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Energy & Environmental Materials 2024年第3期7卷 219-227页

作者： Sihang Cheng Cuimei Liu Yingqi Li Huaqiao tan Yonghui Wang Yangguang Li Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Faculty of ChemistryNortheast Normal UniversityChangchun 130024China

Solar vapor generation(SVC)represents a promising technique for seawater desalination to alleviate the global water crisis and energy *** of its main bottleneck problems is that the evaporation efficiency and stability are limited by salt crystallization under high-salinity ***,we demonstrate that the 3D porous melamine-foam(MF)wrapped by a type of self-assembling composite materials based on reduced polyoxometalates(*** blue,HPB),oleic acid(OA),and polypyrrole(PPy)(labeled with MF@HPB-PPy_(n)-OA)can serve as efficient and stable SVC material at high *** characterizations of MF@HPB-PPy_(n)-OA indicate that both hydrophilic region of HPBs and hydrophobic region of OA co-exist on the surface of composite materials,optimizing the hydrophilic and hydrophobic interfaces of the SVC materials,and fully exerting its functionality for ultrahigh water-evaporation and anti-salt *** optimal MF@HPB-PPy_(10)-OA operates continuously and stably for over 100 h in 10wt%***,MF@HPB-PPy_(10)-OA accomplishes complete salt-water separation of 10wt%brine with 3.3kgm^(-2)h^(-1)under 1-sun irradiation,yielding salt harvesting efficiency of 96.5%,which belongs to the record high of high-salinity systems reported so far and is close to achieving zero liquid ***,the low cost of MF@HPB-PPy_(10)-OA(2.56$m^(-2))suggests its potential application in the practical SVC technique.

关键词： heteropoly blue(HPB) hydrophilic-hydrophobic interface polyoxometalates(POM) salt-water separation solar vapor generation(SVG)

Interfacial reinforcement of core-shell HMX@energetic polymer composites featuring enhanced thermal and safety performance

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Defence Technology（防务技术） 2024年第1期31卷 387-399页

作者： Binghui Duan Hongchang Mo Bojun tan Xianming Lu Bozhou Wang Ning Liu Xi'an Modern Chemistry Research Institute Xi'an710065People's Republic of China State Key Laboratory of Fluorine&Nitrogen Chemicals Xi'an710065People's Republic of China

The weak interface interaction and solid-solid phase transition have long been a conundrum for 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane(HMX)-based polymer-bonded explosives(PBX).A two-step strategy that involves the pretreatment of HMX to endow—OH groups on the surface via polyalcohol bonding agent modification and in situ coating with nitrate ester-containing polymer,was proposed to address the *** types of energetic polyether—glycidyl azide polymer(GAP)and nitrate modified GAP(GNP)were grafted onto HMX crystal based on isocyanate addition reaction bridged through neutral polymeric bonding agent(NPBA)*** morphology and structure of the HMX-based composites were characterized in detail and the core-shell structure was *** grafted polymers obviously enhanced the adhesion force between HMX crystals and fluoropolymer(F2314)*** to the interfacial reinforcement among the components,the two HMX-based composites exhibited a remarkable increment of phase transition peak temperature by 10.2°C and 19.6°C with no more than 1.5%shell content,***,the impact and friction sensitivity of the composites decreased significantly as a result of the barrier produced by the grafted *** findings will enhance the future prospects for the interface design of energetic composites aiming to solve the weak interface and safety concerns.

关键词： HMX crystals Polyalcohol bonding agent Energetic polymer Core-shell structure Interfacial reinforcement

Exploration on electrical resistance tomography in characterizing the slurry spatial distribution in cemented granular materials

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Frontiers of Structural and Civil Engineering 2024年第3期18卷 365-379页

作者： Bohao WANG Wei WANG Feng JIN Handong tan Ning LIU Duruo HUANG State Key Laboratory of Hydroscience and Engineering Tsinghua UniversityBeijing 100084China Institute of Science and Technology China Three Gorges CorporationBeijing 100038China School of Geophysics and Information Technology China University of GeosciencesBeijing 100083China

