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npj Computational Materials 2022年第1期8卷 1406-1416页

作者： Minseok Jeong Joonyoung F.Joung Jinhyo Hwang Minhi Han chang woo koh Dong Hoon Choi Sungnam Park Department of Chemistry and Research Institute for Natural Science Korea UniversitySeoul02841Korea

The highest occupied molecular orbital(HOMO)and lowest unoccupied molecular orbital(LUMO)energies,which are key factors in optoelectronic devices,must be accurately estimated for newly designed ***,we developed a deep learning(DL)model that was trained with an experimental database containing the HOMO and LUMO energies of 3026 organic molecules in solvents or solids and was capable of predicting the HOMO and LUMO energies of molecules with the mean absolute errors of 0.058 ***,we demonstrated that our DL model was efficiently used to virtually screen optimal host and emitter molecules for organic light-emitting diodes(OLEDs).Deep-blue fluorescent OLEDs,which were fabricated with emitter and host molecules selected via DL prediction,exhibited narrow emission(bandwidth=36 nm)at 412 nm and an external quantum efficiency of 6.58%.Our DL-assisted virtual screening method can be further applied to the development of component materials in optoelectronics.

关键词： emitter optoelectronic OLEDs

Optimization of solvent swelling for efficient organic solar cells via sequential deposition

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Materials Reports(Energy) 2021年第4期1卷 77-83页

作者： Qiaogan Liao Bangbang Li Huiliang Sun chang woo koh Xianhe Zhang Bin Liu Han Young woo Xugang Guo Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055GuangdongPR China Guangdong Provincial Key Laboratory of Functional Oxide Materials and Devices Southern University of Science and Technology(SUSTech)Shenzhen 518055GuangdongPR China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001PR China Research Institute for Natural Sciences Department of ChemistryKorea UniversitySeoul 136-713South Korea

Compared to bulk heterojunction(BHJ)organic solar cells(OSCs)prepared by the blend casting in“one step process”,sequential deposition(SD)processed OSCs can realize an ideal profile of vertical component distribution due to the swelling of polymer ***,we did trials on several kinds of second solvents for swelling the polymer layer,and investigated the packing structure and morphology of the swollen films and the performance of the resulting *** found that an optimized morphology can be achieved by solvent swelling while using orthodichlorobenzene(o-DCB)as the second layer processing-solvent,with polymer donor PffBT-3 as bottom layer,PC71BM as top layer and bicontinuous networks in the *** solvent swelling process also makes the SD method exempt from thermal annealing *** device based on SD yields a power conversion effi-ciency(PCE)up to 8.7%without any post-treatment,outperforming those from the devices based on SD using other solvents and that(7.06%)from BHJ device,*** also extended the use of this approach to allpolymer blend system,and successfully improved the efficiency from 4.72%(chloroform)to 9.35%(o-DCB),which is among the highest PCEs in all-polymer-based OSCs fabricated with SD *** results demonstrate that the swelling of the polymer by the second layer solvent is a necessity for SD,paving the way towards additivefree high-performance OSCs.

关键词： Organic solar cells Bulk heterojunction Sequential deposition Solvent swelling Vertical phase separation Second solvent

Surface-modified Ag@Ru-P25 for photocatalytic CO_(2) conversion with high selectivity over CH_(4) formation at the solid–gas interface

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Carbon Energy 2024年第1期6卷 182-196页

作者： Chaitanya B.Hiragond Sohag Biswas Niket SPowar Junho Lee Eunhee Gong Hwapyong Kim Hong Soo Kim Jin-woo Jung chang-Hee Cho Bryan M.Wong Su-Il In Department of Energy Science&Engineering Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea Department of Chemical&Environmental Engineering Materials Science&Engineering ProgramDepartment of ChemistryDepartment of Physics&AstronomyUniversity of California-RiversideRiversideCaliforniaUSA Department of Physics and Chemistry Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea NiceScience Corporation DaeguRepublic of Korea

