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Degradation of Rhodamine B by MnFe-LDH/PMS/O_(3) three-phase catalytic system: performance, mechanism and ecotoxicity studies

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Frontiers of Environmental Science & Engineering 2024年第1期18卷 111-127页

作者： Ying Han Ying Yang Weibao Liu Yilong Hou ce Wang Jiangwei shang Xiuwen Cheng Key Laboratory of Pollutant Chemistry and Environmental Treatment College of Chemistry and Environmental ScienceYili Normal UniversityYining 835000China Key Laboratory for Environmental Pollution Prediction and Control of Gansu Province College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China

This study developed a novel MnFe-LDH/PMS/O3 three-phase catalytic system to degrade the organic dye RhB, which was used to address the drawbacks of persulfate oxidation and ozonation techniques. The structure, ionic and elemental composition, specific surface area, and magnetic properties of the LDHs were investigated using a variety of physicochemical characterization tools. The results showed that MnFe-LDH had a large specific surface area, a rich crystalline phase composition, and a functional group structure. The RhB degradation rate of MnFe-LDH/PMS/O3 was 0.34 min−1, which was much higher than that of other comparative systems. RhB could be completely degraded in 10 min after optimization and had a significant effect on TOC removal. The system was found to be effective over a wide pH range. Common anions were largely unaffected and humic acid acted as an inhibitor. At the same time, the system had generally effective degradation performance for different dyes. Combined with quenching experiments and EPR, it was found that SO4•−, •OH, O_(2)•−, and 1O_(2) all participated in the reaction, and •OH contributed more. The degradation pathway of RhB was derived by LC-MS, and the T.E.S.T. evaluation found that the toxicity of the intermediate product was significantly reduced. Finally, the stability and availability of LDHs were verified using cycling experiments and metal ion leaching. This work provides a theoretical basis and data support for the synergistic catalysis of PMS/O3 and the deep treatment of dye wastewater.

关键词： Rhodamine B Layered double hydroxides Peroxymonosulfate Ozonation

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Biological sources, paleoenvironment, and organic matter enrichment in source rocks of the Ordovician Majiagou Formation, Ordos Basin, China:Evidence from biomarkers,microfossils, and inorganic geochemical analyses

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Journal of Palaeogeography 2024年第1期13卷 92-115页

作者： Jing-Jing Cao Wen-Zhe Gang shang-Ru Yang State Key Laboratory of Petroleum Resources and Prospecting China University of Petroleum(Bejing)Beijing 102249China College of Geosciences China University of Petroleum(Bejing)Beijing 102249China Oil and Gas Technology Research Institute PetroChina Changqing Oifield CompanyXi'an 710018Shaanxi ProvinceChina

Carbonate deposits in the Ordovivian Majiagou Formation are significant source rocks for natural gas generation in the Ordos Basin, northwestern China. Previous studies mainly focused on the organic matter enrichment mechanism of shales rather than carbonate rocks. The biological sources and paleoenvironment of carbonate source rocks, and the main controlling factors of organic matter enrichment in the carbonate source rocks were studied in this paper in combination with evidence from biomarkers, microfossils and inorganic geochemistry analysis. The results show that four types of microfacies were identified in the Majiagou Formation, respectively as: mud flat microfacies, mud-dolomite flat microfacies, dolomite flat microfacies, and open marine microfacies. The biological sources of organic matter are chiefly planktonic algae, followed by bacteria. The mud flat and mud-dolomite flat contain a high abundance of terrigenous detrital inputs, as indicated by the high content of Al_(2)O_(3), TiO_(2), Th, and Zr. The low Sr/Cu and high Rb/Sr values reveal warm and humid paleoclimate conditions in the mud flat and mud-dolomite flat, whereas the dolomite flat and open marine were likely formed in hot and arid paleoclimate conditions. The mud flat and mud-dolomite flat deposits were characterized by high paleoproductivity of the Majiagou Formation. Low Sr/Ba values were found in the mud flat samples, indicating fresh to brackish water condition, whereas samples of other facies have a relatively high degree of salinity. Based on U_(auth), Mo_(auth), Cr_(auth), Co_(auth), δce, and δEu values, the mud flat microfacies was formed in a suboxic and anoxic environment, whereas the mud-dolomite flat, dolomite flat and open marine microfacies were within dysoxic to oxic conditions. A model of organic matter enrichment in the Majiagou Formation is thus established. The level of terrigenous detrital inputs is the principal factor of organic matter enrichment in the Majiagou Formation, secondly are redox condition and then paleoprod

