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Four-coordinate disilyl cobalt(Ⅱ)complexes with NHC ligation:Synthesis,characterization,and reactivity

Chinese Chemical Letters 2024年第3期35卷 292-298页

作者： Lan Zhou Dongyang Wang chengbo yang Liang Deng College of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China School of Chemistry and Materials Science Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China

Silyl cobalt species are putative intermediates in cobalt-catalyzed transformations of hydrosilanes.However,their reactivity has remained poorly understood.Reported here is the investigation on four-coordinate disilyl Co(Ⅱ)complexes with N-hetereocyclic carbene ligation.The reactions of[(ICy)_(2)Co(vtms)](ICy=1,3-dicyclohexylimidazol-2-ylidene,vtms=vinyltrimethylsilane)with primary and secondary hydrosilanes(3 equiv.)furnish the four-coordinate disilyl complexes[trans-(ICy)_(2)Co(SiHRR')_(2)](SiHRR'=SiH_(2)Mes,1;SiH_(2)Ph,2;SiH_(2)Cy,3;SiHPh_(2),4;SiHEt_(2),5)in moderate to good yields.The structures of 1,2 and 4 were established by single-crystal X-ray diffraction.Solution magnetic susceptibility measurement and EPR spectroscopy indicate their low-spin nature(S=1/2).Reactivity studies on 4 led to the establishment of the conversions of 4 to the disilyl dihydride Co(Ⅲ)complex[K(THF)][(ICy)_(2)Co(H)_(2)(SiHPh_(2))_(2)]_n(6)and the fluorosilyl Co(Ⅱ)complex[(ICy)_(2)Co(THF)(SiFPh_(2))][BF_(4)](7)when 4 was treated with excess amount of K and AgBF_(4),respectively,in THF.These conversions hint at the high activity of low-valent and high-valent disilyl cobalt species[trans-(ICy)_(2)Co(SiHPh_(2))_(2)]^(1-)and[trans-(ICy)_(2)Co(SiHPh_(2))_(2)]^(2+).Complex 4 is reactive toward terminal alkynes,but inert toward alkenes and internal alkynes.The reactions of 4 with terminal alkynes CyC≡CH and Me_(3)SiC≡CH(3 equiv.)yield the Co(Ⅱ)complexes[(ICy)_(2)Co(C≡CCy)_(2)](8)and[(ICy)_(2)Co(C≡CSiMe_(3))((SiMe_(3))C=CH_(2))](9),respectively,along with H_(2)SiPh_(2)and alkynylsilanes RC≡CSiHPh_(2)(R=Cy,SiMe_(3)),whereas the reaction with 4-CF_(3)C_(6)H_(4)C≡CH(3 equiv.)produce[(ICy)_(2)Co(C≡CAr)((Ar)C=CH(SiHPh_(2))C=CHAr)](Ar=4-CF_(3)C_(6)H_(4))(10)and H_(2)SiPh_(2).These reactions are proposed to involveσ-bond metathesis reactions between alkyne C(sp)-H bonds and Co-Si bonds in 4.Complexes 6–10 have been characterized by NMR spectroscopy,X-ray diffraction study,and elemental analysis.

关键词： Disilyl Cobalt N-Heterocyclic carbene Four-coordinate

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Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer

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Nano Research 2024年第3期17卷 1500-1507页

作者： Yongbin Jin Huiping Feng Zheng Fang Liu yang Kaikai Liu Bingru Deng Jingfu Chen Xueling Chen Yawen Zhong Jinxin yang chengbo Tian Liqiang Xie Zhanhua Wei Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information DisplaysCollege of Materials Science and EngineeringHuaqiao UniversityXiamen 361021China

