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伟晶岩锂同位素研究进展及其对锂成矿过程的指示

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地质学报 2024年第5期98卷 1600-1614页

作者：陈洁李建康自然资源部成矿作用与资源评价重点实验室中国地质科学院矿产资源研究所北京100037 北京大学地球与空间科学院造山带与地壳演化教育部重点实验室北京100871

花岗伟晶岩是最重要的硬岩型锂资源来源,近年来前人应用锂同位素对伟晶岩成岩成矿过程开展较多的研究工作。本文在综述伟晶岩锂同位素研究进展的基础上,重点分析了伟晶岩的锂同位素在指示伟晶岩熔体源区、指示伟晶岩熔体分离、结晶和流... 详细信息

花岗伟晶岩是最重要的硬岩型锂资源来源,近年来前人应用锂同位素对伟晶岩成岩成矿过程开展较多的研究工作。本文在综述伟晶岩锂同位素研究进展的基础上,重点分析了伟晶岩的锂同位素在指示伟晶岩熔体源区、指示伟晶岩熔体分离、结晶和流体出溶中的研究思路,为揭示伟晶岩的锂成矿过程提供了启示。前人研究表明,伟晶岩熔体结晶分异和流体出溶过程均会产生较明显的锂同位素分馏:(1)结晶分异使残余伟晶岩熔体富集^(7)Li;(2)流体出溶使熔体富集^(6)Li;(3)扩散分馏使快速迁移的^(6)Li累积在熔体远端。全球伟晶岩(包括甲基卡伟晶岩)的Li含量与δ^(7)Li之间均有明显的负相关关系,甲基卡伟晶岩分异程度的增高与δ^(7)Li呈负相关关系。前人研究表明,高分异伟晶岩体系中锂同位素变轻可能是云母和锂辉石等富^(6)Li矿物的大量结晶、富^(7)Li流体出溶丢失或动力分馏作用等原因造成的。另一方面,不平衡结晶分异作用会产生显著的动力分馏,热液蚀变作用会产生强烈的低温分馏,这些过程产生的同位素分馏效应会模糊锂的来源信息,给同位素示踪带来困难。因此,伟晶岩锂同位素组成可能对于指示锂的来源作用有限,但可以较好地指示熔体结晶分异和流体出溶等地质过程,有助于揭示伟晶岩熔体-流体的演化过程,指示锂矿化机制。

关键词：锂同位素伟晶岩成矿作用结晶分异流体出溶

华北克拉通北缘显生宙四次底侵作用及其构造岩浆活动与深部背景

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地学前缘 2020年第4期27卷 124-134页

作者：邵济安周新华张履桥造山带与地壳演化教育部重点实验室北京大学地球与空间科学学院北京100871 中国科学院地质与地球物理研究所岩石圈演化国家重点实验室北京100029 中国科学院大学地球与行星科学学院北京100049 内蒙古地质研究所内蒙古呼和浩特010020

通过对华北克拉通北缘显生宙四次(P1,T3,J1,K1)底侵作用的研究,将华北克拉通的活化与岩石圈深部地幔物质的底辟体上涌联系起来。不同阶段底侵作用在岩浆来源深度、与构造格局关系、对地壳垂向增生的贡献、幔源物质脉动式上涌等方面的差... 详细信息

通过对华北克拉通北缘显生宙四次(P1,T3,J1,K1)底侵作用的研究,将华北克拉通的活化与岩石圈深部地幔物质的底辟体上涌联系起来。不同阶段底侵作用在岩浆来源深度、与构造格局关系、对地壳垂向增生的贡献、幔源物质脉动式上涌等方面的差异与变化,显示它们是一个分阶段连续热演化的深部过程,其动力学机制是深部的高热流和地幔物质的向上运移。对应于地幔物质上涌,必然存在同期的地幔底辟体隆起的岩石圈结构变化。通过对华北中生代盆山系形成机制的讨论,认为该区高分辨率面波层析成像所显示的地幔底辟体上涌的特征可以反映中生代岩石圈底侵作用的深部背景。

关键词：华北克拉通北缘显生宙底侵作用地幔底辟体上涌

华北地块沁水盆地下三叠统刘家沟组古地磁倾角浅化研究

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北京大学学报（自然科学版） 2018年第3期54卷 521-534页