关键词： Biological source Microfacies Trace elements Organic matter Majiagou Formation Ordos Basin

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迁地保护:从植物活体保存到种子库

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生物多样性 2024年第2期32卷 12-13页

作者：张志翔尚策北京林业大学生态与自然保护学院北京100083

随着全球气候变化的加剧和人为活动影响愈加频繁,很多植物物种的栖息地快速缩小,生物多样性面临前所未有的危机。中国是世界上植物多样性最丰富的国家之一,根据生态环境部与中国科学院2023年5月22日联合发布的《中国生物多样性红色名录... 详细信息

随着全球气候变化的加剧和人为活动影响愈加频繁,很多植物物种的栖息地快速缩小,生物多样性面临前所未有的危机。中国是世界上植物多样性最丰富的国家之一,根据生态环境部与中国科学院2023年5月22日联合发布的《中国生物多样性红色名录》,我国有高等植物39,330多种,其中约10%的物种受到威胁。

关键词：生物多样性迁地保护红色名录种子库植物物种中国科学院生态环境植物多样性

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Improving hydrogen storage thermodynamics and kinetics of ce-Mg-Ni-based alloy by mechanical milling with TiF_(3)

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Journal of Magnesium and Alloys 2024年第4期12卷 1593-1607页

作者： Hongwei shang Wei Zhang Xin Wei Yaqin Li Zeming Yuan Jun Li Yanghuan Zhang School of Mechanical and Electrical Engineering Chuzhou UniversityChuzhou 239000China Department of Functional Material Research Central Iron and Steel Research InstituteNo.76 Xueyuannan RoadHaidian DistrictBeijing 100081China Key Laboratory of Integrated Exploitation of Bayan-Obo Multi-Metal Resources Inner Mongolia University of Science and TechnologyBaotou 014010China China Rare Earth New Material(Weishan)Co. Ltd.Jining 277600China

Mg-based hydrides are too stable and the kinetics of hydrogen absorption and desorption is not satisfactory.An efficient way to improve these shortcomings is to employ reactive ball milling to synthesize the nanocomposite materials of Mg and additives.In this experiment,TiF_(3)was selected as an additive,and the mechanical milling method was employed to prepare the experimental alloys.The alloys used in this experiment were the as-cast ce_(5)Mg_(85)Ni_(10),as-milled ce_(5)Mg_(85)Ni_(10)and ce_(5)Mg_(85)Ni_(10)+3 wt.%TiF3.The phase transformation,structural evolution,isothermal and non-isothermal hydrogenation and dehydrogenation performances of the alloys were inspected by XRD,SEM,TEM,Sievert apparatus,DSC and TGA.It revealed that nanocrystalline appeared in the as-milled samples.Compared with the as-cast alloy,ball milling made the particle dimension and grain size decrease dramatically and the defect density increase significantly.The addition of TiF_(3)made the surface of ball milling alloy particles markedly coarser and more irregular.Ball milling and adding TiF_(3)distinctly improved the activation and kinetics of the alloys.Moreover,ball milling along with TiF_(3)can decrease the onset dehydrogenation temperature of Mg-based hydrides and slightly ameliorate their thermodynamics.

