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Nano Research 2024年第6期17卷 4844-4849页

作者： Chang Liu Zongnan Wei Minna cao rong cao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of Sciences Beijing 100049China Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China

The development of effective and stable electrocatalysts for the hydrogen evolution reaction(HER)in acidic electrolytes is a significant *** this work,homogeneous Pt nanodendrites(Pt NDs)with a PtIr shell were successfully synthesized by a two-step wet chemical *** open three-dimensional(3D)dendritic structure exhibited exceptional electrocatalytic characteristics,exposing as many active sites as ***,by alloying Ir with Pt on the surface,catalytic activity was greatly enhanced while ensuring extremely high *** surface-enriched platinum nanodendritic catalysts(Pt@PtIr NDs)outperformed the control samples and the commercial *** acidic HER test,Pt@PtIr NDs had a lower overpotential(22 mV)than Pt NDs(26 mV)and commercial Pt/C(31 mV)at 10 mA/cm^(2),and the activity of Pt@PtIr NDs remained consistent even after undergoing a continuous durability test for at least 168 h,which was much superior to the performance of commercial Pt/C(10 h)under identical test *** study revealed that the application of 3D Pt dendritic metal alloys may offer a chance for the development of enhanced electrocatalysts in acidic HER.

关键词： Pt nanodendrites iridium high stability hydrogen evolution reaction alloy

Taphonomy and Paleoecology of Lycoptera: A Case Study from the Lower Jehol Group in Western Liaoning, Northeastern China

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Journal of Earth Science 2024年第3期35卷 737-746页

作者： Zhongwu Lan rong cao Shujing Zhang State Key Laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China State Key Laboratory of Palaeobiology and Stratigraphy Nanjing Institute of Geology and PalaeontologyChinese Academy of SciencesNanjing 210008China State Key Laboratory of Geological Processes and Mineral Resources China University of GeosciencesWuhan 430078China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China Department of Geology Trinity CollegeDublin 999015Ireland

Taphonomy and paleoecology(biological behavior)of the Early Cretaceous fish fossils are poorly *** study reports for the first time a detailed taphonomical and paleoecological study on Lycoptera in the Mesozoic strata of western Liaoning Province,NE *** XRD analysis shows that gismondine is the dominant clay minerals that could have contributed to the preservation of Lycoptera fossils and microbial mat fragments in the fossil-bearing *** may have formed under volcanism-related hydrothermal regime that was transformed from crystal and lithic ***μ-XRF imaging analysis shows a dominant chemical composition of Al,Si,P,S,Rh,K,Ca,Ti,C,Cr,Mn,Fe,Ni,among which P,Ca,C and S are enriched in the fish skeleton in comparison to the *** suggests a dominant apatite composition for the fish *** influence did not smear off these organic signals probably because of protection of *** coexistance of C and S with Ni is assumed to represent recovered primary productivity following volcanic explosions and toxic gas *** head of juvenile fish stays close to the body of adult *** further discoveries,such phenomenon is interpreted to suggest that adult fish actively protected juvenile fish in the presence of environmental pressures such as anoxia and deterioration of water quality induced by *** acidification and hypoxia in association with volcanism created a harmful environment causing mass extinction of *** adult Lycoptera protected their juveniles by its body at the moment before *** biological behavior will be increasingly reported given the wide occurrence of Lycoptera in Mesozoic strata.

关键词： Lycoptera taphonomy paleoecology fish Jehol Group NE China.

Sub-10-nm-sized Au@AuxIr1-x metal-core/alloy-shell nanoparticles as highly durable catalysts for acidic water splitting

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National Science Review 2024年第4期11卷 130-140页

作者： Huimin Wang Zhe-ning Chen Yuanyuan Wang Dongshuang Wu Minna cao Fanfei Sun rong cao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences University of Chinese Academy of Sciences School of Materials Science and Engineering Nanyang Technological University Shanghai Synchrotron Radiation Facility Shanghai Institute of Applied Physics Chinese Academy of Sciences Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China

The absence of efficient and durable catalysts for oxygen evolution reaction（OER） is the main obstacle to hydrogen production through water splitting in an acidic ele ***,we report a controllable synthesis method of surface IrOxwith changing Au/Ir compositions by constructing a range of sub-10-nm-sized core-shell nanocatalysts composed of an Au core and AuxIr1-xalloy *** particular,Au@Au0.43Ir0.57exhibits 4.5 times higher intrinsic OER activity than that of the commercial Ir/*** X-ray-based spectroscopies,electron microscopy and density functional theory calculations revealed a balanced binding of reaction intermediates with enhanced *** water-splitting cell using a load of 0.02 mgIr/cm2of Au@Au0.43Ir0.57as both anode and cathode can reach 10 mA/cm2at 1.52 V and maintain activity for at least194 h,which is better than the cell using the commercial couple Ir/C‖Pt/C（1.63 V,0.2 h）.

