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Green Carbon 2024年第2期2卷 211-220页

作者： Juping Liu Yang Yang Ziyue Tang Yingquan chen Hanping chen Xianhua Wang Haiping Yang State Key Laboratory of Coal Combustion Huazhong University of Science and Technology WuhanHubei 430074China

To understand the catalytic conversion of lignin into high-value products,lignin depolymerization was performed using a layered polymetallic oxide(CuMgAlO_(x))*** effects of the conversion temperature,hydrogen pressure,and reaction time were studied,and the ability of CuMgAlO_(x)to break the C–O bond was *** CuMgAlO_(x)(Mg/Al=3:1)catalyst contained acidic sites and had a relatively homogeneous elemental distribution with a high pore size and specific surface ***β-O-4 was almost completely converted by disassociating the C–O bond,resulting in yields of 14.74%ethylbenzene,47.58%α-methylphenyl ethanol,and 36.43%*** highest yield of lignin-derived monophenols was 85.16%under reaction conditions of 280℃ and 3 Mpa for 4 *** the reaction progressed,depolymerization and condensation reactions occurred *** temperatures(>280℃)and pressures(>3 Mpa)tended to produce solid *** study establishes guidelines for the high-value application of industrial lignin in the catalytic conversion of polymetallic oxides.

关键词： Lignin Catalytic depolymerization Monophenols CuMgAlO_(x) Layered polymetallic oxide catalyst

Transition metals for stabilizing lithium metal anode:advances and perspectives

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Tungsten 2024年第1期6卷 212-229页

作者： Si-cheng Miao Ye Jia Zhi-Wen Deng Yan Deng Ruo-Xuan chen Xue-Mei Zhang Chang-Haoyue Xu Meng Yao Wen-Long Cai Department of Advanced Energy Materials College of Materials Science and EngineeringSichuan UniversityChengdu 610064China

As the capacity of lithium-ion batteries gradually reaches its limit,the high-capacity characteristics of lithium metal batteries(LMBs)make them one of the most promising electrochemical energy storage devices ***,uncontrolled lithium dendrite growth can cause poor cell performance and severe safety issues,seriously slowing down the commercialization of *** metals(TMs)are lithiophilic materials that effectively stabilize lithium metal anode(LMA)and inhibit dendrite ***,the growth of lithium dendrites and the performance of TMs in stabilizing lithium metals are comprehensively discussed in this ***,we elucidated the formation mechanisms of lithium dendrite,and we put forward several strategies to suppress lithium dendrite formation based on the understanding of these ***,the application of TMs and their compounds to stabilize LMA and their corresponding mechanisms are comprehensively ***,further research perspectives of TMs in stabilizing LMA are emphasized in detail.

关键词： Transition metals Lithium metal batteries Lithium dendrite Solid electrolyte interphase Formation mechanism

贵州省碳吸收/碳排放时空变化特征及其与经济的脱钩效应

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生态学报 2024年第3期44卷 915-929页

作者：陈田田陈果王强重庆师范大学三峡库区地表过程与环境遥感重庆市重点实验室重庆401331 重庆市三峡库区地表生态过程野外科学观测研究站重庆401331 重庆市规划和自然资源调查监测院重庆401121

贵州省是我国喀斯特生态系统的典型分布区,生态敏感且脆弱,同时其也曾是我国的连片特困区,经济发展愿望迫切。对区域环境-经济发展状况及相互作用关系进行研究具有重要意义。研究从植被净生态系统生产力、土壤碳储量、岩溶碳通量三方面... 详细信息

贵州省是我国喀斯特生态系统的典型分布区,生态敏感且脆弱,同时其也曾是我国的连片特困区,经济发展愿望迫切。对区域环境-经济发展状况及相互作用关系进行研究具有重要意义。研究从植被净生态系统生产力、土壤碳储量、岩溶碳通量三方面计算了贵州省陆地生态系统碳吸收,以能源燃烧排放的CO_(2)表征碳排放量,对区域碳吸收和碳排放的时空变化特征进行剖析,在此基础上构建环境碳负荷指数和脱钩弹性系数,用于解析贵州省碳收支状况及环境碳负荷与经济发展之间的脱钩关系。结果显示:(1)贵州省植被净生态系统生产力均值为257.72 g C/m^(2),呈逐步增强趋势,空间上呈现西高东低、南高北低的分布格局;岩溶碳通量的均值为6.71 t C/km^(2),年际波动较大,集中分布在研究区东北和西南部;土壤碳储量的均值为8.38 t/hm^(2),其高值区主要位于研究区南部和东部边缘;(2)区域碳排放呈现出了逐年增长的特征,表明了能源消耗的增强,形成了以城市高值区为中心向外辐射递减,各点之间以道路连通为特征的分布格局;(3)环境碳负荷指数呈逐年增长趋势,表征区域面临的环境压力越来越大,特别是在贵州省主城区出现了明显的收支不平衡,能源结构优化亟待加强;(4)综合脱钩状态整体以弱脱钩和扩张连接为主,且随时间推移脱钩状态由弱脱钩向扩张连接转变,说明环境保护滞后于经济发展,也就意味着贵州省经济的发展一定程度上牺牲了环境保护。未来应进一步强化生态修复工程的可持续性,同时发展绿色经济以促进区域生态-经济可持续发展。

