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Membrane-less moo_(3-x)@TiO_(2)-bromine battery with excellent rate capability and cyclic stability

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Journal of Energy Chemistry 2024年第6期93卷 316-321,I0008页

作者： Wenjie Huang Hui Wang Bin Yuan Liuzhang Ouyang Lichun Yang min Zhu School of Materials Science and Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage MaterialsSouth China University of TechnologyGuangzhou 510640GuangdongChina

Bromine has attracted significant attention as a cathode material for aqueous batteries due to its high reduction potential of 1.05 V(Br_(3)^(-)+2e~-■3Br~-),impressive theoretical specific capacity of 223 mA h g^(-1),and rapid reaction kinetics in the ***,searching for compatible anode materials to match with bromine has posed a challenge due to its highly corrosive *** this study,we developed oxygen-deficient moo_(3) with TiO_(2) coating(referred to as moo_(3-x)@TiO_(2))as an anode material to pair with a bromine cathode in static full *** oxygen deficiency contributes to enhanced electronic and protonic diffusion within the moo_(3-x)lattice,while the TiO_(2) coating mitigates structural dissolution and proton trapping during *** moo_(3-x)@TiO_(2) demonstrates fast charge storage kinetics and excellent resistance to bromine *** impressive compatibility between moo_(3-x)@TiO_(2) and bromine enables the construction of membrane-less full batteries with exceptional rate capability and cyclic *** moo_(3-x)@TiO_(2)-bromine battery achieves an energy density of70.8 W h kg^(-1)at a power density of 328.1 W kg^(-1),showcasing an impressive long-term cyclic life of 20,000 *** study provides valuable insights for the development of high-performance aqueous secondary batteries.

关键词： Molybdenum trioxide Oxygen deficiency TiO_(2)coating Compatibility Bromine-based battery

A highly reduced Mo_(74) polyoxometalate featuring high proton conductivity accessed by building block strategy

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Science China Chemistry 2024年第3期67卷 862-868页

作者： Shi-Yi Liu Xue-Xin Li Wei-Chao Chen Kui-Zhan Shao Xin-Long Wang Chao Qin Zhong-min Su Key Laboratory of Polyoxometalate and Reticular Material Chemistry of ministry of Education Department of ChemistryNortheast Normal UniversityChangchun 130024China State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical ChemistryCollege of ChemistryJilin UniversityChangchun 130021China

Highly reduced polyoxometalates(POMs) are predicted to be used as rather high energy density materials;however,it still suffers from the limited cluster species and reduction *** we demonstrate that it is possible to employ the building block strategy to generate a highly reduced polyoxomolybdate(C_(2)H_(8)N)_(14)(NH_(4))_(4)H_(14)[Mo_(48)-ⅤMo_(26)ⅥO_(202)(OH)_(12)(SO_(4))_(6)]·46H_(2)O(Mo_(74)).The fundamental Mo-based{Mo_x}(x=4,5,and 6) building blocks,which are templated by tetra-coordinated anions{moo_(4)}or{SO_(4)},not only lay foundation for the formation of Mo_(74) featuring an unprecedented reduction ratio of 65%,but also give rise to SBBs-mediated(secondary building blocks) supramolecular dense packing interactions among the isolated Mo_(74) clusters that are favorable for proton ***,high proton conductivity(2.04×10^(-2)S cm^(-1)) had been realized at 50℃ and 90% relative humidity,revealing one of the well-known POMs-based crystalline proton conducting *** result highlights that this building block approach possesses great potential in producing highly reduced POM systems that can achieve controllable reduced ratio and desirable properties.