作者：周庭红黄宝春贾舒斐梁雅伦张东海赵千张也闫永刚造山带与地壳演化教育部重点实验室北京大学地球与空间科学学院北京100871 岩石圈演化国家重点实验室中国科学院地质与地球物理研究所北京100029

对华北地块沁水盆地下三叠统刘家沟组红层样品进行系统的岩石磁学、磁组构和古地磁学研究,并用E/I(elongation/inclination)方法对其进行磁倾角浅化的识别与校正,获得刘家沟组红层磁倾角浅化因子f=0.6。岩石磁学结果显示,刘家沟组红层... 详细信息

对华北地块沁水盆地下三叠统刘家沟组红层样品进行系统的岩石磁学、磁组构和古地磁学研究,并用E/I(elongation/inclination)方法对其进行磁倾角浅化的识别与校正,获得刘家沟组红层磁倾角浅化因子f=0.6。岩石磁学结果显示,刘家沟组红层的主要载磁矿物是赤铁矿及磁铁矿,其磁组构具有典型的静水沉积特征。经地层校正后,15个采样点特征剩磁分量的平均方向为Ds=318.8°,Is=30.9°(α95=6.9°),对应的古地磁极为49.3°N,5.5°E(A95=6.7°),磁倾角浅化校正后的古地磁极为53.5°N,18.0°E。对包括本文数据在内的高质量的华北早三叠世古地磁极数据(Q≥4)进行平均,得到校正前的古地磁极为55.3°N,357.1°E(A95=5.5°),校正后的古地磁极为60.8°N,13.4°E(A95=5.8°)。经过古地磁倾角浅化校正,华北地块早三叠世的古纬度有约10°的明显提高,指示其东部早三叠世时与华南地块之间可能存在一定的纬度差,但是该纬度差很可能并不代表华北地块东部早三叠世时与华南地块尚未对接,而是指示华南地块下三叠统灰岩同样存在显著的磁倾角浅化现象。

关键词：华北地块磁倾角浅化早三叠世刘家沟组古地磁

Evaluating the Provenance of Metasedimentary Rocks of the Jiangxian Group from the Zhongtiao Mountain Using Whole-Rock Geochemistry and Detrital Zircon Hf Isotope

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Acta Geologica Sinica(English Edition) 2009年第3期83卷 550-561页

作者： LI Qiugen chen Xu LIU Shuwen WANG Zongqi zhou Yingkui ZHANG Jian WANG Tao The key laboratory of orogenic belts and crustal evolution MOE School of Earth and Space Sciences Peking University Beijing 100871 China Institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China Jinzhuang Production and Construction Coal Mine of Zaozhuang City Tengzhou 277522 Department of earth sciences University of Waterloo Waterloo Ontario Canada

In this study, whole-rock geochemical and Nd isotopic data, as well as detrital zircon Hf isotopes of Palaeoproterozoic metasedimentary rocks from the Jiangxian Group are presented to evaluate the characteristics of their provenance and the tectonic history. The major and trace element compositions are comparable to Post-Archean upper continental crust （PA-UCC）, but have slight enrichment in the LILE, with the exception of Cs and Sr, and a slight depletion in ferromagnesian elements, HFS elements, such as Nb and Ta, and some major elements, such as CaP and Na2O. The geochemical data reveal that the collected metasedimentary rocks have experienced intermediate source weathering with chemical index of alteration values ranging from 72 to 78, varying degrees of K- metasomatism, and post-depositional loss of Na, as well as negligible sorting, and are derived from the weathering of mostly felsic and non-mafic rocks. The selected Lu-Hf isotopic analysis on detrital zircon points to both the Trans-North china Orogen and Eastern Block of the north china craton as the most likely sources for the metasedimentary rocks of the Jiangxian Group. However, a contribution of detritus from the Western Block of the north china craton can be ruled out. The sediments were probably deposited in a back-arc basin within an active continental margin setting.

