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Accurate identification of glass crystallization helps in selecting high electronic conductivity materials

Progress in Natural Science:Materials International 2024年第3期34卷 503-511页

作者： Fanhou Kong Shuli Li Suoqi Zhao huiwen Li Lin Li Zhenting Zang Rui Zhang hongrui Liu Lehan Wang Changjiu Li Keng h.chung Dongying Key Laboratory of New Energy Materials and Devices & School of Chemical Engineering Shandong Institute of Petroleum and Chemical Technology Special Glass Key Lab of hainan Province & State Key Laboratory of Marine Resource Utilization in South China Sea Hainan University

Though the current research on vanadium-based glass electrodes has made great progress, the conductivity theory of V-based glasses has not been obviously improved and crystals cannot be positioned precisely. The changes in the valence state of V3+, V4+and V5+are regulated by the strong reducing agent Fe2P to realize valence bond transformation of the amorphous electrode, explore the redox process of multi-electron reactions and further optimize the conductivity of electrode materials. VPFe2 and VPFe3 precipitate VO2crystals and VPFe4 precipitates VO2and V6O11crystals. Electron back-scattered diffraction was used to accurately identify the distribution and specific positions of both types of crystals. V6O11crystals exhibit a strong texture according to pole figure and inverse pole figure. XPS reveals that Fe2P and V2O5, undergo a redox reaction during the hightemperature melting process, where V5+is reduced to V4+and V3+and V4+renders a positive influence on conductivity. The addition of Fe2P increases the content of V4+in the glass and VPFe3 glass contains the highest content of V4+, leading to the highest electronic conductivity. V2O5transforms into VO2crystals and VO2transforms into V6O11with the increase of Fe2P content. The type of nanocrystal precipitation in glass affects electronic conductivity.

关键词： Electron back-scattered diffraction Electronic conductivity Glass crystallization Multi-electron reactions V2O5

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Trial characteristics and treatment effect estimates in randomized controlled trials of Chinese herbal medicine: A meta-epidemiological study

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Journal of Integrative Medicine 2024年第3期22卷 223-234页

作者： Betty h.Wang Ya-li Lin Yin-yan Gao Jin-lu Song Lang Qin Ling-qi Li Wen-qi Liu Claire C.W.Zhong Mary Y.Jiang Chen Mao Xiao-bo Yang Vincent C.h.chung Irene X.Y.Wu Jockey Club School of Public health and Primary Care the Chinese University of Hong KongHong Kong 999077China Xiangya School of Public health Central South UniversityChangsha 410006Hunan ProvinceChina School of Chinese Medicine the Chinese University of Hong KongHong Kong 999077China School of Public health Southern Medical UniversityGuangzhou 510080Guangdong ProvinceChina State Key Laboratory of Dampness Syndrome of Chinese Medicine the Second Affiliated Hospital of Guangzhou University of Chinese MedicineGuangzhou 510120Guangdong ProvinceChina Chinese Medicine Syndrome Research Team the Second Affiliated HospitalGuangzhou University of Chinese MedicineGuangzhou 510120Guangdong ProvinceChina Guangdong Provincial Key Laboratory of Clinical Research on Traditional Chinese Medicine Syndrome Guangzhou 510120Guangdong ProvinceChina hunan Provincial Key Laboratory of Clinical Epidemiology Central South UniversityChangsha 410006Hunan ProvinceChina

Background:Previously published meta-epidemiological studies focused on Western medicine have identified some trial characteristics that impact the treatment effect of randomized controlled trials(RCTs).Nevertheless,it remains unclear if similar associations exist in RCTs on Chinese herbal medicine(ChM).Further,Chinese medicine-related characteristics have not been explored ***:To investigate trial characteristics related to treatment effect estimates on ChM *** strategy:This meta-epidemiological study searched 5 databases for systematic reviews on ChM treatment published between January 2011 and July *** criteria:An eligible systematic review should only include RCTs of ChM and conduct at least one *** extraction and analysis:Two reviewers independently conducted data extraction on general characteristics of systematic reviews,meta-analyses and included *** also assessed the risk of bias of RCTs using the Cochrane risk of bias tool.A two-step approach was used for data *** ratio of odds ratios(ROR) and difference in standardized mean differences (dSMD) with 95%confidence interval (CI) were applied to present the difference in effect estimates for binary and continuous outcomes,***:Ninety-one systematic reviews,comprising 1338 RCTs were *** binary outcomes,RCTs incorporated with syndrome differentiation (ROR:1.23;95%CI:[1.07,1.39]),adopting Chinese medicine formula (ROR:1.19;95%CI:[1.03,1.34]),with low risk of bias on incomplete outcome data (ROR:1.29;95%CI:[1.06,1.52]) and selective outcome reporting (ROR:1.12;95%CI:[1.01,1.24]),as well as a trial size≥100 (ROR:1.23;95%CI:[1.04,1.42]) preferred to show larger effect *** for continuous outcomes,RCTs with Chinese medicine diagnostic criteria (dSMD:0.23;95%CI:[0.06,0.41]),judged as high/unclear risk of bias on allocation concealment (dSMD:-0.70;95%CI:[-0.99,-0.42]),with low risk of bias on incomplete outcome data (dSMD:0.30

