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Chinese Journal of Aeronautics 2024年第2期37卷 511-523页

作者： Yunsen hu Jingheng ZHANG Lin wang Fei cheng Xiaozhi hu School of Materials and Chemistry Southwest University of Science and TechnologyMianyang 621000China School of Mechanical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China Engineering Research Center of Biomass Materials Ministry of EducationSouthwest University of Science and TechnologyMianyang 621010China Department of Mechanical Engineering University of Western AustraliaPerthWA 6009Australia

Adhesively Bonded Carbon Fibre Reinforced Plastic(CFRP)and titanium alloy have been extensively used as a hybrid structure in modern aircrafts due to their excellent combination of mechanical properties and chemical *** study utilised NaOH anodising method to create micro-rough titanium surfaces for enhancing adhesive bonding between titanium alloy and CFRP laminates.A special and simple technique named Resin Pre-Coating(RPC)was also employed to improve the surface wetting of anodised titanium and grinded CFRP *** influences of anodising temperature and duration on the surface morphology,wettability and adhesive bond strength were *** single lap shear test results showed that the bond strength of specimens anodised at 20℃for 15 min improved by 135.9%and 95.4%,respectively,in comparison with that of acid pickled and grinded specimens(without RPC treatment).Although increasing the anodising temperature and duration produced rougher titanium surfaces,the adhesively bonded joints were not strong enough due to relatively friable titanium oxide layers.

关键词： Carbon Fibre Reinforced Polymer(CFRP) Titanium alloy Anodising Resin pre-coating Adhesive joints

Propagation Properties of Shock Waves in Polyurethane Foam based on Atomistic Simulations

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Defence Technology（防务技术） 2024年第1期31卷 117-129页

作者： Zhiqiang hu Jianli Shao Shiyu Jia Weidong Song cheng wang State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China

Porous materials are widely used in the field of protection because of their excellent energy absorption *** this work,a series of polyurethane microscopic models are established and the effect of porosity on the shock waves is studied with classical molecular dynamics ***,shock hugoniot relations for different porosities are obtained,which compare well with the experimental *** pores collapse and form local stress wave,which results in the complex multi-wave structure of the shock *** microstructure analysis shows that the local stress increases and the local velocity decreases gradually during the process of pore collapse to complete ***,it leads to stress relaxation and velocity *** shock stress peaks can be fitted with two exponential functions,and the amplitude of attenuation coefficient decreases with the increase of ***,the pore collapse under shock or non-shock are discussed by the entropy increase rate of the *** energy is dissipated mainly through the multiple interactions of the waves under *** energy is dissipated mainly by the friction between atoms under non-shock.

关键词： Polyurethane foam Shock wave Attenuation Atomistic simulation

Time-dependent behavior and permeability evolution of limestone under hydro-mechanical coupling

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Journal of Mountain Science 2024年第5期21卷 1697-1714页

作者： wang Zhilong ZENG Zhengqiang LYU cheng wang Mingnian hu Xiongyu DONG Yucang School of Civil Engineering Southwest Jiaotong UniversityChengdu 61003China College of Civil Engineering Tongji UniversityShanghai 200092China College of Water Resource and Hydropower Sichuan UniversityChengdu 610065China Hebei GEO University Shijiazhuang 050031China

Excessively high pore water pressure presents unpredictable risks to the safety of rock tunnels in mountainous regions that are predominantly composed of limestone. Investigating the creep characteristics and permeability evolution of limestone under varying hydrated conditions is crucial for a better understanding of the delayed deformation mechanisms of limestone rock tunnels. To this end, this paper initially conducts a series of multi-stage triaxial creep tests on limestone samples under varying pore water pressures. The experiment examines how pore water pressure affects limestone’s creep strain, strain rate, long-term strength, lifespan, and permeability, all within the context of hydraulicmechanical(HM) coupling. To better describe the creep behavior associated with pore water pressure, this paper proposes a new nonlinear fractional creep constitutive model. This constitutive model depicts the initial, steady-state, and accelerated phases of limestone’s creep behavior. Finally, the proposed model is applied to the numerical realization of deformation in limestone tunnel, validating the effectiveness of the proposed constitutive model in predicting tunnel’s creep deformation. This research enhances our understanding of limestone’s creep characteristics and permeability evolution under HM coupling, laying a foundation for assessing the longterm stability of mountain tunnels.