关键词： Paleoproterozoic metasediment geochemistry provenance tectonic setting JiangxianGroup north china craton

初论微陆块在中亚造山带演化中的作用:以锡林浩特微陆块为例

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地学前缘 2018年第4期25卷 1-10页

作者：邵济安田伟唐克东周新华造山带与地壳演化教育部重点实验室北京大学地球与空间科学学院北京100871 沈阳地质矿产研究所辽宁沈阳110034 中国科学院地质与地球物理研究所岩石圈演化国家重点实验室北京100029

镶嵌状拼合在中亚造山带众多的古老陆壳块体或微陆块,是前期古亚洲洋的特征之一。本文重点讨论的是锡林浩特微陆块,组成微陆块基底的锡林郭勒杂岩既经历了早古生代的构造热事件,也保留了前寒武纪的古老锆石。当晚古生代(C2—P1)造山带... 详细信息

镶嵌状拼合在中亚造山带众多的古老陆壳块体或微陆块,是前期古亚洲洋的特征之一。本文重点讨论的是锡林浩特微陆块,组成微陆块基底的锡林郭勒杂岩既经历了早古生代的构造热事件,也保留了前寒武纪的古老锆石。当晚古生代(C2—P1)造山带遭受到强烈的伸展变形和底侵作用时,锡林浩特微陆块又起到支柱作用:当微陆块的南、北边缘发生裂谷活动时,微陆块内部却保持了稳定的滨-浅海相沉积环境;在微陆块受到来自上地幔的底侵作用时,微陆块通过伸展背景下非造山的双峰式岩浆活动,及其与微陆块再次重熔有关的碱性花岗岩侵位,使得陆壳发生进一步的垂向增生和固结,保持了造山带的构造格局。本文讨论的正是在底侵作用的深部背景下认识该区在晚石炭世出现的一些独特的地质现象。

关键词：微陆块中亚造山带晚古生代固结底侵作用

Late Mesozoic rifting and its deep dynamic mechanisms in the central Sulu orogenic belt: Records from Lingshan Island

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Science china earth sciences 2022年第9期65卷 1751-1771页

作者： Tengfei zhou Yaoqi zhou Nina SФAGER Paul Martin HOLM Zhenkai ZHANG Jun WANG Zhao LIANG Hongyu MU Yanjun chenG Feifei LIU Miao WANG Yue ZHANG Hui ZHANG Yangjian GU Shihui DONG Hanjie ZHAO Manjie LI Yang chen Yanzi LIU school of Geosciences China University of Petroleum(East China)Qingdao 266580China Department of Geosciences and Natural Resource Management University of CopenhagenCopenhagen-K 1350Denmark Shandong Provincial key laboratory of Deep Oil&Gas China University of Petroleum(East China)Qingdao 266580China Shaanxi Center of Mineral Geological Survey Shaanxi Institute of Geological SurveyXi'an 710068China school of earth sciences Yunnan UniversityKunming 650500China Department of Science and Technology Hebei GEO UniversityShijiazhuang 050031China College of earth Science and Engineering Shandong University of Science and TechnologyQingdao 266590China school of Architectural Engineering Binzhou UniversityBinzhou 256500China Research Institute of Petroleum Exploration and Development Shengli Oilfield CompanySINOPECDongying 257015China key laboratory of Geological Safety of Coastal Urban Underground space Ministry of Natural ResourcesQingdao Geo-Engineering Surveying InstituteQingdao 266101China

The Lingshan Island scientific drill confirms that two episodes(Laiyang period and Qingshan period) of rifting developed in the central Sulu orogenic belt(SOB) in Late Mesozoic. With a set of methods including fieldwork, drilling, core logging, zircon U-Pb dating and whole rock geochemistry applied, the age, the depositional sequence and the deep dynamic mechanisms of rift evolution were unraveled. The stratigraphic sequence of the Laiyang-Qingshan Groups on Lingshan Island was composed of two different rifting sequences:(1) Laiyang Group(147–125 Ma), which consists of deep-water gravity flow deposits with interlayers of intermediate volcanic rocks;and(2) Lower Qingshan Group(125–119 Ma), which unconformably overlies the former sequence and contains subaerial volcanic deposits and terrestrial deposits. The tectonic environment changed during the evolution of these two episodes of rifting: the rift was in a NNW-SSE extensional environment in the Laiyang period and showed the typical passive rifting character that “lithospheric extension and rifting preceded volcanism”. The passive rifting period was ended by a short WNW-ESE compression at about 125 Ma. After that, the tectonic environment transferred to a strong NW-SE extensional environment and the rifting evolved into a volcanic arc basin in the Qingshan period. The igneous rocks are shoshonitic to high-K calc-alkaline trachyandesites to trachytes with a few intercalated lamprophyres and a *** geochemical characteristics of the igneous rocks indicate that they are mantle-derived melts with a metasomatized mantle source and/or crustal contamination. In addition, an increased thinning of the lithosphere happened during the rifting *** low-angle subduction of the Paleo-Pacific plate in the Jurassic weakened the thickened SOB lithospheric mantle. The rollback of the subducting plate started in late Jurassic to early Cretaceous, and the SOB lithospheric mantle was delaminated synchronously because of t