Semi-transparent perovskite solar cells(ST-PSCs)have broad applications in building integrated photovoltaics.However,the stability of ST-PSCs needs to be improved,especially in n-i-p ST-PSCs since the doped 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9'-spirobifluorene(Spiro-OMeTAD)is unstable at elevated temperatures and high humidity.In this work,aπ-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5',7'-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione)](PBDB-T)is selected to form a polymer composite hole transport layer(HTL)with Spiro-OMeTAD.The sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated Pb2+at the perovskite surface,which stabilizes the perovskite/HTL interface and passivates the interfacial defects.The incorporation of the polymer also increases the glass transition temperature and the moisture resistance of Spiro-OMeTAD.As a result,we obtain ST-PSCs with a champion efficiency of 13.71%and an average visible light transmittance of 36.04%.Therefore,a high light utilization efficiency of 4.94%can be obtained.Moreover,the encapsulated device can maintain 84%of the initial efficiency after 751 h under continuous one-sun illumination(at 30%relative humidity)at the open circuit and the unencapsulated device can maintain 80%of the initial efficiency after maximum power tracking for more than 1250 h under continuous one-sun illumination.

关键词： semi-transparent solar cells π-conjugated polymer composite hole transport layer building integrated photovoltaics

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Bacillus licheniformis PF9 improves barrier function and alleviates inflammatory responses against enterotoxigenic Escherichia coli F4 infection in the porcine intestinal epithelial cells

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Journal of Animal Science and Biotechnology 2022年第5期13卷 1413-1427页

作者： Qiao Li Linyan Li Yanhong Chen Changning Yu Paula Azevedo Joshua Gong chengbo yang College of Veterinary Medicine Nanjing Agricultural UniversityNanjing 210095China Department of Animal Science University of ManitobaWinnipegManitoba R3T 2N2Canada Guelph Research and Development Centre Agriculture Agri-Food CanadaGuelphOntario N1G 5C9Canada State Key Laboratory of Food Science and Technology Nanchang UniversityNanchang 330047China

Background:Enterotoxigenic Escherichia coli(ETEC)F4 commonly colonizes the small intestine and releases enterotoxins that impair the intestinal barrier function and trigger inflammatory responses.Although Bacillus licheniformis(B.licheniformis)has been reported to enhance intestinal health,it remains to be seen whether there is a functional role of B.licheniformis in intestinal inflammatory response in intestinal porcine epithelial cell line(IPEC-J2)when stimulated with ETEC F4.Methods:In the present study,the effects of B.licheniformis PF9 on the release of pro-inflammation cytokines,cell integrity and nuclear factor-κB(NF-κB)activation were evaluated in ETEC F4-induced IPEC-J2 cells.Results:B.licheniformis PF9 treatment was capable of remarkably attenuating the expression levels of inflammation cytokines tumor necrosis factor-α(TNF-α),interleukin(IL)-8,and IL-6 during ETEC F4 infection.Furthermore,the gene expression of Toll-like receptor 4(TLR4)-mediated upstream related genes of NF-κB signaling pathway has been significantly inhibited.These changes were accompanied by significantly decreased phosphorylation of p65 NF-κB during ETEC F4 infection with B.licheniformis PF9 treatment.The immunofluorescence and western blotting analysis revealed that B.licheniformis PF9 increased the expression levels of zona occludens 1(ZO-1)and occludin(OCLN)in ETEC F4-infected IPEC-J2 cells.Meanwhile,the B.licheniformis PF9 could alleviate the injury of epithelial barrier function assessed by the trans-epithelial electrical resistance(TEER)and cell permeability assay.Interestingly,B.licheniformis PF9 protect IPEC-J2 cells against ETEC F4 infection by decreasing the gene expressions of virulence-related factors(including luxS,estA,estB,and elt)in ETEC F4.Conclusions:Collectively,our results suggest that B.licheniformis PF9 might reduce inflammation-related cytokines through blocking the NF-κB signaling pathways.Besides,B.licheniformis PF9 displayed a significant role in the enhancement of IPEC-J2 cell integrity.

