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In situ generation of oxyanions-decorated cobalt(nickel)oxyhydroxide catalyst with high corrosion resistance for stable and efficient seawater oxidation

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Journal of Energy Chemistry 2024年第7期94卷 508-516页

作者： Fengting Luo Pei Yu Jueting xiang Junjie Jiang Shijian chen Chongqing Key Laboratory of Interface Physics in Energy Conversion College of PhysicsChongqing UniversityChongqing 401331China Center of Modern Physics Institute for Smart City of Chongqing University in LiyangLiyang 213300JiangsuChina

The development of efficient and robust anode materials for stable alkaline seawater electrolysis is severely limited by chlorine evolution reaction and chloride ***,the sulfur-doped cobalt-nickel bimetallic phosphides(CoNiPS)are specifically designed as a pre-catalyst for navigating a surface reconstruction to fabricate the anions(PO^(3-)_(4) and SO^(2-)_(4))-decorated Co(Ni)OOH catalyst(R-CoNiPS)with exceptional durability and high activity for stable alkaline seawater oxidation(ASO).Various experiment techniques together with theoretical simulations both demonstrate that the in situ-generated PO^(3-)_(4) and SO^(2-)_(4) anions on catalyst surface can improve the oxygen evolution reaction(OER)activity,regulating and stabilizing the catalytic active species Co(Ni)OOH,as well as make a critical role in inhibiting the adsorp-tion of chloride ions and extending the service life of ***,this R-CoNiPS electrode exhi-bits superb OER activity toward AsO and stands out among the non-precious ASO electrocatalysts reported recently,requiring low overpotentials of 420 and 440 mV to attain large current densities of 500 and 1000 mA cm^(-2) in an alkaline natural seawater electrolyte,***,the catalyst displays a negligible chloride corrosion at room temperature during ASO operation(>200 h)at 500 mA cm^(-2).This work opens up a new viewpoint for designing high-activity and durable electrocata-lystsforseawaterelectrolysis.

关键词： Seawater electrolysis Anions Oxygen evolution reaction Chloride corrosion

Electronic structural engineering of bimetallic Bi-Cu alloying nanosheet for highly-efficient CO_(2) electroreduction and Zn-CO_(2) batteries

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Nano Research 2024年第5期17卷 3684-3692页

作者： Wenbo Wu Jiaye Zhu Yun Tong Shuangfei xiang Pengzuo chen School of Chemistry and Chemical Engineering Key Laboratory of Surface and Interface Science of Polymer Materials of Zhejiang ProvinceZhejiang Sci-Tech UniversityHangzhou 310018China

Regulating the electronic structure of Bi-based materials by alloying engineering is promising to promote the electrocatalytic activity,but it remains some challenges to be *** this study,a facile electrochemical co-deposition strategy is developed to synthesize the bimetallic Bi_(9)Cu_(1) alloy nanosheet on carbon cloth(Bi_(9)Cu_(1)/CC),which represents a novel self-supporting electrode for the electrocatalytic carbon dioxide(CO_(2))reduction reaction(CO_(2)RR).The Bi_(9)Cu_(1)/CC catalyst has achieved a remarkable catalytic performance with high Faradaic efficiencies(FE)of over 90%for formate at wide potentials from-0.7 to-1.2 V *** hydrogen electrode(RHE).Moreover,the reversible Zn-CO_(2) battery can be driven by Bi_(9)Cu_(1)/CC cathode with a largest power density of 1.4 mW·cm^(-2),and superior operating *** systematic characterizations and electrochemical results confirm that the improved catalytic active sites,the enhanced mass/charge transport and the optimal reaction kinetics of Bi nanosheet are realized for CO_(2)RR by Cu *** situ attenuated total reflection infrared(ATR-IR)result confirms the bimetallic Bi-Cu active sites prefer to follow the^(*)OCHO conversion *** density functional theory(DFT)calculations suggest that the Cu alloying contributes to the increased density of states near the Fermi surface of Bi and the optimized adsorption of^(*)OCHO intermediates on the Bi sites,resulting in the excellent catalytic performance.

