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Chinese Journal of Chemistry 2024年第9期42卷 963-972页

作者： Haoran Zhang JiaojiaoQin Xiaoyan tang Beijing National Laboratoryfor Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCenterfor Soft Matter Science and EngineeringCollegeof Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China

Poly(3-hydroxybutyrate),a crucial member of the large biodegradable polyhydroxyalkanoate family,suffers from its *** enhance its performance,we employed a straightforward approach involving the ring-opening copolymerization of racemic-β-butyrolactone(rac-β-BL)andβ-propiolactone(β-PL)using the syndio-selective amino-alkoxy-bis(phenolate)-yttrium complex as a catalyst,thanks to the excellent ductility of poly(3-hydroxypropionate).Control over the rac-β-BL/β-PL feeding ratios and polymerization time yielded random or block copolymers with tunable thermal and mechanical properties comparable to traditional fossil-based ***,we achieved one-pot synthesis of hard-soft-hard triblock copolymers by exploiting monomers’different copolymerization rates and a bifunctional initiator,thus transforming polyhydroxyalkanoates from hard and tough plastics to soft and ductile thermoplastic elastomers.

关键词： Ring-opening(co-)polymerization Biodegradable polymers Polyhydroxyalkanoates Copolymers Plastics Elastomers

三酰甘油-葡萄糖指数及其联合人体测量学指标与心血管疾病相关性的研究进展

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中国心血管杂志 2024年第2期29卷 174-177页

作者：卢彦娜梁超唐强北京大学首钢医院心血管内科 100144 首都医科大学附属北京积水潭医院老年医学科

近年研究发现,三酰甘油-葡萄糖(TyG)指数是早期评估胰岛素抵抗简易灵敏的替代指标,在心血管疾病的风险预测、危险分层及预后评估方面有重要意义。一些学者将TyG与人体测量学指标相结合,发现可更好地预测心血管疾病风险。故本文就TyG及... 详细信息

近年研究发现,三酰甘油-葡萄糖(TyG)指数是早期评估胰岛素抵抗简易灵敏的替代指标,在心血管疾病的风险预测、危险分层及预后评估方面有重要意义。一些学者将TyG与人体测量学指标相结合,发现可更好地预测心血管疾病风险。故本文就TyG及其联合人体测量学相关指标在高血压、冠心病等心血管疾病中的应用价值及研究进展进行综述。

关键词：心血管疾病三酰甘油-葡萄糖指数人体测量学指标相关性

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Improvement of Ga_(2)O_(3)vertical Schottky barrier diode by constructing NiO/Ga_(2)O_(3)heterojunction

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Journal of Semiconductors 2024年第4期45卷 63-68页

作者： Xueqiang Ji Jinjin Wang Song Qi Yijie liang Shengrun Hu Haochen Zheng Sai Zhang Jianying Yue Xiaohui Qi Shan Li Zeng Liu Lei Shu Weihua tang Peigang Li School of Integrated Circuits&State Key Laboratory of Information Photonics and Optical Communications Beijing University of Posts and TelecommunicationsBeijing 100876China College of Integrated Circuit Science and Engineering Nanjing University of Posts and TelecommunicationsNanjing 210023China Beijing Microelectronics Technology Institute Beijing 100076China

The high critical electric field strength of Ga_(2)O_(3)enables higher operating voltages and reduced switching losses in power electronic *** Schottky metals and epitaxial films are essential for further enhancing device *** this work,the fabrication of vertical Ga_(2)O_(3)barrier diodes with three different barrier metals was carried out on an n--Ga_(2)O_(3)homogeneous epitaxial film deposited on an n+-β-Ga_(2)O_(3)substrate by metal-organic chemical vapor deposition,excluding the use of edge *** ideal factor,barrier height,specific on-resistance,and breakdown voltage characteristics of all devices were investigated at room *** addition,the vertical Ga_(2)O_(3)barrier diodes achieve a higher breakdown volt-age and exhibit a reverse leakage as low as 4.82×10^(-8)A/cm^(2)by constructing a NiO/Ga_(2)O_(3)***,Ga_(2)O_(3)power detailed investigations into Schottky barrier metal and NiO/Ga_(2)O_(3)heterojunction of Ga_(2)O_(3)homogeneous epitaxial films are of great research potential in high-efficiency,high-power,and high-reliability applications.

