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Exposure of juvenile chinook salmon to effluent from a large urban wastewater treatment *** *** profiling

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Aquaculture and Fisheries 2024年第3期9卷 367-377页

作者： James P.Meador Suzanne c.Ball c.Andrew James Jenifer K.McIntyre dept.of Environmental and Occupational Health Sciences School of Public Health4225 Roosevelt Way NESuite 100SeattleWA98105-6099USA Washington State University School of the EnvironmentPuyallup Research and Extension Center2606 W Pioneer AvePuyallupWA98371USA University of Washington Tacoma Center for Urban Waters326 East D StreetTacomaWA98421-1801USA

Targeted metabolomic analysis was conducted on juvenile chinook salmon exposed for 10 days to wastewater effluent(WWE)from a large urban treatment *** included five dilutions of WWE(20%,5.3%,1.4%,0.4%,and 0.1%)and a control with 7 replicates per *** was extracted from fish and analyzed via liquid chromatography–mass spectrometry(Lc-MS)for 361 endogenous metabolites,of which 185 were ***-versus-treatment comparisons identified several metabolites that were associated with altered biochemical pathways observed for all treatments,including several that are important for energy generation and *** altered pathways are crucial for fish health and may be an early indicator of potential adverse effects on growth,reproduction,behavior,and immune *** ocean-type chinook salmon spend several days to weeks in the nearshore estuary where they may encounter high concentrations of WWE *** are exposed to a wide range of potent pharmaceuticals,personal care products,and industrial compounds from WWE that have the potential to affect physiological homeostasis and disrupt their normal life cycle.

关键词： Wastewater effluent Metabolomics Physiology chinook salmon Pharmaceuticals Metabolic pathways Estuary

dynamic Event-Triggered consensus control for Input constrained Multi-Agent Systems With a designable Minimum Inter-Event Time

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IEEE/cAA Journal of Automatica Sinica 2024年第3期11卷 649-660页

作者： Meilin Li Yue Long Tieshan Li Hongjing Liang c.L.Philip chen the School of Automation Engineering University of Electronic Science and Technology of ChinaChengdu 611731China IEEE the Yangtze delta Region Institute University of Electronic Science and Technology of ChinaHuzhou 313000 the Laboratory of Electromagnetic Space cognition and Intelligent control Beijing 100089China the School of computer Science and Engineering South China University of TechnologyGuangzhou 510006

This paper investigates the consensus control of multi-agent systems(MASs) with constrained input using the dynamic event-triggered mechanism(ETM).consider the MASs with small-scale networks where a centralized dynamic ETM with global information of the MASs is first ***,a distributed dynamic ETM which only uses local information is developed for the MASs with large-scale *** is shown that the semi-global consensus of the MASs can be achieved by the designed bounded control protocol where the Zeno phenomenon is eliminated by a designable minimum inter-event *** addition,it is easier to find a trade-off between the convergence rate and the minimum inter-event time by an adjustable ***,the results are extended to regional consensus of the MASs with the bounded control *** simulations show the effectiveness of the proposed approach.

关键词： constrained input designable minimum inter-event time directed communication topology dynamic event-triggered mechanism MASs consensus control

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cO oxidation under lean and stoichiometric conditions over ceriazirconia with very low metal contents(cu,co,Ag and Pt)

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Journal of Rare Earths 2024年第9期42卷 1669-1681,I0002页

作者： J.c.Martínez-Munuera M.P.Yeste A.García-García McMA Group Department of Inorganic Chemistry and Institute of MaterialsUniversity of AlicanteCarretera de San Vicente del Raspeig s/n03690San Vicente del RaspeigAlicanteSpain Solid chemistry and catalysis Group Department of Materials ScienceMetallurgic Engineering and Inorganic ChemistryInstitute of Electronic Microscopy and Materials ResearchUniversity of CádizAp.40E-11510Puerto RealCádizSpain

