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Electrochemical process of titanium extraction

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中国有色金属学会会刊：英文版 2007年第2期17卷 429-433页

作者： cH. RVs. NAGEsH c. s. ramachandran Defence Metallurgical Research Laboratory HyderabadA.P. India-500058

A wide variety of processes are being pursued by researchers for cost effective extraction of titanium metal. Electrochemical processes are promising due to simplicity and being less capital intensive. some of the promising electrochemical processes of titanium extraction were reviewed and the results of laboratory scale experiments on electrochemical reduction of TiO2 granules were brought out. some of the kinetic parameters of the reduction process were discussed while presenting the quality improvements achieved in the experimentation.

关键词：钛萃取电化学还原过程动力学参数

Feasibility of surface-coated friction stir welding tools to join AIsI 304grade austenitic stainless steel

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Defence Technology（防务技术） 2014年第4期10卷 360-370页

作者： A.K.LAKsHMINARAYANAN c.s.ramachandran V.BALAsUBRAMANIAN Department of Mechanical Engineering SSN College of Engineering Kalavakkam 603 110 Chennai Tamil Nadu India centre for Materials Joining & Research (cEMAJOR) Department of Manufacturing Engineering Annamalai University Annamalai Nagar608 002Tamil Nadu India

An attempt is made to develop the tools that are capable enough to withstand the shear, impact and thermal forces that occur during friction stir welding of stainless steels. The atmospheric plasma spray and plasma transferred arc hardfacing processes are employed to deposit refractory ceramic based composite coatings on the Inconel 738 alloy. Five different combinations of self-fluxing alloy powder and 60% ceramic reinforcement particulate mixtures are used for coating. The best friction stir welding tool selected based on tool wear analysis is used to fabricate the austenitic stainless steel joints.

关键词：摩擦搅拌焊接 304不锈钢奥氏体不锈钢焊接工具 AIsI 表面涂层大气等离子喷涂自熔性合金粉末

Efficiency-Driven custom chatbot Development: Unleashing Langchain, RAG, and Performance-Optimized LLM Fusion

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computers, Materials & continua 2024年第8期80卷 2423-2442页

作者： s.Vidivelli Manikandan ramachandran A.Dharunbalaji school of computing SASTRA Deemed UniversityThanjavurTamilnadu613401India

This exploration acquaints a momentous methodology with custom chatbot improvement that focuses on pro-ficiency close by *** accomplish this by joining three key innovations:Langchain,Retrieval Augmented Generation(RAG),and enormous language models(LLMs)tweaked with execution proficient strategies like LoRA and *** takes into consideration fastidious fitting of chatbots to explicit purposes,guaranteeing engaged and important collaborations with ***’s web scratching capacities engage these chatbots to get to a tremendous store of data,empowering them to give exhaustive and enlightening reactions to *** recovered data is then decisively woven into reaction age utilizing LLMs that have been calibrated with an emphasis on execution *** combination approach offers a triple advantage:further developed viability,upgraded client experience,and extended admittance to *** become proficient at taking care of client questions precisely and productively,while instructive and logically pertinent reactions make a more regular and drawing in cooperation for *** last,web scratching enables chatbots to address a more extensive assortment of requests by conceding them admittance to a more extensive information *** digging into the complexities of execution proficient LLM calibrating and underlining the basic job of web-scratched information,this examination offers a critical commitment to propelling custom chatbot plan and *** subsequent chatbots feature the monstrous capability of these advancements in making enlightening,easy to understand,and effective conversational specialists,eventually changing the manner in which clients cooperate with chatbots.

关键词： Langchain retrieval augumental generation(RAG) fine tuning

Geochemistry and depositional environment of fuchsite quartzites from sargur Group,western Dharwar craton,India

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Acta Geochimica 2024年第3期43卷 555-570页

作者： c.s.sindhuja G.Harshitha c.Manikyamba K.s.V.subramanyam csIR(council of scientific and Industrial Research)-National Geophysical Research Institute(NGRI) Uppal RoadHyderabad 500007India

Meso-Neoarchean fuchsite quartzites are present in different stratigraphic positions of Dharwar craton including the oldest(~3.3 Ga)sargur Group of western Dharwar *** present study deals with the petro-graphic and geochemical characteristics of the fuchsite quartzites from the Ghattihosahalli belt to evaluate their genesis,depositional setting and the enigma involved in the ancient sedimentation *** major mineral assemblages include quartz,fuchsite,and feldspars along with accessory kyanite and *** geochemical com-positions are characterized by high siO_(2),Al_(2)O_(3),low MgO,caO,strongly enriched cr(1326–6899 ppm),Ba(1165–3653 ppm),sr(46–210 ppm),V(107–868 ppm)and Zn(11–158 ppm)contents compared to the upper continental crust(Ucc).The Ucc normalized rare earth element(REE)patterns are characterized by depleted light REE[(La/sm)Ucc=0.33–0.95]compared to heavy REE[(Gd/Yb)_(Ucc)=0.42–1.65]with conspicuous positive Eu-anomalies(Eu/Eu^(*)=1.35–18.27)characteristic of hydrothermal solutions evidenced through the interlayered *** overall major and trace element systematics reflect a combined mafic-felsic provenance and suggest their deposition at a passive continental margin *** comprehensivefield,petrographic,and geo-chemical studies indicate that these quartzites are infiltrated by cr-richfluids released during high-grade metamorphism of associated ultramafic *** sargur and the subse-quent Dharwar orogeny amalgamated diverse lithounits from different tectonic settings,possibly leading to the release of cr-richfluids and the formation of fuchsite quartzite during or after the *** sug-gest a pre-existing stable crust prior to the sargur Group and the link between orogenic events and various mineral deposits in the Dharwar craton.

