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Influence of ammonium sulfate on the corrosion behavior of AZ31 magnesium alloy in chloride environment

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Journal of Magnesium and Alloys 2024年第3期12卷 1082-1101页

作者： Feng Ge Zhongyu cui Yue liu Li Lei xin Wang Hongzhi cui School of Materials Science and Engineering Ocean University of ChinaQingdao 266100China Beijing National Innovation Institute of Lightweight Ltd.Beijing 101499China

Electrochemical corrosion of AZ31 magnesium alloy in the NH_(4)^(+)-SO_(4)2−-Cl−environment is *** of NH_(4)^(+)overshadows that of Cl−as the(NH_(4))_(2)SO_(4) concentration is 0.005 M or higher,yielding an evolution from localized corrosion to uniform *** effect of NH_(4)^(+)can be attributed to that(i)NH_(4)^(+)dissolves the inner MgO and hinders the precipitation of Mg(OH)_(2) and(ii)the buffering ability of NH_(4)^(+)provides H+,enhances the hydrogen evolution,and expedites the corrosion *** latter is demonstrated as the dominant factor with the results in unbuffered and buffered *** severe corrosion and hydrogen process in NH_(4)^(+)-containing solution results in a high Hads coverage and yields an inductive loop within the low ***,SO_(4)^(2−)is helpful in generating cracked but partially protective corrosion products,while Cl−could broaden the corrosion area beneath the corrosion product.

关键词： Magnesium alloy Ammonium corrosion Electrochemical kinetic parameter Anodic dissolution.

Jurassic integrative stratigraphy,biotas,and paleogeographical evolution of the Qinghai-Tibetan Plateau and its surrounding areas

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Science China Earth Sciences 2024年第4期67卷 1195-1228页

作者： Jianguo LI xin RAO Lin MU Xiaohui cui xin LI Hui LUO Peixue liu Center for Excellence in Life and Paleoenvironment Nanjing Institute of Geology and PalaeontologyChinese Academy of SciencesNanjing 210008China Nanjing College University of Chinese Academy of SciencesNanjing 211135China

The Qinghai-Tibetan Plateau experienced a unique geological evolution during the Jurassic,driven by the termination of the Palaeotethys and the reduction of the *** Indian Plate separated from the northern margin of Gondwana and drifted northward from the Southern *** that the timing of strata serves as the basis for reconstructing geological history,the present work aimed to develop a new multiple stratigraphic and chronologic framework for the Jurassic strata of the Qinghai-Tibetan Plateau region via a synthesis of the material on lithostratigraphy,palaeontology,iso-radiometric dating,magnetostratigraphy,and other techniques with an emphasis on recent progress and *** new framework included the Jurassic System from the four major subdivisions of the plateau:the Baryan Har,Qiangtang,Lhasa-Gandise,and Southern Xizang(Himalaya).Ultimately,a more complete,refined biostratigraphic sequence was proposed,comprising the most common fossils in the plateau and those that are stratigraphically significant for the Jurassic stratigraphy,including ammonites,bivalves,brachiopods,foraminifera,radiolarians,and dinoflagellate cysts for the marine strata,and pollen and spores,and charophytes for the terrestrial *** biostratigraphic framework was correlated with the Jurassic international standard zonation of the Geological Time Scale 2020 via standard or representative species or genera of *** on this framework,we constructed a lateral correlation of the Jurassic strata between different basins of the *** palaeontologic correlation in the present work shows that the Lhasa-Gandise Block had a closer relationship with the Qiangtang Block than with the Southern Xizang Himalaya during the Jurassic ***,the Lhasa-Gandise Block and Qiangtang Block shared similar marine fauna features of the north marginal East *** contrasts the opinion suggesting that the Yarlung Zangbo Tethys was a small back-arc basin.A c

关键词： Biostratigraphy Chronostratigraphy Correlation Yarlung Zangbo suture Bangong Co-Nujiang suture Tethys

Risk Factors of Depression Screened by Two-Sample Mendelian Randomization Analysis:A Systematic Review

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Biomedical and Environmental Sciences 2024年第1期37卷 85-95页