关键词： Bacillus licheniformis PF9 Barrier function ETEC F4 Inflammatory response IPEC-J2

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Car-following strategy of intelligent connected vehicle using extended disturbance observer adjusted by reinforcement learning

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CAAI Transactions on Intelligence Technology 2024年第2期9卷 365-373页

作者： Ruidong Yan Penghui Li Hongbo Gao Jin Huang chengbo Wang School of Traffic and Transportation The Beijing Jiaotong UniversityBeijingChina Department of Automation School of Information Science and TechnologyUniversity of Science and Technology of ChinaHefeiChina School of Vehicle and Mobility The Tsinghua UniversityBeijingChina Liverpool Logistics Offshore and Marine Research Institute(LOOM)Liverpool John Moores UniversityLiverpoolUK

Disturbance observer-based control method has achieved good results in the carfollowing scenario of intelligent and connected vehicle(ICV).However,the gain of conventional extended disturbance observer(EDO)-based control method is usually set manually rather than adjusted adaptively according to real time traffic conditions,thus declining the car-following performance.To solve this problem,a car-following strategy of ICV using EDO adjusted by reinforcement learning is proposed.Different from the conventional method,the gain of proposed strategy can be adjusted by reinforcement learning to improve its estimation accuracy.Since the“equivalent disturbance”can be compensated by EDO to a great extent,the disturbance rejection ability of the carfollowing method will be improved significantly.Both Lyapunov approach and numerical simulations are carried out to verify the effectiveness of the proposed method.

关键词： adaptive system autonomous vehicle intelligent control

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Recent advances in intermediate-temperature CO_(2) capture: Materials,technologies and applications

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Journal of Energy Chemistry 2024年第3期90卷 435-452,I0010页

作者： chengbo Zhao Leiming Wang Liang Huang Nicholas M.Musyoka Tianshan Xue Jabor Rabeah Qiang Wang Engineering Research Center for Water Pollution Source Control&Eco-remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China State Key Laboratory of Efficient Production of Forest Resources Beijing Forestry UniversityBeijing 100083China China Machinery Huanyu Certification and Inspection Co. Ltd.Beijing 102609China Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute University of Nottingham Ningbo ChinaNingbo 315100ZhejiangChina Institute of Atmospheric Environment Chinese Research Academy of Environmental SciencesBeijing 100012China Leibniz-Institut für Katalyse e.V. Albert-Einstein-Str.29aRostock D-18059Germany

Carbon capture,utilization and storage(CCUS) is widely recognized as a vital strategy for mitigating the impact of human induced climate change.Among various CO_(2) adsorbents,intermediate-temperature solid adsorbents have garnered significant attention due to their potential applications in hydrogen utilization,specifically in the water gas shift,steam reforming and gasification processes.These processes are crucial for achieving carbon neutrality.While laboratory-level studies have showcased the high adsorption capacity of these materials via various synthesis and modification methods,their practical application in complex industrial environments remains challenging,impeding the commercialization process.This review aims to critically summarize the recent research progress made in intermediatetemperature(200-400℃) solid CO_(2) adsorbents,particularly focusing on indicators such as cyclability,gas selectivity,and formability,which play vital roles in industrial application scenarios.Additionally,we provide an overview of laboratory-level advanced technologies specifically tailored for industrial applications.Furthermore,we highlight several industrial-ready advanced technologies that can pave the way for overcoming the challenges associated with large-scale implementation.The insights provided by this review aim to assist researchers in identifying the most relevant research directions for industrial applications.By promoting advances in the application of solid adsorbents,we strive to facilitate the ultimate goal of achieving carbon neutrality.