关键词： Creep test Hydraulic-mechanical coupling Creep constitutive model Fractional derivatives Pore pressure

Modulating charge separation and transfer for high-performance photoelectrodes via built-in electric field

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International Journal of Minerals,Metallurgy and Materials 2024年第5期31卷 1126-1146页

作者： Houyan cheng Peng Liu Yuntao Cui Ru Ya Yuxiang hu Jinshu wang Key Laboratory of Advanced Functional Materials of Education Ministry of China Faculty of Engineering and ManufacturingBeijing University of TechnologyBeijing 100124China Key Laboratory of Cryogenic Science and Technology and Beijing Key Lab of Cryo-Biomedical Engineering Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Inner Mongolia Academy of Science and Technology Hohhot 010020China

Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical ***,considerable efforts have been devoted to this *** review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and ***,mechanisms and tuning strategies for built-in electric fields are ***,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface ***,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.

关键词： photoelectrochemical water splitting bulk built-in electric field cation intercalation charge separation and transfer

Simultaneously enhanced electrochemical performance and air stability of Ni-rich cathode with a modified washing process

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Rare Metals 2024年第1期43卷 87-97页

作者： Ben-Rui hu Ying-Yi Yuan Yu-cheng wang Xun-hui Xiong School of Environment and Energy Guangdong Provincial Key Laboratory of Advanced Energy Storage MaterialsSouth China University of TechnologyGuangzhou 510640China

Water washing has been regarded as one of the most effective strategies to remove surface residual lithium of nickel-rich layered oxides for lithium-ion batteries(LIBs).However,the loss of lattice lithium during the water washing process deteriorates the electrochemical performances and air ***,washing the LiNi_(0.90)Co_(0.05)Al_(0.02)O_(2)(NCA) with ammonium dihydrogen phosphate(NH_(4)H_(2)PO_(4)) solution has been proposed to simultaneously enhance electrochemical performances and air stability,in which in-situ generated Li_(3)PO_(4) coating layer on surface of NCA can suppress the loss of lattice ***,as a fast ionic conductor,Li_(3)PO_(4) coating layer on NCA can prevent the direct contact with electrolyte/*** a result,the NH_(4)H_(2)PO_(4) solution washed NCA cathode can deliver a high capacity of131.9 mAh·g^(-1) at 10.0C rate as well as impressive cycle stability with a capacity retention of 83.1% after 100 cycles at 1.0C,much higher than those of water washed NCA(WS-NCA) *** exposed in air for 7 days,the NH_(4)H_(2)PO_(4) solution washed NCA electrode can more effectively maintain the structural integrity as well as the electrochemical performances than water-washed *** work provides a simple and effective approach to enhance the cycle stability and air stability of Nickel-rich cathode materials.

关键词： Layered Ni-rich cathode Residual lithium Li_(3)PO_(4)coating Rate performance Air stability

Overcoming the Na-ion conductivity bottleneck for the cost-competitive chloride solid electrolytes

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Journal of Energy Chemistry 2024年第8期95卷 1-8,I0001页

作者： Lv hu hui Li Fang Chen Yating Liu Jinzhu wang cheng Ma Hefei National Research Center for Physical Sciences at the Microscale CAS Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026AnhuiChina National Synchrotron Radiation Laboratory Hefei 230026AnhuiChina