This study investigated the application of electrical resistance tomography(ERT)in characterizing the slurry spatial distribution in cemented granular materials(CGMs).For CGM formed by self-flow grouting,the voids in the accumulation are only partially filled and the bond strength is often limited,which results in difficulty in obtaining in situ samples for quality ***,it is usually infeasible to evaluate the grouting effect or monitor the slurry spatial distribution by a mechanical *** this research,the process of grouting cement paste into high alumina ceramic beads(HACB)accumulation is reliably monitored with *** shows that ERT results can be used to calculate the cement paste volume in the HACB accumulation,based on calibrating the saturation exponent n in Archie’s *** results support the feasibility of ERT as an imaging tool in CGM characterization and may provide guidance for engineering applications in the future.

关键词： electrical resistance tomography cemented granular material grouting spatial distribution Archie’s law

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澧水入湖河床沉积物重金属污染特征及评价

环境科学学报 2017年第9期37卷 3480-3488页

作者：曾等志彭渤张坤方小红谭长银匡晓亮吴蓓娟涂湘林湖南师范大学资源与环境科学学院长沙410081 湖南师范大学环境重金属污染机理与生态修复重点实验室长沙410081 中国科学院广州地球化学研究所广州510640

利用等离子质谱仪(ICP-MS)对澧水入湖段河床沉积物重金属含量进行分析测定,并对沉积物重金属污染程度进行了评价.结果表明,澧水入湖沉积物重金属Cd含量较高,超出土壤背景值3.5~15.6倍,超标率达100%.地累积指数评价结果显示,Cd处于中度... 详细信息

利用等离子质谱仪(ICP-MS)对澧水入湖段河床沉积物重金属含量进行分析测定,并对沉积物重金属污染程度进行了评价.结果表明,澧水入湖沉积物重金属Cd含量较高,超出土壤背景值3.5~15.6倍,超标率达100%.地累积指数评价结果显示,Cd处于中度污染水平,重金属污染程度从高到低为:Cd>Cu>Ni>Mn>Zn>Co>Pb>Cr>V.潜在生态风险评价结果显示,沉积物Cd的生态风险指数RI值在84.3~230之间,表现出很强的生态风险.重金属生态风险排序为:Cd>Cu>Ni>Pb>Co>Cr>V>Mn>Zn,且沉积物重金属Cd对潜在生态风险指数RI值的贡献率最大.健康风险评价结果显示,重金属Mn、V、Pb、Cr、Cu、Co、Zn、Ni、Cd等均没有显著的非致癌风险,儿童致癌风险比成人大1.3~5.6倍,其中,重金属Cr、Co可对儿童和成人构成潜在致癌风险.重金属Cd、Pb、Zn可能主要来自于工矿排放等人为带入,而V、Cr、Mn、Co、Ni、Cu等重金属可能主要来自流域基岩的自然风化、侵蚀等地表作用.流域重金属污染防治应主要针对Cd、Cr、Pb、Zn等重金属污染而进行.

关键词：重金属污染河床沉积物污染程度评价生态风险健康风险澧水

不同肥料长期施用下稻田镉、铅、铜、锌元素总量及有效态的变化

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土壤学报 2009年第3期46卷 412-418页

作者：谭长银吴龙华骆永明徐礼生徐建明谢小立中国科学院南京土壤研究所土壤环境与污染修复重点实验室土壤与农业可持续发展国家重点实验室南京210008 湖南师范大学资源与环境科学学院长沙410081 中国科学院研究生院北京100049 浙江大学环境与资源学院杭州310029 中国科学院亚热带农业生态研究所长沙410125

以中国科学院桃源农业生态实验站的长期田间定位试验为基础,研究了16年长期定量施肥对土壤Cd、Pb、Cu和Zn积累及其有效性的影响。结果表明:单施化肥可使土壤Cd含量降低、Pb含量增加,对Cu和Zn的积累无显著影响,水稻收获时的移出效应可能... 详细信息

