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stable Cycling of All-solid-state Lithium Batteries Enabled by Cyano-Molecular Diamond Improved Polymer Electrolytes

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Nano-Micro Letters 2024年第10期16卷 561-575页

作者： Yang Dai Mengbing Zhuang Yi-Xiao Deng Yuan Liao Jian Gu Tinglu s.ng hao Yan Jin-cheng Zheng Department of Chemical Engineering Shanghai UniversityShangda Road 99Shanghai 200444People's Republic of China Department of Physics Xiamen UniversityXiamen 361005People's Republic of China Experimental Center of Advanced Materials school of Materials science and Engineering Beijing Institute of TechnologyBeijing 100081People's Republic of China Department of Physics and Department of New Energy science and Engineering Xiamen University Malaysia43900 SepangMalaysia

The interfacial instability of the poly(ethylene oxide)(PEO)-based electrolytes impedes the long-term cycling and further application of all-solid-state lithium metal *** this work,we have shown an effective additive 1-adaman-tanecarbonitrile,which con-tributes to the excellent per-formance of the poly(ethylene oxide)-based *** to the strong interaction of the 1-Adamantanecarboni-trile to the polymer matrix and anions,the coordination of the Li^(+)-EO is weakened,and the binding effect of anions is strengthened,thereby improving the Li^(+)conductivity and the electrochemical *** diamond building block on the surface of the lithium anode can sup-press the growth of lithium ***,the 1-Adamantanecarbonitrile also regulates the formation of LiF in the solid electrolyte interface and cathode electrolyte interface,which contributes to the interfacial stability(especially at high voltages)and protects the electrodes,enabling all-solid-state batteries to cycle at high voltages for long periods of ***,the Li/Li symmetric cell undergoes long-term lithium plating/stripping for more than 2000 h.1-Adamantanecarbonitrile-poly(ethylene oxide)-based LFP/Li and 4.3 V Ni_(0.8)Mn_(0.1)Co_(0.1)O_(2)/Li all-solid-state batteries achieved stable cycles for 1000 times,with capacity retention rates reaching 85%and 80%,respectively.

关键词： 1-Adamantanecarbonitrile(ADCN) Poly(ethylene oxide) All-solid-state batteries Interfacial stability High voltage

Effect of micro-Al_(2)O_(3) powders on oxidation and corrosion behaviors of low-carbon MgO-C refractories

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Journal of Iron and steel Research International 2024年第6期31卷 1522-1534页

作者： Yang Chen Zeng-yi Li hao-bo Tan Yu-ran Fu Jun Ding cheng-ji Deng Chao Yu school of Materials science and Engineering Hunan Institute of TechnologyHengyang 421002HunanChina The state Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

To solve the problem of poor high-temperature service performance caused by low carbonization of MgO-C refractories,low-carbon MgO–C refractories with excellent thermal shock,oxidation and corrosion resistances were successfully designed by us.ng siC whiskers as reinforcing phases and introducing micro-Al_(2)O_(3) powders as *** results indicated that the addition of micro-Al_(2)O_(3) powders optimized the internal structure of the material,like the columnar β-si_(3)N_(4) with a stepped distribution and the mosaic structure formed between granular and flaky Mg_(2)siO_(4),which synergistically strengthened and toughened the material and gave the material excellent mechanical properties and thermal shock ***,the cold modulus of rupture and cold crushing strength after thermal shock were increased by 4.1 and 20.3 MPa,***,the addition of micro-Al_(2)O_(3) powders promoted the formation of fine particles of Mg_(2)siO_(4),MgAl_(2)O_(4) and MgO,as well as a dense protective layer of Mg_(2)siO_(4) in the material under high-temperature ***,spinel and high-temperature solid solution were formed in the corrosion *** oxidation and corrosion resistances were greatly improved by 41%and 15%,respectively.

