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large dinosaur egg accumulations and their signific.nce for understanding nesting behaviour

Geoscience Frontiers 2024年第5期15卷 467-488页

作者： l.ezquerro R.coimbra B.Bauluz c.núñez-l.huerta T.Román-Berdiel M.Moreno-Azanza Departamento de Geodinámica Estratigrafía y PaleontologíaFacultad de Ciencias GeológicasUniversidad Complutense de MadridC/JoséAntonio Novais1228040MadridSpain Aragosaurus-IUcA:Recursos Geológicos y Paleoambientales.Departamento de ciencias de la Tierra.Facultad de ciencias Universidad de ZaragozaC/Pedro Cerbuna 1250009 ZaragozaSpain Museu da lourinha LourinhaPortugal GeoBioTec Department of Earth SciencesNOVA School of Science and TechnologyUniversidade Nova de LisboaCaparicaPortugal GeoBioTec Departamento de GeocienciasUniversidade de AveiroAveiroPortugal Insitut catalàde Paleoecologia Humana i EvolucióSocial(IPHES-cERcA) Zona Educacional 4Campus Sescelades URV(Edifici W3)43007 TarragonaSpain Departament d´Història i Història de l´Art Universitat Rovira i VirgiliAv.Catalunya 3543002 TarragonaSpain Geotransfer IUcA Departamento de Ciencias de La TierraFacultad de CienciasUniversidad de ZaragozaZaragozaSpain

The accurate identification of dinosaur egg accumulations as nests or clutches is crucial for understanding the reproductive behaviour of these extinct ***,existing methods often rely on the presence of complete eggs and embryo remains,and sedimentological criteria that are only applicable to well-structured *** this study,we introduce an innovative approach to characterize egg accumulations in structureless sediments,where traditional nest structures may not be *** methodology employs a unique combination of sedimentological,taphonomic,geochemical,and geophysical proxies for the study of egg *** applied this approach to the egg accumulation from Paimogo(Jurassic,Portugal),traditionally interpreted as a *** findings reveal that the Paimogo egg assemblage is a sec.ndary deposit,resulting from a flooding event in a fluvial plain that dismantled several allosauroid and crocodylomorph *** eggshell vapor c.nductance results,coupled with sedimentological evidence,suggest that allosauroid dinosaurs buried their eggs in the dry terrain of overbank areas close to a main channel during the breeding season,likely during the dry season to prevent the embryos from *** research underscores the necessity of multidisciplinary approaches in interpreting egg accumulations and offers a novel methodology for studying these accumulations in structureless *** findings provide new insights into the breeding behaviour and nesting preferences of these extinct organisms,c.ntributing to our understanding of dinosaur ecology.

关键词： Breeding behaviour Theropod Taphonomy Stable isotopes Magnetic susceptibility Jurassic

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Single atom cu-n-c catalysts for the electro-reduction of cO_(2) to cO assessed by rotating ring-disc electrode

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Journal of Energy chemistry 2024年第1期88卷 169-182,I0004页

作者： S.Pérez-Rodríguez M.Gutiérrez-Roa c.Giménez-Rubio D.Ríos-Ruiz P.Arévalo-cid M.V.Martínez-huerta A.Zitolo M.J.lázaro D.Sebastián Instituto de carboquímica(cSIc) Miguel Luesma Castán 450018 ZaragozaSpain Instituto de catálisis y Petroleoquímica(cSIc) Marie Curie 228049 MadridSpain Synchrotron SOlEIl L’Orme des MerisiersDépartementale 12891190France