以中国科学院桃源农业生态实验站的长期田间定位试验为基础,研究了16年长期定量施肥对土壤Cd、Pb、Cu和Zn积累及其有效性的影响。结果表明:单施化肥可使土壤Cd含量降低、Pb含量增加,对Cu和Zn的积累无显著影响,水稻收获时的移出效应可能是Cd含量降低的主要原因;与单施化肥相比,有机物料循环可提高土壤Cd和Pb的积累,但对Cu和Zn的积累无显著影响。试验期内单施化肥对土壤Cd、Pb、Cu和Zn的有效性无显著影响;有机物料循环可显著提高Cd和Zn的有效性,这与有机物料循环引起的土壤有机质含量增加和pH降低有关。

关键词：有机物料循环稻田有机碳 Cd Pb Cu Zn

Transformer-Based Cloud Detection Method for High-Resolution Remote Sensing Imagery

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Computers, Materials & Continua 2024年第7期80卷 661-678页

作者： Haotang tan Song Sun Tian Cheng Xiyuan Shu Key Laboratory of GIS Application Research School of Geography and TourismChongqing Normal UniversityChongqing401331China College of Computer and Information Science Chongqing Normal UniversityChongqing401331China Department of Military Installations Army Logistics AcademyChongqing401331China

Cloud detection from satellite and drone imagery is crucial for applications such as weather forecasting and *** the limitations of conventional convolutional neural networks,we propose an innovative transformer-based *** method leverages transformers,which are adept at processing data sequences,to enhance cloud detection ***,we introduce a Cyclic Refinement Architecture that improves the resolution and quality of feature extraction,thereby aiding in the retention of critical details often lost during cloud *** extensive experimental validation shows that our approach significantly outperforms established models,excelling in high-resolution feature extraction and precise cloud *** integrating Positional Visual Transformers(PVT)with this architecture,our method advances high-resolution feature delineation and segmentation ***,our research offers a novel perspective for surmounting traditional challenges in cloud detection and contributes to the advancement of precise and dependable image analysis across various domains.

关键词： Cloud transformer image segmentation remotely sensed imagery pyramid vision transformer

Training Generative Adversarial Networks with Adaptive Composite Gradient

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Data Intelligence 2024年第1期6卷 120-157页

作者： Huiqing Qi Fang Li Shengli tan Xiangyun Zhang School of Mathematical Sciences East China Normal UniversityShanghai 200241China

The wide applications of Generative adversarial networks benefit from the successful training methods,guaranteeing that an object function converges to the local ***,designing an efficient and competitive training method is still a challenging task due to the cyclic behaviors of some gradient-based ways and the expensive computational cost of acquiring the Hessian *** address this problem,we proposed the Adaptive Composite Gradients(ACG)method,linearly convergent in bilinear games under suitable *** analysis and toy-function experiments both suggest that our approach alleviates the cyclic behaviors and converges faster than recently proposed SOTA *** convergence speed of the ACG is improved by 33%than other *** ACG method is a novel Semi-Gradient-Free algorithm that can reduce the computational cost of gradient and Hessian by utilizing the predictive information in future *** mixture of Gaussians experiments and real-world digital image generative experiments show that our ACG method outperforms several existing technologies,illustrating the superiority and efficacy of our method.

关键词： Generative adversarial networks adaptive composite gradient semi-gradient free game theory bilinear game

Synthesis of Self-assembled Star/Linear Block Copolymer Blends via Aqueous RAFT Dispersion Polymerization

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Chinese Journal of Chemistry 2024年第14期42卷 1606-1614页

作者： Ruiming Wang Wenyu Zhu Li Zhang Xinxin Sheng Jianbo tan Department of Polymeric Materials and Engineering School of Materials and EnergyGuangdong University of TechnologyGuangzhouGuangdong510006 China Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter GuangzhouGuangdong510006 China

Reversible addition-fragmentation chain transfer(RAFT)-mediated polymerization-induced self-assembly(PISA)of star block copolymer and linear block copolymer using a binary mixture of a star-like macro-RAFT agent and a linear macro-RAFT agent is *** this formulation,star block copolymer and diblock copolymer were formed simultaneously to generate colloidally stable star/linear block copolymer *** exclusion chromatography(SEC)analysis confirmed the presence of two types of polymers in the final *** molar ratio of the star-like macro-RAFT agent and the linear macro-RAFT agent has a significant impact on the morphology of polymer *** was found that increasing the amount of star-like macro-RAFT agent facilitated the formation of higher-order ***,effects of other reaction parameters including the length/number of the arm of the star-like macro-RAFT agent,degree of polymer(DP),monomer concentration on the morphology of star/linear block copolymer assemblies were also *** expect that this work will offer new possibilities for the scalable preparation of polymer assemblies with unique structures and functions.

