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Resistance of Cement-based Grouting Materials with Nano- SiO_(2) Emulsion to chloride Ion Penetration

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 114-119页

作者： li Shuiping chENG Jian WEI chao YUAN Bin YU chengxiao College of Architectural Science and Engineering Yangzhou UniversityYangzhou 225127China

The chloride penetration resistance of cement-based grout materials was improved by nano-silica *** of mixtures containing different nano-silica particles or emulsions were exposed in sodium chloride solutions of specific concentrations with different test *** properties of the mixes were assessed in terms of weight loss and compressive strength.X-ray diffraction(XRD)and scanning electron microscopy(SEM)of mixes were performed to analysis the phase evolution and *** results demonstrated that the introduction of nano-SiO_(2) emulsion significantly decreased the compressive strength loss and calcium hydroxide(ch)crystal content of hydration production,and then enhanced the resistance of cement-based grouting materials to chloride ion *** improvement derives from the filling and pozzolanic effects of nano-SiO_(2) particles,which were incorporated via an emulsion and attributed to a well dispersion in grouting matrix.

关键词： grouting materials nano-SiO_(2)emulsion chloride ion penetration,weight loss strength loss

Phase Evolution during the Sintering of Submicron Ti(C,N)-Based Cermets

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Rare Metals 2001年第4期20卷 248-254页

作者： li, ch Xiong, WH Yu, LX Huazhong Univ Sci & Technol State Key Lab Plast Forming Simulat & Die & Mould Wuhan 430074 Peoples R China

The submicron powder mixtures of TiC-TiN-WC-Mo-C-Ni sintered at 1400degreesC or below in vacuum were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses. The results showed that Mo2C formed at 800degreesC or below. Both WC and Mo2C disappeared at 1200degreesC, and TiN disappeared at 1250degreesC. In addition, the variations of lattice constants of the titanium carbonitride and nickel binder phase with sintering temperature were experimentally obtained, and the reason was analyzed.

关键词： submicron cermet phase sintering

A Hyper-ellipsoid Model for Metallurgical Process Modelling by Genetic Algorithm

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Journal of Materials Science & Technology 1998年第6期14卷 567-568页

作者： li, JF li, ch chen, NY Lu, T chinese Acad Sci Shanghai Inst Met Shanghai 200050 Peoples R China Univ SW Louisiana Lafayette LA 70504 USA

A hyper-ellipsoid model, using genetic algorithm as method of computation, has been proposed to be used in certain metallurgical processes. It is especially suitable for the modelling of the metallurgical processes wi... 详细信息

关键词： Metallurgy

Molecule‑Level Multiscale Design of Nonflammable Gel Polymer Electrolyte to Build Stable SEI/CEI for lithium Metal Battery

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Nano-Micro Letters 2025年第1期17卷 404-423页

作者： Qiqi Sun Zelong Gong Tao Zhang Jiafeng li Xianli Zhu Ruixiao Zhu lingxu Wang Leyuan Ma Xuehui li Miaofa Yuan Zhiwei Zhang Luyuan Zhang Zhao Qian Longwei Yin Rajeev Ahuja chengxiang Wang Key Laboratory for liquid‑Solid Structural Evolution and Processing of Materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinan 250061People’s Republic of China Condensed Matter Theory Department of Physics and AstronomyUppsala UniversityUppsala 75120Sweden

The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious interfacial instability,which is a big challenge for design and application of nonflammable ***,a nonflammable GPE(SGPE)is developed by in situ polymerizing trifluoroethyl methacrylate(TFMA)monomers with flame-retardant triethyl phosphate(TEP)solvents and liTFSI–liDFOB dual lithium *** is strongly anchored to PTFMA matrix via polarity interaction between-P=O and-ch_(2)CF_(3).It reduces free TEP molecules,which obviously mitigates interfacial reactions,and enhances flame-retardant performance of TEP *** TEP molecules are also inhibited in solvation of li^(+),leading to anion-dominated solvation sheath,which creates inorganic-rich solid electrolyte interface/cathode electrolyte interface *** coordination structure changes li^(+)transport from sluggish vehicular to fast structural transport,raising ionic conductivity to 1.03 mS cm^(-1) and transfer number to 0.41 at 30℃.The li|SGPE|li cell presents highly reversible li stripping/plating performance for over 1000 h at 0.1 mA cm^(−2),and 4.2 V liCoO_(2)|SGPE|li battery delivers high average specific capacity>120 mAh g^(−1) over 200 *** study paves a new way to make nonflammable GPE that is compatible with li metal anode.

关键词： Anchoring effect Nonflammable gel electrolyte In situ cross-linked Electrode-electrolyte interface li metal battery

chemical pattern recognition applied to materials optimal design and industry optimization

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chinese Science Bulletin 1997年第10期42卷 793-799页

作者： chen, NY li, ch Qin, P Shanghai Institute of Metallurgy Chinese Academy of Sciences Shanghai China

The multi-dimensional spaces, spanned by the dimensionless numbers describing the equilibrium states or the macroscopic chemical kinetics of complicated chemical reaction systems, have been used for the data processing of the process-es in materials preparation or industrial production. It has been found that there are four common topological types of the rela-tions between the optimization zone and the operation zone in the multi-dimensional spaces. Various computation methods us-ing pattern recognition, artificial neural network and genetic algorithm are used for model-building and optimization strategy searching. An integrated system named KDPAG has been built for materials optimal design or industrial optimization. Appli-cation to chemical, petrochemical and metallurgical industries and materials optimal design gives good results.