The electrochemical cO_(2) reduction reaction(cO_(2)RR) to c.ntrollable chemicals is c.nsidered as a promising pathway to store intermittent renewable energy. Herein, a set of catalysts based on copper-nitrogendoped carbon xerogel(cu-n-c) are successfully developed varying the copper amount and the nature of the copper precursor, for the efficient cO_(2)RR. The electrocatalytic performance of cu-n-c materials is assessed by a rotating ring-disc electrode(RRDE), tec.nique still rarely explored for cO_(2)RR. For comparison, products are also characterized by online gas chromatography in a H-cell. The as-synthesized cu-nc catalysts are found to be active and highly cO selective at low overpotentials(from -0.6 to -0.8 V ***) in 0.1 M KHcO_(3), while H_(2) from the competitive water reduction appears at larger overpotentials(-0.9 V vs. RHE). The optimum copper acetate-derived catalyst c.ntaining cu-n_(4) moieties exhibits a cO_(2)-to-cO turnover frequency of 997 h^(-1) at -0.9 V vs. RHE with a H_(2)/cO ratio of 1.8. These results demonstrate that RRDE c.nfiguration c.n be used as a feasible approach for identifying electrolysis products from cO_(2)RR.

关键词： cu-n-c carbon xerogel Rotating ring disc electrode carbon dioxide reduction reaction carbon monoxide

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Role of lipids in the c.ntrol of autophagy and primary cilium signaling in neurons

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neural Regeneration Research 2024年第2期19卷 264-271页

作者： María Paz Hernández-cáceres Daniela Pinto-nuñez Patricia Rivera Paulina Burgos Francisco Díaz-castro Alfredo criollo Maria Jose Yañez Eugenia Morselli Instituto de Investigación en ciencias Odontológicas(IcOD) Facultad de OdontologíaUniversidad de ChileSantiagoChile Department of Basic Sciences Faculty of Medicine and ScienceUniversidad San SebastiánSantiagoChile Physiology Department Faculty of Biological SciencesPontificia Universidad Católica de ChileSantiagoChile Advanced c.nter for chronic Diseases(AccDiS) Facultad de Ciencias Químicas y Farmacéuticas&Facultad de MedicinaUniversidad de ChileSantiagoChile Autophagy Research c.nter SantiagoChile

The brain is,after the adipose tissue,the organ with the greatest amount of lipids and diversity in their composition in the human *** neurons,lipids are involved in signaling pathways c.ntrolling autophagy,a lysosome-dependent catabolic process essential for the maintenance of neuronal homeostasis and the function of the primary cilium,a cellular antenna that acts as a communication hub that transfers extracellular signals into intracellular responses required for neurogenesis and brain development.A crosstalk between primary cilia and autophagy has been established;however,its role in the c.ntrol of neuronal activity and homeostasis is barely *** this review,we briefly discuss the current knowledge regarding the role of autophagy and the primary cilium in *** we review the rec.nt literature about specific lipid subclasses in the regulation of autophagy,in the c.ntrol of primary cilium structure and its dependent cellular signaling in physiological and pathological c.nditions,specifically focusing on neurons,an area of research that could have major implications in neurodevelopment,energy homeostasis,and neurodegeneration.

关键词： autophagic flux cholesterol fatty acids GPcR lysosomal storage diseases neurons nPc1 phosphoinositides primary cilium

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Discovery of new MAX-phase-like layered ternary carbide V_(8)P_(6)c:crystal structure,thermal expansion,and elastic properties

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Journal of Materials Science & Tec.nology 2024年第7期174卷 55-62页

作者： H.X.chen l.Sheng Z.l.Zhang X.c.Wen D.l.Yang X.Y.Ye P.Q.Dai School of Materials Science and Engineering Fujian University of TechnologyFuzhou 350118China Beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of ScienceBeijing 100049China Fujian Provincial Key laboratory of Advanced Materials Processing and Application Fuzhou 350118China State Key laboratory of Structural chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China