关键词： Low-carbon MgO-C refractory Oxidation resistance Corrosion resistance Thermal shock resistance Micro-Al_(2)O_(3)powder

Mass Transfer-Promoted Fe^(2+)/Fe^(3+)Circulation steered by 3D Flow-Through Co-Catalyst system Toward sustainable Advanced Oxidation Processes

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Engineering 2024年第5期36卷 264-275页

作者： Weiyang Lv hao Li Jinhui Wang Lixin Wang Zenglong Wu Yuge Wang Wenkai s.ng Wenkai cheng Yuyuan Yao National Engineering Lab of Textile Fiber Materials and Process.ng Technology(Zhejiang) Zhejiang Sci-Tech UniversityHangzhou 310018China Zhejiang Provincial Innovation Center of Advanced Textile Technology Shaoxing 312000China Jiangsu Ruiya stirring Technology Co. Ltd.Yixing 214200China

Realizing fast and continuous generation of reactive oxygen species(ROss)via iron-based advanced oxidation processes(AOPs)is significant in the environmental and biological ***,current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer and non-durable promotion effect,giving rise to the sluggish Fe^(2+)/Fe^(3+)cycle and low dynamic concentration of Fe^(2+)for ROs ***,we present a three-dimensional(3D)macroscale co-catalyst functionalized with molybdenum disulfide(Mos_(2))to achieve ultra-efficient Fe^(2+)regeneration(equilibrium Fe^(2+)ratio of 82.4%)and remarkable stability(more than 20 cycles)via a circulating flow-through *** the conventional batch-type reactor,experiments and computational fluid dynamics simulations demonstrate that the optimal utilization of the 3D active area under the flow-through mode,initiated by the convectionenhanced mass/charge transfer for Fe^(2+)reduction and then strengthened by Mos_(2)-induced flow rotation for sufficient reactant mixing,is crucial for oxidant activation and subsequent ROs ***,the flow-through co-catalytic system with superwetting capabilities can even tackle the intricate oily wastewater stabilized by different surfactants without the loss of pollutant degradation *** findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based technology,especially in large-scale complex wastewater treatment.

关键词： Advanced oxidation processes 3D co-catalyst Flow-through mode Enhanced mass transfer Complex wastewater treatment

Deep learning-based semantic segmentation of human features in bath scrubbing robots

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Biomimetic Intelligence & Robotics 2024年第1期4卷 70-79页

作者： Chao Zhuang Tianyi Ma Bokai Xuan cheng Chang Baichuan An Minghuan Yin hao sun school of Artificial Intelligence and Data science Hebei University of TechnologyTianjin 300401China Engineering Research Center of Intelligent Rehabilitation Device and Detection Technology Ministry of EducationTianjin 300401China

With the rise in the aging population,an increase in the number of semidisabled elderly individuals has been noted,leading to notable challenges in medical and healthcare,exacerbated by a shortage of nurs.ng *** study aims to enhance the human feature recognition capabilities of bath scrubbing robots operating in a water fog *** investigation focuses on semantic segmentation of human features us.ng deep learning ***,3D point cloud data of human bodies with varying sizes are gathered through light detection and ranging to establish human ***,a hybrid filtering algorithm was employed to address the impact of the water fog environment on the modeling and extraction of human ***,the network is refined by integrating the spatial feature extraction module and the channel attention module based on *** results indicate that the algorithm adeptly identifies feature information for 3D human models of diverse body sizes,achieving an overall accuracy of 95.7%.This represents a 4.5%improvement compared with the PointNet network and a 2.5%enhancement over mean intersection over *** conclusion,this study substantially augments the human feature segmentation capabilities,facilitating effective collaboration with bath scrubbing robots for caregiving tasks,thereby possess.ng significant engineering application value.