In this work,several ceria-zirconia based catalysts with very lo w(and equimolar) metal contents were prepared,characterised and tested for the cO oxidatio n reaction(under lean and stoichiometric conditions),trying to emulate those conditions found in a diesel oxidation catalyst(dOc) system from a diesel engine and those encountered under gasoline exhaust(λ=1).The metals chosen are cu,co,Ag and Pt(as a reliable benchmark).The results reveal enormous differences among reducibility and catalytic activity despite quite similar structural and textural properties of the catalysts,showing differences among dispersion(Ag-catalyst seems to present a low level of dispersion).This catalyst seems to be characterised,as well,by a strong electronic interaction between ce and Ag centres which is suggested to yield an improved reducibility under H_(2)-TPR ***,the order in catalytic activity(cu>Ag>co≈Pt>>support) seems not to follow the order found in reducibility and the cu-catalyst seems to be the most active independently on the reaction conditions,yielding nearly overlapped cO oxidation catalytic *** restingly,a stro ng correlation between the catalytic activity under the two conditions tested and the OSc values of the ce_(0.8)Zr_(0.2)O_(2)-supported metal catalysts is ***,OSc parameter measured at 150℃ can be used as a relevant descriptor to evaluate the cO oxidation activity at low and medium conversions for the investigated catalysts,much better than the H_(2)-TPR measurements.

关键词： cO oxidation Low metal content ceria-zirconia copper species OSc parameter Rare earths

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Exposure of juvenile chinook salmon to effluent from a large urban wastewater treatment *** *** responses

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Aquaculture and Fisheries 2024年第3期9卷 355-366页

作者： Suzanne c.Ball James P.Meador c.Andrew James Jenifer K.McIntyre Washington State University School of the EnvironmentPuyallup Research and Extension Center2606 W Pioneer AvePuyallupWA98371USA dept.of Environmental and Occupational Health Sciences School of Public Health4225 Roosevelt Way NESuite 100SeattleWA98105-6099USA University of Washington Tacoma Center for Urban Waters326 East D StreetTacomaWA98421-1801USA

Wastewater treatment plants release complex mixtures of chemicals into the aquatic environment as wastewater effluent(WWE);however,the effects of these mixtures are still poorly *** salmon(Oncorhynchus tshawytscha)are a culturally important species in the Pacific Northwest and are a vital food resource for southern resident killer whales(Orcinus orca)that are listed as‘critically endangered’under the *** Species Act(ESA).chinook populations have declined drastically in this region and have failed to show significant recovery despite regional-to-federal efforts,resulting in many populations being listed as threatened under the *** source of stress to juvenile chinook is chemical pollution from WWE during their outmigration along river corridors and residency in *** this study,we investigated effects of WWE on juvenile chinook health in a ten-day exposure to dilutions of WWE from 0.1%to 20%.At the end of the exposure,we measured endpoints associated with endocrine disruption,brain function,osmoregulation,stress,and *** to WWE significantly(α=0.1 for all analyses)induced vitellogenesis,indicating endocrine system *** saw significant reductions in plasma glucose,an indication of stress,and brain Na+/K+-ATPase(NKA)activity,an enzyme essential for neuronal ***,metabolism was affected as evidenced by altered total protein,cholesterol,and albumin in plasma,a drastic decrease in whole body lipid content,and a significant increase in visible liver *** compared contaminant concentrations in exposure water with effects concentrations from the literature for chemicals known to induce vitellogenin or inhibit brain *** most contaminants,concentrations in exposure waters were several orders of magnitude below effects concentrations in the *** exception was estrogenic hormones,which were detected at similar concentrations in this study compared to concentrations in other studies tha

关键词： Wastewater effluent chinook salmon Toxicity Sodium potassium ATPase Vitellogenin Physiology Metabolism Glucose

Prevalence of Gender-Based Violence among Sex Workers in Bangui, central African Republic (cAR)

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Advances in Sexual Medicine 2024年第2期14卷 13-20页

作者： d. Mossoro-Kpinde Hermione S. c. diemer Henri R. Tende Nzengou Richard S. Siki Francis J. d. d. Tekpa Bertrand Ministry of Labor Employment Social Protection and Vocational Training Bangui Central African Republic department of Public Health Faculty of Health Sciences University of Bangui Bangui Central African Republic community of the Tree of Life Bangui Central African Republic Traumatology department The Central African Republic RCA Community Hospital Bangui Central African Republic

