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Chinese Journal of Polymer Science 2019年第1期37卷 28-35页

作者： Emine Gul cansu-ergun Department of Electrical and Electronics Engineering Baskent University

An electrochromic copolymer film of 2-(3,3-dihexyl-3,4-dihydro-2 H-thieno[3,4-b][1,4]dioxepin-6-yl)-7-(3,3-dihexyl-3,4-dihydro-2 H-thieno[3,4-b][1,4]dioxepin-8-yl)-9 H-carbazole(M1) and 4,7-bis(thiophen-2-yl)benzo[c][1,2,5]thiadiazole(M2) was prepared via electrochemical technique. The copolymerization was performed with one to one monomer feed ratio. Electrochemical and optical properties of the resulting copolymer film(P3) and the homopolymer films of M1 and M2(P1 and P2) were investigated by using cyclic voltammetry and UV-Vis spectrometry techniques, and the corresponding results were compared. Incorporation of M1 and M2 into copolymer matrix was clearly observed on the resulting cyclic voltammograms and UV-Vis spectra. P3 covered the visible regions coming from both P1 and P2, and exhibited a neutral state darker color than those of homopolymers. P3 film was found to have a multichromic behavior, appearing as brown in its neutral state while changing its color upon oxidation to dark-gray(at about 0.3 V), to blue(at about 0.6 V) and finally to grayish cyan(beyond 0.9 V), with a corresponding optical band gap of 1.65 eV.

关键词： Electrochemical polymerization Copolymer Electrochromic polymers

From“prototype”to“model”:Architectural and spatial development of Block A(1924—1945)of Istanbul’s Heybeliada Sanatorium

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Frontiers of Architectural Research 2024年第1期13卷 1-20页

作者： Deniz Avci-Hosanli cansu Degirmencioglu Department of Interior Architecture and Environmental Design Izmir University of EconomicsIzmir 35330Turkey TUM School of Engineering and Design Department of ArchitectureTechnical University of MunichMunich 80333Germany

This article examines Block A,the first block-style building in Heybeliada Sanatorium in *** purpose of this research is to understand its architectural and spatial development and discuss how in fact it was a“prototype”of Turkish *** with a three-step methodology(documentation/evaluation/results)this research conducts architectural and spatial analysis on Block *** sources like architectural documentation and restitution drawings,the writings of the institution’s head doctor Tevfik Ismail Gökçe,periodicals on tuberculosis(TB),as well as pertinent literature are *** findings demonstrate that Block A’s development(1924—1945)was the result of knowledge transfer that introduced the universal sanatorium design principles,spatial experiments,adaptation to sociocultural norms,and trial-and-error *** only it had a major impact on shaping of the second block-type building in the complex,the“model”Block B,but it also became exemplary of the subsequent Turkish *** originality of this article is its exploration of the changing and evolving Block A in its resonation with the cultural tensions of Turkey’s modernization *** was established via the assessment of budgetary issues,medical developments and climatic experiments,the social issue of scarcity of TB beds in the country,spatial practices to separate the sexes as reflections of local traditions and culture in the shaping of spaces.

关键词： Sanatorium architecture Tuberculosis History of healthcare Early republican Turkey Istanbul

Immunotherapy in gastric cancer with liver metastasis:Challenges and opportunities

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World Journal of Gastrointestinal Surgery 2024年第6期16卷 1513-1516页

作者： Murat Bardakçi Yakup ergun Department of Medical Oncology Diyarbakır Gazi Yasargil Training and Research HospitalDiyarbakir 021000KayapinarTürkiye Department of Medical Oncology Antalya City HospitalAntalya 07080Türkiye

In this editorial,we review the article by Liu et al published in the World Journal of Gastrointestinal Surgery investigating the efficacy and safety of immunotherapy in patients with gastric cancer(GC)and liver ***,the fifth most com-monly diagnosed malignancy worldwide,presents a significant challenge due to its multifactorial etiology and a grim prognosis for unresectable or recurrent *** advent of immune checkpoint inhibitors(ICIs)has revolutionized oncology;yet liver metastasis has been associated with reduced response rates,progression-free survival,and overall survival in various *** Che-ckMate-649 and KEYNOTE-859 trials demonstrated promising results with ICIs in advanced GC,particularly in patients with liver ***,a meta-analysis of liver metastatic solid tumors revealed worse outcomes with ICIs,high-lighting the need for further *** combined therapies,including ICIs with local treatments,show promise in improving outcomes,the nuanced landscape of ICIs in liver metastatic GC necessitates continued research for robust *** current contradictions in the literature underscore the impor-tance of cautious interpretation and the exploration of tailored approaches to enhance clinical efficacy in this challenging patient population.