关键词： Dharwar craton Ghattihosahalli Fuchsite quartzite Provenance Depositional setting

Early Phases of star Formation: Testing chemical Tools

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Research in Astronomy and Astrophysics 2024年第1期24卷 96-118页

作者： N.c.Martinez s.Paron cONIcET-Universidad de Buenos Aires.Instituto de Astronomía y Física del Espacio Ciudad Universitaria(C1428EGA)Ciudad Autónoma de Buenos AiresArgentina

star-forming processes strongly influence the IsM ***,many high-quality databases are available at millimeter *** them,it is possible to carry out studies that review and deepen previous *** these studies involve large samples of sources,it is preferred to use direct tools to study the molecular *** the aim of testing these tools such as the use of the HcN/HNc ratio as a thermometer,and the use of H^(13)cO^(+),Hc_(3)N,N_(2)H^(+) and c_(2)H as "chemical clocks," we present a molecular line study toward 55 sources representing massive young stellar objects at different evolutionary stages:infrared dark clouds(IRDcs),highmass protostellar objects(HMPOs),hot molecular cores(HMcs) and ultracompact H II *** found that the use of the HcN/HNc ratio as a universal thermometer in the IsM should be taken with care because the HcN optical depth is a big issue that can affect the ***,this tool should be utilized only after a careful analysis of the HcN spectrum,checking that no line,neither the main nor the hyperfine ones,presents absorption *** point out that the analysis of the emission of H^(13)cO^(+),Hc_(3)N,N_(2)H^(+) and c_(2)H could be useful to trace and distinguish regions among IRDcs,HMPOs and *** molecular line widths of these four species increase from the IRDc to the HMc stage,which can be a consequence of the gas dynamics related to the starforming processes taking place in the molecular *** results not only contribute with more statistics,acting as a probe of such chemical tools,useful to obtain information in large samples of sources,but also complement previous works through the analysis of other types of sources.

关键词： stars:formation IsM:molecules IsM:clouds

Local MFs Matrix Decomposition Algorithms for Elliptic BVPs in Annuli

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Numerical Mathematics(Theory,Methods and Applications) 2024年第1期17卷 93-120页

作者： c.s.chen Andreas Karageorghis Min Lei school of Mathematics and Natural sciences University of Southern MississippiHattiesburgMS 39406USA Department of Mathematics and statistics University of CyprusP.O.Box 20537Nicosia 1678Cyprus college of Mathematics Taiyuan University of TechnologyTaiyuan 030024P.R.China

We apply the local method of fundamental solutions(LMFs)to boundary value problems(BVPs)for the Laplace and homogeneous biharmonic equations in *** appropriately choosing the collocation points,the LMFs discretization yields sparse block circulant system *** a result,matrix decomposition algorithms(MDAs)and fast Fourier transforms(FFTs)can be used for the solution of the systems resulting in considerable savings in both computational time and storage *** accuracy of the method and its ability to solve large scale problems are demonstrated by applying it to several numerical experiments.

关键词： Local method of fundamental solutions Poisson equation biharmonic equation matrix decomposition algorithms fast Fourier transforms

Mathematical modeling and simulations of stress mitigation by coating polycrystalline particles in lithium-ion batteries

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Applied Mathematics and Mechanics(English Edition) 2024年第6期45卷 947-962页

作者： N.IQBAL J.cHOI s.F.sHAH c.LEE s.LEE Department of Mechanical Roboticsand Energy EngineeringDongguk University-SeoulSeoul 04620Republic of Korea

A chemo-mechanical model is developed to investigate the effects on the stress development of the coating of polycrystalline Ni-rich LiNixMnyco_(z)O_(2)(x≥0.8)(NMc)particles with poly(3,4-ethylenedioxythiophene)(PEDOT).The simulation results show that the coating of primary NMc particles significantly reduces the stress generation by efficiently accommodating the volume change associated with the lithium diffusion,and the coating layer plays roles both as a cushion against the volume change and a channel for the lithium transport,promoting the lithium distribution across the secondary particles more ***,the lower stiffness,higher ionic conductivity,and larger thickness of the coating layer improve the stress *** paper provides a mathematical framework for calculating the chemo-mechanical responses of anisotropic electrode materials and fundamental insights into how the coating of NMc active particles mitigates stress levels.