Due to the laminated structure,MAX phases and MAX-phase-like compounds possess outstanding dam-age tolerance capability with good thermal/electrical c.nductivity and other charming functional prop-erties,showing a bright future for structural-functional ***,a new MAX-phase-like ternary car-bide V_(8)P_(6)c with layered characteristics was *** to the alternate stacking of hexagonal-arranged M/A/X atom layers in MAX phases,V_(8)P_(6)c has a layered structure formed by a repeated stacking of the slabs c.nsisting of V_(6)c-octahedrons and VP 6-distorted-octahedrons in three-atomic layers *** thermal expansion anisotropy was revealed,with the thermal expansion coefficients(TEcs)along a-axis,c-axis,and the average value,equal toα_(a)=8.55(5)μK^(−1),α_(c)=10.23(5)μK^(−1),andα_(l)=9.14(5)μK^(−1),*** dilation along the c-axis was mainly dominated by out-plane V-P bonds be-tween layered *** to the pressure-dependent lattice parameters,the polycrystalline bulk modulus(B_(0)=185(9)GPa)and high compressibility anisotropy factor(B_(a)/B_(c)=1.64)was ***-while,the sec.nd-order elastic c.nstants were calculated,and the elastic moduli,E=303 GPa,B=198 GPa,G=122 GPa,andν=0.246,were *** the weak c.nnection between layer slabs by out-plane V1-P bond was revealed by the bond stiffness model,with a bond stiffness close to the M-A bond in MAX ***,good damage tolerance capability was predicted according to Paugh’s ratio(G/B=0.616)and cauchy pressure(P_(a)=0 GPa,P_(c)=-7.5 GPa),even better than those of typical MAX *** discovery of V_(8)P_(6)c provides a new member of MAX-phase-like damage-tolerant ceramic with relatively low density,moderate thermal expansion,and anisotropic compressibility,and the unique lay-ered structure is inspiring for exploring new layered ternary ceramics.

关键词： new ternary carbide MAX phase Thermal expansion Elastic c.nstants Anisotropy

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Solar-assisted photocatalytic water splitting using defective UiO-66 solids from modulated synthesis

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nano Research 2024年第5期17卷 4134-4150页

作者： celia M.Rueda-navarro María cabrero-Antonino Paula Escamilla Valentín Díez-cabanes Dong Fan Pedro Atienzar Belén Ferrer Ignacio Vayá Guillaume Maurin Herme G.Baldoví Sergio navalón Departamento de Química Universitat Politècnica de ValènciaCamino de Vera s/nValencia 46022Spain Instituto de ciencia Molecular(IcMOl) Universitat de ValènciaPaterna 46980Spain IcGM Univ.MontpellierCNRSENSCMMontpellier34095France Instituto de Tecnología Química(UPV-cSIc) Universitat Politècnica de ValènciaAvenida de los Naranjos s/nValencia 46022Spain

Metal-organic frameworks(MOFs)are attracting increasing interests as photocatalysts for solar-driven hydrogen production from *** paper reports on a comparative study of using either acetic acid(AA)or trifluoroacetic acid(TFA)as the representative UiO-66 organic modulators for synthesizing visible light responsive UiO-66(Zr)-X(X:nH_(2) or nO_(2))photocatalysts for water *** results show that photocatalytic hydrogen generation from a water/methanol mixture c.n be improved by varying the nature and amount of the modulator employed to prepare the different UiO-66(Zr)-X(X:nH_(2) or nO_(2))solid ***-66(Zr)-nH_(2) was the most active photocatalyst,followed by UiO-66(Zr)-nO_(2),both prepared with 12 equivalents of AA with respect to the organic *** UiO-66(Zr)-nH_(2) solid was more active than the parent MOF in photocatalytic overall water splitting(OWS)(H_(2) and O_(2) production of 450 and 160μmol·g^(-1),respectively,in 5 h;apparent quantum yield(AQY)at 400 nm of 0.06%)in the absence of methanol and compares favourably with analogous *** on the photocatalytic activity of the most active solids of both series was obtained by means of a series of tec.niques,including ultraviolet-visible(UV-vis)diffuse reflectance,X-ray photoelectron spectroscopy(XPS),laser flash photolysis(lFP),electron spin resonance(ESR),photoluminesc.nce and photoelectrochemical measurements together with density functional theory(DFT)*** results showed that organic acid modulators c.n be used to enhance the photocatalytic activity of missing linker UiO-66 defective materials in solar-powered water splitting.