关键词： Intermediate-temperature CO_(2) capture MgO LDHs Industrialization

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Crosstalk between trace elements and T-cell immunity during early-life health in pigs

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中国科学:生命科学英文版 2023年第9期66卷 1994-2005页

作者： Shunshun Jin Liuqin He chengbo yang Xinmiao He Heshu Chen Yanzhong Feng Wenjie Tang Jianzhong Li Di Liu Tiejun Li Hunan Provincial Key Laboratory of Animal Intestinal Function and Regulation Hunan International Joint Laboratory of Animal Intestinal Ecology and HealthCollege of Life SciencesHunan Normal UniversityChangsha 410081China Department of Animal Science University of ManitobaWinnipegManitoba R3T2N2Canada CAS Key Laboratory of Agro-ecological Processes in Subtropical Region Institute of Subtropical AgricultureHunan Provincial Key Laboratory of Animal Nutritional Physiology and Metabolic ProcessNational Engineering Laboratory for Pollution Control and Waste Utilization in Livestock and Poultry ProductionChangsha 410125China Heilongjiang Academy of Agricultural Sciences Harbin 150086China Animal Breeding and Genetics Key Laboratory of Sichuan Province Sichuan Animal Science AcademyChengdu 610066China

With gradual ban on the use of antibiotics, the deficiency and excessive use of trace elements in intestinal health is gaining attention. In mammals, trace elements are essential for the development of the immune system, specifically T-cell proliferation,and differentiation. However, there remain significant gaps in our understanding of the effects of certain trace elements on T-cell immune phenotypes and functions in pigs. In this review, we summarize the specificity, development, subpopulations, and responses to pathogens of porcine T cells and the effects of functional trace elements(e.g., iron, copper, zinc, and selenium) on intestinal T-cell immunity during early-life health in pigs. Furthermore, we discuss the current trends of research on the crosstalk mechanisms between trace elements and T-cell immunity. The present review expands our knowledge of the association between trace elements and T-cell immunity and provides an opportunity to utilize the metabolism of trace elements as a target to treat various diseases.

关键词： trace elements T cells pig gut immunity

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Impact of essential oils and organic acids on the growth performance,digestive functions and immunity of broiler chickens

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Animal Nutrition 2018年第4期4卷 388-393页

作者： Xin yang Hongliang Xin chengbo yang Xiaojun yang College of Animal Science and Technology Northwest A&F UniversityYangling712100China Jefo Nutrition Inc. Saint-HyacintheQuebecJ2S 7B6Canada

The aim of the experiment was to study the effects of feeding blends of sorbic acid, fumaric acid, and thymol(EOA) on growth performance, digestive functions, and immunity of broiler chickens. A total of 640 one-day-old male Cobb 500 chicks with similar BW(41.8 ± 0.6 g) were randomly divided into 4dietary treatment groups consisting of 10 replicates with 16 birds per replicate and fed a basal diet until d 42(CON) or diets with 0.15 g/kg enramycin during the grower period(AG), 0.30 g/kg EOA during the grower period(EG), or 0.30 g/kg EOA during the finisher period(EF). At d 42, the feed conversion ratio was reduced(P < 0.05) for birds in EG group compared with other groups. Birds in EG group showed a higher villus height of the duodenum and jejunum and muscular layers of the duodenum and ileum than birds in CON group(P < 0.05). Compared with other groups, crypt depth of the jejunum and ileum was markedly increased(P < 0.05) by EOA supplementation during the finisher period at d 42. The EOA supplementation during grower period increased significantly lipase, trypsin and chymotrypsin activities of the duodenum at d 21 and 42, as well as lipase and trypsin at d 21, and trypsin and chymotrypsin at d 42 in the jejunum, and trypsin and chymotrypsin activities of the ileum at d 21 compared to the control diet(P < 0.05). Birds of EG and EF groups showed a higher(P < 0.05) spleen index than birds of CON group. The level of secretory immunoglobulin A in duodenal and ileal mucosa was increased(P < 0.05) in EF group at d 42 compared with other groups. In conclusion, the results indicate that EOA can be effectively applied in broiler diets, especially during the grower phase by improving intestinal morphology and increasing digestive enzyme activity.