Chloride solid electrolytes possess multiple advantages for the construction of safe,energy-dense allsolid-state sodium batteries,but presently the chlorides with sufficiently high cost-competitiveness for commercialization almost all exhibit low Na-ion conductivities of around 10^(-5)S cm^(-1)or ***,we report a chloride solid electrolyte,Na_(2.7)ZFCl_(5.3)O_(0.7),which reaches a Na-ion conductivity of 2.29×10^(-4)S cm^(-1)at 25℃without involving overly expensive raw materials such as rare-earth chlorides or Na_(2)*** addition to the efficient ion transport,Na_(2.7)ZrCl_(5.3)O_(0.7)also shows an excellent deformability surpassing that of the widely studied Na_(3)PS_(4),Na_(3)SbS_(4),and Na_(2)ZrCl_(6)solid *** combination of these advantages allows the all-solid-state cell based on Na_(2.7)ZrCl_(5.3)O_(0.7)and NaCrO_(2)to realize stable room-temperature cycling at a much higher specific current than those based on other non-viscoelastic chloride solid electrolytes in literature(120 mA g^(-1)vs.12-55 mA g^(-1));after 100 cycles at such a high rate,the Na_(2.7)ZFCl_(5.3)O_(0.7)-based cell can still deliver a discharge capacity of 80 mAh g^(-1)at25℃.

关键词： All-solid-state sodium batteries Ionic conductivities Solid electrolytes Chlorides High voltage stability

Fabrication of CuFe_(2)O_(4)/Bi_(12)O_(17)Cl_(2) photocatalyst with intrinsic p-n junction for highly efficient bisphenol A degradation

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Journal of Environmental Sciences 2024年第2期136卷 547-558页

作者： Yong wang cheng Liu Haoyun hu Qiujun Lu Haiyan wang Chenxi Zhao Fuyou Du Ningli Tang Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials College of Chemistry and BioengineeringGuilin University of TechnologyGuilin 541004China College of Biological and Environmental Engineering Changsha UniversityChangsha 410022China

The construction and application of novel highly efficient photocatalysts have been the focus in the field of environmental pollutant *** this work,a novel CuFe_(2)O_(4)/Bi_(12)O_(17)Cl_(2)photocatalysts were synthesized by simple hydrothermal and chemical precipitation *** fabricated CuFe_(2)O_(4)/Bi_(12)O_(17)Cl_(2)composite exhibited much higher photocatalytic activity than pristine CuFe_(2)O_(4)and Bi_(12)O_(17)Cl_(2)in the removal of bisphenol A(BPA)under visible-light illumination,which ascribed to the intrinsic p-n junction of CuFe_(2)O_(4)and Bi_(12)O_(17)Cl_(2).The photocatalytic degradation rate of BPA on CuFe_(2)O_(4)/Bi_(12)O_(17)Cl_(2)with an optimized CuFe_(2)O_(4)content(1.0 wt.%)reached 93.0%within 30 *** capture experiments of active species confirmed that the hydroxyl radicals(·OH)and superoxide radicals(·O_(2)^(-))played crucial roles in photocatalytic BPA degradation ***,the possible degradation mechanism and pathways of BPA was proposed according to the detected intermediates in photocatalytic reaction process.

关键词： Bi_(12)O_(17)Cl_(2) CuFe_(2)O_(4) Heterojunction Bisphenol A Photocatalytic degradation

Implication of Water-Rock Interaction for Enhancing Shale Gas Production

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Fluid Dynamics & Materials Processing 2024年第7期20卷 1441-1462页

作者： Qiuyang cheng Lijun You cheng Chang Weiyang Xie Haoran hu Xingchen wang Shale Gas Research Institute PetroChina Southwest Oil and Gas Field CompanyChengdu610056China Sichuan Province Key Laboratory of Shale Gas Evaluation and Exploitation PetroChina Southwest Oil and Gas Field CompanyChengdu610056China State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu610500China

Horizontal well drilling and multi-stage hydraulic fracturing technologies are at the root of commercial shale gas development and *** these processes,typically,a large amount of working fluid enters the formation,resulting in widespread water-rock *** understanding such effects is required to optimize the production *** this study,the mechanisms of water-rock interaction and the associated responses of shale fabric are systematically reviewed for working fluids such as neutral fluids,acid fluids,alkali fluids and oxidative *** is shown that shale is generally rich in water-sensitive components such as clay minerals,acidsensitive components(like carbonate minerals),alkali-sensitive components(like quartz),oxidative-sensitive components(like organic matter and pyrite),which easily lead to change of rock fabric and mechanical properties owing to water-rock *** to the results,oxidizing acid fluids and oxidizing fracturing fluids should be used to enhance shale gas *** study also indicates that an aspect playing an important role in increasing cumulative gas production is the optimization of the maximum shut-in time based on the change point of the wellhead pressure drop *** important influential factor to be considered is the control of the wellhead pressure considering the stress sensitivity and creep characteristics of the fracture network.