关键词： polyoxometalate building block molybdenum highly reduced state proton conduction

Boosting ammonia production in electrocatalytic NO_(x)reduction on a robust Fe/Femoo_(4)catalyst

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Nano Research 2024年第7期17卷 5801-5806页

作者： Dong-Xue Liu Xin Deng Yong-Fu Zhu Zhe Meng Xue-Feng Sun Miao-Miao Shi Hai-Xia Zhong Jun-min Yan Key Laboratory of Automobile Materials Ministry of EducationSchool of Materials Science and EngineeringJilin UniversityChangchun 130022China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China

Electrocatalytic reduction of nitrate(NO_(3)^(−))and nitride(NO_(2)^(−))to ammonia(NH3)is of wide interest as a promising alternative to the energy-intensive Haber-Bosch route for mitigating the vast energy consumption and the accompanied carbon dioxide emission,as well as benefiting for the relevant sewage ***,exploring an efficient and low-cost catalyst with high atomic utilization that can effectively facilitate the slow multi-electron transfer process remains a grand ***,we present an efficient hydrogenation of NO_(3)^(−)/NO_(2)^(−)species to NH3 in both alkaline and neutral environments over the Fe_(2)(moo_(4))_(3)derived hybrid electrocatalyst with the metallic Fe site on Femoo_(4)(Fe/Femoo_(4)).The Mo ingredient can play a synergistically positive role in further promoting the NH3 production on *** a result,Fe/Femoo_(4)behaves well in the electrochemical NH3 generation from NO_(2)^(−)with a maximum NH3 Faradaic efficiency(FE)of 96.53%and 87.68%in alkaline and neutral electrolyte,corresponding to the NH3 yield rate of 640.68 and 302.56 mg·h^(−1)·mgcat.^(−1),respectively,which outperforms the Fe and Mo counterpart and other similar catalyst,showing the robust catalytic capacity of each active site.

关键词： ammonia synthesis NO_(x)reduction synergistic effect alkaline/neutral electrolyte

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冠心生脉丸质量标准提升

中成药 2024年第3期46卷 724-729页

作者：刘静玉金武燮谷丽华吴立宏王峥涛上海中医药大学中药研究所中药标准化教育部重点实验室国家中医药管理局中药新资源与质量评价重点实验室上海201203 上海中药标准化中心上海201203

目的提升冠心生脉丸质量标准。方法TLC法定性鉴别人参和三七,分析采用硅胶G薄层板,以三氯甲烷-甲醇-水(13∶7∶2)10℃以下放置的下层溶液为展开剂,10%硫酸乙醇溶液为显色剂。HPLC法测定人参皂苷Rg1、人参皂苷Re、人参皂苷Rb1、人参皂苷R... 详细信息

目的提升冠心生脉丸质量标准。方法TLC法定性鉴别人参和三七,分析采用硅胶G薄层板,以三氯甲烷-甲醇-水(13∶7∶2)10℃以下放置的下层溶液为展开剂,10%硫酸乙醇溶液为显色剂。HPLC法测定人参皂苷Rg1、人参皂苷Re、人参皂苷Rb1、人参皂苷Rd的含量,分析采用Thermo Accucore-C18色谱柱(4.6 mm×150 mm,2.6μm);流动相乙腈-水,梯度洗脱;体积流量0.8 mL/min;柱温20℃;检测波长203 nm。结果TLC斑点清晰,阴性无干扰。4种成分在各自范围内线性关系良好(R^(2)≥0.9999),平均加样回收率91.21%~106.86%,RSD 0.68%~1.43%。结论该方法专属性、重复性良好,可为冠心生脉丸质量控制提供参考。

关键词：冠心生脉丸人参三七人参皂苷定性鉴别含量测定 TLC HPLC

Calcium and Calmodulin-Mediated Regulation of Gene Expression in Plants

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Molecular Plant 2009年第1期2卷 13-21页

作者： min Chul Kim Woo Sik Chung Dae-Jin Yun moo Je Cho Division of Applied Life Science (BK21 Program) Plant Molecular Biology and Biotechnology Research Center and Environmental Biotechnology National Core Research Center Gyeongsang National University Jinju 660-701 Korea

Sessile plants have developed a very delicate system to sense diverse kinds of endogenous developmental cues and exogenous environmental stimuli by using a simple Ca^2＋ ion. Calmodulin （CAM） is the predominant Ca^2＋ sensor and plays a crucial role in decoding the Ca^2＋ signatures into proper cellular responses in various cellular compartments in eukaryotes. A growing body of evidence points to the importance of Ca^2＋ and CaM in the regulation of the transcriptional process during plant responses to endogenous and exogenous stimuli. Here, we review recent progress in the identification of transcriptional regulators modulated by Ca^2＋ and CaM and in the assessment of their functional significance during plant signal transduction in response to biotic and abiotic stresses and developmental cues.

