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structural effects induced by dialysis-based purification of carbon nanomaterials

Nano materials science 2024年第4期6卷 475-483页

作者： A.D.veloso A.m.Ferraria A.m.Botelho do Rego A.s.viana A.J.s.Fernandes A.J.Fielding R.A.videira m.c.Oliveira cQ-vR and chemistry Department University of Trás-os-Montes e Alto Douro BsIRG iBB-Institute for Bioengineering and BiosciencesDepartment of Chemical Engineeringand Associate Laboratory i4HB-Institute for Health and BioeconomyInstituto Superior TécnicoUniversidade de Lisboa centro de Química Estrutural Institute of Molecular SciencesDepartamento de Química e BioquímicaFaculdade de CiênciasUniversidade de Lisboa I3N and Physics Department University of AveiroCampus de Santiago Faculty of science Pharmacy and Biomolecular SchoolLiverpool John Moores University REQUImTE/LAQv Laborat orio de FarmacognosiaDepartamento de QuímicaFaculdade de Farm aciaUniversidade do Porto

Dialysis plays a crucial role in the purification of nanomaterials but its impact on the structural properties of carbon nanomaterials was never ***,a carbon-based nanomaterial generated electrochemically in potassium phosphate buffer,was characterized before and after dialysis against pure *** is shown that dialysis affects the size of the carbon domains,structural organization,surface functionalization,oxidation degree of carbon,and grade of ***,dialysis drives the nanomaterial organization from discrete roundish carbon domains,with sizes ranging from 70 to 160 nm,towards linear stacking structures of small nanoparticles （m）.In parallel,alcohol and ether （epoxide） surface groups evolve into more oxidized carbon groups （e.g.,ketone and ester groups）.Investigation of the as-prepared nanomaterial by electron paramagnetic resonance （EPR） revealed a resonance signal consistent with carbon-oxygen centred ***,this study brings to light the selective affinity of the carbon nanomaterial under study to capture Na+ions,a property greatly enhanced by the dialysis process,and its high ability to trap oxygen,particularly before *** findings open new perspectives for the application of carbon-based nanomaterials and raise awareness of the importance of structural changes that can occur during the purification of carbon-based nanomaterials.

关键词： Nanocarbon surface functionalization NmR XPs Hydrophilic carbon Paramagnetic

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Thermogravimetric,kinetic study and gas emissions analysis of the thermal decomposition of waste-derived fuels

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Journal of Environmental sciences 2024年第3期137卷 155-171页

作者： vadim v.Dorokhov Galina s.Nyashina Pavel A.strizhak Heat and mass Transfer Laboratory National Research Tomsk Polytechnic University30 Lenin AvenueTomsk 634050Russia

A wide range of wastes can potentially be used to generate thermal and electrical *** co-combustion of several types of waste as part of water-containing waste-derived fuels is a promising method for their *** this research,we use thermogravimetric analysis and differential scanning calorimetry to study the thermal behavior and kinetics of coal slime,biomass,waste oils,and blends on their *** also analyze the concentrations of gaseous *** results show that biomass,oils,and coal slime significantly affect each other in the course of their co-combustion when added to slurry *** preparation of coal-water slurry based on slime and water reduced the ignition and burnout temperature by up to 16%.Adding biomass and waste oils additionally stimulated the slurry ignition and burnout,which occurred at lower *** to dry coal slime,threshold ignition temperatures and burnout temperatures decreased by 6%–9%and 17%–25%,***,the use of biomass and waste oils as part of slurries inhibited NOхand sO_(2)emission by 2.75 *** to the kinetic analysis,added biomass and waste turbine oil provide a 28%–51%reduction in the activation energy as compared to a coal-water slurry without additives.

关键词： coal-water slurry Water-containing composite fuels combustion Emission Kinetic TGA-Dsc

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In vivo measurement of NADH fluorescence lifetime in skeletal muscle via -ber-coupled time-correlated single photon counting

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Journal of Innovative Optical Health sciences 2024年第1期17卷 121-134页

作者： Kathryn m.Priest Jacob v.schluns Nathania Nischal colton L.Gattis Jeffrey c.Wolchok Timothy J.muldoon Department of Biomedical Engineering University of Arkansas FayettevilleARUSA