作者： WANG Han Lin XUE Yan Feng cui Bao Qiu liu Hong SHEN xin xin Shandong Provincial Research Center for Bioinformatic Engineering and Technique School of Life SciencesShandong University of TechnologyZibo 255049ShandongChina Shanxi Province Cancer Hospital/Shanxi Hospital Affiliated to Cancer Hospital Chinese Academy of Medical Sciences/Cancer Hospital Affiliated to Shanxi Medical UniversityTaiyuan 030013ShanxiChina State Key Laboratory of Infectious Disease Prevention and Control National Institute for Viral Disease Control and PreventionChinese Center for Disease Control and PreventionBeijing 102206China

Objective This study explored the potentially modifiable factors for depression and major depressive disorder(MDD)from the MR-Base database and further evaluated the associations between drug targets with *** We analyzed two-sample of Mendelian randomization(2SMR)using genetic variant depression(n=113,154)and MDD(n=208,811)from Genome-Wide Association Studies(GWAS).Separate calculations were performed with modifiable risk factors from MR-Base for 1,001 *** MR analysis was performed by screening drug targets with MDD in the DrugBank database to explore the therapeutic targets for *** variance weighted(IVW),fixed-effect inverse variance weighted(FE-IVW),MR-Egger,weighted median,and weighted mode were used for complementary *** The potential causal relationship between modifiable risk factors and depression contained 459 results for depression and 424 for ***,the associations between drug targets and MDD showed that SLC6A4,GRIN2A,GRIN2C,SCN10A,and IL1B expression are associated with an increased risk of *** contrast,ADRB1,CHRNA3,HTR3A,GSTP1,and GABRG2 genes are candidate protective factors against *** This study identified the risk factors causally associated with depression and MDD,and estimated 10 drug targets with significant impact on MDD,providing essential information for formulating strategies to prevent and treat depression.

关键词： Risk factors Drug targets Depression Major depressive disorder Two-sample Mendelian randomization

Recent advances in high charge density triboelectric nanogenerators

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International Journal of Extreme Manufacturing 2024年第4期6卷 1-19页

作者： xin cui Jiaheng Nie Yan Zhang School of Physics University of Electronic Science and Technology of ChinaChengdu 611731People's Republic of China School of Cybersecurity Chengdu University of Information TechnologyChengdu 610225People's Republic of China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 100083People's Republic of China School of Nanoscience and Technology University of Chinese Academy of SciencesBeijing 100049People's Republic of China

Triboelectric materials with high charge density are the building-block for the commercial application of triboelectric nanogenerators(TENGs).Unstable dynamic processes influence the change of the charge density on the surface and inside of triboelectric *** charge density of triboelectric materials depends on the surface and the internal charge transfer *** focus of this review is on recent advances in high charge density triboelectric materials and advances in the fabrication of *** summarize the existing strategies for achieving high charge density in triboelectric materials as well as their fundamental *** then review current optimization methods for regulating dynamic charge transfer processes to increase the output charge density:first,increasing charge injection and limiting charge dissipation to achieve a high average surface charge density,and second,regulating the internal charge transfer process and storing charge in triboelectric materials to increase the output charge ***,we present the challenges and prospects in developing high-performance triboelectric materials.

关键词： triboelectric nanogenerator charge density charge transfer charge store

Optimization of confined aquifer dewatering for long-deep excavation using simulation–optimization method

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Underground Space 2024年第4期17卷 246-266页

作者： Yanxiao Sun Zhenxiong Jiang Liyuan Tong Jiawei Sun Jia cui xin Zhou Songyu liu Institute of Geotechnical Engineering Southeast UniversityNanjing 211189China Nanjing Modern Multimodal Transportation Laboratory Nanjing 211100China Jiangsu Provincial Transportation Construction Bureau Nanjing 210004China