关键词： Sulu orogenic belt Lingshan Island Late Mesozoic Rifting Slab subduction Basin dynamics

碰撞后岩浆作用与陆壳生长:以柴北缘超高压变质带为例

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地球科学 2023年第12期48卷 4481-4494页

作者：周辰傲宋述光造山带与地壳演化教育部重点实验室北京大学地球与空间科学学院北京100871

碰撞后岩浆活动对于了解造山带垮塌和去根过程及陆壳生长具有重要意义.总结了柴北缘超高压变质带中形成于400~360 Ma的碰撞后花岗岩-辉长岩侵入体和镁铁质岩脉的年代学和地球化学特征.其中,花岗岩侵入体具有典型的I-型花岗岩特征,形成... 详细信息

碰撞后岩浆活动对于了解造山带垮塌和去根过程及陆壳生长具有重要意义.总结了柴北缘超高压变质带中形成于400~360 Ma的碰撞后花岗岩-辉长岩侵入体和镁铁质岩脉的年代学和地球化学特征.其中,花岗岩侵入体具有典型的I-型花岗岩特征,形成于壳幔相互作用的岩浆混合.来自地幔的镁铁质岩脉可以划分为两组:(1)392~375 Ma中基性岩脉;(2)约360Ma超基性岩脉.其地球化学特征表明,镁铁质岩脉的微量元素和同位素随形成时间的变新而逐渐亏损,地幔源区从岩石圈地幔变为软流圈地幔.这种源自地幔的镁铁质岩浆活动是碰撞后岩浆活动开始和造山带垮塌的关键指标.结合碰撞后岩浆作用的特征,提出了一个地球动力学模型来解释柴北缘约35百万年(Ma)的造山带垮塌去根过程,在395~375 Ma发生缓慢的岩石圈地幔侵蚀,360 Ma前岩石圈发生拆沉作用,岩石圈地幔垮塌,同时软流圈地幔上升.地幔岩浆的加入表明碰撞后阶段是大陆生长的重要时期.

关键词：大陆碰撞碰撞后岩浆作用造山带垮塌拆沉作用陆壳生长岩石学地球化学

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对内蒙古贺根山蛇绿岩的新认识

岩石学报 2019年第9期35卷 2864-2872页

作者：邵济安张丽莉周新华张履桥唐克东造山带与地壳演化教育部重点实验室北京大学地球与空间科学学院北京100871 中国科学院地质与地球物理研究所中国科学院油气资源研究重点实验室北京100029 中国科学院地质与地球物理研究所岩石圈演化国家重点实验室北京100029 中国科学院大学地球与行星科学学院北京100049 内蒙古地质研究所呼和浩特010020 沈阳地质矿产研究所沈阳110034

本文将华北板块和中亚-蒙古陆块缝合带中前人划分的"贺根山蛇绿岩套"划分为三个不同组分、不同成因的岩系:以含金刚石和其它幔源矿物的变质橄榄岩系为主,包括堆晶杂岩在内的镁铁-超镁铁岩系;含放射虫硅质岩夹层的玄武岩系;上覆的火山-... 详细信息