Nicotinamide adenine dinucleotide(NADH)is a cofactor that serves to shuttle electrons during metabolic processes such as glycolysis,the tricarboxylic acid cycle,and oxidative phosphorylation(OXPHOs).NADH is autofluorescent,and itsfluorescence lifetime can be used to infer metabolic dynamics in living ***-coupled time-correlated single photon counting(TcsPc)equipped with an implantable needle probe can be used to measure NADH lifetime in vivo,enabling investigation of changing metabolic demand during muscle contraction or tissue *** study illustrates a proof of concept for point-based,minimally-invasive NADHfluorescence lifetime measurement in *** muscle loss(vmL)injuries were created in the left tibialis anterior(TA)muscle of male sprague Dawley *** lifetime measurements were collected before,during,and after a 30 s tetanic contraction in the injured and uninjured TA muscles,which was subsequently-t to a biexponential decay model to yield a metric of NADH utilization(cytoplasmic vs protein-bound NADH,the A11/A22 ratio).On average,this ratio was higher during and after contraction in uninjured muscle compared to muscle at rest,suggesting higher levels of free NADH in contracting and recovering muscle,indicating increased rates of *** injured muscle,this ratio was higher than uninjured muscle overall but decreased over time,which is consistent with current knowledge of inflammatory response to injury,suggesting tissue regeneration has *** data suggest that-ber-coupled TcsPc has the potential to measure changes in NADH binding in vivo in a minimally invasive manner that requires further investigation.

关键词： Glycolysis oxidative phosphorylation energy metabolism volumetric muscle loss

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Photoluminescence,structural and antibacterial properties of co-dopedβ-ca_(3)(PO_(4))_(2)-type phosphates ca_(8)cuRE(PO_(4))_(7)(RE=Eu-Er)

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Journal of Rare Earths 2024年第9期42卷 1658-1668,I0002页

作者： Ivan v.Nikiforov Ekaterina v.Iliin Bogdan I.Lazoryak sergey m.Aksenov Pavel v.slukin Dina v.Deyneko Department of chemistry Lomonosov Moscow State University119991MoscowRussia Laboratory of Arctic mineralogy and material sciences Kola Science CentreRussian Academy of Sciences184209ApatityRussia Geological Institute Kola Science CentreRussian Academy of Sciences184209ApatityRussia state scientific center of Applied microbiology and Biotechnology of Rospotrebnadzor 24 Block A142279ObolenskRussia

Novel ca_(8)cuRE(PO_(4))_(7)where RE^(3+)=Eu^(3+),Tb^(3+),Dy^(3+),Ho^(3+)and Er^(3+)were synthesized by a solid-state method in *** structures of the samples were characterized by powder X-ray diffraction using Rietveld refinement to determine the occupation of crystal *** samples are found to have a centrosymmetric structure with space group R3c,as shown by dielectric *** synthesized ca_(8)cuRE(PO_(4))_(7)samples have multifunctional *** cu^(2+)ions provide antibacterial properties,while the rare earth elements ions exhibit luminescence properties,and theβ-ca_3(PO_(4))_(2)-type host is *** photoluminescence properties of RE^(3+)ions were studied and compared with other simmilar ca_(8)mRE(PO_(4))_(7)phosphates,where m is a divalent *** photoluminescence intensity quenching in terms of energy transfer from RE^(3+)to cu^(2+)is *** bioactive properties were studied in relation to antibacterial activity against *** and *** syntesized ca_(8)cuRE(PO_(4))_(7)samples demonstrate very high and stable inhibition of bacteria *** correlation between crystal structure and properties is *** combining multiple approaches to the directio nal design of such materials,several important properties within a single chemical compound to achieve biovisualization and bioactive properties simultaneously can be combined.

关键词： β-ca_(3)(PO_(4))_(2) Whitlockite-type structure Bioactive phosphates TcP Photoluminescence Rare earths

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Effect of the anionic composition of sulfolane based electrolytes on the performances of lithium-sulfur batteries

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Journal of Energy chemistry 2024年第8期95卷 231-240,I0005页

作者： Elena v.Karaseva Elena v.Kuzmina Bo-Quan Li Qiang Zhang vladimir s.Kolosnitsyn Ufa Institute of chemistry of the Ufa Federal Research centre of the Russian Academy of science 71Prospect OktyabryaUfa 450054BashkortostanRussia Advanced Research Institute of multidisciplinary science Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Green chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

In lithium-sulfur batteries,cell design,specifically electrolyte design,has a key impact on the battery *** effect of lithium salt anion donor number(DN)(DN[PF_(6)]^(-)=2.5,DN[N(sO_(2)cF_(3))_(2)]^(-)=5.4,DN[clO_(4)]^(-)=8.4,DN[sO_(3)cF_(3)]^(-)=16.9,and DN[NO_(3)]^(-)=21.1)on the patterns of lithium-sulfur batteries and lithium metal electrode performances with sulfola ne-based electrolytes is *** increase in DN of lithium salt anions leads to an increase in the depth and rate of electrochemical reduction of sulfur and long-chain lithium polysulfides and to a decrease in those for medium-and short-chain lithium *** of lithium salt anions has weak effect on the discharge capacity of lithium-sulfur batteries and the coulomb efficiency during cycling,with the exception of LisO_(3)cF_(3)and LiNO_(3).An increase in DN of lithium salt anions leads to an increase in the cycling duration of lithium metal anodes and to a decrease in the presence of lithium *** sulfolane solutions of LiNO_(3)and LisO_(3)cF_(3),lithium polysulfides do not affect the cycling duration of lithium metal anodes.