Systematic optimization of the photocatalyst and investigation of the role of each component is important to maximizing catalytic activity and comprehending the photocatalytic conversion of CO_(2) reduction to solar fuels.A surface-modified Ag@Ru-P25 photocatalyst with H_(2)O_(2) treatment was designed in this study to convert CO_(2) and H_(2)O vapor into highly selective *** doping followed by Ag nanoparticles(NPs)cocatalyst deposition on P25(TiO_(2))enhances visible light absorption and charge separation,whereas H_(2)O_(2) treatment modifies the surface of the photocatalyst with hydroxyl(–OH)groups and promotes CO_(2) ***-resonance transmission electron microscopy,X-ray photoelectron spectroscopy,X-ray absorption near-edge structure,and extended X-ray absorption fine structure techniques were used to analyze the surface and chemical composition of the photocatalyst,while thermogravimetric analysis,CO_(2) adsorption isotherm,and temperature programmed desorption study were performed to examine the significance of H_(2)O_(2) treatment in increasing CO_(2) reduction *** optimized Ag1.0@Ru1.0-P25 photocatalyst performed excellent CO_(2) reduction activity into CO,CH4,and C2H6 with a~95%selectivity of CH4,where the activity was~135 times higher than that of pristine TiO_(2)(P25).For the first time,this work explored the effect of H_(2)O_(2) treatment on the photocatalyst that dramatically increases CO_(2) reduction activity.

关键词： gas-phase CO_(2) reduction H_(2)O_(2) treatment plasmonic nanoparticles solar fuel photocatalyst surface modification

Absence of enhancement in a lesion does not preclude primary central nervous system T-cell lymphoma:A case report

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World Journal of Clinical Cases 2024年第2期12卷 374-382页

作者： Chan-Seop Kim Chi-Hoon Choi Kyung Sik Yi Yook Kim Jisun Lee chang Gok woo Young Hun Jeon Department of Radiology Chungbuk National University HospitalChungbuk National University College of MedicineCheongju-si 28644Chungcheongbuk-doSouth Korea Department of Pathology Chungbuk National University HospitalChungbuk National University College of MedicineCheongju-si 28644Chungcheongbuk-doSouth Korea Department of Radiology Seoul National University HosptialSeoul 03080South Korea

BACKGROUND Primary central nervous system lymphoma(PCNSL)is a non-Hodgkin lymphoma that originates in the central nervous system(CNS)and is exclusively limited to the *** most PCNSLs are diffuse large B-cell lymphomas,primary CNS T-cell lymphomas(PCNSTLs)are *** typically demonstrate some degree of enhancement on contrast-enhanced magnetic resonance imaging(MRI).To the best of our knowledge,non-enhancing PCNSTL has not been reported *** SUMMARY A 69-year-old male presented to the neurology department with complaints of mild cognitive impairment and gradual onset of left lower leg weakness over a span of two *** MRI showed asymmetric T2-hyperintense lesions within the *** enhancement was observed on the contrast-enhanced T1 *** initial diagnosis was neuro-Behçet’s *** high-dose steroid therapy,no alterations in the lesions were identified on initial *** patient’s symptoms deteriorated *** MRI performed one month after the initial scan revealed an increased lesion ***,brain biopsy confirmed the diagnosis of *** patient underwent definitive combined ***,the patient developed bacteremia and died of septic shock approximately three months after *** The absence of enhancement in the lesion did not rule out PCNSTL.A biopsy approach is advisable for pathological confirmation.

关键词： Central nervous system neoplasms Non-Hodgkin Lymphoma T-cell Lymphoma Primary central nervous system lymphoma Primary central nervous system T-cell lymphoma Case report

Glucose-mediated mitochondrial reprogramming by cholesterol export at TM4SF5-enriched mitochondria-lysosome contact sites

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Cancer Communications 2024年第1期44卷 47-75页