关键词： electronic regulation bismuth nanosheet copper alloying CO_(2)electroreduction Zn-CO_(2)batteries

Single-atom Co alloyed Ru for electrocatalytic nitrite reduction to ammonia

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Nano Research 2024年第5期17卷 3660-3666页

作者： Fuzhou Wang Jiaqi xiang Guike Zhang Kai chen Ke Chu School of Materials Science and Engineering Lanzhou Jiaotong UniversityLanzhou 730070China

Electrochemical converting NO_(2)^(-)into NH_(3)(NO_(2)RR)holds an enormous prospect to attain efficient NH_(3) electrosynthesis and polluted NO_(2)^(-)***,we report single-atom Co alloyed Ru(Co_(1)Ru)as an efficient and durable NO_(2)RR *** experimental and theoretical investigations reveal that single-atom Co alloying of Ru enables the construction of Co_(1)-Ru heteronuclear active sites to synergistically promote NO_(2)^(-)activation/hydrogenation while suppressing the competitive H_(2) evolution,rendering the greatly enhanced activity and selectivity of Co_(1)Ru towards the NO_(2)***,Co_(1)Ru assembled within a flow cell exhibits an impressive NH_(3) yield rate of 2379.2μmol·h^(-1)·cm^(-2) with an NH_(3)-Faradaic efficiency of 92%at a high current density of 415.9 mA·cm^(-2),which is among the highest NO_(2)RR performances reported to date.

关键词： electrochemical converting NO_(2)-into NH3 single-atom alloys theoretical computations industrial-level current density

From atomistic modeling to materials design:computation-driven material development in lithium-ion batteries

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Science China Chemistry 2024年第1期67卷 276-290页

作者： xiangrong Li xiang chen Qiang Bai Yifei Mo Yizhou Zhu Research Center for Industries of the Future and School of Engineering Westlake UniversityHangzhou 310030China Department of Chemical Engineering Tsinghua UniversityBeijing 100084China College of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China Department of Materials Science and Engineering University of MarylandCollege Park 20742United States

As an advanced energy storage system,lithium-ion batteries play an essential role in modern *** their ubiquitous success,there is a great demand for continuous improvements of the battery performance,including higher energy density,lower safety risk,longer cycling life,and lower *** performance improvement requires the design and development of novel electrode and electrolyte materials that exhibit desirable properties and satisfy strict *** modeling can provide a unique perspective to fundamentally understand and rationally design battery *** this paper,we review a few recent successful examples of computation-driven discovery and design in electrode and electrolyte ***,we highlight how atomistic modeling can reveal the underlying mechanisms,predict the important properties,and guide the design and engineering of electrode and electrolyte *** have a conclusion with a discussion of the unique capability of atomistic modeling in battery material development and provide a perspective on future challenges and directions for computation-driven battery material developments.

关键词： materials design computation modeling batteries electrolyte electrode

Microstructure Characteristics,Texture Evolution and Mechanical Properties of Al-Mg-Si-Mn-xCu Alloys via Extrusion and Heat Treatment

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Acta Metallurgica Sinica(English Letters) 2024年第9期37卷 1501-1522页

作者： Zulai Li Yingxing Zhang Junlei Zhang xiang chen Suokun chen Lujian Cui Shengjie Han College of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China College of Materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002China National and Local Joint Engineering Laboratory of Advanced Metal Solidification Forming and Equipment Technology Kunming University of Science and TechnologyKunming 650093China Chinalco International Al Application Engineering Co. Ltd.Beijing 100089China