关键词：净生态系统生产力土壤碳储量岩溶碳通量碳排放脱钩效应

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高原铁路站房地板辐射系统的分区供暖效果

西南交通大学学报 2024年第1期59卷 62-69页

作者：郑嘉诚余涛雷波陈辰吕瑞欣西南交通大学机械工程学院四川成都610031 成都市建筑设计研究院有限公司四川成都610041

为了解决高原铁路站房部分区域在强太阳辐射的影响下出现过热、地板辐射供暖系统能耗浪费的问题,以某高原铁路车站为研究对象,根据站房内太阳照射情况对地板辐射系统提出了分区供暖方案;利用建筑能耗模拟软件Energyplus对该铁路站房进... 详细信息

为了解决高原铁路站房部分区域在强太阳辐射的影响下出现过热、地板辐射供暖系统能耗浪费的问题,以某高原铁路车站为研究对象,根据站房内太阳照射情况对地板辐射系统提出了分区供暖方案;利用建筑能耗模拟软件Energyplus对该铁路站房进行模拟分析,对比了地板辐射系统分区前后站房内的热环境和系统供暖量.结果表明:地板辐射系统采用统一的设计及运行控制方案供暖时,站房内太阳直射影响区的平均操作温度在日间最高可达27℃,与非直射影响区之间的温差超过5℃;在地板辐射系统分区供暖时,直射影响区的平均操作温度最高为26℃,室内温度分布更为均匀,局部过热现象得到缓解;在保证站房热舒适性的前提下,地板辐射系统的分区供暖方案能够使直射影响区整个供暖季的供暖量降低38.2%.

关键词：铁路站房太阳辐射地板辐射供暖室内热环境系统供暖量

Inonotus obliquus polysaccharides prevent UVB-induced skin photodamage by modulating Sirt3-activated Foxo3a/PINK1-Parkin pathway: an in vitro and in vivo study

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Food Science and Human Wellness 2024年

作者： Pei Lin Yin-ying Lu Hong-yu Shi Zhen-dong chen Jun Lin School of Life Sciences and Health Engineering Jiangnan University

Inonotus obliquus， an edible and medicinal fungus， has proven to be beneficial for relieving body aging. Previous research has shown that Inonotus obliquus polysaccharide (IOP) can effectively reduce oxidative stress and alleviate photoaging in UVB-treated HaCaT cells. However， the underlying mechanism is still unclear. This study aimed to investigate the mechanism through which IOP mitigates skin photodamage by modulating mitochondrial autophagy through both in vivo and in vitro experiments. The results indicated that IOP alleviated the thickening of the stratum corneum and inflammatory infiltration caused by UVB radiation. Moreover， IOP effectively inhibited the mRNA expression of MMP1 and MMP3 to prevent collagen breakdown and decreased the expression of aging-related proteins (P53 and P21) and inflammatory factors (TNF-α and IFN-γ) in UVB-induced mice. Both in vitro and in vivo studies demonstrated that IOP increased Sirt3 expression， activated the Foxo3a/PINK1-Parkin pathway and enhanced mitochondrial autophagy to reduce photodamage. Additionally， IOP could regulate the gut microbes in photodamaged mice and increase the relative abundance of Clostridium＿XlVa， Desulfovibrio， and Barnesiella， which are important for protecting the intestinal barrier and alleviating intestinal dysfunction. These results provide a theoretical foundation for the use of IOP as a natural component to reduce skin photodamage.