关键词： Abiotic/environmental stress calcium signaling/transport gene expression.

Effect of parallel resonance on the electron energy distribution function in a 60 MHz capacitively coupled plasma

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Plasma Science and Technology 2023年第4期25卷 69-78页

作者： You HE Yeong-min LIM Jun-Ho LEE Ju-Ho KIM moo-Young LEE Chin-Wook CHUNG Department of Electrical Engineering Hanyang University17 Haengdang-dongSeongdong-guSeoul 133-791Republic of Korea Department of Nanoscale Semiconductor Engineering Hanyang University17 Haengdang-dongSeongdong-guSeoul 133-791Republic of Korea

In general,as the radio frequency(RF)power increases in a capacitively coupled plasma(CCP),the power transfer efficiency decreases because the resistance of the CCP *** this work,a parallel resonance circuit is applied to improve the power transfer efficiency at high RF power,and the effect of the parallel resonance on the electron energy distribution function(EEDF)is investigated in a 60 MHz *** CCP consists of a power feed line,the electrodes,and *** reactance of the CCP is positive at 60 MHz and acts like an inductive load.A vacuum variable capacitor(VVC)is connected in parallel with the inductive load,and then the parallel resonance between the VVC and the inductive load can be *** the capacitance of the VVC approaches the parallel resonance condition,the equivalent resistance of the parallel circuit is considerably larger than that without the VVC,and the current flowing through the matching network is greatly ***,the power transfer efficiency of the discharge is improved from 76%,70%,and 68%to 81%,77%,and 76%at RF powers of 100 W,150 W,and 200 W,*** parallel resonance conditions,the electron heating in bulk plasma is enhanced,which cannot be achieved without the VVC even at the higher RF *** enhancement of electron heating results in the evolution of the shape of the EEDF from a biMaxwellian distribution to a distribution with the smaller temperature difference between high-energy electrons and low-energy *** to the parallel resonance effect,the electron density increases by approximately 4%,18%,and 21%at RF powers of 100 W,150 W,and 200 W,respectively.

关键词： capacitively coupled plasma parallel resonance electron energy distribution function

Cs_(2)AgBi_(0.75)Sb_(0.25)Br_(6)钙钛矿太阳能电池的优化设计

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物理学报 2024年第2期73卷 317-326页

作者：王月荣田汉民张登琪刘维龙马旭蕾河北工业大学电子信息工程学院天津300401 天津电子材料与器件实验室天津300401

双钙钛矿太阳能电池以其低成本、高性能、环境友好、稳定性强而备受关注.本研究使用Silvaco TCAD分析了Cs_(2)AgBi_(0.75)Sb_(0.25)Br_(6)太阳能电池的钙钛矿层厚度、能带偏移、金属电极功函数、传输层厚度及掺杂浓度与器件效率的关系,... 详细信息

双钙钛矿太阳能电池以其低成本、高性能、环境友好、稳定性强而备受关注.本研究使用Silvaco TCAD分析了Cs_(2)AgBi_(0.75)Sb_(0.25)Br_(6)太阳能电池的钙钛矿层厚度、能带偏移、金属电极功函数、传输层厚度及掺杂浓度与器件效率的关系,以提升器件性能.基于空穴传输层为Spiro-OMeTAD,电子传输层为ZnO的器件进行初始研究,其显示出12.66%的光电转换效率.结果表明,当钙钛矿层厚度大于500 nm时,效率趋于饱和.最佳导带偏移量为0—+0.5 eV,最佳价带偏移量为-0.1—+0.2 eV.在改变器件的电子传输层为ZnOS,空穴传输层分别为moo_(3),Cu_(2)O和CuSCN的情况下,优化其厚度和掺杂浓度,最终空穴传输层为Cu_(2)O的双钙钛矿太阳能电池理论光电转换效率达22.85%,比目前报道的理论效率值相对提升了25.6%.此外,当金属电极功函数小于-4.9 eV时易实现最佳效率.本工作为开发高性能无铅钙钛矿太阳能电池提供了理论指导.