关键词： Donor number Lithium salt sulfolane Lithium polysulfide Electrolyte Lithium-sulfur battery Lithium metal electrode

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Bio-Inspired Intelligent Routing in WsN: Integrating mayfly Optimization and Enhanced Ant colony Optimization for Energy-Efficient cluster Formation and maintenance

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computer modeling in Engineering & sciences 2024年第10期141卷 127-150页

作者： v.G.saranya s.Karthik Department of Electronics and communication Engineering Faculty of Engineering&TechnologySRM Institute of Science and TechnologyVadapalani CampusChennai600026India

Wireless sensor Networks(WsNs)are a collection of sensor nodes distributed in space and connected through wireless *** sensor nodes gather and store data about the real world around ***,the nodes that are dependent on batteries will ultimately suffer an energy loss with time,which affects the lifetime of the *** research proposes to achieve its primary goal by reducing energy consumption and increasing the network’s lifetime and *** present technique employs the hybrid mayfly Optimization Algorithm-Enhanced Ant colony Optimization(mFOA-EAcO),where the mayfly Optimization Algorithm(mFOA)is used to select the best cluster head(cH)from a set of nodes,and the Enhanced Ant colony Optimization(EAcO)technique is used to determine an optimal route between the cluster head and base *** performance evaluation of our suggested hybrid approach is based on many parameters,including the number of active and dead nodes,node degree,distance,and energy *** objective is to integrate mFOA-EAcO to enhance energy efficiency and extend the network life of the WsN in the *** proposed method outcomes proved to be better than traditional approaches such as Hybrid squirrel-Flying Fox Optimization Algorithm(HsFLBOA),Hybrid social Reindeer Optimization and Differential Evolution-Firefly Algorithm(HsRODE-FFA),social spider Distance sensitive-Iterative Antlion Butterfly cockroach Algorithm(sADss-IABcA),and Energy Efficient clustering Hierarchy strategy-Improved social spider Algorithm Differential Evolution(EEcHs-IssADE).

关键词： Enhanced ant colony optimization mayfly optimization algorithm wireless sensor networks cluster head base station(Bs)

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Hydrocarbon indication in Rio Bonito Formation sandstone:Implication for cO_(2)storage in são Paulo,Brazil

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Energy Geoscience 2024年第1期5卷 331-341页

作者： Richardson m.Abraham-A Haline v.Rocha saulo B.de Oliveira colombo c.G.Tassinarri Orlando c.da silva Institute of Energy and Environment University of São PauloSão PauloBrazil Research centre for Greenhouse Gas Innovation University of São PauloSão PauloBrazil

são Paulo state has witnessed cO_(2)storage-based investigations considering the availability of suitable geologic structures and proximity to primary cO_(2)source sinks related to bioenergy and carbon capture and storage(BEccs)*** current study presents the hydrocarbon viability evaluations and cO_(2)storage prospects,focusing on the sandstone units of the Rio Bonito *** objective is to apply petrophysical evaluations with geochemical inputs in predicting future hydrocarbon(gas)production to boost cO_(2)storage within the study *** study used data from eleven wells with associated wireline logs(gamma ray,resistivity,density,neutron,and sonic)to predict potential hydrocarbon accumulation and fluid mobility in the investigated *** samples(shale and carbonate)obtained from depths>200 m within the study location have shown bitumen *** geochemistry data of the Rio Bonito Formation shale beds suggest they are potential hydrocarbon source rocks and could have contributed to the gas accumulations within the sandstone *** drilled well data,e.g.,cB-1-sP and TI-1-sP,show hydrocarbon(gas)presence based on the typical resistivity and the combined neutron-density responses at depths up to 3400 m,indicating the possibility of other hydrocarbon members apart from the heavy oil(bitumen)observed from the near-surface rocks *** the three-dimensional(3-D)model,the free fluid indicator(FFI)is more significant towards the southwest and southeast of the area with deeper depths of occurrence,indicating portions with reasonable hydrocarbon recovery rates and good prospects for cO_(2)injection,circulation and permanent ***,future studies based on contemporary datasets are required to establish the hydrocarbon viability further,foster gas production events,and enhance cO_(2)storage possibilities within the region.