关键词： controllable synthesis of surface IrOx oxygen evolution reaction acidic water splitting catalytic stability transition metal catalysts

Residual levels and health risk assessment of trace metals in Chinese resident diet

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Journal of Environmental Sciences 2024年第2期136卷 451-459页

作者： Yubing Dai Shuai Sun rong cao Haijun Zhang Jiping Chen Ningbo Geng CAS Key Laboratory of Separation Science for Analytical Chemistry Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Shenyang Pharmaceutical University Shenyang 110016China University of Chinese Academy of Sciences Beijing 100049China

Large-scale metal contamination across the food web is an intractable problem due to increasing pollutant emissions,atmospheric transport,and dry and wet deposition of *** present study focus on several trace metals that are rarely studied but have special toxicity,including tin(Sn),antimony(Sb),gold(Au),hafnium(Hf),palladium(Pd),platinum(Pt),ruthenium(Ru),tellurium(Te)and iridium(Ir).We investigated trace metals residues and distribution characteristics,and further evaluated the potential health risks from major daily food intakes in 33 cities in ***,Sb,Ir,Hf,and Au were frequently detected in food samples with the concentrations ranged from ND(not detected)to 24.78μg/kg ww(wet weight).Eggs exhibited the highest residual level of all detected metals(13.70±14.70μg/kg ww in sum),while the lowest concentrations were observed in vegetables(0.53±0.17μg/kg ww in sum).Sn accounting for more than 50%of the total trace metals concentration in both terrestrial and aquatic animal origin *** terrestrial plant origin foods,Sn and Ir were the most abundant *** and Au were the most abundant elements in egg *** addition,Sb and Ir showed a clear trophic dilution effect in terrestrial environments,while in aquatic ecosystems,Sn,Hf,and Au exhibited obvious trophic amplification *** calculated average estimated daily intake(EDI)via food consumption in five regions of China was 0.09μg/(kg·day),implying the health risk of aforementioned elements was acceptable.

关键词： Trace metals Accumulation characteristics Dietary exposure Estimated daily intake(EDI)

Electrocatalysts with atomic-level site for nitrate reduction to ammonia

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Journal of Energy Chemistry 2024年第9期96卷 642-668页

作者： Shuai Yin rong cao Yifan Han Jiachangli Shang Jing Zhang Wei Jiang Guigao Liu National Special Superfine Powder Engineering Research Center School of Chemistry and Chemical EngineeringNanjing University of Science and TechnologyNanjing 210094JiangsuChina School of Pharmacy Jiangsu UniversityZhenjiang 212013JiangsuChina

Ammonia(NH_(3))is an important raw material for modern agriculture and industry,being widely demanded to sustain the sustainable development of modern ***,the industrial production methods of NH_(3),such as the traditional Haber-Bosch process,have drawbacks including high energy consumption and significant carbon dioxide *** recent years,the electrocatalytic nitrate reduction reaction(NO_(3)RR)powered by intermittent renewable energy sources has gradually become a multidisciplinary research hotspot,as it allows for the efficient synthesis of NH_(3)under mild *** this review,we focus on the research of electrocatalysts with atomic-level site,which have attracted attention due to their extremely high atomic utilization efficiency and unique structural characteristics in the field of NO_(3)***,we introduce the mechanism of nitrate reduction for ammonia synthesis and discuss the in-situ characterization techniques related to the mechanism ***,we review the progress of the electrocatalysts with atomic-level site for nitrate reduction and explore the structure-activity relationship to guide the rational design of efficient ***,the conclusions of this review and the challenges and prospective of this promising field are presented.