关键词： Broiler chicken Digestive functions Essential oils Growth performance Immunity Organic acids

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Selective nano-buckling improves the performance of graphene logic transistors

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National Science Review 2024年第2期11卷 95-96页

作者： Tong yang Ming yang Department of Applied Physics The Hong Kong Polytechnic University Research Centre for Nanoscience and Nanotechnology The Hong Kong Polytechnic University

The massive integration of silicon-based transistors into modern electronic devices greatly increases power consumption and heat generation/dissipation[1]. In this concern, transistors based on atomically-thin graphene that exhibit high electric and thermoelectric conductivities with negligible contact resistance,

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Efficient FPGA-based graph processing with hybrid pull-push computational model

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Frontiers of Computer Science 2020年第4期14卷 13-28页

作者： chengbo yang Long ZHENG Chuangyi GUI Hai JIN National Engineering Research Center for Big Data Technology and System/Service Computing Technology and System Lab/Cluster and Grid Computing Lab School of Computer Science and TechnologyHuazhong University of Science and TechnologyWuhan430074China

Hybrid pull-push computational model can provide compelling results over either of single one for processing real-world graphs.Programmability and pipeline parallelism of FPGAs make it potential to process different stages of graph iterations.Nevertheless,considering the limited on-chip resources and streamline pipeline computation,the efficiency of hybrid model on FPGAs often suffers due to well-known random access feature of graph processing.In this paper,we present a hybrid graph processing system on FPGAs,which can achieve the best of both worlds.Our approach on FPGAs is unique and novel as follow.First,we propose to use edge block(consisting of edges with the same destination vertex set),which allows to sequentially access edges at block granularity for locality while still preserving the precision.Due to the independence of blocks in the sense that all edges in an inactive block are associated with inactive vertices,this also enables to skip invalid blocks for reducing redundant computation.Second,we consider a large number of vertices and their associated edge-blocks to maintain a predictable execution history.We also present to switch models in advance with few stalls using their state statistics.Our evaluation on a wide variety of graph algorithms for many real-world graphs shows that our approach achieves up to 3.69x speedup over state-of-the-art FPGA-based graph processing systems.

关键词： graph processing efficiency computational model FPGAs

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Soft-Magnetic High-Entropy AlCoFeMnNi Alloys with Dual-Phase Microstructures Induced by Annealing

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Acta Metallurgica Sinica(English Letters) 2020年第8期33卷 1124-1134页

作者： chengbo yang Jing Zhang Meng Li Xuejian Liu College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Guangdong Institute of Materials and Processing Guangzhou 510650China

The simultaneous enhancement of magnetic and mechanical properties is desirable but challenging for soft-magnetic materials.A fabrication strategy to meet this requirement is therefore in high demand.Herein,bulk equiatomic dual-phase AlCoFeMnNi high-entropy alloys were fabricated via a magnetic levitation induction melting and casting process followed by annealing at 700-1000℃,and their microstructures as well as mechanical and magnetic properties were investigated.The as-cast alloy possessed a single metastable B2-ordered solid solution that decomposed upon annealing into a dual-phase structure comprising an Al-and Ni-rich body-centered cubic(BCC)matrix and Fe-and Mn-rich face-centered cubic(FCC)precipitates both in the grain interior and along the grain boundaries.The magnetic and mechanical properties were closely related to the relative volume fraction of FCC in the alloy.The FCC volume fraction could be increased by increasing the annealing temperature,thereby offering tunable properties.The optimal annealing temperature for balanced magnetic and mechanical properties was found to be 800℃.The alloy annealed at this temperature had an average BCC grain size of 12±3μm and FCC volume fraction of 41±4%.Correspondingly,the s aturation magnetization and coercivity reached 82.57 Am^2/kg and 433 A/m,respectively.The compressive yield strength and fracture strength were 1022 and 2539 MPa,respectively,and the plasticity was 33%.Owing to its adjustable microstructure and properties,the AlCoFeMnNi alloy has potential for use as a multi-functional soft-magnetic material.

关键词： High-entropy alloy Microstructure Phase transformation Soft-magnetic material Precipitation

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