关键词： Shale gas reservoir hydraulic fracturing working fluid water-rock interaction oxidation shut-in production system

Determination of ice jam thickness—A new approach

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Journal of Hydrodynamics 2024年第3期36卷 570-581页

作者： Jun wang Lian-sheng Sang Fei-hu Song Tie-jie cheng Jueyi Sui School of Civil and Water Engineering Hefei University of TechnologyHefei230009China School of Engineering University of Northern British ColumbiaPrince GeorgeCanada

In winter,rivers in cold regions often experience flood disasters resulted from ice jams or ice *** of the variation of ice jam thickness and water level during an ice jammed period are not only a practical need for ice prevention to avoid disaster and plan water resource,but also essential for the development of any mathematical model for predicting the evolution of ice *** far,some equations based on the energy equation have been proposed to describe the relationship between ice jam thickness and water ***,in the derivation of these equations,the local head loss coefficient at the ice jam head and the riverbed slope factor were ***,those reported equations cannot be used to preciously describe the flow energy equation with ice jams and accurately calculate the ice jam thickness and water *** the present study,a more comprehensive theoretical model for hydraulic calculation of ice jam thickness has been derived by considering important and essential factors including riverbed slope and local head loss coefficient at the ice jam ***,based on the data collected from laboratory experiments of ice jam accumulation,the local head loss coefficient at the ice jam head has been calculated,and the empirical equation for calculating the local head loss coefficient has been established by considering flow Froude number and the ratio of ice discharge to flow *** results of this study not only provide a new reference for calculating ice jam thickness and water level,but also present a theoretical basis for accurate CFD simulation of ice jams.

关键词： Energy equation ice jam thickness local head loss coefficient ice jam head riverbed slope

Optimizing magnetoelastic properties by machine learning and high-throughput micromagnetic simulation

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Rare Metals 2024年第5期43卷 2251-2262页

作者： Jian-hu Gong Zheng-Ming Zhang cheng-Liang Zhang Peng-Qiang hu Chao Zhou Dun-hui wang Sen Yang Division of Microelectronic Materials and Devices Hangzhou Dianzi UniversityHangzhou 310018China School of Physics MOEKey Laboratory forNonequilibrium Synthesis and Modulation of Condensed Matter and State Key Laboratory for Mechanical Behavior of MaterialsXi'an Jiaotong UniversityXi'an 710049China National Laboratory of Solid State Microstructures Nanjing UniversityNanjing210093China

Magnetoelastic couplings in giant magnetostrictive materials(GMMs)attract significant interests due to their extensive applications in the fields of spintronics and energy harvesting *** the role of the selection of materials and the response to external fields is essential for attaining desired functionality of a ***,machine learning(ML)models are conducted to predict saturation magnetostrictions(λ_(s))in RFe_(2)-type(R=rare earth)GMMs with different *** to ML-predicted composition–λsrelations,it is discovered that the values ofλshigher than1100×10^(-6)are almost situated in the composition space surrounded by 0.26≤x≤0.60 and 1.90≤y≤2.00 for the ternary compounds of Tb_(x)Dy_(1-x)Fe_(y).Assisted by ML predictions,the compositions are further narrowed down to the space surrounded by 0.26≤x≤0.32 and 1.92≤y≤1.97 for the excellent piezomagnetic(PM)performance in the Tb_(x)Dy_(1-x)Fe_(y)based PM device through our developed high-throughput(HTP)micromagnetic simulation(MMS)***,high sensitivities up to10.22-13.61 m T·MPa^(-1)are observed in the optimized range within which the available experimental data fall *** work not only provides valuable insights toward understanding the mechanism of magnetoelastic couplings,but also paves the way for designing and optimizing highperformance magnetostrictive materials and PM sensing devices.

关键词： Magnetostriction Piezomagnetic effect Machine learning Micromagnetic simulation