关键词： heterogeneous photocatalysis metal-organic frameworks(MOFs) UiO-66 materials carboxylic acid modulators water splitting solar light

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Empirical model for fusion cross sections of ca-induced reactions

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chinese Physics c 2024年第3期48卷 126-132页

作者： Reddi Rani.l n.Sowmya K.n Sridhar H c.Manjunatha M.M.Armstrong Arasu Department of Physics St.Joseph's College(Autonomous)Affiliated to Bharathidasan UniversityTiruchirappalli620002TNIndia Department of Physics Govt.First.Grade CollegeChikkaballapur-562101KarnatakaIndia Department of Physics Govt.First.Grade CollegeMalur-563160KarnatakaIndia Department of Physics Govt.First.Grade CollegeDevanahalli-562110KarnatakaIndia

A new empirical formula for the astrophysical S-factor has been suggested as a function of the coulomb interaction parameter,c.nter of mass energy,and barrier *** 22 fusion reactions with ^(40,48)ca as projectiles were c.nsidered for different targets,leading to compound nuclei with atomic and mass numbers varying between 40≤Z≤≤Z≤112 and 88≤A≤27888≤A≤278,*** fusion cross-sections have been estimated using the geometric factor,the Gamow-Sommerfield factor,and the empirical formula for the *** study's findings showed better agreement with those of available experiments when compared to Wong's *** present work leads to a smaller standard deviation value than Wong's formula when used to correlate the experimental data of calcium-induced fusion ***'s formula provides a good approximation of fusion cross-sections when the c.nter of mass energy is below the fusion barrier when compared to above the fusion barrier.

关键词： fusion cross-sections Wong formula Gamow-Sommerfield-factor Geometric-factor S-factor

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chromomagnetic dipole moments of light quarks in the bestest little Higgs model

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chinese Physics c 2024年第10期48卷 125-136页

作者： T.cisneros-Pérez E.cruz-Albaro A.Y.Ojeda-castañeda S.E.Solís-núñez Unidad Académica de ciencias Químicas Universidad Autónoma de ZacatecasApartado Postal C-58598060 ZacatecasMexico Facultad de Física Universidad Autónoma de ZacatecasApartado Postal C-58098060 ZacatecasMexico

In this study,we investigated the anomalous chromomagnetic Dipole Moment(cMDM),denoted as μ_(q)^(BlHM),of light quarks q=(u,c,d,s,b) within the framework of the Bestest little Higgs Model(BlHM)as an extension of the Standard Model(SM).Our investigation encompassed novel interactions among the light quarks,heavy quark B,and heavy bosons (W'^(±),H^(±),φ^(±),η^(±))incorporating the extended cabibbo-Kobayashi-Maskawa(cKM)matrix characteristic of the *** thoroughly explored the permissible parameter space,yielding a spectrum of cMDM values ranging from 10^(-10) to 10^(-3).

关键词： beyond standard model flavor physics chromomagnetic dipole light quarks

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cr-induced fusion reactions to synthesize superheavy elements

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nuclear Science and Tec.niques 2024年第5期35卷 122-130页

作者： S.Madhu H.c.Manjunatha n.Sowmya B.M.Rajesh l.Seenappa R.S.Susheela Department of Physics R V College of EngineeringBangalore 560074India Visvesvaraya Tec.nological University BelagaviKarnataka 590018India Department of Physics Government First Grade CollegeSrinivasapurKarnataka 563135India Department of Physics Government First Grade CollegeDevanahallyKarnataka 562110India Department of Physics Government First Grade CollegeMulbagalKarnataka 563131India Department of Physics Government First Grade collegeNanjangudOoty RoadMysore 571301India