关键词： chemical pattern recognition materials design industrial optimization.

The Transient Time-Resolved Absorption Spectra of 1-Naphthylacetic Acid

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chinese chemical Letters 2000年第3期11卷 261-262页

作者： li, W Tung, ch Ye, JP chinese Acad Sci Inst Photog Chem Beijing 100101 Peoples R China

The transient absorption spectra of 1-naphthylacetic acid in tetrahydrofuran have been obtained by laser flash photolysis technique. The transient species bands are at 509, 535 and 553 nm. These peak intensities incre... 详细信息

关键词： transient spectra laser chemistry 1-naphthylacetic acid

Photoisomerization of norbornadiene group in a rigid bichromophoric compound initiated by remote keto chromophore: long-distance through-bond triplet energy transfer

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chinese Journal of chemistry 1996年第4期14卷 377-380页

作者： Tung, ch Zhang, LP li, Y chINESE ACAD SCI INST PHOTOG CHEMBEIJING 100101PEOPLES R CHINA

A diad compound 3 beta(bicyclo[2,2,1]hepta-2,5-diene-2-methylcarboxylate-3-carboxy)-androst-5-en-17-one (NBD-S-ONE) was synthesized and its photochemistry was examined. Irradiation of NBD-S-ONE in acetonitrile at lambda > 300 nm selectively excited the keto chromophore. After intersystem crossing, the triplet energy of the keto group was transferred to the NBD group with 18.6% efficiency via a through-bond mechanism, resulting in the isomerization of the latter group to the quadricyclane group.

关键词： norbornadiene photoisomerization through-bond triplet energy transfer

Synergistic promotion strategy of “dual-site” and “dual-path” to enhance the C–C coupling between CO2 and HchO driven by photoelectrocatalysis

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Journal of Energy chemistry 2025年第1期100卷 39-49页

作者： Hongqiang Yang Jianfeng Zheng Guoyu Wang Yifei Gao Yatao Yang Jia li Xiaojin Han Yan Cui Zhanggen Huang National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal Institute of Coal Chemistry Chinese Academy of Science University of chinese Academy of Science Shenyang University of chemical Technology

Photoelectrocatalytic coupling CO2and volatile organic compounds （VOCs） is a promising green strategy for the synergistic conversion of the two carbon-containing resources to *** catalytic efficiency is always at the mercy of chemical inertness of CO2and the competitive hydrogen evolution of ***,a modified g-C3N4/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely *** Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol *** revealed by in-situ characterizations and density functional theory calculations,CO2and HchO were absorbed at Zn site and N site,***,*CO generated from CO2and HchO was converted to*ch3O and*chO on the dual-active-site *** detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*ch3O in electrocatalysis *** from the“*CO+*ch3O”path,another“*CO+*chO”coupling path was also detected in photoelectrocatalytic *** selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO2and HchO simultaneously driven by light and electricity.

关键词： Ethanol

Phosphine/Benzocyclone-based Neutral Nickel Catalysts for Ethylene Polymerization and Copolymerization with Polar Monomers

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chinese Journal of Polymer Science 2024年第2期42卷 202-212,I0007页

作者： Fei Wang li Pan Vladislav A.Tuskaev Svetlana ch.Gagieva Yue-Sheng li Tianjin Key Lab of Composite&Functional Materials School of Material Science and EngineeringTianjin UniversityTianjin300072China Department of chemistry Lomonosov Moscow State UniversityRussian Federation InstitutionLeninskie Gory 1Moscow119991Russian Federation A N Nesmeyanov Institute of Organoelement Compounds Russian Academy of SciencesVavilova st.28Moscow119991Russian Federation

The efficient copolymerization of olefin with polar monomers using nickel-based catalysts presents a longstanding challenge. In this contribution, three phosphine-benzocyclone ligands and corresponding neutral nickel catalysts(Ni1: Ar = Ph;Ni2: Ar = 2-(C_(6)H_(5))C_(6)H_(4);Ni3: Ar = 2-[2',6'-(Me O)_(2)-C_(6)H3]C_(6)H_(4)) were prepared and applied for the ethylene polymerization and copolymerization with polar monomers without any cocatalyst. The bulky substituent groups in complexes Ni2 and Ni3 contributed to high catalytic activities(up to 7.24×10^(6) and 9.04×10^(6)g·mol Ni^(-1)·h^(-1), respectively), and produced high-molecular-weight polyethylene(Mw up to 545.7 k Da). Complex Ni3 exhibited high activities for ethylene polymerization at the level of 10^(6) g·mol Ni^(-1)·h^(-1) across a wide range from 30 ℃ to 120 ℃, exhibiting excellent high temperature tolerance. These nickel complexes were also effectively employed in the copolymerization of ethylene with methyl acrylate, ethyl acrylate, butyl acrylate and lauryl acrylate, producing copolymers with high molecular weights(Mw up to 80.5 k Da) and high polar monomer incorporation(up to 8.2 mol%). Microstructure analyses revealed that the introduction of large sterically hindered substituents facilitated the incorporation of polar functional units into the polymer backbone. This study demonstrates the potential of these nickel-based catalysts for efficient copolymerization of olefin with polar monomers.

关键词： Neutral nickel catalyst Ethylene polymerization Copolymerization Polar acrylate monomers