关键词： Ammonia synthesis Nitrate reduction Electrocatalysts with atomic-level site Reaction mechanism In-situ characterization techniques

Development of SV2A Ligands for Epilepsy Treatment:A Review of Levetiracetam,Brivaracetam,and Padsevonil

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Neuroscience Bulletin 2024年第5期40卷 594-608页

作者： Peng-Peng Wu Bi-rong cao Fu-Yun Tian Zhao-Bing Gao Center for Neurological and Psychiatric Research and Drug Discovery Shanghai Institute of Materia MedicaChinese Academy of SciencesShanghai201203China University of Chinese Academy of Sciences Beijing100049China Zhongshan Institute for Drug Discovery Shanghai Institute of Materia MedicaChinese Academy of SciencesZhongshan528400China

Epilepsy is a common neurological disorder that is primarily treated with antiseizure medications(ASMs).Although dozens of ASMs are available in the clinic,approximately 30%of epileptic patients have medically refractory seizures;other limitations in most traditional ASMs include poor tolerability and drug-drug ***,there is an urgent need to develop alternative ***(LEV)is a first-line ASM that is well tolerated,has promising efficacy,and has little drug-drug *** it is widely accepted that LEV acts through a unique therapeutic target synaptic vesicle protein(SV)2A,the molecular basis of its action remains *** so,the next-generation SV2A ligands against epilepsy based on the structure of LEV have achieved clinical *** review highlights the research and development(R&D)process of LEV and its analogs,brivaracetam and padsevonil,to provide ideas and experience for the R&D of novel ASMs.

关键词： Levetiracetam Epilepsy Antiseizure medications Synaptic vesicle protein 2A Brivaracetam Padsevonil

Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH_(2)-UiO-66 core-shell nanostructures

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Chinese Chemical Letters 2024年第4期35卷 506-510页

作者： Yuan Zhang Shenghao Gong A.R.Mahammed Shaheer rong cao Tianfu Liu Fujian Science Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350007China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China

MOF-based core-shell structures with high surface area, abundant active sites, and broad absorption bands are viable alternatives to traditional single-component photocatalysts. In this report, we describe the design and construction of delicate Ag nanowires@NH_(2)-UiO-66 with a core-shell structure for use as photocatalysts in imine synthesis under light. The optimized composites exhibited 80% imine production, which was higher than both MOF and Ag NWs. The significant improvement in photocatalytic activity under light may be attributed to the plasmonic effect of silver nanowires and their core-shell structure, which promotes the separation of electron-hole pairs. Moreover, the photocatalytic activity of the core-shell nanostructure may provide valuable insight into the design and construction of MOF-based composite photocatalysts for oxidative coupling of amines.

关键词： Metal-organic frameworks Plasmonic silver nanowires Photocatalyst Core-shell nanostructure Oxidative coupling of amines

Tandem catalysis of Cu/Ni multi-sites promotes oxygen reduction reaction

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Science China Materials 2024年第9期67卷 2934-2940页

作者： Bin-Bin Feng Ke-Ke Chang Wan-Feng Xiong Duan-Hui Si Shui-Ying Gao Hong-Fang Li rong cao College of Chemistry and Materials Science Fujian Normal UniversityFuzhou350007China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou350108China University of Chinese Academy of Sciences Beijing100049China

The special electronic characteristics and high atom usage efficiency of metal-nitrogen-carbon(M-N-C)materials have made them extremely attractive for oxygen reduction reactions(ORRs).However,it is inevitable that hydrogen peroxide(H_(2)O_(2))will be formed via the two-electron pathway in ***,the Cu nanoparticles(NPs)have been encapsulated into Ni doped hollow mesoporous carbon spheres(Ni-HMCS)to reduce the generation of H_(2)O_(2)in *** tests confirm that the introduction of Cu NPs improves the ORR performance *** obtained Cu/Ni-HMCS exhibits a half-wave potential of 0.82 V *** hydrogen electrode and a limited current density of 5.5 mA cm^(-2),which is comparable with the commercial Pt/***,Cu/Ni-HMCS has been used in Zn-air battery,demonstrating a high power density of 161 mW cm^(-2)and a long-term recharge capability(50 h at 5 mA cm^(-2)).The theoretical calculation proposes a tandem catalysis pathway for Cu/Ni multi-sites catalysis,that is,H_(2)O_(2)released from the Ni-N_(4)and Cu-N_(4)sites migrates to the Cu(111)face,on which the captive H_(2)O_(2)is further reduced to H_(2)*** work demonstrates an interesting tandem catalytic pathway of dual-metal multi-sites for ORR,which provides an insight into the development of effective fuel cell electrocatalysts.