关键词： Chinese herbal medicine Randomized controlled trial Risk of bias Meta-epidemiological study Effect estimates

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Factors that affect heart rate variability following acute resistance exercise:A systematic review and meta-analysis

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Journal of Sport and health Science 2022年第3期11卷 376-392页

作者： Sajith U.Marasingha-Arachchige JacoboÁ.Rubio-Arias Pedro E.Alcaraz Linda h.chung UCAM Research Center for high Performance Sport Catholic University of MurciaMurcia 30107Spain LFE Research Group Department of Health and Human PerformanceFaculty of Physical Activity and Sport Science-INEFUniversidad Politécnica de MadridMadrid 28040Spain Faculty of Sport Catholic University of MurciaMurcia 30107Spain

Background:There is controversial evidence regarding the effect of acute resistance exercise(ARE) on heart rate variability(hRV) parameters,which indicates the activities of the cardiac autonomic nervous *** aim of this study was to perform a systematic review and meta-analysis of the literature on the effect of ARE on hRV parameters and identify its possible moderating ***:The PubMed-Medline,Web of Science,SPORTDiscus,and Cochrane Library databases were *** Preferred Reporting Items for Systematic Reviews and Meta-Analyses(PRISMA) declaration was followed,and the methodological quality of the studies was *** level of significance was set at p≤***-six studies met the inclusion *** effect analyses between pre-and post-test interventions demonstrated an increase in normalized units low frequency(p high frequency ratio(p he normal-to-normal(NN)interval(p he successive differences(p high frequency(p healthy individuals range:15 ± 1 to 48 ± 2 years;mean ± SD).Results:There were differences between the subgroups in the number of sets used in an exercise(p=0.05) for root mean square of the successive differences,as well as for exercise intensity(p=0.01) and rest between sets(p=0.05) for normalized units high ***,there were differences between the subgroups in training volume for root mean square of the successive differences(p=0.01),normalized units high frequency(p=0.003) and normalized units low frequency(p=0.02).Conclusion:Overall,there was a withdrawal of cardiac parasympathetic and activation of cardiac sympathetic modulations following ARE,and th

关键词： Cardiac Parasympathetic Sympathetic

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hetero-deformation promoted strengthening and toughening in BCC rich eutectic and near eutectic high entropy alloys

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Journal of Materials Science & Technology 2023年第15期146卷 1-9页

作者： D.h.chung J.Lee Q.F.he Y.K.Kim K.R.Lim h.S.Kim Y.Yang Y.S.Na Department of Special Alloys Extreme Materials Research InstituteKorea Institute of Materials ScienceChangwonThe Republic of Korea Department of Mechanical Engineering City University of Hong KongKowloon TongKowloonHong KongChina Graduate Institute of Ferrous Technology Pohang University of Science and TechnologyPohangThe Republic of Korea Center for heterogenic Metal Additive Manufacturing Pohang University of Science and TechnologyPohangThe Republic of Korea Department of Materials Science and Engineering City University of Hong KongKowloon TongKowloonHong KongChina

heterostructured eutectic high-entropy alloys(EhEAs)have attracted significant attention owing to their novel properties,such as balanced combinations of strength and fracture ***,the toughening/strengthening mechanisms of these EhEAs have not been thoroughly *** this study,we developed a series of dual-phase Al_((18–2x))Co_(30)Cr_((11+x))Fe_((11+x))Ni_(3)0(x=-1,0,1)eutectic and neareutectic hEAs containing face-centered cubic(FCC)and body-centered cubic(BCC)*** the high amount of BCC,which is referred to as the brittle phase,newly developed EhEAs exhibited superior fracture ***,we discovered that a fully eutectic hEA exhibited further improvements in both yield stress and fracture toughness,outperforming our off-eutectic and other previously reported *** combining experiments and theoretical models,we demonstrated that the synergistic increase in both strength and toughness in our fully eutectic hEA was derived from the high hetero-deformationinduced(hDI)strengthening/toughening associated with a high misorientation angle at the grain/phase boundaries.

