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A Coupled Thermodynamic Model for Prediction of Inclusions Precipitation during Solidification of Heat-resistant Steel Containing Cerium

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Journal of Iron and Steel Research International 2015年第6期22卷 457-463页

作者： Yan-dong LI cheng-jun LIU Chun-long LI Mao-fa jiang Key Laboratory for Ecological Metallurgy of Multimetallic Minerals(Ministry of Education) Northeastern University Baotou Iron and Steel(Group)Company

A coupled thermodynamic model of inclusions precipitation both in liquid and solid phase and microseg- regation of solute elements during solidification of heat-resistant steel containing cerium was established. Then the model was validated by the SEM analysis of the industrial products. The type and amount of inclusions in solidifica- tion structure of 253MA heat-resistant steel were predicted by the model, and the valuable results for the inclusions controlling in 253MA steel were obtained. When the cerium addition increases, the types of inclusions transform from SiO2 and MnS to Ce2 O3 and Ce2O2 S in 253MA steel and the precipitation temperature of SiO2 and MnS decrea- ses. The inclusions CeS and CeN convert to Ce2 O3 and Ce2 O2 S as the oxygen content increases and Ce2 O3 and CeN convert to Ce2 O2 S, Ce3 S4, and MnS as the sulfur content increases. The formation temperature of SiO2 increases when the oxygen content increases and the MnS precipitation temperature increases when the sulfur content increa ses. There is only a small quantity of inclusions containing cerium in 253MA steel with high cleanliness, i. e. , low oxygen and sulfur contents. By contrast, a mass of SiO2 , MnS and Ce2 O2 S are formed in steel when the oxygen and sulfur contents are high enough. The condition that MnS precipitates in 253MA steel is 1.2wEo[O] ＋W[s]〉0. 01% and SiO2 precipitates when 2w[O] ＋wrs[S]〉0. 017% （W[S]0. 005%） and w[O]〉0. 006% （w[S]〉0. 005%）.

关键词： heat-resistant steel rare earth steel inclusion microsegregationl solidification thermodynamic model

Growth and aggregation control of spinel by shear-force-based melting modification of stainless steel slag

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International Journal of Minerals,Metallurgy and Materials 2018年第10期25卷 1140-1147页

作者： Qing Zhao cheng-jun Liu Tian-ci Gao Long-hu Cao Mao-fa jiang Key Laboratory for Ecological Metallurgy of Multimetallic Minerals (Ministry of Education) Northeastern University School of Metallurgy Northeastern University

To improve the efficiency of melting modification for stainless steel(SS) slag, a shear force was introduced in this work and its effects on the spinel and silicate melt were experimentally investigated. The results indicated that the use of shear force changed the nucleation and growth behaviors of spinel and that the effects of shear force varied with its intensity. The aggregation behavior of spinel under different shear-force conditions was studied, revealing that large spinel clusters could be formed when the stirring speed was controlled. However, no notable change in the melt structure of the silicate was detected in this study. The optimal stirring speed for the melting modification treatment was 50 r·min^(-1), which substantially promoted spinel growth and aggregation, resulting in modified SS slag with excellent chromium sequestration capability.

关键词： stainless steel slag spinel crystal growth melting modification shear force chromium sequestration

Development of Glass Ceramics Made From Ferrous Tailings and Slag in China

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Journal of Iron and Steel Research International 2007年第2期14卷 73-78页

作者： LIU cheng-jun SHI Pei-yang ZHANG Da-yong jiang Mao-fa School of Materials and Metallurgy Northeastern University Shenyang 110004 Liaoning China

A great amount of ferrous tailings and slag cause severe damage to the ecological environment, which must be reclaimed and utilized. The composition, type, and characteristics of ferrous tailings and slag in China were introduced. The research status and the application outlook of glass ceramics made from ferrous tailings and slag were discussed. Glass ceramics made from ferrous tailings and slag can be applied to various fields, and it will be environmentally conscious materials in the 21st century.

