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MICROPOROUS PVDF-HFP-BASED POLYMER MEMBRANES FORMED FROM SUPERCRITICAL CO_2 INDUCED PHASE SEPARATION

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Chinese Journal of Polymer Science 2008年第1期26卷 13-21页

作者： cao, jian-hua Zhu, Bao-ku Zuo, Dan-ying Xu, You-yi Li, Ji-ding Zhejiang Univ Inst Polymer Sci Hangzhou 310027 Yuquan Peoples R China Tsinghua Univ Dept Chem Engn Membrane Technol & Engn Res Ctr Beijing 100084 Peoples R China

Microporous poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP)membranes following supercritical CO_2 induced phase separation process were prepared using four *** solid electrolytes of PVDF-HFP were formed by microporous PVDF-HFP membranes filled and swollen by a liquid *** effect of the solvents on the morphology and structure,electrolyte absorptions and lithium ionic conductivity of the activated membranes were *** was approved that all the membrane had the similar...

关键词： Poly(vinylidene fluoride-co-hexafluoropropylene) Microporous membrane Conductivity Supercritical CO_2

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热镀锌沉没辊系粘滞阻力及其影响因素研究

铜陵学院学报 2024年第3期23卷 104-109页

作者：钱胜曹建华刘格非顾清王孝建黄山学院机电工程学院安徽黄山245041 燕山大学国家冷轧板带装备及工艺工程技术研究中心河北秦皇岛066004

针对沉没辊系所受锌液粘滞阻力无法获取的问题,首先分析粘滞阻力影响机理和影响因素,根据辊及带钢的运动特性划分边界层,构建沉没辊系粘滞阻力新模型,通过改变辊插入量调控辊转动状态来反求边界层粘滞阻力,最后将该模型应用于某镀锌机... 详细信息

针对沉没辊系所受锌液粘滞阻力无法获取的问题,首先分析粘滞阻力影响机理和影响因素,根据辊及带钢的运动特性划分边界层,构建沉没辊系粘滞阻力新模型,通过改变辊插入量调控辊转动状态来反求边界层粘滞阻力,最后将该模型应用于某镀锌机组。结果表明,两种规格带钢在锌锅内各分区粘滞阻力计算误差都在15%范围内满足机组要求;在实际工况下,带钢与锌液速度差对锌液粘滞阻力影响呈现非线性递增规律,锌液粘滞阻力随带钢表面镀锌量增加而呈现非线性递减趋势但其波动幅度不同,而锌液粘滞阻力随带钢与锌液的温差递增呈现不同程度下降趋势。

关键词：热镀锌带钢区段粘滞阻力新模型边界层厚度过流长度

Regulation of Ti(C,N)deposition on hot surface of refractory in blast furnace hearth

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Journal of Iron and Steel Research International 2024年第6期31卷 1423-1435页

作者： jian cao Cui Wang Jjan-liang Zhang Ke-xin Jiao Guo-hua Zhang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China

Ti(C,N)concentration was found to be lower on the hearth sidewall of a blast furnace and increased gradually toward the bottom of the blast *** Ti(C,N)protective layer in a blast furnace is ***,the formation of a Ti(C,N)protective layer was promoted by studying the heterogeneous nucleation principle of titanium compounds on different substances and regulation measures for the deposition process of titanium compounds on refractories or *** lattice disregistry between the titanium compounds and the main components in the refractory or the main impurities in the protective layer was calculated using a two-dimensional disregistry equation to study the heterogeneous nucleation principle of titanium *** results revealed that in refractory materials,the heterogeneous nucleation of carbonitride is weak when C,SiO_(2),and Al_(2)O_(3) are used as heterogeneous nucleation substrates,and the heterogeneous nucleation of carbonitride is strong when TiO_(2) and SiC are used as heterogeneous nucleation *** nucleation phases,TiC,TiN,Ti(C_(0.3),N_(0.7)),and Ti(C_(0.5),N_(0.5))have similar heterogeneous nucleation ability in single component refractory,and the type of carbonitride has little effect on the lattice *** impurities in the protective layer as the substrate phases are not conducive to the heterogeneous nucleation of *** CaS was used as the substrate phase,the heterogeneous nucleation ability of carbonitride was the *** carbon and alumina were not conducive to the heterogeneous nucleation of carbonitride,but carbon was more unfavourable than alumina.