The confined aquifer dewatering for long-deep excavations usually encounters challenges due to complicated geotechnical conditions,large excavation sizes,and high hydraulic *** propose the most efficient scheme of confined aquifer dewatering for long-deep excavations,dewatering optimizations were performed using the simulation–optimization *** open cut tunnel of the Jiangyin-Jingjiang Yangtze River Tunnel Project was taken as an *** methods of finite element and linear programming(LP)were combined to optimize the dewatering process.A three-dimensional finite element model was *** simulating the pumping tests,hydraulic conductivity was ***,necessary parameters in the LP method were determined by simulating dewatering with each pumping well,and various LP models were developed based on some important influence factors such as dewatering sequence,considered pumping wells,and pumping rate ***,the optimal pumping rates were solved and applied to the numerical model,with induced drawdown and ground settlement computed for *** results indicate that the optimization can significantly reduce the required wells in the original *** in the deepest zone exhibits the highest efficiency for long-deep excavations with gradually varying *** the dewatering sequence from the shallowest to the deepest zone,more pumping wells are required but less energy is *** quantity and more advantageous locations of pumping wells in the LP model usually result in lower total pumping rate,drawdown,and ground *** more pumping wells are considered in the deepest zone,pumping rate limitation of single well will only slightly increase the total pumping rate,number of required pumping wells,drawdown,and ground settlement.

关键词： Dewatering Confined aquifer Simulation-optimization Linear programming Open cut tunnel

Influence of Polluted SY River on Child Growth and Sex Hormones

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Biomedical and Environmental Sciences 2012年第3期25卷 291-296页

作者： TANG Chun Yu LI An Qi GUAN Yong Bo LI Yan CHENG Xue Min LI Ping LI Shi Qun LUO Yi xin HUANG Qi CHEN Hong Yang cui liu xin Department of Environmental Health School of Public Health Zhengzhou University Zhengzhou 450001Henan China School of Basic Medicine Zhengzhou University Zhengzhou 450001 Henan China.

Objective To investigate the influence of the polluted SY River on children＇s growth and sex hormones, and provide scientific data for assessment of the polluted status of the SY River. Methods The study areas were selected randomly from the SY River Basin. Lead （Pb）, mercury （Hg）, arsenic （As）, phthalates （DEP, DBP, DMP, DEHP）, and bisphenol A （BPA） were measured both in the river water and in the drinking water. School children were selected by cluster sampling （n=254）. Physical development indexes （height, weight, bust-circumference, and skinfold thickness） and sex hormones [testosterone （T） and estradiol （E2）] were measured for all the children. Results The contents of Pb and Hg exceeded Class V standards of surface water quality in each section of the river and other indicators exceeded Class Ill. Compared to the control area, the concentrations of Pb, Hg, As, BPA, DEP, and DBP in the drinking water were significantly higher than in the polluted area （P〈0.05）. Children from the control area had significantly lower E2 and T than children from the polluted area （P〈O.05）. Among anthropometric results, only skinfold thickness had statistically significant difference between the two groups （P〈0.05）, while the other indexes showed no significant differences between the two groups （P〉0.05）. Conclusion The drinking water has been polluted by the SY River and affected serum sex hormone levels of children living in the polluted area.

关键词： Water pollution Children Growth and development Estradiol Testosterone

Green carbonization of waste coffee grounds into porous C/Fe hybrids for broadband and high-efficiency microwave absorption

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Journal of Materials Science & Technology 2024年第3期170卷 1-10页

作者： xin Wen cui Li Hui liu Guohua Fan Yanan Tang Chuncheng Hao Lili Ma Pingan Song Institute of Advanced Electrical Materials College of Materials Science and EngineeringQingdao University of Science and TechnologyQingdao 266042China Center for Future Materials University of Southern QueenslandSpringfieldQLD 4300Australia School of Agriculture and Environmental Science University of Southern QueenslandSpringfieldQLD 4300Australia

Recently great effort s have been focused on designing high-performance microwave absorbers using sustainable biomass resources,but there remains a lack of green and efficient fabrication ***,inspired by natural porous character of biomass waste,we demonstrated a green one-step route to convert waste coffee grounds into porous C/Fe hybrids,and further explored their potential applications for broadband and high-efficiency microwave *** this design,the WCG-20-750(incorporated 20 wt%Fe(C_(5)H_(7)O_(2))_(3)catalyst and carbonized at 750℃)exhibited porous microstructure with the highest char yield of 55.45 wt%.Furthermore,the as-prepared C/Fe hybrids from WCG-20-750 displayed excellent microwave absorption ***,the minimum reflection loss(RL_(min))reached to-52.86 dB and the widest effective absorption bandwidth(EAB)was 6.40 GHz at the thickness of 3.0 *** work provides an economically viable and environmentally friendly strategy to convert biomass wastes into value-added microwave absorbers,ultimately making contributions to the upcycling of renewable biomass resources and the fostering of sustainable environment.