Background: Violence against women has become an international public health and human rights issue in recent decades. The violence suffered by sex workers is of little interest for research, yet it constitutes a major health and safety problem. We propose to assess the extent of the phenomenon of gender-based violence (GBV) among sex workers (SWs) in the city of Bangui in the cAR. Methodology: This is a descriptive cross-sectional epidemiological study covering the period from July to October 2021 carried out among SWs in Bangui, the capital of the cAR. Given that the SWs association had only 159 members in Bangui, an exhaustive sampling was retained. Were included in the study, any SW present during the data collection period and having given their written consent. The parameters studied were socio-demographic characteristics: age, sex, residence, level of education, marital status, and characteristics linked to violence: the notion of violence during their professional activity, the type of violence, the declaration and the declaration if necessary, the response and management of this violence. The data collected was analyzed using Epi info version 7 software. Results: Of the 159 SWs that counted the association, 108 had been included. The average age was 27.0 years with extremes of 14 and 46 years. The age groups of 25 to 34 years were the most represented (43.5%). Fifty-six SWs (51.9%) had reached the secondary level. Unemployed SWs were in the majority at 74.1%;Sixty-six (66) SWs in our sample (61.1%) had already been victims of violence during the exercise of their activity Sexual violence was the most represented (28.5%) followed by verbal violence (22.4%). Sixty-eight (62.9%) wanted to stop the professional activity of SWs and 93.1% would accept another income-generating activity in place of sex work. conclusion: It is necessary to supervise SWs and protect them within the framework of respect for human rights, rather than criminalizing them and the exploit

关键词： Female Sex Workers Gender-Based Violence central African Republic

Enantioselective iridium-catalyzed allylic substitution with a Reformatsky reagent: direct construction of β-stereogenic homoallylic esters

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Science china chemistry 2024年第11期67卷 3791-3797页

作者： debasis Pal Kirana d.Veeranna Yuk Fai Wong P.Andrew Evans department of chemistry Queen's University Xiangya School of Pharmaceutical Sciences Central South University

The Reformatsky reagent derived from ethyl bromoacetate circumvents the challenge associated with the direct regio-and enantioselective iridium-catalyzed allylic alkylation with an unstabilized aliphatic ester enolate. Notably, this work represents the first example of using a Reformatsky reagent in a metal-allyl reaction, which permits the direct construction of enantioenriched β-stereogenic homoallylic esters without preactivation of the pronucleophile or post-reaction modification of the product(e.g., thermal decarboxylation of a 1,3-dicarbonyl). Moreover, the process allows the coupling of a broad range of sterically and electronically diverse electrophiles bearing aryl, heteroaryl and alkenyl derivatives, including the significantly more challenging alkyl-substituted allylic carbonates. The versatility of the ester product is exemplified by a series of functional group manipulations and the development of a concise and efficient enantioselective total synthesis of the natural product,(+)-descurainolide A. Finally, mechanistic studies indicate that the zinc enolate behaves as a soft nucleophile that undergoes outer-sphere alkylation.

关键词： allylic substitution asymmetric catalysis mechanistic studies natural product synthesis Reformatsky reagent

Insm1:orchestrating cellular mimicry in the thymus medulla

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cellular & Molecular Immunology 2024年第4期21卷 414-416页

作者： K.d.James J.E.cowan UcL Institute of Immunity and Transplantation The Pears BuildingRowland Hill StreetLondonNW32PPUK

The thymus is the primary production site for a functional and self-tolerant T-cell *** establishment of immune tolerance is mediated by the generation and presentation of tissue-restricted self-antigens(TRAs)by medullary thymic epithelial cells(mTEcs),which screen T-cell receptors for self-reactivity to eliminate autoreactive T *** studies have extended our understanding of mTEc heterogeneity by examining the mechanisms by which mTEcs mimic the peripheral self[1].