关键词： Ti(C,N) Lattice disregistry Lattice constant Heterogeneous nucleation Regulation measure

Quantitative characterizations of anisotropic dynamic properties in organic-rich shale with different kerogen content

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Petroleum Science 2024年第2期21卷 855-865页

作者： jian-Yong Xie Yan-Ping Fang Xing-hua Wu jian'er Zhao Jun-Cheng Dai Jun-Xing cao Ji-Xin Deng State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of TechnologyChengdu610059SichuanChina Key Lab of Earth Exploration&Information Techniques of Ministry of Education Geophysical InstituteChengdu University of TechnologyChengdu610059SichuanChina PetroChina Southwest Oil&Gasfield Company Chengdu610017SichuanChina

Understanding the quantitative responses of anisotropic dynamic properties in organic-rich shale with different kerogen content(KC)is of great significance in hydrocarbon exploration and *** controlled experiments with a single variable is challenging for natural shales due to their high variations in components,diagenesis conditions,or pore *** employed the hot-pressing technique to construct 11 well-controlled artificial shale with varying *** artificial shale samples were successive machined into prismatic shape for ultrasonic measurements along different *** revealed bedding perpendicular P-wave velocities are more sensitive to the increasing KC than bedding paralleling velocities due to the preferential alignments of *** elastic stiffnesses except C_(13)are generally decreasing with the increasing KC,the variation of C_(1) and C_(33)on kerogen content are more sensitive than those of C_(44)and C_(66).Apparent dynamic mechanical parameters(v and E)were found to have linear correlation with the true ones from complete anisotropic equations independent of KC,which hold value towards the interpretation of well logs consistently across formations,Anisotropic mechanical parameters(ΔE and brittlenessΔB)tend to decrease with the reducing KC,withΔB showing great sensitivity to KC *** the range of low KC(10%)shale,compilation of data from natural organic rich-shales globally verified the similar systematic relationships that can be empirically used to predict the fraction of KC in shales.

关键词： Elastic properties Organic shale Anisotropy Kerogen content Physical modeling

Measurements of the Differential Elastic and Inelastic Scattering Cross Sections of ^(12)C

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Chinese journal of nuclear physics 1995年第2期17卷 171-173页

作者： Zhang Kun cao jian-hua Dai Yun-shen Wan Dai-rong(Institute of Nuclear Science and Technology,Sichuan University,Chengdu 610064) 四川大学原子核科学技术所四川成都

The differential elastic and inelastic scattering neutron cross sections of 12C atEn=14.7 MeV produced by the T（d,n）4He reaction were measured using an associatedparticle fast neutron TOF spectrometer at 15 angles ranging from 15° to 130°.Theflight path was 2.54 *** neutron detector consisting of an ST-451 liquid scintillatorwas massively shielded.

关键词： Elastic scattering Inelastic Scattering Differential cross section

Decreased AKAP4/PKA signaling pathway in high DFI sperm affects sperm capacitation

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Asian Journal of Andrology 2024年第1期26卷 25-33页

作者： Kun Zhang Xiu-hua Xu jian Wu Ning Wang Gang Li Gui-Min Hao Jin-Feng cao Hebei Key Laboratory of Infertility and Genetics Department of Reproductive MedicineSecond Hospital of Hebei Medical UniversityShijiazhuang 050000China Department of Reproductive Medicine Affiliated Hospital of Xuzhou Medical UniversityXuzhou 221000China Department of Neurology The 980th Hospital of the People's Liberation Army Joint Logistics Support Force(Bethune International Peace Hospital)Shijiazhuang 050000China.

The sperm DNA fragmentation index(DFI)is a metric used to assess DNA fragmentation within *** in vitro fertilizationembryo transfer(IVF-ET),high sperm DFI can lead to a low fertilization rate,poor embryo development,early miscarriage,etc.A kinase anchoring protein(AKAP)is a scaffold protein that can bind protein kinase A(PKA)to subcellular sites of specific substrates and protects the biophosphorylation *** protein antigen 17(SPA17)can also bind to *** study intends to explore the reason for the decreased fertilization rate observed in high sperm DFI(H-DFI)patients during *** addition,the study investigates the expression of AKAP,protein kinase A regulatory subunit(PKARIl),and SPA17 between H-DFI and low sperm DFI(L-DFI)***17 at the transcriptional level is abnormal,the translational level increases in H-DFI patients,and the expression of AKAP4/PKARIl protein decreases.H,O,has been used to simulate oxidative stress damage to spermatozoa during the formation of sperm *** indicates that H,O,increases the expression of sperm SPA17 protein and suppresses AKAP4/PKARIl protein *** processes inhibit sperm capacitation and reduce acrosomal *** culture data and IVF outcomes have been *** H-DFI group has a lower fertilization ***,the results indicate that the possible causes for the decreased fertilization rate in the H-DFI patients have included loss of sperm AKAP4/PKARIl proteins,blocked sperm capacitation,and reduced occurrence of acrosome reaction.