关键词： Gastric cancer Liver metastasis Immunotherapy Immune checkpoint in-hibitors Transarterial chemoembolization Tumor microenvironment

Continuous Lithium-Ion Extraction From Seawater and Mine Water With a Fuel Cell System and Ceramic Membranes

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ENERGY & ENVIRONMENTAL MATERIALS 2024年第6期7卷 254-261页

作者： Koek, cansu Wang, Lei Ruthes, Jean Gustavo A. Quade, Antje Suss, Matthew E. Presser, Volker INM Leibniz Inst New Mat Campus D2 2 D-66123 Saarbrucken Germany Saarland Univ Dept Mat Sci & Engn Campus D2 2 D-66123 Saarbrucken Germany Saarene Saarland Ctr Energy Mat & Sustainabil Campus C4 2 D-66123 Saarbrucken Germany Leibniz Inst Plasma Sci & Technol Felix Hausdorff Str 2 D-17489 Greifswald Germany Technion Israel Inst Technol Fac Mech Engn IL-3200003 Haifa Israel Technion Israel Inst Technol Wolfson Dept Chem Engn IL-3200003 Haifa Israel Technion Israel Inst Technol Grand Technion Energy Program IL-3200003 Haifa Israel

The demand for electronic devices that utilize lithium is steadily increasing in this rapidly advancing technological world. Obtaining high-purity lithium in an environmentally friendly way is challenging by using commercialized methods. Herein, we propose the first fuel cell system for continuous lithium-ion extraction using a lithium superionic conductor membrane and advanced electrode. The fuel cell system for extracting lithium-ion has demonstrated a twofold increase in the selectivity of Li+/Na+ while producing electricity. Our data show that the fuel cell with a titania-coated electrode achieves 95% lithium-ion purity while generating 10.23 Wh of energy per gram of lithium. Our investigation revealed that using atomic layer deposition improved the electrode's uniformity, stability, and electrocatalytic activity. After 2000 cycles determined by cyclic voltammetry, the electrode preserved its stability. To achieve high purity and selectivity in lithium-ion extraction, using ceramic membranes that are selective to lithium is ideal, and titania can be employed as a protective layer on the gas diffusion electrode to improve the catalyst's durability. Our data show that a lithium superionic conductor can be used in fuel cells for extracting lithium. A fuel cell-based lithium extraction system can achieve a purity level of 95% while generating 0.12 Wh of energy. image

关键词： atomic layer deposition cation selectivity electrochemical lithium-ion extraction fuel cell ATOMIC LAYER DEPOSITION RECOVERY BATTERY ELECTROCATALYSTS PRINCIPLES ENERGY TIO2

A case of post traumatic mitral chordae rupture mimicking acute respiratory distress syndrome

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World Journal of Emergency Medicine 2024年第4期15卷 322-324页

作者： Hülya Deniz Misir Nalan Demir Ferit Kasimzade cansu Yahşi Intensive Care Department Ankara Bilkent City HospitalAnkara 06800Turkiye Intensive Care Department University of Health Sciences Ankara Bilkent City HospitalAnkara 06800Turkiye Cardiovascular Surgery Department Ankara Bilkent City HospitalAnkara 06800Turkiye Pulmonary Medicine Department University of Health Sciences Ankara Bilkent City HospitalAnkara 06800Turkiye

Traumatic mitral chordae rupture is a rare and known cause of acute mitral valve regurgitation and de novo heart *** pathologies in a trauma patient may mask the findings of de novo heart failure due to mitral chordae *** patients may also have other potential pre-diagnoses that could explain symptoms related to heart failure,such as tachycardia,circulatory shock,and acute *** possibility of traumatic chordae tendinea rupture being a preventable cause of mortality should be carefully evaluated.

关键词： rupture mitral acute

Proppant transport in rough fracture networks using supercritical CO_(2)

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Petroleum Science 2024年第3期21卷 1852-1864页

作者： Yong Zheng Meng-Meng Zhou ergun Kuru Bin Wang Jun Ni Bing Yang Ke Hu Hai Huang Hai-Zhu Wang School of Petroleum Engineering Xi'an Shiyou UniversityXian710065ShaanxiChina Shaanxi Key Laboratory of Carbon Dioxide Sequestration and Enhanced Oil Recovery Xi'an710075ShaanxiChina State Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing2249China School of Mining and Petroleum Engineering University of AlbertaEdmontonTG2W2AlbertaCanad Shaanxi Yanchang Petroleum(Group)Co. Ltd.Xi'an710075ShaanxiChina