关键词： 3D point cloud Human model LiDAR semantic segmentation

The Crystallization Behavior of L-Poly(lactic acid)/Polypropylene Blends:The Acceleration for Both L-Poly(lactic acid)and Polypropylene

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Chinese Journal of Polymer science 2024年第6期42卷 775-786页

作者： shuang-cheng Li Wei-Jia Zhou Wen-Jie Wu Jun shao shui-Liang Chen hao-Qing Hou sheng Xiang College of Chemistry&Chemical Engineering and Nanofiber Engineering Center of Jiangxi Province Jiangxi Normal UniversityNanchang330022China National Engineering Research Center for Carbohydrate synthesis/Key Lab of Fluorine and silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal UniversityNanchang330022China Wenzhou Institute University of Chinese Academy of SciencesWenzhou325001China

For a polymer/polymer dismissible blend with two crystallizable components,the crystallization behavior of different components and the reciprocal influences between different crystals are interesting and important,but did not investigate in *** this study,the L-poly(lactic acid)/polypropylene(PLLA/PP)blends with different weight ratios were prepared by melt mixing and the crystallization behavior of the blends were *** showed that the crystalline structures of PLLA and PP were not altered by the *** the crystallization of PLLA,both the diffusion of chain segments and crystallization rate were enhanced under the existence of PP *** the crystallization of PP,its crystallization rate was depressed under the existence of amorphous PLLA molecular *** the PP crystallized from the existence of PLLA crystals,although the diffusion rate of PP was reduced by PLLA crystals,the nucleation positions were obviously enhanced,which accelerated the formation of PP *** investigation would supply more basic data for the application of PLLA/PP blend.

关键词： L-poly(lactic acid) Polypropylene Blends Crystalization behavior Crystallization acceleration

Electrostatic interaction-mediated 1:1 complexes for high-contrast mitochondrial-targeted phosphorescence bioimaging

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science China Chemistry 2024年第10期67卷 3406-3413页

作者： Jianshuo cheng hao sun Lulu Zhou Glib V.Baryshnikov Mouwei Liu shen shen Hans ?gren Liangliang Zhu state Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan University Laboratory of Organic Electronics Department of Science and TechnologyLink?ping University Department of Physics and Astronomy Uppsala University

Organelle-targeted imaging can provide information on cellular functions and intracellular interactions, being significant for disease diagnosis. The use of room-temperature phosphorescence(RTP) in organelle-targeted imaging can fully utilize its unique characteristics of long wavelength and deep penetration. However, this technology has long been plagued by insufficient probe targeting and limited luminous intensity. In this work, we prepared a series of complexes composed of multicationic persulfurated arenes and biomacromolecules via electrostatic interactions in 1:1 stoichiometry for high-contrast mitochondrial-targeted RTP imaging. such an electrostatic interaction design effectively prevented the self-aggregation of the probes, which is not conducive to mitochondrial targeting. simultaneously, it suppressed the non-radiative decay to the maximum extent, enabling the probes to exhibit strong RTP signals both in aqueous solution and at the cellular level. Furthermore, the biomacromolecules can serve as carriers for an electrostatic interaction transfer of the persulfurated arenes to mitochondria. This leads to high mitochondrial targeting Pearson's correlation coefficients of the probes and high-contrast RTP imaging effects, as well as the independence of the co-incubated probe concentration. These results provide new insights for the development of targeted imaging technologies.

关键词： room-temperature phosphorescence mitochondrial targeting bioimaging complex electrostatic interaction

Emerging hierarchical mesoporous materials of covalent organic frameworks

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science China Chemistry 2024年第9期67卷 2796-2802页

作者： Lingyan Huang Wenda Li Hongyi Zhang shanzhe Ke hao Chen Jianwei Fu chengbin Jing Jiangong cheng shaohua Liu state Key Laboratory of Precision spectroscopy/Engineering Research Center of Nanophotonics&Advanced Instrument(Ministry of Education) School of Physics and Electronic ScienceEast China Normal UniversityShanghai 200241China school of Materials science and Engineering Zhengzhou UniversityZhengzhou 450052China state Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghai 200050China

Benefiting from abundant exposed active sites,minimized diffusion resistance of guest molecules,facilitated mass transfer process and enhanced storage capacity,covalent organic frameworks(COFs)have gained widespread scientific attention[1–4].Further construction of mesopores regarding pore engineering(pore size,pore geometry,pore volume,and framework compositions)in COFs can improve mass transport,accessibility as well as size-selectivity of the special guest moieties,thus exhibiting potential in catalysis,energy storage and separation and so on[5,6].