关键词： Eutectic high entropy alloy Fracture toughness heterogeneous structure hetero deformation induced strengthening Misorientation angle

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Development of a group support system to support collaborative works in value management workshops

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Journal of harbin Institute of Technology(New Series) 2004年第1期11卷 91-97页

作者： chung J K h Dept. of Building and Real Estate Hong Kong Polytechnic University Kowloon Hong Kong China

Value Management (VM) is a rigorous and systematic approach to improve the value and optimise the overall cost of a facility. It identifies opportunities to remove unnecessary costs while assuring that quality, reliability, performance, and other critical factors will meet or exceed the customers’ expectations. It has been widely used in the construction industry in a number of countries. A recent survey, however, revealed several problems that hinder the wider use of this methodology in the industry. To overcome these problems, a feasibility study has been conducted to investigate whether or not a Group Support System (GSS) can support collaborative works in VM workshops. This paper introduces the development and structure of a prototype GSS which is designed to support the collaborative works of stakeholders in VM workshops. It begins with an introduction to the conceptual GSS framework and job plan, illustrating what GSS supports can be provided to VM workshops. This is followed by a detailed description of the GSS prototype system to demonstrate how these supports can be performed as an integrated computer system. The testing of the system is also discussed. The research findings provide strong evidence in supporting the notion of using GSS to improve VM implementation. The information support of GSS has been ranked to be the most useful GSS functions and most of the practitioners interviewed are highly interested in applying GSS to support VM workshops in the future.

关键词：价值管理 VM 生产成本可靠性产品质量群支持系统 GSS

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Self-adhesive pads in defi brillation or cardioversion: risks due to unfamiliarity and recommendations

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World Journal of Emergency Medicine 2024年第1期15卷 64-66页

作者： hansol chung Department of Emergency Medicine Yeungnam University College of MedicineDaegu 42415Republic of Korea

During cardiopulmonary resuscitation(CPR),defibrillation,or cardioversion,the use of self-adhesive pads instead of conventional paddles has gradually become *** particular,it was recommended during the COVID-19 pandemic,as it allows defibrillation or cardioversion to be performed without close contact between the rescuer and patient.[1,2]Self-adhesive pads can minimize the downtime of chest compressions before and after defibrillation and protect the patient from electric arc formation,skin burns,and fi *** the pads are attached,electrocardiographic rhythm analysis,defibrillation,synchronous cardioversion,and cardiovascular support are all *** paddles,self-adhesive pads can save time because the application of conductive jelly,repeated positioning,and application of 10-12 kg of pressure on the chest are not *** European Resuscitation Council(ERC)Guidelines 2021 state that the use of self-adhesive pads is recommended in advanced cardiovascular life support(ACLS).[3]Nevertheless,some medical staff still tend to prefer the use of conventional paddles instead of self-adhesive pads in hospitals.

关键词： attached cardio conductive

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Molecular composition of naphthenic acids in a Chinese heavy crude oil and their impacts on oil viscosity

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Petroleum Science 2023年第2期20卷 1225-1230页

作者： Qian-hui Zhao Shuai M Jian-Xun Wu Wei-Feng Chang Sheng-Fei Zhang Xin-Ge Sun Bing Zhou Zeng-Min Lun Keng h.chung Quan Shi State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Sinopec Petroleum Exploration and Production Research InstituteBeijing 100083China State Key Laboratory of heavy Oil Processing Petroleum Molecular Engineering Center(PMEC)China University of PetroleumBeijing 102249China Research Institute of Petroleum Exploration and Development CNPCBeijing 100083China Xinjiang Oilfield Company CNPCKaramayXinjiang 834000China Well Resources Inc. EdmontonCanada

Most heavy crude oils underwent biodegradation and generated a significant amount of naphthenic acids. Naphthenic acids are polar compounds with the carboxylic group and are considered as a major factor affecting the oil viscosity. however, the relationship between the molecular composition of naphthenic acids and oil viscosity is not well understood. This study examined a “clean” heavy oil with low contents of heteroatoms but had a high content of naphthenic acids. Naphthenic acids were fractionated by distillation and caustic extraction. The molecular composition was characterized by high-resolution Orbitrap mass spectrometry. It was found that the 2- and 3-ring naphthenic monoacids with 15–35 carbon atoms are dominant components of the acid fractions;the caustic extraction is capable of isolating naphthenic acids with less than 35 carbons, which is equivalent to the upper limit of the distillable components, but not those in the residue fraction;the total acid number of the heavy distillates is higher than that of the residue fraction;the viscosity of the distillation fraction increases exponentially with an increased boiling point of the distillates. Blending experiments indicates that there is a strong correlation between the oil viscosity and acids content, although the acid content is only a few percent of the total oil.