关键词： Mg-based hydrides TiF_(3) Ball milling Thermodynamics Kinetics

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Review of heterogeneous material objects modeling in additive manufacturing

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Visual Computing for Industry,Biomedicine,and Art 2020年第1期3卷 53-70页

作者： Bin Li Jianzhong Fu Jiawei Feng ce shang Zhiwei Lin State Key Laboratory of Fluid Power and Mechatronic Systems College of Mechanical EngineeringZhejiang UniversityHangzhou 310027China Key Laboratory of 3D Printing Process and Equipment of Zhejiang Province College of Mechanical EngineeringZhejiang UniversityHangzhou 310027China

This review investigates the recent developments of heterogeneous objects modeling in additive manufacturing(AM),as well as general problems and widespread solutions to the modeling methods of heterogeneous objects.Prevalent heterogeneous object representations are generally categorized based on the different expression or data structure employed therein,and the state-of-the-art of process planning procedures for AM is reviewed via different vigorous solutions for part orientation,slicing methods,and path planning strategies.Finally,some evident problems and possible future directions of investigation are discussed.

关键词： Review Heterogeneous objects modeling Heterogeneous materials Additive manufacturing

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A review of the design methods of complex topology structures for 3D printing

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Visual Computing for Industry,Biomedicine,and Art 2018年第1期1卷 34-49页

作者： Jiawei Feng Jianzhong Fu Zhiwei Lin ce shang Bin Li State Key Laboratory of Fluid Power and Mechatronic Systems College of Mechanical EngineeringZhejiang UniversityHangzhou 310027China Key Laboratory of 3D Printing Process and Equipment of Zhejiang Province College of Mechanical EngineeringZhejiang UniversityHangzhou 310027China

As a matter of fact,most natural structures are complex topology structures with intricate holes or irregular surface morphology.These structures can be used as lightweight infill,porous scaffold,energy absorber or micro-reactor.With the rapid advancement of 3D printing,the complex topology structures can now be efficiently and accurately fabricated by stacking layered materials.The novel manufacturing technology and application background put forward new demands and challenges to the current design methodologies of complex topology structures.In this paper,a brief review on the development of recent complex topology structure design methods was provided;meanwhile,the limitations of existing methods and future work are also discussed in the end.

关键词： Complex topology structure Computer-aided design 3D printing Optimization design

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Posture control of a 3-RPS pneumatic parallel platform with parameter initialization and an adaptive robust method

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Frontiers of Information Technology & Electronic Engineering 2017年第3期18卷 303-316页

作者： Guo-liang TAO ce shang De-yuan MENG Chao-chao ZHOU The State Key Laboratory of Fluid Power Transmission and Control Zhejiang University School of Mechatronic Engineering China University of Mining and Technology

A control algorithm for a 3-RPS parallel platform driven by pneumatic cylinders is discussed. All cylinders are controlled by proportional directional valves while the kinematic and dynamic properties of the system are modeled. The method of adaptive robust control is applied to the controller using a back-stepping approach and online parameter estimation. To compensate for the uncertainty and the influence caused by estimations, a fast dynamic compensator is integrated in the controller design. To prevent any influence caused by the load applied to the moving platform changing in a practical working situation, the identification of parameters is taken as the initialization of unknown parameters in the controller, which can improve the adaptability of the algorithm. Using these methods, the response rate of the parameter estimation and control performance were improved significantly.The adverse effects of load and restriction forces were eliminated by the initialization and online estimation.Experiments under different situations illustrated the effectiveness of the adaptive robust controller with parameter initialization, approaching average tracking errors of less than 1%.