关键词： oxygen reduction reaction tandem catalysis pathway dual-metal multi-sites Cu nanoparticles

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游移的“小传”:《图绘宝鉴》及其续作书写

文艺研究 2024年第7期 127-143页

作者：曹蓉上海博物馆书画研究部

画人小传是构成传统画史著作的主要内容,它具备一定的文本结构、内容要素、叙述顺序,具有单元化写作的特征。由此形成的画史著作传统,内容上呈现明显的沿续性,也因小传写作方式的变动产生著作重心的移易。文本层次分明的《图绘宝鉴》能... 详细信息

画人小传是构成传统画史著作的主要内容,它具备一定的文本结构、内容要素、叙述顺序,具有单元化写作的特征。由此形成的画史著作传统,内容上呈现明显的沿续性,也因小传写作方式的变动产生著作重心的移易。文本层次分明的《图绘宝鉴》能够说明上述内容,其中的小传承袭前人文献中小传的人地、事迹单元,删除“陈旧”的画事、画说、载文等,加入“时新”的技艺单元。新增的技艺单元呈现分析化、知识化的特点,致使画史著作增多绘画鉴赏的趣味。这一趣味在明代持续蔓延,促使小传铺陈细节、变化形式、配以插图,更清晰地“解释”风格,这反映了鉴赏群体的扩大、鉴赏需求的成熟。

关键词：内容要素单元化文本结构文本层次叙述顺序小传写作方式知识化

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咪唑鎓盐基材料电催化二氧化碳还原研究进展

物理化学学报 2024年第4期40卷 131-145页

作者：张强黄远标曹荣中国科学院福建物质结构研究所结构化学国家重点实验室福州350002 中国福建光电信息科学与技术创新实验室福州350108 中国科学技术大学化学与材料科学学院化学系合肥230000 中国科学院大学北京100049

随着化石能源的使用日益增加,大气中CO_(2)的浓度不断上升,给环境带来了挑战。通过催化将CO_(2)转化为高附加值化学品为解决这些问题提供了一个机会,并为燃料合成开辟了一条新的途径,最终有助于减少CO_(2)排放并实现碳中和。在众多的方... 详细信息

随着化石能源的使用日益增加,大气中CO_(2)的浓度不断上升,给环境带来了挑战。通过催化将CO_(2)转化为高附加值化学品为解决这些问题提供了一个机会,并为燃料合成开辟了一条新的途径,最终有助于减少CO_(2)排放并实现碳中和。在众多的方法中,利用可再生清洁能源进行CO_(2)电还原反应(CO_(2)RR)以其反应条件温和、反应进度可控、环境友好以及可以产生大量的附加值产品而受到重视。在此背景下,咪唑鎓基材料及其衍生物已成为CO_(2)RR的有潜力的候选材料。这些材料对CO_(2)有很强的亲和力,并且在CO_(2)RR系统中作为电解质和电催化剂都有应用。所以它们的主要优点之一是能够在催化体系中富集CO_(2),有效地抑制析氢副反应(HER),并提高CO_(2)RR产物的选择性。了解电催化条件下咪唑鎓基离子液体(Im-ILs)与CO_(2)分子之间的相互作用机制对于从分子角度深入了解为什么添加Im-ILs可以改善CO_(2)RR性能至关重要。此外在非均相电催化剂中,Im-ILs作为表面修饰基团和捕集剂,可以显著改变催化剂的表面环境和疏水性,从而促进CO_(2)RR。值得注意的是,Lehn型和金属卟啉分子催化剂中的咪唑鎓基团已被发现对这些催化剂在CO_(2)RR中的性能有影响。N-杂环卡宾(NHC)基电催化剂作为咪唑鎓与CO_(2)相互作用的活性形式之一,表现出优异的CO_(2)RR性能。将NHC基电催化剂引入多孔多相催化剂和分子催化剂中,可以稳定金属纳米颗粒,提高捕获CO_(2)的能力,从而提高CO_(2)RR活性。总之,在CO_(2)RR中使用咪唑鎓基材料对于推进CO_(2)转化,实现可持续、有效合成高附加值化学品具有巨大的前景。

关键词： CO_(2)电还原离子液体咪唑鎓盐氮杂环卡宾金属纳米颗粒