关键词： medullary eliminate restricted

某工业场地土壤砷的空间分布及As(Ⅲ)迁移规律研究

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土壤通报 2024年第2期55卷 502-512页

作者：左玉涛孔文亮代义彬 SEIdOU c.d. 王铁军天津大学地球系统科学学院表层地球系统科学研究院天津300072 天津北大港湿地自然保护区管理中心天津300270 天津大学天津环渤海滨海地球关键带国家野外科学观测研究站天津300072 天津大学天津市环渤海关键带科学与可持续发展重点实验室天津300072

[目的]旨在掌握某工业场地土壤中砷(As)的空间分布特征并揭示其迁移规律,为该工业场地土壤As污染防治提供数据与理论基础。[方法]本文选取葫芦岛市某工业场地为研究区,首先统计分析了场地内土壤As含量的空间分布特征,并比较了等温与动... 详细信息

[目的]旨在掌握某工业场地土壤中砷(As)的空间分布特征并揭示其迁移规律,为该工业场地土壤As污染防治提供数据与理论基础。[方法]本文选取葫芦岛市某工业场地为研究区,首先统计分析了场地内土壤As含量的空间分布特征,并比较了等温与动态吸附两种获取土壤中As(Ⅲ)吸附参数的实验方法的特点与适用性,最终利用HYdRUS-1d模型反演计算了As(Ⅲ)在供试土壤中的d_(L)、K、α、β等迁移参数。[结果]场地土壤As浓度水平分布具有显著差异,在垂向上主要富集于40 cm深度内,且随深度增加而降低。等温吸附实验的结果表明:土样中As(Ⅲ)的平衡固相浓度随液相浓度增加呈非线性增长趋势,Langmuir模型(R^(2)=0.988)对实测数据的拟合效果优于Henry和Freundlich模型。动态吸附实验结果展示了As(Ⅲ)相对浓度完全穿透土柱所需的污染液体积随As(Ⅲ)初始浓度的增加而减少的规律;HYdRUS-1d反演结果表明三类吸附模型中,Langmuir模型(R^(2)=0.990)更适用于模拟土样中As(Ⅲ)的动态吸附过程。相较于等温吸附实验,使用动态吸附实验模拟As(Ⅲ)迁移行为更接近其在土壤中的真实迁移过程。[结论]该场地中的As污染来源于工业活动,主要集中在浅层土壤;土壤中As(Ⅲ)的迁移行为表现为非线性过程,较高的初始浓度将加速As(Ⅲ)的垂向迁移。动态吸附实验方法应优先应用于土壤As迁移过程及其参数获取的研究中。

关键词：土壤砷工业污染等温吸附动态吸附 HYdRUS-1d

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Polyhydroxyurethanes from Biobased Monomers and cO_(2):A Bridge between Sustainable chemistry and cO_(2) Utilization

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chinese Journal of chemistry 2024年第6期42卷 652-685页

作者： Tharinee Theerathanagorn Tanika Kessaratikoon Hafeez Ur Rehman Valerio d'Elia daniel crespy VISTEc Advanced Laboratory for Environment-Related Inorganic and Organic Syntheses Department of Materials Science and EngineeringVidyasirimedhi Institute of Science and Technology21210Wang ChanRayongThailand department of Materials Science and Engineering Vidyasirimedhi Institute of Science and Technology21210Wang ChanRayongThailand

Polyhydroxyurethanes(PHUs)have received considerable attention in the last decade as potential alternatives to traditional phosgene-based polyurethanes(PUs).The development of suitable 5cc(five membered-ring cyclic carbonate)precursors bearing multiple carbonate moieties(multi-5ccs)is a key requisite for preparing PHUs by polyaddition reaction with bis-or *** sustainable PHUs from cO_(2)-based five-membered cyclic carbonates(5ccs)obtained from biobased epoxides is a valuable strategy to bridge cO_(2) utilization and the upcycling of renewable *** this context,while many multi-5cc monomers reported in the literature are oil-based,recent efforts have led to the development of a large variety of multifunctional 5ccs that are produced by the combination of cO_(2) and renewable resources such as fatty acids and vegetable oils,lignin,terpenes,and *** this work,recent crucial advances(2019—2023)on PHUs prepared from bis-and multi-5ccs produced from cO_(2) and(partially/potentially)biobased substrates are reviewed with respect to their synthesis,thermal and mechanical properties,and their recent,emerging applications.

关键词： cO_(2) conversion Polyhydroxyurethanes cyclic carbonates Biobased compounds Fatty acids Functional polymers Monomers Renewable resources