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Oncogenic β-catenin-driven liver cancer is susceptible to methotrexate-mediated disruption of nucleotide synthesis

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Chinese Medical Journal 2024年第2期137卷 181-189页

作者： Fangming Liu Yuting Wu Baohui Zhang Shuhui Yang Kezhuo Shang Jie Li Pengju Zhang Weiwei Deng Linlin chen Liang Zheng Xiaochen Gai Hongbing Zhang Department of Physiology State Key Laboratory of Common Mechanism Research for Major DiseasesHaihe Laboratory of Cell EcosystemInstitute of Basic Medical Sciences and School of Basic MedicineChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100005China Department of Physiology Institute of Basic Medical Sciences and School of Basic MedicineGraduate School of Peking Union Medical CollegeChinese Academy of Medical SciencesBeijing100005China Department of Physiology School of Life ScienceChina Medical UniversityShenyangLiaoning 110122China School of Life Sciences Westlake UniversityHangzhouZhejiang 310024China Key Laboratory of Pediatric Hematology and Oncology Ministry of HealthInstitute of Pediatric Translational MedicineShanghai Children’s Medical CenterShanghai Jiao Tong School of MedicineShanghai 200127China

Background:Liver cancer is largely resistant to *** study aimed to identify the effective chemotherapeutics forβ-catenin-activated liver cancer which is caused by gain-of-function mutation of catenin beta 1(CTNNB1),the most frequently altered proto-oncogene in hepatic ***:Constitutiveβ-catenin-activated mouse embryonic fibroblasts(MEFs)were established by deleting exon 3(β-catenin^(Δ(ex3)/+)),the most common mutation site in CTNNB1 gene.A screening of 12 widely used chemotherapy drugs was conducted for the ones that selectively inhibitedβ-catenin^(Δ(ex3)/+)but not for wild-type *** metabolomics was carried out to examine the alterations of metabolites in nucleotide *** efficacy and selectivity of methotrexate(MTX)onβ-catenin-activated human liver cancer cells were determined in ***-deficient nude mice subcutaneously inoculated withβ-catenin wild-type or mutant liver cancer cells and hepatitis B virus(HBV);β-catenin^(lox(ex3)/+)mice were used,respectively,to evaluate the efficacy of MTX in the treatment ofβ-catenin mutant liver ***:MTX was identified and validated as a preferential agent against the proliferation and tumor formation ofβ-catenin-activated *** nucleotide synthesis was the major metabolic aberration inβ-catenin-active cells,and this alteration was also the target of ***,MTX abrogated hepatocarcinogenesis of HBV;β-catenin^(lox(ex3)/+)mice,which stimulated concurrent Ctnnb1-activated mutation and HBV infection in liver ***:MTX is a promising chemotherapeutic agent forβ-catenin hyperactive liver *** repurposing MTX has the advantages of lower risk,shorter timelines,and less investment in drug discovery and development,a clinical trial is warranted to test its efficacy in the treatment ofβ-catenin mutant liver cancer.

关键词： Liver cancer β-catenin Methotrexate Nucleotide synthesis Chemotherapy

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基于余弦相似性的定向注意力行为识别模型

系统仿真学报 2024年第1期36卷 67-82页

作者：李晨何明董晨李伟陆军工程大学指挥控制工程学院江苏南京210007 陆军政治工作部军事人力资源保障中心北京100072

针对传统点积注意力缺乏方向性的问题,建立了一种基于余弦相似性的定向注意力模型(directed attention model,DAM)。为有效表示视频帧时空特征间的方向关系,运用余弦相似性理论,定义了注意力机制中关系函数,能够去除特征间关系绝对值;... 详细信息

针对传统点积注意力缺乏方向性的问题,建立了一种基于余弦相似性的定向注意力模型(directed attention model,DAM)。为有效表示视频帧时空特征间的方向关系,运用余弦相似性理论,定义了注意力机制中关系函数,能够去除特征间关系绝对值;为降低注意力机制计算量,从时间和空间两个维度上对运算进行分解;结合线性注意力运算,进一步优化计算复杂度。实验分为两个阶段:对定向注意力各模块开展了4个消融实验,以表现DAM在精确度和效率方面的最佳性能;该模型在Sth-Sth V1(somethingsomething V1)数据集上的精确度较I3D-NL(inflated 3D ConvNet non-local)高7.3%,在UCF101(101 human action classes from videos in the wild)数据集上的识别精确率为95.7%。研究成果在安全监控、自动驾驶等方面应用前景广泛。