关键词： glass ceramics ferrous tailings slag

Recent progress on photoactive nonprecious transition-metal complexes

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Science China Chemistry 2025年第1期 46-95页

作者： Zhong-Liang Gong Hong-Jie Zhang Yan cheng Jianxun Liu Yuhan Ai Yaqin Li Zhihui Feng Qiong Zhang Shaolong Gong Yong Chen Chang-jiang Yao Yuan-Yuan Zhu Liang-Jin Xu Yu-Wu Zhong CAS Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences State Key Laboratory of Structural Cemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences School of Chemistry and Chemical Engineering Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of Technology State Key Laboratory of Explosion Science and Safety Protection School of Mechatronical Engineering Beijing Institute of Technology College of Chemistry and Molecular Sciences Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Wuhan University School of Chemistry and Chemical Engineering Anhui University Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences

Photoactive complexes of nonprecious transition metals, mainly including those in the first-row and partially the second-row of the Periodic table of elements, have received increasing attention in view of their low cost and long-term sustainability. They are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices, artificial photosynthesis, photocatalysis, biodiagnostics, and therapeutics, etc. This review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes, including photoactive Zr, V, Cr, Mo, and W complexes, Mn complexes and hybrids, Fe, Co, Ni, and Cu complexes, and Zn and Cd complexes and hybrids. A particular focus is given on the molecular design, modulation of photophysical and photochemical properties, and applications of the representative and lately-developed nonprecious metal complexes. In addition, a perspective on the future development in this field is provided at the end of this review.

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A quantum chemistry study on reaction mechanisms of SO_2 with O_3 and H_2O_2

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2009年第9期10卷 1327-1333页

作者： Shu-dong jiang Zhi-hua WANG Jun-hu ZHOU Zheng-cheng WEN Ke-fa CEN State Key Laboratory of Clean Energy Utilization Zhejiang University Hangzhou 310027 China

Reaction mechanisms of SO2 with O3 and H2O2 were investigated using quantum chemistry ab initio methods. Structures of all reactants, products, and transition states were optimized at the B3LYP/6-311G＋（3df,2p） level, and energy calculations were made at the G2M level. SO2 reactions with O3 and H2O2 occurred by O-abstraction and OH-abstraction by SO2, respectively, at length forming SO3＋O2 （3Eg） and H2SO4. For SO2＋O3 reactions the barrier height was predicted to be 9.68 kcal/mol with a rate constant of 3.61 × 10^-23 cm^3/（molecule.s） at 300 K, which is below the experimental upper limit. The rate constant predicted for this reaction accords well with the one provided by National Institute for Standards and Technology （NIST） in 250-500 K. For SO2＋H2O2 reactions the barrier height was predicted to be 62.39 kcal/mol with a rate constant of 2.48× 10^-61 cm^3/（molecule.s） at 300 K.

关键词： Sulfur dioxide Ozone Hydrogen peroxide Reaction mechanism Rate constant Quantum chemistry

Physical Simulation of Molten Slag Granulation by Rotary Disk

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Journal of Iron and Steel Research International 2013年第9期20卷 26-32页

作者： MIN Yi HUANG Jian LIU cheng-jun jiang Mao-fa YU Xue-qing School of Materials and Metallurgy Northeastern University Benxi Steel Group Corporation

A physical model of molten slag granulation by rotary disk was developed based on the mechanism of New-tonian liquid granulation. For geometrical similarity, the radius ratio of model disk to the prototype disk was chosen as 1 ： 1. For dynamic similarity, equality of Ohnesorge number between the model and the prototype was achieved firstly by compounding rosin and paraffin wax with mass ratio of 4 ~ 1 as simulation liquid of molten blast furnace （BF） slag, and the simulation material can satisfy the similarity of liquid solid transformation during falling in the medium; then equality of Reynolds number and Weber number was obtained by controlling the volumetric flow rate and the rotary speed, respectively. Model accuracy was verified by comparing the simulation data with the results re ported in literature, which showed good agreement with the calculation results of empirical equation and the actual molten BF slag granulation from the view point of particle size. Furthermore, influences of disk radius, rotary speed and liquid flow rate on granulation were discussed using the developed model, and the Kitamura equation was modi-fied according to the simulation data which can predict particle size more accurately. Using the modified equation, the operation parameters were predicted according to the flow rate of molten industrial BF slag.