关键词： Parameter initialization Adaptive robust control Parallel mechanism Pneumatic cylinders

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新疆3种维管植物新记录

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中国野生植物资源 2024年第6期43卷 113-117页

作者：郭绍宇曲上陈俊通周可柔尚策北京林业大学生态与自然保护学院北京100083 中国科学院昆明植物研究所东亚植物多样性与生物地理学重点实验室云南昆明650201

报道了1个中国维管植物新记录种—波叶菊(Chrysanthemum sinuatum Ledeb.),2个新疆维管植物新记录种—刺果茶藨子(Ribes burejense Fr. Schmidt.)、赛北紫堇[Corydalis impatiens (Pall.) Fisch.]。根据标本和野外观察对3个新记录种进行了形态描述,并提供了部分形态特征和生境照片。该报道丰富了新疆地区维管植物多样性,为该地区的植物保护以及物种编目提供了基础数据。

关键词：维管植物新记录额尔齐斯河流域新疆

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中国杨属叶表皮毛状体微形态特征

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植物研究 2024年第3期44卷 341-348页

作者：吴恙崔兴勇苑福林张志翔尚策北京林业大学生态与自然保护学院北京100083

为讨论叶表皮毛状体特征的分类学价值和系统学意义,借助体视显微镜和扫描电镜对中国杨属(Populus)33个物种的叶表皮毛状体进行了观察和分析。结果表明:杨属物种叶片毛状体整体上是非腺状的、简单的、基底固定的;除胡杨(P.euphratica)叶... 详细信息

为讨论叶表皮毛状体特征的分类学价值和系统学意义,借助体视显微镜和扫描电镜对中国杨属(Populus)33个物种的叶表皮毛状体进行了观察和分析。结果表明:杨属物种叶片毛状体整体上是非腺状的、简单的、基底固定的;除胡杨(P.euphratica)叶表皮没有毛状体外,其余物种叶表皮均被有毛状体,但毛状体的分布、形态、长度等在物种间存在不同程度差异。毛状体外形(圆柱状至条带状)、弯曲程度(直立至曲卷)、相对于叶表皮表面的方向(伏贴或不伏贴)及毛状体长度具有一定的分类学意义。结合分子系统发育研究提供的进化框架,本研究认为杨属叶表皮毛状体特征在亚属水平难以区分,但胡杨亚属(subg.Turanga)和白杨亚属(subg.Populus)在种间水平可区分很多物种,尤其是白杨亚属内的物种毛状体差异大;脂杨亚属(subg.Tacamahaca)内叶片毛状体相似且稳定,但不同分支上的叶片毛状体在长度上有差异。毛状体特征整合后可划分为以下类型:无毛、毡毛、绢毛、短柔毛和长柔毛。

关键词：杨属叶片表皮毛微形态特征系统学分类学

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Properties,combustion behavior,and kinetic triplets of coke produced by low-temperature oxidation and pyrolysis:Implications for heavy oil in-situ combustion

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Petroleum Science 2021年第5期18卷 1483-1491页

作者： Shuai Zhao Wan-Fen Pu Lei Su ce shang Yang Song Wei Li Hui-Zhuo He Yi-Gang Liu Zhe-Zhi Liu State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengduSichuan610500China Post-Doctorate R&D Base Southwest Petroleum UniversityChengduSichuan610500China E&D Research Institute of Liaohe Oilfield CNPC PanjinLiaoning124000China School of Oil and Gas Engineering Chongqing University of Science and TechnologyChongqing401331China

This work aimed at investigating the crucial factor in building and maintaining the combustion front during in-situ combustion(ISC),oxidized coke and pyrolyzed coke.The surface morphologies,elemental contents,and non-isothermal mass losses of the oxidized and pyrolyzed cokes were thoroughly examined.The results indicated that the oxidized coke could be combusted at a lower temperature compared to the pyrolyzed coke due primarily to their differences in the molecular polarity and microstructure.Kinetic triplets of coke combustion were determined using iso-conversional models and one advanced integral master plots method.The activation energy values of the oxidized and pyrolyzed cokes varied in the range of 130-153 k J/mol and 95-120 kJ/mol,respectively.The most appropriate reaction model of combustion of the oxidized and pyrolyzed cokes followed three-dimensional diffusion model(D_(3)) and random nucleation and subsequent growth model(F_(1)),respectively.These observations assisted in building the numerical model of these two types of cokes to simulate the ISC process.

关键词： Oxidized coke Pyrolyzed coke Heavy oil In-situ combustion Kinetic triplets

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