关键词： lithium-ion battery(LIB) polycrystalline particle coating finite element simulation Ni-rich LiNixMnyco_(z)O_(2)(x>0.8)(NMc)

structural insights on anti-biofilm mechanism of heated slightly acidic electrolyzed water technology against multi-resistant staphylococcus aureus biofilm on food contact surface

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Food science and Human Wellness 2024年第3期13卷 1556-1566页

作者： Pianpian Yan ramachandran chelliah Kyoung Hee Jo Xiuqin chen Akanksha Tyagi Hyeon Yeong Jo Fazle Elahi Nam chan Woo Min seung Wook Deog Hwan Oh Department of Food science and Biotechnology College of Agriculture and Life SciencesKangwon National UniversityChuncheon 24341South Korea Kangwon Institute ofInclusive Technology(KIIT) Kangwon National UniversityChuncheon 24341South Korea saveetha school of Engineering (SIMATS)UniversitySriperumbudur 600124India seoulin Bioscience company Seongnam-si 13488South Korea

slightly acidic electrolyzed water(sAEW)has proven to be an efficient and novel sanitizer in food and agriculture *** study assessed the efficacy of sAEW(30 mg/L)at 40℃on the inactivation of foodbome pathogens and detachment of multi-resistant staphylococcus aureus(MRsA)*** underlying mechanism of MRs A biofilm under heated sAEW at 40℃treatment on metabolic profiles was *** results showed that the heated sAEW at 40℃significantly effectively against foodbome pathogens of 1.96-7.56(lg(cFU/g))reduction in pork,chicken,spinach,and *** heated sAEW at 40℃treatment significantly reduced MRs A biofilm cells by 2.41(lg(cFU/cm^(2))).The synergistic effect of sAEW treatment showed intense anti-biofilm activity in decreasing cell density and impairing biofilm cell *** metabolic response of MRsA biofilms,treated by sAEW at 40℃,revealed the alterations of intracellular metabolites,including amino acids,organic acid,fatty acid,and ***,signaling pathways involved in amino acid metabolism,energy metabolism,nucleotide synthesis,carbohydrate metabolites,and lipid biosynthesis were functionally disrupted by the sAEW at 40℃*** per our knowledge,this is the first research to uncover the potential mechanism of heated sAEW treatment against MRsA biofilm on food contact surface.

关键词： Multi-resistant staphylococcus aureus Metabolic profile sAEW Biofilm Hurdle technology Electrode material

A global analysis of the introduction pathways and characteristics associated with non-native fish species introduction, establishment, and impacts

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Ecological Processes 2024年第2期13卷 16-31页

作者： camille Bernery céline Bellard Franck courchamp sébastien Brosse Boris Leroy cNRs Agro Paris Tech Ecologie Systématique Evolution Université Paris-Saclay Unité Biologie des Organismes et Ecosystèmes Aquatiques (BOREA UMR 8067) Muséum National d’Histoire Naturelle Sorbonne Universités Université de Caen Normandie Université des Antilles CNRS IRD Laboratoire évolution & Diversité Biologique (EDB UMR5174) Université Paul Sabatier-Toulouse 3 CNRS IRD UPS

Background The invasion success of introduced freshwater fishes is influenced by many factors, including ecological, species, and socioeconomic characteristics. Most studies that document the importance of these characteristics are conducted at local scales and/or focus on a single step of the invasion process. In this study, we aim to determine the species characteristics, ecological characteristics, and socioeconomic characteristics of non-native freshwater fish invasions. Our assessment was done at the global scale and considers all three steps of the invasion(i.e., introduction, establishment, and impact). For this purpose, we applied generalized linear models to 20 variables collected for 307 non-native species and modeled them as a function of ecological characteristics(i.e., environmental features), species traits(i.e., functional and morphological), and socioeconomic characteristics(i.e., human use and introduction pathways). We considered the number of countries in which each species was introduced, established, or had ecological impacts as a proxy of invasion step success. We also explored the specifics of species introduced through the aquaculture and the ornamental fish trade *** We found that non-native freshwater fishes with broad diets, high parental care, and multiple introduction pathways are the most widely introduced and established worldwide. The number of countries with impacts reported was best explained by the type of introduction pathway(i.e., aquaculture or fisheries). Moreover, among non-native species introduced through aquaculture, those belonging to cypriniformes and having broad diets were the most widely introduced and established species. In contrast, the species introduced through the ornamental fish trade pathway belonged to various taxonomic orders but were mainly native to tropical *** considering several types of factors is important when analyzing the invasion success of freshwater fish and disentang

关键词： Aquaculture Ecology Exotic Freshwater fish Introduction pathway Invasion step Morphology Ornamental fish trade socioeconomic Trait