关键词： physical model simulation liquid molten slag granulation rotary disk

Coexistence of breakpoint cluster region-Abelson1 rearrangement and Janus kinase 2 V617F mutation in chronic myeloid leukemia: A case report

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World Journal of Clinical Cases 2019年第9期7卷 1087-1092页

作者： Xue-Bing Shi Ji-fa jiang Feng-Xiang Jin Wei cheng Department of Hematology and Oncology Tongling People's Hospital

BACKGROUND The Janus kinase 2(JAK2) V617 F mutation is common in patients with breakpoint cluster region-Abelson1(BCR-ABL1)-negative myeloproliferative neoplasms,including polycythemia vera, essential thrombocythemia and primary myelofibrosis, but is rarely detected in BCR-ABL1-positive chronic myeloid leukemia(CML) patients. Here, we report a CML patient with both a BCR-ABL1 rearrangement and JAK2 V617 F *** SUMMARY A 45-year-old Chinese woman was admitted to our department with a history of significant thrombocytosis for 20 d. Color Doppler ultrasound examination showed mild splenomegaly. Bone marrow aspiration revealed a karyotype of 46,XX, t(9;22)(q34;q11.2) in 20/20 metaphases by cytogenetic analysis,rearrangement of BCR-ABL1(32.31%) by fluorescent polymerase chain reaction(PCR) and mutation of JAK2 V617 F(10%) by PCR and Sanger DNA *** patient was diagnosed with CML and JAK2 V617 F mutation. Following treatment with imatinib for 3 mo, the patient had an optimal response and BCRABL1(IS) was 0.143%, while the mutation rate of JAK2 V617 F rose to 15%.CONCLUSION Emphasis should be placed on the detection of JAK2 mutation when CML is diagnosed to distinguish JAK2 mutation-positive CML and formulate treatment strategies.

关键词： Chronic myeloid leukemia JAK2 V617F BCR-ABL1 Imatinib Myeloproliferative neoplasm Case report

Effect of projectile parameters on opening behavior of PELE penetrating RC target

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Defence Technology（防务技术） 2021年第3期17卷 859-873页

作者： Li-zhi Xu cheng-xin Du Chun cheng Xiao-dong Wang jiang-bo Wang Zhong-hua Du Guang-fa Gao School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing210094China

When a penetrator with enhanced lateral effect(PELE) impacts on a reinforced concrete(RC) target,the target is damaged with a large *** understanding of how PELE projectile parameters affect the opening dimension,is essential for effective design of the PELE *** this study,under the condition that the impact velocity and target parameters(strength and thickness) were fixed values,the important influence factors of the PELE(jacket wall thickness B,jacket material strength Y1,filling material strength Y2 and angle of monolithic jacket θ) were determined by a dimensional *** and simulations of the PELE penetrating the RC target were conducted to analyze the influence of these factors on opening diameter(D,an equivalent diameter under relative kinetic energy).Based on the test and simulation results,it is found that the influence of these factors B,Y1 and θ on the deformation mode of the jacket shows a similar trend:as values of the three factors decrease,the jacket deforms from small bending deformation to large one,and then to curling *** causes the opening diameter to first increase with the decrease of these three factors,and then *** is well known that the bending resistance of the jacket is related to these factors B,Y1 and θ.Therefore,a plastic limit bending moment(M0) of the jacket was quoted to characterize the influence of these factors on the bending deformation of the jacket and the opening diameter of the *** influence factor Y2 causes D to first increase with the increase of Y2,and then decreases.A formula was developed to predict the opening diameter,whose influence parameters were considered in a dimensionless *** has been shown that the dimensionless opening diameter D/d1 is dependent on two dimensionless parameters■ and■,where d1 and fc are the outer diameter of the projectile and the compressive strength of the target,respectively.

关键词： Penetrator with enhanced lateral effect Opening behaviour Reinforced concrete target Dimensional analysis

Crystallization Temperature and Crystallization Ratio of Mold Flux

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Journal of Iron and Steel Research International 2005年第6期12卷 23-26页

作者： ZHU Chuan-yun HAN Wen-dian LIU cheng-jun jiang Mao-fa Northeastern University Shenyang 110004 China Central Iron and Steel Research Institute Beijing 100081 China

The factors influencing the crystallization ratio of mold flux were researched by rapid cooling technolo gy, and the factors affecting crystallization temperature were studied by single thermocouple technique. The results showed that the crystallization ratio of mold flux increases with the basicity and the content of Na2O, CaF2, Li2O and NaF, and decreases with the increase of the content of Al2O3, MgO, BaO, MnO and B2O3. However, the crystallization temperature of mold flux rises with the basicity and the content of NaF, Na2O and CaF2, and reduces with the increase of the content of Al2O3, MgO, BaO, MnO and B2O3. But for Li2O, crystallization temperature decreases firstly to a minimum value at 2%, and then increases gradually with the increase of Li2O.

关键词： mold flux crystallization temperature crystallization ratio viscosity solidification temperature