In this work,the impact of extrusion and post-extrusion heat treatment(T6)on the microstructure and mechanical properties of the Al-1.2Mg-0.8Si-0.5Mn alloy with different Cu contents(0,0.6,1.3 and 2.0 wt%)was *** characterization showed that all extruded alloys exhibited elongated grain structure with an average grain size of~4.8μ*** dominant texture components were deformation texture(A*,Copper and P texture),while the proportion of random texture initially increased and then decreased with increasing Cu *** T6 treatment,the grain size of the four alloys increased significantly,but the growth trend decreased with increasing Cu content,and the textures transformed into recrystallized textures(Cube,A and Goss texture).Tensile testing revealed that the designed T6 alloys with 2.0%Cu content exhibited an excellent strength-ductility balance,i.e.,a yield strength of 342.9 MPa,an ultimate tensile strength of 424.8 MPa and an elongation of 15.9%.The enhanced strength was mainly attributed to fine grain strengthening,solid solution strengthening and aging strengthening *** superior ductility was due to the pinning effect of fine precipitates and high dislocation accommodation capacity caused by heat treatment.

关键词： Al-Mg-Si-Mn alloy Cu addition Microstructure texture Mechanical Properties

Yttrium‐and nitrogen‐doped NiCo phosphide nanosheets for high‐efficiency water electrolysis

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Carbon Energy 2024年第8期6卷 214-231页

作者： Guangliang chen Huiyang xiang Yingchun Guo Jun Huang Wei chen Zhuoyi chen Tongtong Li Kostya(Ken)Ostrikov Department of Materials Engineering Huzhou UniversityHuzhouChina School of Materials Science and Engineering Zhejiang Sci‐Tech UniversityHangzhouChina School of Physics and Electronic Information Gannan Normal UniversityGanzhouChina School of Chemistry and Physics Centre for Materials ScienceCentre for Clean Energy Technologies and PracticesCentre for Waste−Free WorldQueensland University of Technology(QUT)BrisbaneQueenslandAustralia

Engineering high‐performance and low‐cost bifunctional catalysts for H_(2)(hydrogen evolution reaction[HER])and O_(2)(oxygen evolution reaction[OER])evolution under industrial electrocatalytic conditions remains ***,for the first time,we use the stronger electronegativity of a rare‐Earth yttrium ion(Y^(3+))to induce in situ NiCo‐layered double‐hydroxide nanosheets from NiCo foam(NCF)treated by a dielectric barrier discharge plasma NCF(PNCF),and then obtain nitrogen‐doped YNiCo phosphide(N‐YNiCoP/PNCF)after the phosphating process using radiofrequency plasma in *** obtained NYNiCoP/PNCF has a large specific surface area,rich heterointerfaces,and an optimized electronic structure,inducing high electrocatalytic activity in HER(331mV vs.2000mA cm^(−2))and OER(464mV vs.2000mA cm^(−2))reactions in 1MKOH electrolyte.X‐ray absorption spectroscopy and density functional theory quantum chemistry calculations reveal that the coordination number of CoNi decreased with the incorporation of Y atoms,which induce much shorter bonds of Ni and Co ions and promote long‐term stability of N‐YNiCoP in HER and OER under the simulated industrial ***,the CoN‐YP_(5)heterointerface formed by plasma N‐doping is the active center for overall water *** work expands the applications of rare‐Earth elements in engineering bifunctional electrocatalysts and provides a new avenue for designing highperformance transition‐metal‐based catalysts in the renewable energy field.