关键词： Star block copolymer Reversible addition-fragmentation chain transfer Polymerization-induced self-assembly Livingpolymerization Copolymers

不同土地利用方式下土壤养分和重金属元素垂直分布特征

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环境工程学报 2018年第6期12卷 1791-1799页

作者：梁玉峰谭长银曹雪莹何其辉朱上游谢雨呈代兵湖南师范大学资源与环境科学学院环境重金属污染机理及生态修复重点实验室长沙410081

为探讨不同土地利用方式下土壤养分和重金属元素垂直分布特征,对2种母质的自然土壤、耕作土壤、休耕土壤养分和重金属元素垂直分布状况进行了比较研究。结果表明:不同土地利用方式下土壤表层养分元素含量总体表现为休耕土壤>耕作土壤>... 详细信息

为探讨不同土地利用方式下土壤养分和重金属元素垂直分布特征,对2种母质的自然土壤、耕作土壤、休耕土壤养分和重金属元素垂直分布状况进行了比较研究。结果表明:不同土地利用方式下土壤表层养分元素含量总体表现为休耕土壤>耕作土壤>自然土壤,土壤表层重金属含量总体表现为农田土壤(耕作土壤和休耕土壤)>自然土壤,耕作土壤与休耕土壤差异较小,土壤淀积层到母质层养分和重金属元素差异逐渐减小;土壤养分元素和Cu、Zn、Pb、Cd随土层深度的增加而减小,而Cr表现出相反的趋势;农田土壤耕作层有效钾含量最高可达215.6 mg·kg^(-1);耕作层Cd含量最高可达0.74 mg·kg^(-1)。3种土地利用方式中,休耕土壤养分和重金属含量相对较高,建议在休耕期间种植伴矿景天等重金属高积累植物进行植物修复。

关键词：土地利用土壤养分重金属土壤污染

Integrated approach of predicting rock stability in high mountain valley underground caverns

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Underground Space 2024年第6期19卷 317-341页

作者： Fuyuan tan Haosen Guo Pengzhi Pan Zhaofeng Wang Xufeng Liu Yangyi Zhou East China Jiaotong University Nanchang 467200China State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan 430071China Key Laboratory of Liaoning Province on Deep Engineering and Intelligent Technology Northeastern UniversityShenyang 110819China University of Chinese Academy of Sciences Beijing 100049China

High mountain valleys are characterized by the development of intricate ground stress fields due to geological processes such as tectonic stress,river erosion,and rock *** processes introduce considerable stability concerns in the surrounding rock formations for underground engineering projects in these regions,highlighting the imperative need for rigorous stability assessments during the design phase to ensure construction *** paper introduces an innovative approach for the pre-evaluation of the stability of surrounding rocks in underground caverns situated within high mountain *** methodology comprises several pivotal ***,we conduct inverse calculations of the ground stress field in complex geological terrains,combining field monitoring and numerical ***,we ascertain stress-strength ratios of the surrounding rocks using various rock strength *** assess the stability characteristics of the surrounding rocks in the 1^(#)spillway cave within our project area,we employ numerical simulations to compute stress-strength ratios based on different rock strength ***,we undertake a comparative analysis,utilizing data from the 5^(#)Underground Laboratory(Lab 5)of Jinping II Hydropower Station,aligning the chosen rock strength criterion with the damage characteristics of Lab 50s surrounding *** analysis serves as the cornerstone for evaluating other mechanical responses of the surrounding rocks,thereby validating the pre-evaluation *** pre-evaluation method takes into account the intricate geological evolution processes specific to high mountain *** also considers the influence of the initial geostress field within the geological range of underground *** comprehensive approach provides a robust foundation for the analysis and assessment of the stability of surrounding rocks,especially in high mountain valley areas,during the design phase of underground engi

关键词： High mountain valley Underground cavern Stability of surrounding rock On-site monitoring Stress-strength ratio Numerical simulation