关键词：行为识别深度学习注意力机制余弦相似性时空分解

Recent progress of hybrid cathode interface layer for organic solar cells

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Journal of Energy Chemistry 2024年第4期91卷 383-406页

作者： Jianru Wang Dan Zhou Zhentian Xu Yujie Pu Senmei Lan Fang Wang Feiyan Wu Bin Hu Yongfen Tong Ruizhi Lv Honglin Chu Lie chen Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources RecycleNanchang Hangkong UniversityNanchang 330063JiangxiChina College of Chemistry and Chemical Engineering/Institute of Polymers and Energy Chemistry(IPEC) Nanchang UniversityNanchang 330031JiangxiChina

Organic solar cells(OSCs)have gained conspicuous progress during the past few decades due to the development of materials and upgrading of the device *** power conversion efficiency(PCE)of the single-junction device had surpassed 19%.The cathode interface layer(CIL),by optimizing the connection between the active layer and the cathode electrode,has become a momentous part to strengthen the performances of the ***,CIL is also indispensable to illustrating the working mechanism of OSCs and enhancing the stability of the *** this essay,hybrid CILs in OSCs have been ***,the advancement and operating mechanism of OSCs,and the effects and relevant design rules of CIL are briefly concluded;secondly,the significant influence of CIL on enhancing the stability and PCE of OSCs is presented;thirdly,the characteristics of organic hybrid CIL and organic-inorganic hybrid CIL are ***,the conclusion and outlook of CIL are summarized.

关键词： Organic solar cells Theoperation mechanism Organic hybrid cathode interface layer Organic-inorganic hybrid CIL

Transcription factors involved in tomato fruit quality improvement

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Food Quality and Safety 2024年第1期8卷 50-54页

作者：石艳娜戴正蓉陈昆松 College of Agriculture and Biotechnology Zhejiang UniversityZijingang CampusHangzhouChina Zhejiang Provincial Key Laboratory of Horticultural Plant Integrative Biology Zhejiang UniversityZijingang CampusHangzhouChina State Agriculture Ministry Laboratory of Horticultural Plant Growth Development and Quality ImprovementZhejiang UniversityZijingang CampusHangzhouChina

Fruit quality is both a consumer demand and an important goal for horticultural *** exploration of quality-related genes provides targets to create high-quality germplasm using biotechnology,of which transcription factors(TFs)exhibit dosage effects compared with structural ***,an important horticultural crop as well as model fruit,has been widely ***,we focused on TFs with potential utilization value that control appearance(***,pigment)and internal(***,texture,shelf life and health benefits)quality in ***,potential strategies to generate high-quality tomato fruit are discussed.

关键词： Fruit quality transcription factor tomato.

Aggregation-induced delayed electrochemiluminescence of organic dots in aqueous media

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Aggregate

Aggregate 2024年第1期5卷 167-174页

作者： Hang Gao Shen-Yu Shi Shu-MinWang Qian-Qian Tao Hui-Li Ma Jun Hu Hong-Yuan chen Jing-Juan Xu State Key Laboratory of Analytical Chemistry for Life Science School of Chemistry and Chemical EngineeringNanjing UniversityNanjingChina Key Laboratory of Flexible Electronics(KLOFE)and Institute of Advanced Materials(IAM) Nanjing Tech UniversityNanjingChina School of Life Science and Health Engineering Jiangnan UniversityWuxiChina

Full utilization of the excited species at both singlet states(1R*)and triplet states(3R*)is crucial to improving electrochemiluminescence(ECL)efficiency but is challenging for organic luminescent ***,an aggregation-induced delayed ECL(AIDECL)active organic dot(OD)containing a benzophenone acceptor and dimethylacridine donor is reported,which shows high ECL efficiency via reverse intersystem crossing(RISC)of non-emissive 3R*to emissive 1R*,overcoming the spin-forbidden radiative decay from 3R*.By introducing dual donor-acceptor pairs into luminophores,it is found that nonradiative pathway could be further suppressed via enhanced intermolecular weak interactions,and multiple spin-up conversion channels could be *** a consequence,the obtained OD enjoys a 6.8-fold higher ECL efficiency relative to the control AIDECL-active ***-crystal studies and theoretical calculations reveal that the enhanced AIDECL behaviors come from the acceleration of both radiative transition and *** work represents a major step towards purely organic,high-efficiency ECL dyes and a direction for the design of next-generation ECL dyes at the molecular level.

关键词： aggregation-induced delayed electrochemiluminescence benzophenone dimethylacridine organic dots reverse intersystem crossing