作者： Ji Eon Kim So-Young Park Chulhwan Kwak Yoonji Lee Dae-Geun Song Jae woo Jung Haesong Lee Eun-Ae Shin Yangie Pinanga Kyung-hee Pyo Eun Hae Lee Wonsik Kim Soyeon Kim chang-Duck Jun Jeanho Yun Sun Choi Hyun-woo Rhee Kwang-Hyeon Liu Jung Weon Lee Department of Pharmacy College of PharmacySeoul National UniversitySeoulRepublic of Korea Research Institute of Pharmaceutical Sciences College of PharmacySeoul National UniversitySeoulRepublic of Korea BK21 FOUR Community-Based Intelligent Novel Drug Discovery Education Unit College of Pharmacy and Research Institute of Pharmaceutical SciencesKyungpook National UniversityDaeguRepublic of Korea Department of Chemistry Seoul National UniversitySeoulRepublic of Korea College of Pharmacy Chung-Ang UniversitySeoulRepublic of Korea Natural Product Informatics Research Center Korea Institute of Science and Technology(KIST)Gangneung-siGangwon-doRepublic of Korea School of Life Sciences Gwangju Institute of Science and Technology(GIST)GwangjuRepublic of Korea Department of Biochemistry College of MedicineDong-A UniversityBusanRepublic of Korea Global AI Drug Discovery Center College of Pharmacy and Graduate School of Pharmaceutical SciencesEwha Womans UniversitySeoulRepublic of Korea Interdisciplinary Program in Genetic Engineering Seoul National UniversitySeoulRepublic of Korea

Background:Transmembrane 4 L six family member 5(TM4SF5)translocates subcellularly and functions metabolically,although it is unclear how intracellu-lar TM4SF5 translocation is linked to metabolic *** is thus of interests to understand how the traffic dynamics of TM4SF5 to subcellular endosomal membranes are correlated to regulatory roles of ***:Here,we explored the metabolic significance of TM4SF5 localization at mitochondria-lysosome contact sites(MLCSs),using in vitro cells and in vivo animal systems,via approaches by immunofluorescence,proximity labelling based proteomics analysis,organelle reconstitution ***:Upon extracellular glucose repletion following depletion,TM4SF5 became enriched at MLCSs via an interaction between mitochondrial FK506-binding protein 8(FKBP8)and lysosomal *** labeling showed molecular clustering of phospho-dynamic-related protein I(DRP1)and certain mitophagy receptors at TM4SF5-enriched MLCSs,leading to mitochondrial fis-sion and ***4SF5 bound NPC intracellular cholesterol transporter 1(NPC1)and free cholesterol,and mediated export of lysosomal cholesterol to mitochondria,leading to impaired oxidative phosphorylation but intact tri-carboxylic acid(TCA)cycle andβ-*** mouse models,hepatocyte Tm4sf5 promoted mitophagy and cholesterol transport to mitochondria,both with positive relations to liver ***:Our findings suggested that TM4SF5-enriched MLCSs regu-late glucose catabolism by facilitating cholesterol export for mitochondrial reprogramming,presumably while hepatocellular carcinogenesis,recapitulating aspects for hepatocellular carcinoma metabolism with mitochondrial repro-gramming to support biomolecule synthesis in addition to glycolytic energetics.

关键词： cholesterol fluorescent imaging glucose catabolism hepatocellular carcinogenesis mem-brane contact sites mitochondria function mitophagy oxidative phosphorylation protein-protein interaction tetraspanin

Biomass seaweed-derived n itrogen self-doped porous carb on anodes for sodium-ion batteries:Insights into the structure and electrochemical activity

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Journal of Energy Chemistry 2022年第1期31卷 286-295,I0008页

作者： Chenrayan Senthil Jae woo Park Nitheesha Shaji Gyu Sang Sim chang woo Lee Department of Chemical Engineering(Integrated Engineering)&Center for the SMART Energy Platform College of EngineeringKyung Hee University1732 Deogyeong-daeroCihuengYonginGyeonggi 17104South Korea

Sustainable transformation and efficient utilization of biomasses and their derived materials are environ-mentally as well as economically compliant *** seaweed-derived nitrogen self-doped porous carbon with tailored surface area and pore structures are prepared through carb on izatio n and *** in fluence of carb on ization temperature on morphology,surface area,and heteroatom dopants are investigated to optimize sodium-ion storage ***-derived nitrogen selfdoped activated carbon(SAC)as anode materials for sodium-ion batteries exhibits remarkable reversible capacity of 303/192 mAh g^(-1) after 100/500 cycles at current densities of 100/200 mA g^(-1) respectively,and a good rate *** interconnected and porous conducting nature along with the heteroatom dopant role in creating defective sites and charge stabilization are favorable for ion storage and diffusion and electron transport,indicating the electrodes can offer improved electrochemical *** addition,post-mortem analysis of the cycled carbon electrodes through ex-situ tools demonstrates the sodium-ion storage mechanism.

