO.

关键词： MAX-DOAS Verticle distribution HONO Hydroxyl radical Secondary source

在线全文

学校读者我要写书评

暂无评论

有机液体载氢储运技术研究进展及应用场景

储能科学与技术 2024年第2期13卷 643-651页

作者：邢承治赵明尚超张思婧张自力刘杨中化学建设投资集团科技产业发展有限公司中化学建设投资集团有限公司北京102308

在“双碳”战略目标背景下,氢能产业在深度和广度上都获得了高速发展,上游制氢资源丰富,下游用氢市场广阔,由于跨地区氢能供需失衡,中游氢能储运已经成为氢能产业链的短板,严重制约了氢能产业的进一步发展。在这种情况下,有机液体载氢(L... 详细信息

在“双碳”战略目标背景下,氢能产业在深度和广度上都获得了高速发展,上游制氢资源丰富,下游用氢市场广阔,由于跨地区氢能供需失衡,中游氢能储运已经成为氢能产业链的短板,严重制约了氢能产业的进一步发展。在这种情况下,有机液体载氢(LOHC)储运技术应运而生,以一种化学储氢方式完美克服了高压气态储氢、低温液态及固态等物理储氢方式的缺陷。与其他氢能储运技术相比,LOHC储运技术在安全、成本、技术、效率等方面具有突出的优势,有望补齐氢能储运的短板,完善氢能产业链。本文对三种主要LOHC储运技术,从工艺原理、储氢载体、综合成本、科研发展等方面进行比较分析。认为甲苯、N-乙基咔唑和二苄基甲苯等三种LOHC储运技术已完成了理论研究、实验验证及中试放大等工作,技术趋于完善,具备了工业化推广应用的条件。在未来展望角度上,对包括大型氢能储运基地和分布式脱氢加氢一体化站在内的两种LOHC储运技术的新型应用场景进行了分析,并梳理了目前LOHC储运技术研究面临的问题和研究方向,并提出了希望和建议。

关键词：氢能有机液体载氢(LOHC) 储运应用场景