Proppant transport within fractures is one of the most critical tasks in oil,gas and geothermal reservoir stimulation,as it largely determines the ultimate performance of the operating *** transport in rough fracture networks is still a relatively new area of research and the associated transport mechanisms are still *** this study,representative parameters of rough fracture surfaces formed by supercritical CO_(2) fracturing were used to generate a rough fracture network model based on a spectral synthesis *** fluid dynamics(CFD)coupled with the discrete element method(DEM)was used to study proppant transport in this rough fracture *** reveal the turning transport mechanism of proppants into branching fractures at the intersections of rough fracture networks,a comparison was made with the behavior within smooth fracture networks,and the effect of key pumping parameters on the proppant placement in a secondary fracture was *** results show that the transport behavior of proppant in rough fracture networks is very different from that of the one in the smooth fracture *** turning transport mechanisms of proppant into secondary fractures in rough fracture networks are gravity-driven sliding,high velocity fluid suspension,and fracture structure *** the same injection conditions,supercritical CO_(2)with high flow Reynolds number still has a weaker ability to transport proppant into secondary fractures than *** of the supercritical CO_(2)needs to be increased beyond a certain value to have a significant effect on proppant carrying,and under the temperature and pressure conditions of this paper,it needs to be increased more than 20 times(about 0.94 m Pa s).Increasing the injection velocity and decreasing the proppant concentration facilitates the entry of proppant into the branching fractures,which in turn results in a larger stimulated reservoir *** results help to understand the pro

关键词： Reservoir stimulation CCUS Rough fracture network Supercritical CO_(2) Proppanttransport

Inflammatory responses in esophageal mucosa before and after laparoscopic antireflux surgery

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World Journal of Gastrointestinal Surgery 2024年第3期16卷 871-881页

作者： Pelin ergun Sezgi Kipcak Nur Selvi Gunel Eser Yildirim Sozmen Serhat Bor Department of Otolaryngology Medical College of WisconsinMilwaukeeWI 53226United States Division of Gastroenterology Ege UniversityFaculty of MedicineEge Reflux GroupIzmir 35100Turkiye Department of Medical Biology Ege UniversityFaculty of MedicineIzmir 35100Turkiye Department of Medical Biochemistry Ege UniversityFaculty of MedicineIzmir 35100Turkiye

BACKGROUND Currently,the primary treatment for gastroesophageal reflux is acid suppression with proton pump inhibitors,but they are not a cure,and some patients don’t respond well or refuse long-term ***,alternative therapies are needed to understand the disease and develop better *** anti-reflux surgery(LARS)can resolve symptoms of these patients and plays a significant role in evaluating esophageal healing after preventing harmful *** LARS improves typical gastroesophageal reflux symptoms in most patients,main-ly by reducing the exposure time to gastric contents in the ***-ration of the inflammatory response and a recovery response in the esophageal epithelium is expected following the cessation of the noxious *** To explore the role of inflammatory biomolecules in LARS and assess the time required for esophageal epithelial *** Of 22 patients with LARS(pre-and post/5.8±3.8 months after LARS)and 25 healthy controls(HCs)were *** subjects underwent 24-h multichannel intraluminal impedance-pH monitoring and upper gastrointestinal endoscopy,during which esophageal biopsy samples were collected using endoscopic *** molecules in esophageal biopsies were investigated by reverse transcription-polymerase chain reaction and multiplex-enzyme-linked immunosorbent *** Post-LARS samples showed significant increases in proinflammatory cytokines[interleukin(IL)-1β,interferon-γ,C-X-C chemokine ligand 2(CXCL2)],anti-inflammatory cytokines[CC chemokine ligand(CCL)11,CCL13,CCL17,CCL26,CCL1,CCL7,CCL8,CCL24,IL-4,IL-10],and homeostatic cytokines(CCL27,CCL20,CCL19,CCL23,C-CL25,CXCL12,migration inhibitory factor)compared to both HCs and pre-LARS ***17 and CCL21 levels were higher in pre-LARS than in HCs(P<0.05).The mRNA expression levels of AKT1,fibroblast growth factor 2,HRAS,and mitogen-activated protein kinase 4 were significantly decreased post-LARS vs pre-LARS.