关键词： Biomass Heteroatom self-doping Porous carbon Anode Sodium-ion batteries Post-mortem ex-situ analysis

Effect of Al addition on corrosion behavior of high-purity Mg in terms of processing history

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Journal of Magnesium and Alloys 2023年第3期11卷 851-868页

作者： Sang Kyu woo Byeong-Chan Suh Ha Sik Kim chang Dong Yim Helmholtz Zentrum Hereon Max-Planck-Straße 1Geesthacht D-21502Germany Korea Institute of Materials Science 797 Changwondae-roSeongsan-guChangwonGyeongnam 51508Republic of Korea University of Science and Technology 217 Gajeong-roYuseong-guDaejeon 34113Republic of Korea

In this study,the effects of Al addition on the corrosion behavior of pure Mg with controlled impurity contents were systematically analyzed according to the processing *** results revealed that the corrosion behavior of high-purity Mg-Al alloys is strongly related to changes in the microstructure,including theβphase and Al-Mn or Al-Fe phases,and the protectiveness of the surface film according to the Al content and processing *** the as-cast alloys,the corrosion rate increased due to the increase ofβphase as the Al content increased,but in the as-extruded alloys,the corrosion rate,which was high due to intermetallic compounds caused by impurities in the low Al alloy,decreased as the Al content increased,and then increased *** is due to the combined effect of the increase of theβphase and decrease of the impurity effect,and the increase of the dissolved Al *** results suggest that it is necessary to analyze the effect of alloying elements on the corrosion behavior of pure Mg with information concerning the impurity content and processing history.

关键词： Mg High purity Mg-Al alloys Processing history Micro-galvanic Surface film

Augmenting freshwater availability in mountain headwater streams:Assessing the sustainability under baseline and future climate change scenarios

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International Soil and Water Conservation Research 2022年第2期10卷 293-307页

作者： Bisrat Ayalew Yifru Il-Moon Chung Min-Gyu Kim Sun woo chang Department of Land Water and Environment ResearchKorea Institute of Civil Engineering and Building TechnologyGoyang10223South Korea Department of Civil and Environmental Engineering University of Science and TechnologyDaejeon34113South Korea

Mountain headwater streams are important freshwater sources,but they are mostly intermittent and highly susceptible to climate *** paper examines the sustainability of augmented freshwater availability in mountain headwater streams for water supply under baseline and future climate change scenarios using an integrated modeling *** climate change data in the 2040s(2030e2059),under Representative Concentration Pathway 4.5 and 8.5 scenarios,were downscaled for the impact *** the region,climate change raises the average precipitation by 5e7%and the temperature by 13e15%in the *** model,integrating Soil and Water Assessment Tool(SWAT2012)and finite-difference Modular Groundwater Flow(MODFLOW)models in a single package,was used to assess the water *** show that extracting a minimum of 16.2 m^(3)/day from the sand storage and 30 m^(3)/day from the aquifer was possible without affecting the groundwater table and water *** average annual catchment recharge was 6%of the precipitation under the baseline *** change is projected to reduce the average water yield and groundwater recharge by 26%and 19%,***,the water supply-demand is significantly small compared to the exploitable rate of water in the *** study was based on limited data,and therefore the findings need to be interpreted with caution,though the model output was validated using satellite *** of a series of sand dams is suggested to maximize the benefit under the potential climate change and water supply-demand increase.