关键词： AKAP PKA SPA17 sperm capacitation sperm DNA fragmentation index

A new liquid membrane diffusion model for characterizing the adsorption kinetics of europium by using a continuous measurement of adsorption platform

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Nuclear Science and Techniques 2024年第1期35卷 59-72页

作者： Hao-Qi Yu Tao Yu jian-hua Ye State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013China CGN Cangnan Nuclear Power Co. Ltd.Cangnan 325800China jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices East China University of TechnologyNanchang 330013China School of Nuclear Science and Engineering East China University of TechnologyNanchang 330013China

To explore the kinetic adsorption under continuous and nonequilibrium states, an integration of continuous measurement and adsorption platform kinetics method was proposed, which was initially called the ICM-AP kinetics method, and a corresponding kinetic adsorption experimental method was developed. Adsorption experiments of europium(Eu) on Ca-bentonite,Na-bentonite, and the D231 cation exchange resin were performed using the ICM-AP kinetics method and continuous measurements. Because the kinetic experimental results observed in this study were different from those of traditional batch adsorption data, pseudo-first-order or pseudo-second-order kinetic models were unsuitable for fitting the experimental ***, a liquid membrane diffusion(LMD) model was developed based on the assumption of simultaneous adsorption/desorption to discuss the mechanism of kinetic adsorption. The kinetic adsorption mechanism was also studied by using *** results indicated that the proposed adsorption model can fit the experimental data more suitably, and the adsorption/desorption behaviors of Eu on bentonite and the D231 resin were simultaneously observed, suggesting that the adsorption kinetics of Eu(Ⅲ) was mainly dominated by hydrated Eu(Ⅲ) ions on the liquid membrane.

关键词： ICM-AP method LMD model Adsorption mechanism Eu(Ⅲ)

Pulmonary myopericytoma： a case report and review of the literatures

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Chinese Medical Journal 2009年第6期122卷 755-757页

作者： cao jian-hua XU Jin-ping LI Yong-cheng LAI Jun LI Qiang Department of Respiratory Medicine Xiaoshan No.1 People's Hospital Medical College of Hangzhou Normal University Hangzhou Zhejiang 311201 China Department of Pathology Xiaoshan No.1 People's Hospital Medical College of Hangzhou Normal University Hangzhou Zhejiang 311201 China Department of Respiratory Medicine Changhai Hospital Second Military Medical University Shanghai 200433 China

Myopericytoma belongs to a family of benign tumors .that exhibit a myoid/pericytic line of differentiation. The most common anatomical sites for myopericytoma are the skin and superficial soft tissues of the distal extremities. With increased clinical recognition, a wider distribution has been described; however, a pulmonary lesion has never been reported. We now report a case of primary pulmonary myopericytoma and review the literature on this rare entity.

关键词： myopericytoma lung immunohistochemistry

Electrolyte effect on electrochemical behaviors of manganese fluoride material for aqueous asymmetric and symmetric supercapacitors

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Rare Metals 2024年第3期43卷 1048-1061页

作者： Zheng-hua He jian-Fei Gao Ling-Bin Kong State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou University of TechnologyLanzhou730050China School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou730050China

Exploring wide voltage window materials is not only an available measure to enhance the energy density of hybrid supercapacitor(HSCs),but also avoids the dynamic mismatch caused by different energy storage mechanisms of two electrodes in assembled symmetrical ***,there are few reports about the wide potential window materials except Bi_(2)O_(3)and VO_(2).Therefore,the MnF_(2)synthesized by solvothermal reaction was served as the electrode for *** MnF_(2)exhibited electrochemical activity in alkaline solution in three-electrode system,especially with a wide potential window from-0.8 to+0.5 V in 2 mol·L^(-1)***,the assembled MnF_(2)//MnF_(2)symmetrical HSC had a potential window of 1.5 V,and it exhibited outstanding long-cycle ***,when MnF_(2)was taken as the negative and positive respectively,the potential windows of asymmetric devices CoMoO_(4)//MnF_(2)and MnF_(2)//Activated Carbon(AC)could reach 1.3 and 1.45 V,respectively,showing excellent cycle *** work shows that MnF_(2)material has great research value in HSC,and provides a new research direction for developing high-performance devices.

关键词： Manganese fluoride Potential window Hybrid supercapacitors Electrochemical performance