关键词： Ga_(2)O_(3) Schottky barrier diode NiO/Ga_(2)O_(3)heterojunction

Transcriptional regulation in the development and dysfunction of neocortical projection neurons

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Neural Regeneration Research 2024年第2期19卷 246-254页

作者： Ningxin Wang Rong Wan Ke tang Precise Genome Engineering Center School of Life SciencesGuangzhou UniversityGuangzhouGuangdong ProvinceChina

Glutamatergic projection neurons generate sophisticated excitatory circuits to integrate and transmit information among different cortical areas,and between the neocortex and other regions of the brain and spinal *** development of cortical projection neurons is regulated by certain essential events such as neural fate determination,proliferation,specification,differentiation,migration,survival,axonogenesis,and *** processes are precisely regulated in a tempo-spatial manner by intrinsic factors,extrinsic signals,and neural *** generation of correct subtypes and precise connections of projection neurons is imperative not only to support the basic cortical functions(such as sensory information integration,motor coordination,and cognition)but also to prevent the onset and progression of neurodevelopmental disorders(such as intellectual disability,autism spectrum disorders,anxiety,and depression).This review mainly focuses on the recent progress of transcriptional regulations on the development and diversity of neocortical projection neurons and the clinical relevance of the failure of transcriptional modulations.

关键词： autism spectrum disorders cognition differentiation excitatory circuits intellectual disability neocortex neurodevelopmental disorders projection neuron specification transcriptional regulation

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抗偏移混合拓扑恒流无线充电系统研究

电力系统保护与控制 2024年第15期52卷 105-114页

作者：梁雨晴唐忠上海电力大学电气工程学院上海200090

针对电动汽车无线充电系统因偏移导致充电效率降低的实际问题,提出一种新型强抗偏移的恒流无线充电系统。首先,在磁耦合设计上,引入DDQD大解耦线圈有效减缓X、Y两方向偏移耦合系数衰减,通过与DDQ线圈的对比体现所提出的DDQD线圈在抗偏... 详细信息

针对电动汽车无线充电系统因偏移导致充电效率降低的实际问题,提出一种新型强抗偏移的恒流无线充电系统。首先,在磁耦合设计上,引入DDQD大解耦线圈有效减缓X、Y两方向偏移耦合系数衰减,通过与DDQ线圈的对比体现所提出的DDQD线圈在抗偏移方面的优越性。然后,在补偿拓扑设计上,通过DDQD线圈将随耦合系数呈不同变化趋势的LCC拓扑和LC拓扑进行串联,使输出功率变化平缓,进一步提高了系统的抗偏移能力,并且使系统具有恒流输出特性。最后,通过仿真实验验证了该方案的有效性,在磁耦合机构发生偏移时,减缓了无线充电系统的线圈耦合系数和传输效率的下降程度,具有一定的现实意义。

关键词：电动汽车无线电能传输恒流输出抗偏移串联混合型

An efficient physics-guided Bayesian framework for predicting ground settlement profile during excavations in clay

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第4期16卷 1411-1424页

作者： Cong tang Shuyu He Wanhuan Zhou State Key Laboratory of Internet of Things for Smart City and Department of Civil and Environmental Engineering University of MacaoChina

Recently,the application of Bayesian updating to predict excavation-induced deformation has proven successful and improved prediction accuracy ***,updating the ground settlement profile,which is crucial for determining potential damage to nearby infrastructures,has received limited *** address this,this paper proposes a physics-guided simplified model combined with a Bayesian updating framework to accurately predict the ground settlement *** advantage of this model is that it eliminates the need for complex finite element modeling and makes the updating framework ***,the model is physically interpretable,which can provide valuable references for construction *** effectiveness of the proposed method is demonstrated through two field case studies,showing that it can yield satisfactory predictions for the settlement profile.

关键词： Bayesian updating Excavations Ground settlement profile Simplified model Uncertainty

Experimental study on reactions between alkaline basaltic melt and orthopyroxenes: constraints on the evolution of lithospheric mantle in the North China Craton

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Acta Geochimica 2024年第2期43卷 354-365页

作者： Hanqi He Mingliang Wang Hongfeng tang Key Laboratory for High Temperature and High Pressure Study of the Earth’s Interior Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China University of Chinese Academy of Sciences Beijing 100049China School of Resource and Civil Engineering Suzhou UniversitySuzhou 234000AnhuiChina

The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this *** reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric *** starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei *** results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T *** formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff *** is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the *** also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted *** formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this ***,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 *** addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions betwe

关键词： Alkaline basaltic melt Orthopyroxene Melt–mineral reaction High-temperature and high-pressure experiment Genesis of basalt Evolution of lithospheric mantle in the North China Craton