本文将华北板块和中亚-蒙古陆块缝合带中前人划分的"贺根山蛇绿岩套"划分为三个不同组分、不同成因的岩系:以含金刚石和其它幔源矿物的变质橄榄岩系为主,包括堆晶杂岩在内的镁铁-超镁铁岩系;含放射虫硅质岩夹层的玄武岩系;上覆的火山-沉积岩系。根据地质学与年代学证据,可以认为蛇绿岩形成于晚泥盆-早石炭世。在此基础上,本文重点讨论了三个问题:(1)结合不同尺度的构造研究,将含金刚石等幔源矿物的超镁铁岩看作源自地幔转换带的幔源熔-流体,在软流圈底辟体上涌的背景下持续上升,在板块对接的过程中构造侵位的岩石。据此,对现有的蛇绿岩概念提出了补充;同时提出贺根山在板块汇聚过程未发生明显的俯冲和碰撞,而是通过拼贴的方式连为一体的;(2)贺根山具有OIB特征的玄武岩与朝克山MORB的对比,表明不同来源的多地块的存在及板块闭合时间的差异均反映了陆间小洋盆的特征;(3)将上覆在玄武岩系之上的火山沉积岩系看作洋盆最后充填的产物,反映了古亚洲洋闭合过程中小洋盆直接从洋壳转化为陆壳的过程,最后从时空角度进一步讨论了小洋盆闭合的特征。

关键词：缝合带镁铁-超镁铁岩玄武岩上覆岩系小洋盆闭合贺根山

REE and C-O Isotopic Geochemistry of Calcites from the World-class Huize Pb-Zn Deposits,Yunnan,china:Implications for the Ore Genesis

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Acta Geologica Sinica(English Edition) 2010年第3期84卷 597-613页

作者： HUANG Zhilong LI Xiaobiao zhou Meifu LI Wenbo JIN Zhongguo State key laboratory of Ore Deposit Geochemistry Institute of Geochemistry the Chinese Academy of Sciences Guiyang 550002 China Department of earth sciences University ofHong Kong Hong Kong China Graduate school the Chinese Academy of Sciences Beijing 100039 China MOE key laboratory of orogenic belts and crustal evolution Peking University Beijing 100871 China

The world-class Huize Pb-Zn deposits of Yunnan province,in southwestern china,located in the center of the Sichuan-Yunnan-Guizhou Pb-Zn polymetallic metallogenic province,has Pb＋Zn reserves of more than 5 million tons at Pb＋Zn grade of higher than 25%and contains abundant associated metals,such as Ag,Ge,Cd,and *** deposits are hosted in the Lower Carboniferous carbonate strata and the Permian Emeishan basalts which distributed in the northern and southwestern parts of the *** is the only gangue mineral in the primary ores of the deposits and can be classified into three types,namely lumpy,patch and vein calcites in accordance with their *** is not intercalated contact between calcite and ore minerals and among the three types of calcite,indicating that they are the same ore-forming age with different stages and its forming sequence is from lumpy to patch to vein calcites. This paper presents the rare earth element（REE） and C-O isotopic compositions of calcites in the Huize Pb-Zn *** lumpy to patch to vein calcites,REE contents decrease as LREE/ HREE ratios *** chondrite-normalized REE patterns of the three types of calcites are characterized by LREE-rich shaped,in which the lumpy calcite shows（La）_N〈（Ce）_N〈（Pr）_N≈（Nd）_N with Eu/Eu~＊〈1.the patch calcite has（La）_N〈（Ce）_N〈（Pr）_N≈（Nd）_N with Eu/Eu~＊〉1,and the vein calcite displays（La）_N〉（Ce）_N〉（Pr）_N〉（Nd）_N with Eu/Eu~＊〉*** REE geochemistry of the three types of calcite is different from those of the strata of various age and Permian Emeishan basalt exposed in the ***δ^（13） C_（PDb） andδ^（18）O_（Smow） values of the three types of calcites vary from-3.5‰to-2.1‰and 16.7‰to 18.6‰,respectively,falling within a small field between primary mantle and marine carbonate in theδ^（13）C_（PDb） vsδ^（18）O_（Smow） diagram. Various lines of evidence demonstrate that the three types of calcites in the deposits are produced from the same source with different *** ore-forming f

关键词： gangue calcite REE geochemistry C-O isotope ore-forming fluid Huize Pb-Zn deposits