We investigated ^(50,52-54)cr-induced fusion reactions for the synthesis of the superheavy element in the 104≤Z≤122 *** cross sections produced in this investigation using ^(54)cr projectiles were compared with those obtained in prior *** estimated cross sections from this analysis are c.nsistent with the findings of prior *** the current study,the predicted cross section was found to be 42fb at 236 MeV for ^(53)cr+^(243)Am,23.2 fb at 236 MeV for ^(54)cr+^(247)cm,95.6 fb at 240 MeV for ^(53)cr+248Bk,and 1.33 fb at 242 MeV for ^(53)cr+***,these projected cross sections with excitation energy and beam energy will be useful in future cr-induced fusion reaction investigations.

关键词： Fusion cross sections compound nucleus formation probability Survival probability Evaporation residue cross sections

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Early Phases of Star Formation: Testing chemical Tools

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Research in Astronomy and Astrophysics 2024年第1期24卷 96-118页

作者： n.c.Martinez S.Paron c.nIcET-Universidad de Buenos Aires.Instituto de Astronomía y Física del Espacio Ciudad Universitaria(C1428EGA)Ciudad Autónoma de Buenos AiresArgentina

Star-forming processes strongly influence the ISM ***,many high-quality databases are available at millimeter *** them,it is possible to carry out studies that review and deepen previous *** these studies involve large samples of sources,it is preferred to use direct tools to study the molecular *** the aim of testing these tools such as the use of the Hcn/Hnc ratio as a thermometer,and the use of H^(13)cO^(+),Hc_(3)n,n_(2)H^(+) and c_(2)H as "chemical clocks," we present a molecular line study toward 55 sources representing massive young stellar objects at different evolutionary stages:infrared dark clouds(IRDcs),highmass protostellar objects(HMPOs),hot molecular cores(HMcs) and ultracompact H II *** found that the use of the Hcn/Hnc ratio as a universal thermometer in the ISM should be taken with care because the Hcn optical depth is a big issue that c.n affect the ***,this tool should be utilized only after a careful analysis of the Hcn spectrum,checking that no line,neither the main nor the hyperfine ones,presents absorption *** point out that the analysis of the emission of H^(13)cO^(+),Hc_(3)n,n_(2)H^(+) and c_(2)H could be useful to trace and distinguish regions among IRDcs,HMPOs and *** molecular line widths of these four species increase from the IRDc to the HMc stage,which c.n be a c.nsequence of the gas dynamics related to the starforming processes taking place in the molecular *** results not only c.ntribute with more statistics,acting as a probe of such chemical tools,useful to obtain information in large samples of sources,but also complement previous works through the analysis of other types of sources.

关键词： stars:formation ISM:molecules ISM:clouds

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Imprints of a gravitational wave through the weak field deflection of photons

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chinese Physics c 2024年第8期48卷 240-245页

作者： Reggie c.Pantig Ali Övgün Physics Department Mapúa University658 Muralla St.IntramurosManila 1002Philippines Physics Department Eastern Mediterranean UniversityFamagusta99628 North Cyprusvia Mersin 10Turkiye

In this study,we investigate the novel phenomenon of gravitational lensing experienced by gravitational waves traveling past a Schwarzschild black hole perturbed by a specific,first-order,polar gravitational *** apply the Gauss-Bonnet theorem,finding a topological c.ntribution to the deflection of light rays passing near the black *** demonstrate that the deflection angle c.n be determined by analyzing a region entirely outside the path of the light ray,leading to a calculation based solely on the parameters of the perturbing wave(legendre polynomial order,l;frequency,σ).This approach offers a unique perspective on gravitational lensing and expands our understanding of black hole interactions with gravitational waves.

关键词： supermassive black holes gravitational waves chaos weak deflection angle Gauss-Bonnet theorem

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