A combinatorial synthesis method for identification of orally bioavailable cyclic peptide

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Science China Chemistry 2024年第8期67卷 2429-2430页

作者： Zhenzhen Liu Li Liu Bo tang College of Chemistry Chemical Engineering and Materials ScienceKey Laboratory of Molecular and Nano ProbesMinistry of EducationCollaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of ShandongInstitutes of Biomedical SciencesShandong Normal UniversityJinan 250014China Laoshan Laboratory Qingdao 266237China

Cyclic peptides are a type of polypeptide with macrocyclic structure formed by canonical and non-canonical amino *** to their rigid conformation and large surface area,cyclic peptides typically exhibit high binding affinity and specificity with target proteins,particularly those considered undruggable by traditional small molecule drugs,such as protein-protein interactions[1].Additionally,they are convenient to be chemical modified to improve the pharmacological or pharmacokinetic properties.

关键词： properties. canonical synthesis

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Improved multi-scale inverse bottleneck residual network based on triplet parallel attention for apple leaf disease identification

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Journal of Integrative Agriculture 2024年第3期23卷 901-922页

作者： Lei tang Jizheng Yi Xiaoyao Li College of Computer&Information Engineering Central South University of Forestry and TechnologyChangsha 410004China Yuelushan Laboratory Carbon Sinks Forests Variety Innovation Center Changsha 410000China

Accurate diagnosis of apple leaf diseases is crucial for improving the quality of apple production and promoting the development of the apple industry. However, apple leaf diseases do not differ significantly from image texture and structural information. The difficulties in disease feature extraction in complex backgrounds slow the related research progress. To address the problems, this paper proposes an improved multi-scale inverse bottleneck residual network model based on a triplet parallel attention mechanism, which is built upon ResNet-50, while improving and combining the inception module and ResNext inverse bottleneck blocks, to recognize seven types of apple leaf(including six diseases of alternaria leaf spot, brown spot, grey spot, mosaic, rust, scab, and one healthy). First, the 3×3 convolutions in some of the residual modules are replaced by multi-scale residual convolutions, the convolution kernels of different sizes contained in each branch of the multi-scale convolution are applied to extract feature maps of different sizes, and the outputs of these branches are multi-scale fused by summing to enrich the output features of the images. Second, the global layer-wise dynamic coordinated inverse bottleneck structure is used to reduce the network feature loss. The inverse bottleneck structure makes the image information less lossy when transforming from different dimensional feature spaces. The fusion of multi-scale and layer-wise dynamic coordinated inverse bottlenecks makes the model effectively balances computational efficiency and feature representation capability, and more robust with a combination of horizontal and vertical features in the fine identification of apple leaf diseases. Finally, after each improved module, a triplet parallel attention module is integrated with cross-dimensional interactions among channels through rotations and residual transformations, which improves the parallel search efficiency of important features and the recogniti

关键词： multi-scale module inverse bottleneck structure triplet parallel attention apple leaf disease

Digital Twin-Assisted Semi-Federated Learning Framework for Industrial Edge Intelligence

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China Communications 2024年第5期21卷 314-329页

作者： Wu Xiongyue tang Jianhua Marie Siew Shien-Ming Wu School of Intelligent Engineering South China University of TechnologyGuangzhou 511442China Electrical and Computer Engineering Department Carnegie Mellon UniversityPittsburghPA 15213United States

The rapid development of emerging technologies,such as edge intelligence and digital twins,have added momentum towards the development of the Industrial Internet of Things(IIo T).However,the massive amount of data generated by the IIo T,coupled with heterogeneous computation capacity across IIo T devices,and users’data privacy concerns,have posed challenges towards achieving industrial edge intelligence(IEI).To achieve IEI,in this paper,we propose a semi-federated learning framework where a portion of the data with higher privacy is kept locally and a portion of the less private data can be potentially uploaded to the edge *** addition,we leverage digital twins to overcome the problem of computation capacity heterogeneity of IIo T devices through the mapping of physical *** formulate a synchronization latency minimization problem which jointly optimizes edge association and the proportion of uploaded nonprivate *** the joint problem is NP-hard and combinatorial and taking into account the reality of largescale device training,we develop a multi-agent hybrid action deep reinforcement learning(DRL)algorithm to find the optimal *** results show that our proposed DRL algorithm can reduce latency and have a better convergence performance for semi-federated learning compared to benchmark algorithms.

关键词： digital twin edge association industrial edge intelligence(IEI) semi-federated learning