关键词： ParanáBasin Hydrocarbon indication sandstone reservoirs Rio Bonito Formation cO_(2)storage Hydrocarbon recovery factor Fluid injection rate

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^(4)He monolayer on graphene:a quantum monte carlo study

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communications in Theoretical Physics 2024年第9期76卷 149-157页

作者： s Yu m Boninsegni Department of Physics University of AlbertaEdmontonAlbertaT6G 2H5Canada

We revisit the problem of adsorption of a single^(4)He layer on graphene,focusing on the commensurate(c_(1/3))crystalline phase,specifically on whether it may possess a nonzero superfluid response,and on the existence of superfluid phases,either(metastable)liquid or vacancy-doped *** make use of canonical quantum monte carlo simulations at zero and finite temperature,based on a realistic microscopic model of the *** results confirm the absence of any superfluid response in the commensurate crystal,and that no thermodynamically stable uniform phase exists at lower *** evidence of a possibly long-lived,metastable superfluid phase at c_(1/3)coverage is ***,the results of ground-state projection methods and finite-temperature simulations are entirely consistent.

关键词： superfluidity low-dimensional systems quantum monte carlo helium supersolids

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Direct microwave leaching conditions of rare earth elements in fluorescent wastes

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Journal of Rare Earths 2024年第6期42卷 1165-1174,I0007页

作者： A.Bilen B.Birol m.N.saridede s.s.Kaplan m.s.sonmez Department of metallurgical and materials Engineering Yildiz Technical UniversityIstanbulTurkey Department of chemical Engineering and materials science Stevens Institute of TechnologyNew JereyUSA Department of metallurgical and materials Engineering Istanbul Technical UniversityIstanbulTurkey

The luminescent phosphor powder in the fluorescent lamp constitutes 2%of the lamp’s *** can be mentioned that fluorescent wastes are a crucial raw material to produce rare earth *** the present study,microwave leaching process was conducted to dissolve rare earth elements yttrium(Y),europium(Eu),and remaining rare earth elements(REEs)present in the phosphor powder of the fluorescent *** the yields were *** the microwave leaching process,the effects of the temperature(80-160℃),acid type(hydrochloric acid(Hcl),nitric acid(HNO_(3)),sulphuric acid(H_(2)sO_(4))),acid concentration(0.5-6 mol/L),solid to liquid ratio(0.1:10-0.5:10)and reaction time(5-90 min)parameters on leaching efficiencies of varying rare earth elements and calcium were *** highest yield was obtained in the direct microwave leaching of fluorescent waste with the experimental conditions of 6 mol/L Hcl,160℃,0.1:10 solid-to-liquid ratio(s:L),and 90 *** energy calculations were made,and kinetic models of the reactions were obtained,and it is observed that Y and Eu dissolution is diffusion-controlled,on the other hand,lanthanum(La),cerium(ce),and terbium(Tb)were examined to be chemical reaction ***,calcium(ca)and gadolinium(Gd)seem coherent with the mixed ***,mathematical models of all experimental studies are created with the response surface Box-Behnken method and the correlation coefficients of all the models are over 90%.

关键词： Rare earth elements(REEs) Direct microwave leaching Fluorescent waste Kinetic models Response surface method

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Early Phases of star Formation: Testing chemical Tools

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Research in Astronomy and Astrophysics 2024年第1期24卷 96-118页

作者： N.c.martinez s.Paron cONIcET-Universidad de Buenos Aires.Instituto de Astronomía y Física del Espacio Ciudad Universitaria(C1428EGA)Ciudad Autónoma de Buenos AiresArgentina

star-forming processes strongly influence the Ism ***,many high-quality databases are available at millimeter *** them,it is possible to carry out studies that review and deepen previous *** these studies involve large samples of sources,it is preferred to use direct tools to study the molecular *** the aim of testing these tools such as the use of the HcN/HNc ratio as a thermometer,and the use of H^(13)cO^(+),Hc_(3)N,N_(2)H^(+) and c_(2)H as "chemical clocks," we present a molecular line study toward 55 sources representing massive young stellar objects at different evolutionary stages:infrared dark clouds(IRDcs),highmass protostellar objects(HmPOs),hot molecular cores(Hmcs) and ultracompact H II *** found that the use of the HcN/HNc ratio as a universal thermometer in the Ism should be taken with care because the HcN optical depth is a big issue that can affect the ***,this tool should be utilized only after a careful analysis of the HcN spectrum,checking that no line,neither the main nor the hyperfine ones,presents absorption *** point out that the analysis of the emission of H^(13)cO^(+),Hc_(3)N,N_(2)H^(+) and c_(2)H could be useful to trace and distinguish regions among IRDcs,HmPOs and *** molecular line widths of these four species increase from the IRDc to the Hmc stage,which can be a consequence of the gas dynamics related to the starforming processes taking place in the molecular *** results not only contribute with more statistics,acting as a probe of such chemical tools,useful to obtain information in large samples of sources,but also complement previous works through the analysis of other types of sources.

关键词： stars:formation Ism:molecules Ism:clouds

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