关键词： Headwater stream Sand dam Korea SWATeMODFLOW Water conservation Climate change

Advancing Li-ion storage performance with hybrid vertical carbon/Ni_(3)S_(2)-based electrodes

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Journal of Energy Chemistry 2022年第4期31卷 8-18页

作者： Neelakandan M.Santhosh Nitheesha Shaji d Petra Stražar Gregor Filipič Janez Zavašnik chang Won Ho Murugan Nanthagopal chang woo Lee UrošCvelbar Department of Gaseous Electronics(F6) Jožef Stefan InstituteJamova cesta 39SI-1000 LjubljanaEUSlovenia Jožef Stefan International Postgraduate School Jamova cesta 39SI-1000 LjubljanaEUSlovenia Faculty of Mathematics and Physics University of LjubljanaJadranska cesta 19SI-1000 LjubljanaEUSlovenia Department of Chemical Engineering(Integrated Engineering) College of EngineeringKyung Hee University1732 Deogyeong-daeroGiheungYonginGyeonggi 17104South Korea Center for the SMART Energy Platform College of EngineeringKyung Hee University1732 Deogyeong-daeroGiheungYonginGyeonggi 17104South Korea

Conversion-reaction induced charge storage mechanisms of transition metal sulphides have received considerable interest in designing high-capacity electrodes for electrochemical energy storage ***,their low conductivity and structural degradation during cycling limit their applications as energy storage devices.A combination of different nickel sulphide phases tailored with carbon nanostructures is suggested to address these ***,a facile,two-step approach is demonstrated for fabricating a hybrid electrode,consisting of trinickel disulphide(Ni_(3)S_(2))formed on a metallic Ni nanoparticle supported by vertical carbon nanotubes(VCN)backbone in the form Ni_(3)S_(2)/Ni@***_(3)S_(2)/Ni@VCN electrodes were tested as anode for lithium-ion batteries,and the electrode featured outstanding lithiumstorage capabilities with a high reversible capacity(1113 m Ah g^(-1) after 100 cycles at 100 m A g^(-1)),excellent long-term cycling stability(770 m Ah g^(-1) after 500 cycles at 200 m A g^(-1)),and good rate *** resulting electrode performance is one of the best Li-ion storage capabilities in the Ni_(3)S_(2)-type anode materials described.A unique “broccoli-like”structure of polycrystalline Ni_(3)S_(2)capped on conductive VCN backbone helps the interface storage process and boosts lithium storage performance.

关键词： Ni_(3)S_(2) Vertical carbon nanostructures Hierarchical structures Binder-free electrode Lithium-ion batteries

Large retroperitoneal atypical spindle cell lipomatous tumor,an extremely rare neoplasm:A case report

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World Journal of Clinical Cases 2022年第8期10卷 2584-2590页

作者： Jung-Min Bae chang-Yeon Jung woo-Sung Yun Joon Hyuk Choi Department of Surgery Yeungnam University College of MedicineDaegu 42415South Korea Kyungpook National University School of Medicine Jung-guDaegu 41944Korea Department of Pathology Yeungnam University College of Medicine Nam-guDaegu 42415Korea

BACKGROUND Atypical spindle cell lipomatous tumor(ASLT)is a rare soft tissue neoplasm with a low potential for *** frequently occurs in the limb and limb ***,large retroperitoneal ASLTs are extremely *** was no concrete case report of retroperitoneal *** SUMMARY An 18-year-old woman presented with abdominal pain and a palpable *** computed tomography revealed a large fatty mass that was approximately 30 cm in size and filled the entire abdominal *** excision was *** tumor did not invade the adjacent *** pelvic cavity was then too narrow to dissect *** mass was successfully excised without tumor rupture or adjacent organ ***,the neoplasm was a well-differentiated adipocytic *** staining showed that the spindle cells were positive for CD34 and desmin,in addition to multifocal positivity for S100 *** histological features were consistent with an *** patient’s postoperative course was *** the 12-mo followup,no evidence of recurrence or metastasis was *** To the best of our knowledge,our study is the first concrete report of a large retroperitoneal ASLT in the English *** the large retroperitoneal ASLT located in the pelvic cavity,which made it too narrow and tight to dissect,complete excision is difficult but very important because of recurrence *** large retroperitoneal ASLTs are considered extremely rare,their detection is important for accurate evaluation and *** to their significant rarity,retrospective multicenter case studies are required to determine the clinicopathologic characteristics.

关键词： Neoplasms Retroperitoneal space Spindle cell Case report