关键词： Waste recycling Microwave absorption Green carbonization Porous carbon Biomass

Thermal-hydraulic performance analysis and multi-objective optimization of a microchannel with staggered semi-elliptical ribs

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Science China Technological Sciences 2024年第10期67卷 3152-3167页

作者： cui Pan liu Wei liu ZhiChun School of Energy and Power Engineering Huazhong University of Science and Technology

To enhance the cooling capacity of traditional microchannels for high heat flux electronic devices,a microchannel design with staggered semi-elliptical ribs is proposed in this *** numerical simulations,the flow characteristics of the designed microchannel are compared with those of a smooth one,and the effects of rib width（Wr）,rib height（Hr）,and rib length（Lr）,on the thermal-hydraulic performance are investigated under laminar flow *** results show that the periodically arranged ribs induce periodic vortices within the microchannel,effectively promoting fluid mixing and enhancing heat *** Hrhave similar effects on microchannel performance,with an increase in them leading to an enhanced thermal performance at the expense of deteriorated hydraulic ***,Lrhas a comparatively weaker influence,with both the heat transfer and flow resistance initially growing with increasing Lrand then *** strike a balance between the two performances,a multi-objective optimization on the three geometrical parameters is conducted at a Reynolds number（Re） *** with simulation data,artificial neural networks are trained as surrogate models,and a multi-objective genetic algorithm is employed to derive the Pareto *** the TOPSIS decision-making method,an optimal compromise solution is determined as Wr=0.2415 mm,Hr=0.0976 mm,and Lr=0.6486 *** testing on the optimized microchannel reveals that it exhibits high heat transfer,middle flow resistance,and excellent overall performance,with the performance evaluation criterion（PEC） falling between 1.572 and 1.723 within the Re range of 220–660.

关键词： heat transfer enhancement microchannel semi-elliptical rib numerical simulation multi-objective optimization

Activity regulation and applications of metal-organic framework-based nanozymes

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Rare Metals 2024年第3期43卷 900-914页

作者： Ge Fang Shou-xin Bao Gen-Xiu Zhou cui-cui Ge State Key Laboratory of Radiation Medicine and Protection School of Radiation Medicine and ProtectionSchool for Radiological and Interdisciplinary Sciences(RAD-X)Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education InstitutionsSoochow UniversitySuzhou 215123China Suzhou Nanomicro Technology Co. LtdSuzhou 215000China

As a new generation of artificial enzymes,nanozymes show outstanding advantages such as high stability,low cost,and facile synthesis,which endow them with promising applications in biomedical and environmental *** the various reported nanozymes,metal-organic frameworks(MOFs)could mimic the active center of natural enzymes and provide a hydrophobic environment,which makes MOFs attractive alternatives to natural *** to the highly structural diversity and tailorability of MOFs,rational design will contribute to improve the activity of MOF-based nanozymes and promote their potential applications in both biomedical and environmental ***,a comprehensiye suminary of activity regulatory strategies of MOF-based nanozymes is urgently ***,we summarized the activity regulatory strategies of MOFs with intrinsic enzyme-like activities via modulation of metal nodes,ligands,structures and *** the applications of MOF-based nanozymes in biosensing,hazardous degradation,antibacterial,and cancer therapy were also ***,the current challenges and future perspectives were discussed in *** is highly expected that this review will provide a better understanding on the rational design of novel high-performance MOF-based nanozymes.

关键词： Metal-organic frameworks(MOF)-based nanozymes Activity regulation Biosensing Cancer therapy Hazardous degradation Antibacterial