关键词：双钙钛矿太阳能电池光电转换效率能带偏移电极功函数

基于水热合成法制备的moo_(3-x)纳米槽SERS基底的特性研究

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人工晶体学报 2024年第6期53卷 1061-1068页

作者：舒敏梁俊辉陈达陈招秦来顺中国计量大学材料与化学学院杭州300018 温州赵氟隆有限公司温州325016

表面增强拉曼散射(SERS)技术可以快速检测微量分子,在医药材料分析、有害物残留、食品安全等领域受到广泛关注。而SERS对被检测物质的响应极限则取决于基底性能,并直接影响最终检测效果。本文着眼于增加基底的比表面积及其与被检测物之... 详细信息

表面增强拉曼散射(SERS)技术可以快速检测微量分子,在医药材料分析、有害物残留、食品安全等领域受到广泛关注。而SERS对被检测物质的响应极限则取决于基底性能,并直接影响最终检测效果。本文着眼于增加基底的比表面积及其与被检测物之间的光诱导电荷转移能力,通过简单的水热合成法成功制备出具有氧空位缺陷的moo_(3-x)纳米槽。结合X射线光电子能谱(XPS)、紫外-可见光谱(UV-Vis)、傅里叶变换红外光谱(FT-IR)等手段,对moo_(3-x)纳米槽的电子结构、光学性质和表面化学环境进行了分析。使用moo_(3-x)纳米槽作为SERS基底,对罗丹明6G(R6G)、结晶紫(CV)和玫瑰红B(RhB)三种有机染料分子进行了检测,实验结果显示,其对R6G的检测极限可以达到10^(-10)mol/L,与同类型的半导体基底相比,它具有更好的拉曼增强活性。

关键词： moo_(3-x)纳米槽表面增强拉曼散射微量分子检测氧空位缺陷光诱导电荷转移 R6G

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The effectiveness and safety of acupuncture for poor semen quality in infertile males： a systematic review and meta-analysis

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Asian Journal of Andrology 2014年第6期16卷 884-891页

作者： Ui min Jerng Jun-Young Jo Seunghoon Lee Jin-moo Lee Ohmin Kwon Class of Oncology Class of Gynecology Department of Clinical Korean Medicine Kyung Hee University Graduate School Seoul Korea Conmaul Hospital Seoul Korea Class of Acupuncture and Moxibustion Department of Clinical Korean Medicine Kyung Hee University Graduate School Seoul Korea Medical History and Literature Group Korea Institute of Oriental Medicine Daejeon Korea

The aim of this review is to evaluate the effectiveness and safety of acupuncture for poor semen quality in infertile men. We searched for relevant trials registered up to May 2013 in 14 databases. We selected randomized controlled trials （RCTs） that compared acupuncture, with or without additional treatment, against placebo, sham, no treatment, or the same additional treatment. Two reviewers independently performed the study selection, data extraction, risk of bias and reporting quality appraisal. Risk of bias and reporting quality were appraised by the Cochrane risk of bias tool, the consolidated standards of reporting trials and Standards for Reporting Interventions in Clinical Trials of Acupuncture. The outcomes were sperm motility, sperm concentration, pregnancy rate, and adverse events. Pregnancy was defined as a positive pregnancy test. Four RCTs met the eligibility criteria. Acupuncture increased the percentage of sperm with rapid progression （mean difference - 6.35, 95% confidence interval （CI）. 4.38-8.32, P〈 0.00001） and sperm concentration （mean difference - 6.42, 95% CI. 4.91-7.92, P〈 0.00001）, but these two outcomes were substantially heterogeneous among the studies （F = 72% and 58%, respectively）. No differences in pregnancy rate were found between acupuncture and control groups （odds ratio 1.60, 95% CI. 0.70-3.69, P= 0.27, F = 0%）. No participants experienced adverse events. The current evidence showing that acupuncture might improve poor semen quality is insufficient because of the small number of studies, inadequacy of procedures and/or insufficient information for semen analysis, high levels of heterogeneity, high risk of bias, and poor quality of reporting. Further large, well-designed RCTs are required.

关键词： acupuncture asthenozoospermia male infertility oligozoospermia sperm quality