关键词： heavy crude oil Viscosity high-resolution mass spectrometer Naphthenic acid

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Molecular characterization of polar heteroatom species in oilsands bitumen-derived vacuum residue fractions by Fourier transform ion cyclotron resonance mass spectrometry

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Petroleum Science 2019年第5期16卷 1196-1207页

作者： Fang Zheng Warren chung Eusebio Palmisano Dahai Dong Quan Shi Zhiming Xu Keng h.chung State Key Laboratory of heavy Oil Processing China University of PetroleumBeijing 102249China Well Resources Inc EdmontonCanada Cenovus Energy Inc CalgaryCanada Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of SciencesQingdao 266101China

A Canadian in situ oilsands bitumen-derived vacuum residue(VR)was subjected to supercritical fluid extraction and fractionation(SFEF)into 13 extractable fractions and an unextractable end-cut and characterized by positive-and negative-ion electrospray ionization(ESI)Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS).The results of negative-ion ESI FT-ICR MS showed that the N1 class species was the most abundant and the multifunctional group compounds,such as N1 O1,N1 O2,N1 S1,N1 S2,and N2 class species became abundant as the SFEF fraction became *** positive-ion ESI mode,the relative abundance of N1 class species decreased gradually in the heavy SFEF fractions while that of multifunctional group compounds *** relative abundance of N4 V1 O1 increased dramatically in heavy fractions and the *** distributions of polar heteroatom species of VR derived from oilsands bitumen were similar with those of VR derived from the Venezuela Orinoco extra heavy oil.

关键词： Molecular characterization Canadian oilsands bitumen SFEF ESI FT-ICR MS

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Characterization of Ultra Fine Solids(BS) in Athabasca Bitumen

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Chinese Journal of Structural Chemistry 2004年第7期23卷 751-754页

作者：李再峰 Judy KUNG 涂云 Luba S.Kotlyar Keng h.chung College of Chemistry and Molecular Engineering Qingdao University of Science and TechnologyShandong 266042China National Research Council of Canada Institute for Chemical Process andEnvironmental TechnologyMontreal Road CampusOttawaOntarioCanada K1A 0R6 Syncrude Canada Ltd.Edmonton Research Centre9421-17th Avenue EdmontonAlberta Canada T6N 1H4

The ultra fine (<200 nm) inorganic solids (BS) were separated from bitumen which was washed by toluene and centrifugated at 2000 rpm. The result of PAS FTIR and image of TEM showed that the structure of BS particles w... 详细信息

The ultra fine (hich was washed by toluene and centrifugated at 2000 rpm. The result of PAS FTIR and image of TEM showed that the structure of BS particles was smiliar to that of kaolinite clay. On the surface of BS, both toluene insoluble organic matter and structural Oh group are detected at the same time. The surface characteristics imparted a bi-wettable nature to the BS. As a result, the BS is able to stabilize fine water emulsion in the bitumen phase. The organic matter associated with BS is a possible factor of the fouling on catalyst and equipment.

关键词：超细无机粉末沥青甲苯离心法制备表面特征高岭石

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hydrodesulfurization and hydrodenitrogenation Kinetics of a heavy Gas Oil over NiMo/Al_2O_3 Catalysts

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高校化学工程学报 2005年第6期19卷 762-766页

作者： DUAN Ai-jun XU Chun-ming LIN Shi-xiong chung Keng h State Key Laboratory of heavy Oil Processing University of Petroleum Beijing 102249 China Syncrude Canada Ltd. 9421 - 17 Avenue Edmonton Alberta Canada T6N IH4

The kinetics of Athabasca bitumen derived heavy gas oil over NiMo/Al2O3 catalysts were studied in a JQ-II high-pressure microscale hydrotreator unit under different operation conditions, including temperature, pressure, h/O ratio and LhSV. The multi-parameter models of hydrodesulfurization and hydrodenitrogenation were proposed. The model parameters verify that the hDS and hDN reactions follow 1.5-order and 1.6-order kinetic rules, respectively. The kinetic activation energies of hDN and hDS over Com, hom1 and hom2 show that homemade catalysts exhibit higher activities in hDN than commercial catalyst. Using the multi-parameter kinetic model to predict the contents of sulfur and nitrogen in products is in good agreement with the experimental data.

关键词：加氢脱硫加氢脱氮动力学模型重气油 NiMo/Al2O3催化剂

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