关键词： Anti-reflux surgery Gastroesophageal reflux disease Cytokine Inflammatory response Esophagus

Performance Comparison of Commercial and Home-Made Lipases for Synthesis of Poly(δ-Valerolactone)Homopolymers

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Journal of Renewable Materials 2019年第4期7卷 335-343页

作者： cansu Ulker Zeynep Gok Yuksel Guvenilir Istanbul Technical University Department of Chemical EngineeringAyazaga CampusIstanbul34469Turkey

Novozyme 435,which is the commercially available immobilized form of Candida antarctica lipase B,has been successfully conducted ring opening polymerization of lactones in organic *** this paper,it was aimed to introduce an alternative biocatalyst for Novozyme *** antarctica lipase B immobilized onto rice husk ashes via physical adsorption(with a specific activity of 4.4 U/mg)was prepared in previous studies and used as a biocatalyst for poly(δ-valerolactone)synthesis in the present *** reactions were proceeded at various reaction temperatures and periods via both two immobilized enzyme *** resulting products were characterized spectroscopically and *** highest molecular weight(Mn=9010 g/mol)was obtained via Novozyme 435 catalysis at 40℃and 24 *** performance of home-made lipase,which resulted in a molecular weight of 8040 g/mol,was close to commercial one.

关键词： Poly(δ-valerolactone) Candida antarctica lipase B Novozyme 435 immobilization enzymatic ring opening polymerization

Dithiothreitol and PEG Induced Combined Stress May Affect the Expressions of ABA Aldehyde Oxidase, Sucrose Synthase and Proline Metabolic Genes in Maize Seedlings

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Phyton-International Journal of Experimental Botany 2020年第3期89卷 487-495页

作者： cansu Altuntas Rabiye Terzi Faculty of Science Department of BiologyKaradeniz Technical UniversityTrabzon61080Turkey

The endoplasmic reticulum(ER)is an organelle in the cell where proteins are created and *** is a very elaborate process that is often interrupted by various biotic and abiotic stresses,leading to the formation of unfolded and misfolded proteins called ER ***(DTT)-induced unfolded protein response(UPR)in endoplasmic reticulum(ER)has been recently reported in ***,previous studies demonstrated that treatment with polyethylene glycol(PEG 6000)could stimulate water deficit in ***,further researches should be conducted to elucidate the molecular mechanism of ER stress response and the relationship between water deficiency and *** this study,we examined the expressions of sucrose synthase(SuS)gene,proline metabolic genes and abscisic aldehyde oxidase(AAO3)gene in maize seedlings that were subjected to DTT and PEG induced combined stresses by using quantitative real-time *** weeks old detached maize seedlings were treated with or without DTT and PEG 6000 for 12 *** treatment with DTT increased about 2-fold the expression of gene encoding proline synthesis enzyme,pyrroline-5-carboxylate synthetase(P5CS)but no statistically affected the proline catabolism enzyme,proline dehydrogenase(ProDH)in comparison with un-treated *** treatment was also up-regulated P5CS while it was down-regulated *** relative expression levels of SuS and AAO3 genes statistically enhanced about 2.5 fold under the DTT-induced ER ***,the expression levels of SuS and AAO3 genes were up-regulated in the detached seedlings exposed to PEG-induced water ***,the induced gene expressions were down-regulated under the combined stress,the DTT-induced ER stress and PEG-induced water deficit in comparison with the singular stress responses(DTT or PEG).The results indicated that the expressions of genes,related to the synthesis of some signal osmolyte compounds such as proline and sucrose can be suppressed when ER s

关键词： ER stress water deficit sucrose proline metabolism ABA synthesis gene expression

Intraocular pressure elevation after intravitreal triamcinolone acetonide injection: a Meta-analysis

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International Journal of Ophthalmology(English edition) 2016年第1期9卷 139-144页

作者： cansu Yuksel-Elgin Ceyhun Elgin Department of Ophthalmology Sariyer Ismail Akgun Public Hospital Department of Economics Bogazici University

AIM：To report on intraocular pressure（IOP）after intravitreal injections of triamcinolone acetonide.·M ETHODS：Systematic literature review of studies that investigated the effects of an injection of triamcinolone Intravitreal triamcinolone acetonide on IOP was conducted according to the Cochrane Collaboration methodology and the reported effects have been analyzed with Meta-analysis.·RESULTS：We found that the IOP follows an inverted-U shape pattern over time starting with an average value of14.81±1.22 mm Hg before the injection,rising to a maximum of 19.48±2.15 mm Hg after one month of injection and falling down to 16.16±1.92 mm Hg ***,country of study,age,previous history of glaucoma and gender compositions matter for crossstudy were different in reported IOP changes.·CONCLUSION：Our findings may be helpful in determining pressure elevation risk of intravitreal triamcinolone acetonide therapy as well as comparing it with those of more recent therapies such as the antivascular endothelial growth factor agents.

关键词： intravitreal injections intraocular pressure Meta-analysis