关键词： gained catalysis separation

Advancements in machine learning for material design and process optimization in the field of additive manufacturing

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China Foundry 2024年第2期21卷 101-115页

作者： hao-ran Zhou hao Yang Huai-qian Li Ying-chun Ma sen Yu Jian shi Jing-chang cheng Peng Gao Bo Yu Zhi-quan Miao Yan-peng Wei National Key Laboratory of Advanced Casting Technologies Shenyang Research Institute of Foundry Co.Ltd.CAMShenyang 110022China Department of Mechanical Engineering Tsinghua UniversityBeijing 100084China Key Laboratory of space Physics Beijing 100076China school of Materials science and Engineering Nanyang Technological University639798Singapore

Additive manufacturing technology is highly regarded due to its advantages,such as high precision and the ability to address complex geometric ***,the development of additive manufacturing process is constrained by issues like unclear fundamental principles,complex experimental cycles,and high *** learning,as a novel artificial intelligence technology,has the potential to deeply engage in the development of additive manufacturing process,assisting engineers in learning and developing new *** paper provides a comprehensive overview of the research and applications of machine learning in the field of additive manufacturing,particularly in model design and process ***,it introduces the background and significance of machine learning-assisted design in additive manufacturing *** then further delves into the application of machine learning in additive manufacturing,focus.ng on model design and process ***,it concludes by summarizing and forecasting the development trends of machine learning technology in the field of additive manufacturing.

关键词： additive manufacturing machine learning material design process optimization intersection of disciplines embedded machine learning

High-Performance and Large-Area Inverted Perovskite solar Cells Based on NiO_(x) Films Enabled with A Novel Microstructure-Control Technology

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Energy & Environmental Materials 2024年第1期7卷 153-159页

作者： Guibin shen Xin Li Yuqin Zou Hongye Dong Dongping Zhu Yanglin Jiang Xin Ren ng Fen Lin Peter Müller-Buschbaum cheng Mu Key Laboratory of Advanced Light Conversion Materials and Biophotonics Department of ChemistryRenmin University of ChinaBeijing 100872China solar Energy Research Institute of s.ngapore(sERIs) National University of SingaporeSingapore 117574Singapore Physik-Department Lehrstuhl für Funktionelle MaterialienTechnische Universität MünchenJames-Franck-Straße 185748Garching Germany Heinz Maier-Leibnitz Zentrum(MLZ) Technische Universität MünchenLichtenbergstr.185748Garching Germany

The improvement in the efficiency of inverted perovskite solar cells(PsCs)is significantly limited by undesirable contact at the NiO_(x)/perovskite *** this study,a novel microstructure-control technology is proposed for fabrication of porous NiO_(x)films us.ng Pluronic P123 as the structure-directing agent and acetylacetone(AcAc)as the coordination *** synthesized porous NiO_(x)films enhanced the hole extraction efficiency and reduced recombination defects at the NiO_(x)/perovskite ***,without any modification,the power conversion efficiency(PCE)of the PsC with MAPbl_(3)as the absorber layer improved from 16.50%to 19.08%.Moreover,the PCE of the device composed of perovskite Cs0.05(MA_(0.15)FA_(0.85))_(0.95)Pb(I_(0.85)Br_(0.15))_(3)improved from 17.49%to 21.42%.Furthermore,the application of the fabricated porous NiO_(x)on fluorine-doped tin oxide(FTO)substrates enabled the fabrication of large-area PsCs(1.2 cm^(2))with a PCE of 19.63%.This study provides a novel strategy for improving the contact at the NiO_(x)/perovskite interface for the fabrication of high-performance large-area perovskite solar cells.

关键词： interfacial contact inverted and large-area perovskite solar cells photovoltaic materials porous NiO_(x)films renewable energy