关键词： overall water splitting plasma etching plasma N‐doping rare‐earth electrocatalyst yttrium incorporation

Ceramic-based meta-material absorber with high-temperature stability

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Rare Metals 2024年第9期43卷 4433-4440页

作者： Xing-cong chen Wei-Jia Luo Run-Ni Zhao Yong-Zheng Wen Ji Zhou State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua University

With the continuous exploration of uncharted and extreme environments,enhanced temperature robustness of passive devices has become particularly *** this study,a ceramic-based meta-material absorber with exceptional temperature stability is developed using a fusion design approach that combines rare metal-based tungsten bronze structural ceramics and ***,the absorbance of the meta-material array based on Mie resonance exceeds 49.0%in both waveguides and free space,approaching the theoretical *** to impedance analysis,the absorption performance can be distinctly correlated with the dielectric loss （Q_f）.Notably,the high-temperature robustness is verified to still be effective at 400℃.These advancements in our design allow for the use of monolithic materials in fabricating temperature-stable perfect absorbers,providing greater freedom in the dielectric performance and expanding their potential applications,including in space exploration and 5G millimeter-wave scenarios.

关键词： Meta-material absorber Microwave absorption Miniaturization Rare metal-based ceramics Temperature robustness

Optical manipulation of ratio-designable Janus microspheres

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Photonics Research 2024年第6期12卷 1239-1249页

作者： YULU chen cong ZHAI XIAOQING GAO HAN WANG ZUZENG LIN XIAOWEI ZHOU CHUNGUANG HU State Key Laboratory of Precision Measuring Technology and Instruments Tianjin UniversityTianjin 300072China

Angular optical trapping based on Janus microspheres has been proven to be a novel method to achieve controllable *** contrast to natural birefringent crystals,Janus microspheres are chemically synthesized of two compositions with different refractive ***,their structures can be artificially regulated,which brings excellent potential for fine and multi-degree-of-freedom manipulation in the optical ***,it is a considerable challenge to model the interaction of heterogeneous particles with the optical field,and there has also been no experimental study on the optical manipulation of microspheres with such designable refractive index *** the specific structure affects the kinematic properties of Janus microspheres remains ***,we report systematic research on the optical trapping and rotating of various ratio-designable Janus *** employ an efficient T-matrix method to rapidly calculate the optical force and torque on Janus microspheres to obtain their trapped postures and rotational characteristics in the optical *** have developed a robust microfluidic-based scheme to prepare Janus *** experimental results demonstrate that within a specific ratio range,the rotation radii of microspheres vary linearly and the orientations of microsphere are always aligned with the light polarization *** is of great importance in guiding the design of Janus *** their orientations flip at a particular ratio,all consistent with the *** work provides a reliable theoretical analysis and experimental strategy for studying the interaction of heterogeneous particles with the optical field and further expands the diverse manipulation capabilities of optical tweezers.

关键词： polarization ratio refractive

Intelligent overheating fault diagnosis for overhead transmission line using semantic segmentation

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High Voltage 2024年第2期9卷 309-318页

作者： xiangyu Yang Youping Tu Zhikang Yuan Zhong Zheng Geng chen cong Wang Yan Xu Beijing Key Laboratory of High Voltage and EMC North China Electric Power UniversityBeijingChina College of Electronic and Information Engineering Tongji UniversityShanghaiChina

The strain clamps and leading wires are important components that connect conductors on overhead transmission lines and conduct *** operation,poor contact between these components can cause abnormal overheating,leading to electric failures and threatening power system ***,the use of unmanned aerial vehicles equipped with infrared thermal imagers for strain clamp and leading wire maintenance has become increasingly *** learning-based image recognition shows promising prospects for intelligent fault diagnosis of overheating faults.A pre-treatment method is proposed based on dynamic histogram equalisation to enhance the contrast of infrared *** DeepLab v3+network,loss function,and existing networks with different backbones are *** DeepLab v3+network with ResNet101 and convolutional block attention module added,and the Focal Loss function achieved the highest performance with an average pixel accuracy of 0.614,an average intersection over union(AIoU)of 0.567,an F1 score of 0.644,and a frequency weighted intersection over union of 0.594 on the test *** optimised Atrous rates has increased the AIoU by 12.91%.Moreover,an intelligent diagnosis scheme for evaluating the defect state of the strain clamps and leading wires is proposed and which achieves a diagnostic accuracy of 91.0%.

关键词： union fault diagnosis